𝐵𝐴𝐿𝐴𝑁𝐶𝐸𝐷 EQUATION: 𝑁 ≡ 𝑁 + 2(𝑁 − 𝐻) → 𝑁𝐻₂ − 𝑁𝐻₂ +H₂

71)Energy needed to break bonds in reactants = ∑ E(Reactants)

= 𝛥𝐻(𝑁 ≡ 𝑁) + 2𝛥𝐻(𝑁 − 𝐻)
= 945KJ + 391KJ
= 1336KJ
72) Energy needed for product formation = ∑ E(Products)

= ∆H(N-N)+4∆H(N-H)+ ∆H(H-H)
= 2158KJ
73) ∆Hf= 2158-1336=+822KJ ; Endothermic reaction ANS
[𝑠𝑎𝑙𝑡]
74)Generally 𝑝𝐻 = 𝑝𝐾𝑎 + log
[𝑎𝑐𝑖𝑑]

Hence comparing our answer to the alternatives ,we can take

𝑝𝐻 = 3.8 + log 2.5; ANS C
75)
ELEMENT Zn C O
MASS 1.3 0.24 0.96
1.3 0.24 0.96
MOLE
65 12 16
0.02 0.02 0.06
RATIO
0.02 0.02 0.02

RESULT 1 1 3
E.F = ZnCO3
 3𝐶 + 4𝐻₂ → 𝐶₃𝐻₈
5𝑂2 5𝑂2

3𝐶𝑂₂ + 4𝐻₂𝑂

𝛥𝐻1 = 3 ∆𝐻𝑐0 [𝐶] + 4∆𝐻𝑐0[H2]

= 3(-393KJ )+4(-286KJ )
= -2323KJ
𝛥𝐻2 =∆𝐻𝑐0[C₃H₈] = -2220KJ
𝛥𝐻𝑓 = 𝛥𝐻1 − 𝛥𝐻2
= -103KJ

FOR H: 2a +b=2c+2e
FOR S: a=c
FOR O: 4a= e
FOR I : b=2d
For a=1, we have e=4,c=1,b=8,d=4 ANS B
80)
H
C1=C2=O HYBRIDISATION
H C1 :SP2 C2 :SP3

81) ANS C( NOTES)

82) Carbonyl compounds give a strong signal at 1710cm-1 to 1740cm-1 in an IR
spectrum, which is closer to 1700. ANS C
83)

3 absoption bands

84)ANS C
85)1S22S22P6 3S23P5
GROUP7, PERIOD 3
ANS B