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92
T. M. Guidish et al 93
WELL
depth of water at each time of deposition. This is the back-
SECTCNl
stripping process.
However, in order to calculate burial history and geohis-
— ml —
tory and construct plots in which compaction is modeled,
it is necessary to model the changes in rock porosity with
— g — depth. This modeling is illustrated by considering the rate
of sediment accumulation (R) with respect to time given by
— f _
van Hinte (1978):
— e —
R = Tp(l-</.)/A(l-.>o). (1)
— d —
where T^ is the thickness at present porosity (0), A is the
time duration, and ^o is porosity at time of deposition.
Thus, in order to model layer thickness as a function of
time, it is necessary to model the change in porosity as a
function of time or, equivalently, as a function of depth.
Van Hinte (1978) has illustrated how to do this for present
porosities taken from well data and from arbitrarily cho-
sen initial porosities. In the absence of porosity data from
wells, phenomenological models can be used to relate
— TD —
porosity to depth or load for various lithologies. One such
model proposed by Sclater and Christie (1980) supposes
•1500—J an exponential decrease in porosity with depth. The pre-
factor and exponential decay constant depend on the
Figure 1—Geohistory diagram for a hypothetical weU. Upper
curve shows water-depth history for location; lower curves show lithology of the rock in question. Even though actual val-
subsidence and uplift at that location. Times TD through c repre- ues of porosity are variable and depend on compositional
sent era of tectonic subsidence; c through g represent era of uplift variations of lithology, effects of overpressure or under-
(after van Hinte, 1978). compaction, and/or diagenesis, they generally decrease
..JBWMa.
Hi
...SBJlMa
ih
...SaQ.Ma
ir
JJ.5.g_Ma
176.1 Ma
r o \
W^-
rli] 'li^-'-n.
AGE [MILLION YEARSI AGE [MILLION YEARSI
Figure 2—Machine-generated burial history plot of Norway well. R„ = 0.5 and R„ = 0.7 curves represent Waples' thresholds for
onset and maximum generation of oil, respectively. Rates of sediment accumulation, subsidence, and basement subsidence as a func-
tion of age are also shown.
94 Basin Evaluation Using Burial History Calculations
time • time •
time •
sediment
depth
sediment sediment
depth depth
U N C O N F O R M I T V T R E A T E D AS U N C O N F O R M I T Y T R E A T E D AS MASS
EQUAL TIME OF D E P O S I T I O N D E P O S I T E D AT PR E - U N C O N F O R M I T Y
UNCONFORMITY TREATED AND EQUAL TIME OF E R O S I O N RATE F O L L O W E D BY EQUAL M A S S
AS NO D E P O S I T I O N . NO E R O S I O N . AT SOME FIXED RATE E R O D E D AT P O S T - U N C O N F O R M I T Y
T A K E N TO BE RATE RATE_
PRIOR TO U N C O N F O R M I T V
Figure 3—Geohistory diagram for hypothetical well with unconformities handled in different ways.
with depth. Sclater and Christie's (1980) model approxi- h, = f [l-0(z)] dz, (5)
mates this overall depth behavior in porosity. Based on the
data of Athy (1930) and Hedberg (1936) for normal pres- that is.
sures, the porosity ((^) can be represented by:
h^ = (Z2 - Zi) - (0o/c) ( e" ^1 -e-"2 ). (6)
0 = 0„e-' (2)
Hence, knowing that a rock layer was on the surface at a
where <^<, is the surface (z = 0) porosity. The constant (c) previous time, where z, = 0, we can calculate its base by
must be given for each different lithology. A table of val- solving equation 6 self-consistently. Then the depths and
ues for 0 and c is given by Sclater and Christie (1980, Table thicknesses of all lower layers can be obtained sequentially
Ala). Values of ^o and c from actual bore-hole porosity and self-consistently. A similar equation is obtained in the
measurements can be obtained by fitting an exponential Falvey-Middleton analysis:
function via least-squares techniques. An alternate phe-
nomenological model of porosity versus depth has been Z4-Z3 = h, -H (l/k)fn([ l/0„ -H k z j / l 1/0,, -t^ kz3 ]). (7)
proposed by Falvey and Middleton (1981). In this model,
the porosity decreases as a function of the load on the layer Given the compaction parameters and drill-hole values of
being considered. depth, age, and paleowater depth, a computer program
Falvey and Middleton (1981) argued that in most cases can be designed that will give the burial-history and geo-
exponential porosity-depth relationships do not fit shal- history curves as shown in Figures 1 and 2.
lower depth data particularly well. They formulated a Another important factor to consider in conjunction
relationship by assuming the incremental change in poros- with porosity is the modeling of unconformities. At least
ity (d<l>/(j>) is proportional to the change in load (dL) and three possible ways to model an unconformity (Figure 3)
the void ratio (e) as: are:
1. As a depositional hiatus.
d(^/(/> = -kedL, (3) 2. As a period of deposition and erosion in which the
thickness of eroded section and the absolute age marking
where the beginning of erosion are determined from a knowledge
of the local geology (see van Hinte, 1978); these parame-
e = 0/(1 - 0) ters may be varied to see which model best fits other
and observed data (e.g., present-day vitrinite reflectance and/
or behavior of velocity or density logs).
dL==(l-0)dz, 3. As a period of deposition and erosion in which the
thickness of eroded section and the age at the beginning of
with dz being the change in depth of sediment due to the erosion are calculated as follows:
change in load and k a lithology-dependent constant. This
has the solution AGEE = (Rl X AGE 1 + R2 X AGE2)/(R1 -I- R2).
1/0 = l/0„ -h k z. (4) Eroded thickness = Rl x ( A G E E - A G E I ) ,
where 4>o is the initial uncompacted porosity and z is the where AGEE is the age at the beginning of erosion, AGEl
depth. and AGE2 are the observed ages of sediment immediately
Equations 2 and 3 make it relatively easy to correct well above and below the unconformity, and Rl and R2 are the
data for the effects of compaction. First, the total amount calculated sedimentation rates in the immediately overly-
(hs) of skeletal or solid material in an interval (z, to Zj) is ing and underlying sediment layers.
given in the Sclater-Christie model by Knowing the depth and thickness of each layer as a func-
T. M. Guidish e t a l 95
MODEL OF UNLOADED needed: (a) amount of oil and gas generated per square
GEOLOGIC COLUMN kilometer in each source rock and in every part of the
COLUMN basin, (b) timing of hydrocarbon formation, timing of the
development of impermeable seals, and timing of folding
Sea Level
and faulting, so traps can be identified, (c) amounts of oil
and gas that have been expelled from the source rock into
WATER COLUMN the porous reservoirs and how much is still retained in the
OF HEIGHT W^ source rock, and (d) evaluation of the ukimate oil and gas
reserves of a sedimentary basin.
Sea Floor
SEDIMENT COLUMN Only a quantitative approach, allowing a computation
OF HEIGHT S, of the amount of oil and gas generated in any place in the
WITH POROSITY h basin as a function of time, can provide this information.
GIVEN BY ^ ( Z ) I
However, because many of the intermediate steps in petro-
/ leum and gas generation from kerogen degradation are
RADIOMETRIC
AGE MARKERS unknown, such a scheme has to be phenomenological;
that is, parameters have to be determined by least-squares
fitting to basin and laboratory data. Such a mathematical
FULLY COMPACTED model of petroleum generation accounting explicitly for
SEDIMENTS AND
CRYSTALLINE ROCKS
geologic time was first introduced by Tissot (1969) and is
EQUATE discussed fully by Tissot and Espitalie (1975). The model is
OVERBURDEN
MANTLE
<-WEIGHTS AT-i>'''
based on kinetics of kerogen degradation and uses the gen-
DEPTH OF eral scheme of first-order chemical kinetics. Kerogen is a
COMPENSATION macromolecule composed of polycondensed nuclei bear-
Figure 4—Schematic diagram of reconstructed Ooaded) sedi- ing alkyl chains and functional groups—the links between
mentary section and baclistripped (unloaded) sedimentary sec- nuclei being heteroatomic bonds or carbon chains. As the
tion. Parameters are defined in text (from Steckler and Watts, burial depth and temperature increase, the bonds are suc-
1978). cessively broken, roughly in order of increasing rupture
energy. The products generated are heavy heteroatomic
tion of time, and also knowing the lithologies of the layers compounds, carbon dioxide, and water, then progressively
and their densities, it is possible to determine the basement smaller molecules, and finally hydrocarbons. At the same
subsidence as a function of time by applying Airy (1855) time, the residual kerogen becomes progressively more
isostasy calculations. The depth of the earth's crust into aromatic and evolves toward a carbon residue.
the medium is determined by the load on the crust, as has Validity of a phenomenological model depends on two
been discussed by Bomford (1971). We can then apply factors: (1) the validity of the physics and chemistry
isostasy arguments, as discussed by Steckler and Watts involved in the calculation, and (2) the values of the
(1978), to backstrip (remove) the layers of sediment and parameters chosen. Tissot and Welte (1978) compared the
replace these layers by water. The basement subsidence (Y) figures computed by the model with the corresponding
in terms of the water depth at time of sediment deposition amounts of petroleum generated in various basins. They
(Wj) and sediment thickness (S) is given by (see also Figure claimed a quadratic deviation lower than 10'^ and a corre-
4): lation coefficient better than 0.9. The model has been
claimed to simulate experimental heating during various
Y = S[(p„ - ft)/(p^ - pj] + Wd - AsL [p^/(p„ - Pw)], (8) times from 1 hr to 1 yr—again with satisfactory agreement
with laboratory experiments. The same set of constants
where p„ is the average mantle density, p^ is the average given by Tissot and Welte (1978, Table V.4.1) is sufficient
water density, p^ is the average sediment density, ASL is the to account for all conditions of kerogen degradation
change in elevation of mean sea level, and Y is the depth to including: (a) evolution at relatively low temperatures
basement without sediment and water loads and repre- (50°-150°C; 122°-302°F) over a time of 10 to 400 m.y., (b)
sents the subsidence caused by tectonic effects. artificial evolution through laboratory experiments (180°-
The terms W^, and AgL must be determined from sedi- 250°C; 356°-482°F), and (c) high-temperature (400°-
ments by paleobathymetric analysis. 500°C; 752°-932°F) retorting of oil shales.
The constants, however, were determined using constant
geothermal gradients. Strictly speaking, the use of Q (heat
HYDROCARBON GENERATION AND flow/unit time) or bottom-hole temperature data gener-
THERMAL HISTORY ates changing thermal gradients with depth and time and
requires a recalibration of values for greater validity and
One of the principal goals of explorationists using applicability.
burial-history technology is the prediction of source rock To apply the phenomenological model of Tissot and
maturity and the ranking of prospects. Welte (1978) to the prediction of change in hydrocarbon
Involved in the evaluation of a sedimentary basin is the content of rocks with respect to time and temperature, it is
determination of the amounts of oil and gas that have necessary to assume first-order chemical reaction kinetics
been generated and accumulated and the locations in for the breakdown of kerogen to hydrocarbons as gov-
which they occur. To do this, the following information is erned by
96 Basin Evaluation Using Burial History Calculations
- d X i / d t = kiXi {9a) where T,(t) is the temperature at the top of the layer as a
function of time, D(t) is the layer thickness as a function of
time, and K(t,z) is the thermal conductivity of the layer as
-Ei/kBT(t) a function of time and depth. Thus, in order to predict
A;e (9b) basin maturity as a function of time, it is necessary to
know Q(t), D(t), and K(t,z). Although D(t) and K(t,z) can
be determined from the burial history and lithology, in
where X| is the number density of component i, kj is the order to make accurate predictions of hydrocarbon matu-
reaction rate for this reaction, kg is Boltzmann's constant, rity, Q(t) must be determined also over the range of the age
A; is the reaction rate in the limit of high temperature, E, is of the basin to the present. The previous section showed
the activation energy, and T(t) is the temperature as a func- how to determine layer thickness D(t) using porosity-
tion of time acting on the element X;. depth relations and the decompaction relation given.
In the Tissot and Welte scheme, three types of initial To estimate paleotemperature, it is necessary to know the
kerogens are considered. The three types differ in their thermal conductivity as a function of time—K(t,z). For
hydrogen-to-carbon ratio. Loosely speaking, these three two reasons, it is difficult to extrapolate the data in a par-
types can be considered type 1 (algal) with a high petro- ticular basin back into the past. First, there are large dif-
leum potential, type 2 (amorphous) with an intermediate ferences in lithology; second, most extrapolation
petroleum potential, and type 3 (woody) with a low petro- techniques involving empirical relations connecting ther-
leum potential. Each of these types of kerogen is assumed mal conductivity to porosity have been worked out only
to have six different bond types. These six bond types have for sandstones. Sandstones often occur only in limited
strengths or activation energies in the range 10 to 80 kcal/ areas and may have been deposited during relatively brief
mole. The amount of organic material (x,) reacting in the time intervals in a basin. However, these empirical tech-
i'th reaction (breaking of the i'th bond type) for i = 1 to 6 niques provide the basis for tackling other lithologies,
is specified for each of the three kerogen types. Calibra- such as shales or limestones. Evans (1977) and Sclater and
tions for the formation of gas have been made from labo- Christie (1980) have shown that such empirical relations
ratory experiments on hydrocarbon cracking. have considerable validity for the pre-Tertiary shales,
Consideration of a single reaction with an activation marls, and chalks of the North Sea. Thus, if a reasonable
energy of 80 kcal/mole seems convenient to account for estimate of the porosity can be determined, it is then possi-
gas generation in the deep parts of sedimentary basins. ble to relate thermal conductivity to porosity The point
Tables of the activation energies (E;), the reaction con- here is that, if a sediment contains water in its matrix, at
stants (A;), and the initial values (x,) for each kerogen type 100% porosity the sediment will have the conductivity of
have been given by Tissot and Welte (1978, Table V.4.1). water, whereas, when totally compacted, it will have the
To calculate the quantity of hydrocarbons produced by conductivity of the matrix. The conductivity will vary
potential source rocks, it is necessary to use the above cal- between the two extremes, and it is only necessary to
culations and measurements or estimates of the percent- obtain some values in between in order to obtain a relation
age of organic material in those source rocks. Nakayama between porosity and conductivity that is reasonably valid
and Van Siclen (1981) detailed the methodology of this sys- throughout the expected range of porosity. Such phenom-
tem to work out a hydrocarbon budget for a basin. In enological relations have been obtained from the data of
order to make predictions about the hydrocarbon history Sclater and Christie (1980) and Evans (1977) for shale,
of a basin, it is also necessary to determine the temperature sands, chalks, shaly sand, and salt. The dependence of
as a function of time. Tissot and Welte (1978) assumed thermal conductivity on temperature is not included in this
that heat flux was constant and used constant geothermal calculation, but it is important.
gradients in their models. However, by allowing the heat To estimate the paleotemperature, it is necessary to know
flux to vary with time, their model is improved. The tem- thermal conductivity as a function of depth and time.
perature, as a function of time, for a basin with a variable Because this cannot be measured, it is necessary to rely on
basement heat source, Q(t), located at Z = Z^as^^^^, is given a phenomenological relation between thermal conductiv-
by the heat-diffusion equation: ity and some other parameter that can be deduced at pre-
vious times. A particularly useful relation exists between
thermal conductivity and porosity, because porosity as a
dT/di = ( p C ) - V • (KVT) + ( p C ) - ' Q(t) 6(Z - Zb,,emen.). (10) function of time is calculated in the burial-history compu-
tation. Sclater and Christie (1978, Appendk B) have given
a relation between thermal conductivity and porosity for
where C is the specific heat, p is the density, K is the ther- North Sea chalks and shales. Their porosity values are
mal conductivity, and 6(Z) is the Dirac 6-function.
If Q(t) varies slowly as a function of time compared to
the diffusion time scale through the top 3-5 km (9,800- 'The precise solution is T = Tj + Q J dz7K(z' ,t), where Tj is the surface
16,400 ft) of the earth's crust and sediment (i.e., slowly on temperature. For a layer of thickness D(t) at depth z with a temperature on the
top of the layer of T,(z), we can equally write
a time scale compared to about 4 or 5 m.y.), then the solu-
tion of the heat diffusion equation is approximated by^: T = T,(z) + 0(t)D(t)/<K(t,z)>,
taken from deep sea clays and the shallow water North
Atlantic sediments of Ratchffe (1960). Observed thermal
1 ' 1 '1 ' 1 '
6.0 — 0 SHALE
conductivities are from Evans (1977). The relation n
between these two quantities is summarized in Figure ^ A CHALK
(Sclater and Christie, 1980, Appendix B). For porosities o ^*
intermediate between the data points shown in Figure 5, a -<J 5.0 — / ^
Unear interpolation scheme is used to obtain thermal con- COo / y^
ductivities. When few or no data are available, about the b
best that can be done is to write K^ = Kr(K„/K,)'^, where
4.0 —
K,, K„, and K^ are the thermal conductivities of rock // ~
matrix, water, and sediment, respectively, and (t> is the frac-
tional porosity (Lewis and Rose, 1970).
These values of the thermal conductivity have been o 3 3.0
inferred from the relationship between porosity and con- O
z 1 CHALK
ductivity; their reliability depends on porosity calcula- o
tions. Thermal conductivity is also a function of - I o 2 SHALES
temperature; however, to our knowledge this dependence < 2.0
has not been tested for its effect on real data. Kappelmeyer CO 111
and Haenel (1974) have summarized the available data on X
variation of thermal conductivity with temperature for L I . I . I . I ,
several rock types. The thermal conductivities of most 100 80 60 40 20 0
materials decrease with increasing temperature. The only
POROSITY (%)
material recorded whose thermal conductivity increases
with increasing temperature is shale. Shale is the most Figure 5—Relation between tliermal conductivity and porosity
common sedimentary rock occurring in most basins. for North Sea chall(S and shales. For porosities greater than 40%,
Using a small thermal conductivity (K) has the effect of values are taken from deep-sea clays and shallow-water North
increasing the temperature calculated at a given depth. Atlantic sediments of Ratcliffe (1960). Observed conductivities
Thus, the effect would be to predict that oil is mature, are from Evans (1977), with porosities estimated using relation of
Sclater and Christie (1980) (from Sclater and Christie, 1980).
whereas the oil actually may not yet be mature, or to pre-
dict that gas occurs, whereas the rock actually may be still
in the oil window, Thus, in order to make accurate predic-
areinfairagreementwiththe 1.19to 1.48 X lO'^cal/m^-
tions of hydrocarbon maturity, it is necessary to include
sec cited by Harper (1971). In contrast, Sclater and Chris-
the temperature dependence of thermal conductivity in
tie (1980) cited a heat flow of 1.7 x 10"^ cal/m^ • sec with
calculating temperatures via
no quoted error.
where a is a poshive constant and b is a positive constant Backstripped subsidence (Y) can be predicted by geo-
for all materials except shale, where it is negative. logic models. By comparing our backstripped subsidence
Total thermal conductivity is the sum of a lattice conduc- (Y) with the predicted subsidence of a particular geologic
tivity (KL) that decreases with increasing temperature, and model, we can: (1) evaluate the validity of that geologic
a radiative part (KR) that increases with increasing temper- model by examining the root-mean-square (r.m.s.) differ-
ature. For most materials, it is possible to ignore KR and ence between the predicted subsidence and the back-
only consider KL. According to Kappelmeyer and Haenel stripped subsidence, (2) make predictions of heat-flow
(1974), thermal conductivities typically decrease by a fac- history using the geologic model, (3) calibrate the geologic
tor of about two between 0°C and 430°C (32°F and model against thermal indicators like vitrinite reflectance
806° F). This large effect occurs over the temperature or the annealing of fission track scars etc, and (4) predict
range that is the prime window for oil generation. It there- the maturity of potential source rocks, as a function of
fore appears necessary to include the effects of tempera- time, away from wells using the crustal subsidence derived
ture variation of thermal conductivity in thermal from seismic sections.
maturation calculations. Thus, geologic models are an important source of infor-
Any model of paleoheat flow must satisfy the condition mation on the change in heat flow as a function of time.
that it agrees with the present-day heat flow as determined However, the several available models do not agree even in
from bottom-hole or formation temperatures, surface areas like the North Sea where we found that the heat flux
temperatures, and thermal conductivities determined could be increasing for one model and be decreasing for
from present-day lithologies. For example, we found that another. Also, in the Michigan basin, Cercone (1984) pro-
heat flows for the North Sea, which we determined using duced a model of heat-flow history that suggests much
the measured surface temperature, the corrected bottom- higher heat flows in the past than those of Nunn (1981),
hole temperatures, and thermal conductivities based on Nunn et al (1984), and others. Thus, it is important to be
the empirical porosity-thermal conductivity relations, are able to assess quantitatively geologic models for basin for-
in the range 1.0 to 1.8 x 10"^ cal/m^ • sec. These numbers mation by comparing their predictions for subsidence and
98 Basin Evaluation Using Burial History Calculations
caUbrating their heat flow to independent measuremenis. crust, as suggested by Sleep, is to erode it while it is
In this paper, we examine four basic models: the McKen- uplifted. The change in elevation with respect to base level
zie lithosphere stretching model (McKenzie, 1978), ihe is the sum of the change due to thermal contraction and to
dike intrusion model (Royden et al, 1980), the thermal erosion. In the limit that the erosion time constant and the
expansion model (Sleep, 1971), and the deep crustal meta- heat-flow time constant are equal, Sleep gives a solution
morphism model (Falvey, 1974). A model not reviewed for the elevation (E) with respect to the final level as a
here is the important two-layer extensional model, which function of time:
expands on the McKenzie (1978) model and has been
described by Royden and Keen (1980) and Hellinger and E = E„ (l-[K7rVc11) exp (-KirVh), (17)
Sclater (1983) and used by them to explain problems they
have with the models we discuss. where E„ is the initial elevation.
We begin with the thermal expansion model of Sleep From the elevation, it is possible to calculate the subsi-
(1971). This model was designed to give the thermal his- dence. Thus, by doing a least-squares comparison (dis-
tory of the Atlantic continental margin. This margin cussed below in greater detail), it is possible to use
formed when spreading began between Africa, Europe, equation 13 to obtain parameters determining the heat
and the Americas. It is proposed that the thermal history flow as a function of time, depth, and horizontal extent.
of the margin resembles that of an oceanic crust as it The thermal cooling model has been further considered by
spreads away from a mid-oceanic ridge, so the thermal Turcotte and Ahern (1977) as well as by Keen (1978). These
structure of continental margins is deduced by studying authors found that the subsidence as a function of time is
mid-ocean ridges. The most obvious feature of a mid- proportional to the square root of the time elapsed since
oceanic ridge is its topographic anomaly. This anomaly is cooling began.
interpreted as isostatically compensated thermal expan- Several authors, including Hellinger and Sclater (1983),
sion of hot material that intrudes along the axis of the have criticized the Sleep model. Within the Sleep model,
ridge. Due to thermal expansion, an initial uplift occurs. material must be removed on a large scale by erosion when
Then, as the continental edge is removed from the source uplift occurs. For example, we would agree that there is no
of the thermal anomaly at the ridge crest, thermal contrac- evidence that 2 km (6,500 ft) or more of rock was removed
tion occurs and, consequently, subsidence. The elevated from the North Sea after block faulting during the Juras-
surface gradually subsides to its original position as the sic and Cretaceous (McKenzie, 1978). Erosion that did
lithosphere cools. However, to produce the configuration occur is local and associated with the horsts produced by
of many continental margins, material must be removed normal faulting.
on a large scale by erosion when uplift occurs. Another model for the development of sedimentary
In the Sleep model, the temperature is given by basins, which has been proposed by McKenzie (1978),
avoids the necessity for material removal by erosion. In
T(x) = g(x) E exp (-K7r^n^tc"^)A„sin (nx z/c), (13) the McKenzie model, a rapid stretching of continental lith-
n odd osphere produces thinning and passive upwelling of hot
where asthenosphere. This stage is associated with block faulting
and subsidence. The lithosphere then thickens by cooHng,
A„ = (2/c) i' T(z) sin (nxz/c) dz, (14) and slow subsidence occurs, with this latter not associated
with faulting. The slow subsidence and heat flow are
K is the thermal diffusivity, x is the horizontal extent, z is explained as depending only on the amount of stretching,
the depth, and c is the maximum depth (i.e., thickness of which can be estimated numerically. In the McKenzie
the crust). model, the initial subsidence (Sj) is given by
The function g(x) is a measure of the width of the ridge.
The amount of upMft u(x) caused by isostatically compen- Si = a [(p„ - p j (t,/a) (1 - aT, [t,/2a]) -(aT,p„/2)]
sated thermal expansion is then given by
x(l-l//3)/[p„(l-aT,)-pJ, (18)
u(x) = (2ac/7r) g(x) L (A„/n) exp (-KirVtc'^ ), (15)
nodd
where a is the thickness of the lithosphere, t;. is the initial
where a is the volume coefficient of thermal expansion. thickness of the continental crust, p^ is the density of the
Because the first overtone attenuates nine times faster mantle, p^ is that of the continent, p„ is the density of the
than the fundamental, it is an excellent approximation to sea water, a is the thermal expansion coefficient of the
keep only the first terms in equations 14 and 15. Then mantle, Tj is the temperature of the asthenosphere, and /?
is the crustal stretching factor.
u(x) = UQ (X) exp (-uTi^fh) (16) For large values of time and small values of |8, the eleva-
tion is given by
where E(t) = [4ap,aT,/x^(p„ - pj] e"\ (19)
u„(x) = (2ac/7r) A,g(x). where
T = a^/TT^K (20)
No sediments would accumulate if the lithosphere of the
newly formed continental margin expanded and then con- and K is the thermal diffusivity.
tracted without any crustal thinning. One way to thin the The heat flow Q(t) is given by:
T. M. Guidish et al 99
Q(t) = (KT|/a) [1 + (2/3/x)sin(7r/^)e (21 where T„ is the temperature at the base of the mantle, I is
the thickness of the lithosphere, K is the thermal dif fusivity
For small values of 0 and large values of time, a straight of the lithosphere, a is the thermal expansion coefficient
line fit which best approximates equation 19 for the subsi- of the mantle, p^ is the density of the mantle, p^ is the den-
dence is given by sity of water, and K is the thermal conductivity.
The theories of basin formation thus far considered all
= E„r[(2t/er)"^-2e'"' + 1] (22) rely on the thermal contraction of the crust to produce
subsidence. An alternative explanation has been proposed
where by Falvey (1974) and elaborated by Middleton (1980) and
Falvey and Middleton (1981). This explanation suggests
Eo = 4ap(,aT,/7r^(p<3-p„) (23a) that the initial stage of subsidence is caused by deep crustal
metamorphism in basins of relatively young, or unaltered,
r = (13/T) sin (TT/JS) (23b)
crust. Falvey (1974) has demonstrated that elevation of the
and geotherm during the rifting of continental margins may
produce subsidence of the margin due to deep crustal
T = 62.8 m.y. (23c) metamorphism, and has also suggested that formation of
intracratonic basins may entail such a metamorphism.
The subsidence predicted by the McKenzie model is simi- The deep crustal metamorphism mechanism implies a sub-
lar in form to that predicted by the TUrcotte-Ahern model. sidence of:
In the McKenzie model, prior to the time of stretching,
the heat flow is given by the leading coefficient in equation IPmiPl - P\VP\ (Pm - Ps)] L(0. (26)
21 (i.e., KT,/a). Sclater and Christie (1980) pointed out
that the present-day heat flow (approximately 0.8 x 10"^ where L(t) is the thickness of greenschist facies rocks meta-
cal/m^ • sec) predicted by the McKenzie model (see Figure morphosed to amphibolite facies rocks at time t, /o, is the
15) is too low to agree with the present measurements of density of the greenschist facies, pj is the density of the
heat flow measured in the North Sea (approximately 1.5 amphibolite facies, p, is the density of the sediments, and
X 10"^ cal/m^ • sec). Sclater and Christie liave proposed a p„ is the density of upper mantle rocks. Falvey (1974) has
modification of the McKenzie model in which the heat suggested that the metamorphism that drives the basin
flow has an additional component of 0.8 x 10"^ cal/m^ • subsidence occurs predominantly at the greenschist-
sec coming from the decay of radioactive elements within amphibolite facies boundary. The model entails a period
the crust. Another modification has been proposed by of heating followed by a period of cooling. Subsidence due
Keen et al (1981), in which the effect of thermal blanketing to deep crustal metamorphism occurs during the later part
by low thermal conductivity sediments is included, slow- of the heating period and is followed immediately by sub-
ing the cooling of the lithosphere. This effect is claimed to sidence due to thermal contraction during the cooling per-
be particularly important to studies of older rifted mar- iod. The time of transition between the heating phase and
gins, as in the North Sea, where large thicknesses on the the cooling phase is t,.
order of 15 km (49,000 ft) of sediments have been depos- Subsidence is proposed to occur in two stages (see Figure
ited. Royden and Keen (1980) and Hellinger and Sclater 6). Initially, subsidence is thought to be due to deep-crustal
(1984) have proposed a modified stretching model encom- metamorphism and will continue as long as crustal tem-
passing two layers. This model was proposed to handle peratures increase. This is followed by subsidence due to
some problems not confronted by McKenzie. Specifically, thermal contraction of the lithosphere, and this occurs
it explains uplift and erosion on the flanks of a rift basin. over periods of time greater than tj (i.e., for the cooling
Another model that provides an exponential subsidence phase). The downward movement, ((t), of the earth's sur-
compatible with observational data involves the fracture face due to metamorphism of the heating stage of the ther-
of the continental lithosphere and its intrusion by dikes mal event is offset by the tendency for uplift, h(t). Total
from the mantle. Replacement of light crustal rocks by displacement, taking these two factors into account, and
denser ultramafic material results in initial subsidence and neglecting erosion, is given by
avoids the general problem of uplift as in Sleep's theory.
This model has been proposed by Royden et al (1980). If y^ S(t) = f(t)-h(t) (27)
is the fraction of lithosphere composed of dike material
intruded from the asthenosphere, then the heat flow Q(t), for i{t) < h(t), and
and surface elevation u(t), respectively, are given by
s(t) = ipj(fi^-p,)][m-m)] (28)
00
Q(t) = ( T „ K / 0 ( l + 2 7 d E e" nV^/(t/^\ (24)
n=l for e{t) > h(t), where -S(t) is uplift, p^ is the density of
mantle, p^ is the density of the sediment, and p^/(p,rrPd is
the isostatic loading factor.
Subsidence due to thermal contraction is given by
u(t) = Kp„T„/(p„-pJ](47,M
X I^jj [l/(2n + 1)^] exp(-(2n + 1) \ht/e^), (25)
S(t) = [P™/(P„ -Ps)] [h(t,) -h(t) -I- h(t -1,)]. (29)
100 Basin Evaluation Using Burial History Calculations
FALVEY MODEL
THERMAL HISTORY
(PALEOHEAT FLOW)
-ISB' -168* -157' -ise* 154° - 153' ise= -isa* -18fl' -155' -1S<* -183' -H2'
CENOMANIAN
.miGOK,
-laa* -161' -no* -1S9' -15«» -1!7' -156' "25.S- -.S<- -153- -.S2-
MID-EOCENE
71
,S BARROW
E SIMPSON • „ D R ^ P T t . J . V V D . L T O «
;KUORiJAl
•^S MEADE --....^^^
JkTIGARU PUT1
,TUNAIIK1 •UK1^< ' i \ ^ ' I
N.KALIKPIK^ \ S H A R R S N B 1
W.FISHCREEK ?0 ^FISHCREEK I
.,»».,
Figure 8—Contour map of vitrinite reflectance through time of Anisian sediments in National Petroleum Reserve of Alaska.
vitrinite is determined by the relative index of refraction of annealing of apatite fission scars (Gleadow et al, 1983),
vitrinite in oil. Because the refractive index, TIQ, of the the variation in ""Ar/^Ar (Harrison and Be, 1983), tem-
immersion oil is known (typically n^ is 1.518), the reflec- perature data extracted from fluid inclusions (Burruss et
tance is determined entirely by the index of refraction of al, 1983), and magnetic history as tied to thermal events
the vitrinite, which depends on the number density of the (Middleton and Schmidt, 1982). Of these, the apatite
reflecting molecules and on the oscillator strengths of the fission-scar annealing and the """Ar/^Ar indicators seem
molecules. Toth et al (1981) and Lerche et al (1984) have the most promising for tying to vitrinite-reflectance heat
shown that it is possible to obtain the initial number den- history.
sity multiplied by oscillator strength from the value of Thermal indicators provide knowledge of the paleoheat
vitrinite reflectance on the surface. Using the constant flow as a function of time. This information has two uses.
thus determined, the change in vitrinite reflectance with First, a basin in which vitrinite reflectance is measured, or
depth is determined by the change in number density with where some other thermal indicator is used, allows us to
depth. This variation in number density is due to the determine the heat flow and, hence, the thermal maturity
change in number density of optically reflecting molecules of the acreage that is being explored. Second, for a given
due to first-order chemical kinetics, which are tempera- basin, knowing the heat flow allows us to evaluate quanti-
ture dependent. Because we know the measured reflec- tatively the geologic models that have been proposed for
tances, it is possible to determine the temperature as a the origin of the basin. Thus, in principle, it is possible to
function of time. determine which is an optimal geologic model for basins
The physical theory of vitrinite reflectance can be used to of a specific tectonic setting. Then, in other basins of the
determine the heat flow, Q(t). Assume a heat flow that is same tectonic setting, it is possible to use this optimal geo-
characterized by several different parameters. Then, by logic model to make predictions of maturity before drill-
least-squares optimization of these parameters (by com- ing on the basis of seismic data. Thus, it is possible to rank
paring predicted vitrinite reflectance to those measured in basin maturities in the absence of bore-hole measure-
a bore hole), an optimized Q as a function of time is ments. Therefore, we have a predictive tool for use in
obtained (Toth et al, 1981; Lerche et al, 1984). For further hydrocarbon exploration.
details of the vitrinite reflectance theory and its implemen-
tation, the reader is referred to Lerche et al (1984). Figure 8
shows the use of this theory in making maps of vitrinite CONCLUSIONS: POTENTIAL INPUTS AND OUTPUTS
reflectance through time for specific formations. One OF THERMAL MATURITY AND BURIAL HISTORY
point is worth mentioning here, and is emphasized in CALCULATIONS FOR USE IN HYDROCARBON
Lerche et al (1984). We can trust determinations of EXPLORATION
paleoheat flow and paleotemperature no further than we
can trust the quality of the vitrinite reflectance data which, Inputs
most often, could be significantly improved. Errors in
determination of paleoheat flow can then be ascribed to The inputs for thermal maturity and burial-history cal-
both errors in burial history evaluation and errors in data culations are stratigraphic and biostratigraphic data gen-
input. Both of these points, and others, are dealt with in erally available from well logs, well reports, and in some
great detail in Lerche et al (1984). cases from interpreted seismic sections. Inputs include lay-
Other indicators provide measures of the variations in ers enveloped by stratigraphic stage boundaries or mark-
heat flow with time. Some of these indicators are: (1) the ers, depth of water at the well, height of the kelly bushing
transition of smectite to illite, (2) the variation of porosity relative to sea level, present-day temperature gradient or
with depth and temperature, (3) the molecular optical present-day heat flow, present surface temperature, and
activity of oils as a result of asymmetric carbon-atom posi- measured bottom-hole or formation temperature. For
tionings, (4) the even-odd aliphatic chain effect in oils, (5) each layer of rock, it is necessary to give the depth of that
the molecular weight distribution in oils, (6) "C to '^C,' O layer relative to the top of the kelly bushing, the age of that
to '*0, and '"'Ar/"Ar isotope anomalies with depth, (7) layer (from biostratigraphic and radiometric data), the
annealing of fission tracks in apatite, zircon, and sphene, water depth at time of deposition of that layer, and the
(8) magnetic history, and (9) fluid inclusions. lithology of the layer (which could be one of several gen-
However, only indicators 1, 2, 6, and 7 are generally eral types like shale, sand, carbonate, shaly sand, or salt;
available from bore-hole measurements and indicators 3, or which may be basin specific, in which case porosity/
4, and 5 require the presence of oil. Vitrinite reflectance is decompaction parameters must be supplied).
a generally available indicator from bore-hole measure- If one wishes to do thermal modeling using the vitrinite
ments and does not require the presence of oil. The smec- reflectance approach, depth and percent reflectance pairs
tite to illite transition depends on the presence of must also be input. Also, if one wishes to model hydrocar-
potassium as a catalyzing agent and can be poisoned by bon maturity history, kerogen type and its concentration
excess sodium concentration. To use this indicator success- as a function of depth need to be recorded.
fully would require a detailed knowledge of fluid migra-
tion whhin the geologic layers. The vitrinite reflectance Outputs
method of determining heat-flow history is believed by us
to be the most accurate and probably the best method The results of a modeling program can be divided into
available at this time. However, this method needs to be three classes—burial history, thermal maturity, and com-
tested against independent thermal indicators such as the bined outputs.
T. M. GuJdJshetal 103
The burial history outputs can include the burial history mined from corrected bottom-hole and/or formation
versus time (i.e., the depth below depositional surface as a temperatures and lithologies, (3) the heat flow determined
function of time in milhons of years); geohistory or toial from the McKenzie crustal-stretching model with parame-
subsidence plots (Figure 1) (i.e., depth below current sea ters determined by the least-squares optimization of
level as a function of time); subsidence due to compaction; model basin subsidence and backstripped subsidence, (4)
amount of subsidence due to isostatic response to sedi- the heat flow determined from the Falvey crustal-
ment load; basement subsidence (Figure 9) (i.e., the depth metamorphism model with least-squares optimization of
to the basement with the sediments removed as a function parameters, (5) the heat flow determined from the Royden
of time); rate of sediment accumulation, subsidence, and dike-intrusion model with least-squares optimization of
basement subsidence as a function of time; and sea level parameters, (6) the heat flow determined from the Hel-
plots as a function of time. linger and Sclater (1983) two-layer extentional model, and
Thermal maturity calculations and plots can include the (7) the heat flow as derived from vitrinite reflectance data
time-temperature integral (TTI) of Waples (1980) versus or some other thermal indicator.
depth at present, vitrinite reflectance in percent versus Combined thermal history and burial history calcula-
depth at present (Figure 10), vitrinite reflectance versus tions and outputs can include burial and/or geohistory
TTI (Figure 14), and percent of kerogen converted to oil or and thermal maturation (i.e., percent kerogen converted
gas for each layer and each kerogen type (type 1, type 2, to oil and/or gas for various geologic eras), burial history,
and type 3) as a function of time. At least seven possible and Waples time-temperature integral (TTI) calculations.
options of heat flow as a function of time could be mod- Plots of constant TTI can be produced and outlined on
eled: (1) constant temperature gradient, (2) the present geohistory plots (Figures 10, 12). Also, one can construct
heat flow is assumed not to vary with time and is deter- plots or make calculations of predicted basin subsidence
,:ir[]pimi,'iiiBrfirr
IS
IS
UJ
>
LU 12.0 Ma
-J
<
35.0 Ma
LU
(0
43.0 Ma
+3.0 Ma
O s ..
CO 63.0 Ma 64.3 Ma 66,0 Ma
u.
I-
UJ _82^0_Ma_
LU
LL
_88.B Ma 90.0 Ma
91.5 Ma
_3Si&_Ma_
I- U 2 i.0. M.a. . i l l • 5. Mj_
Q. s
LU IS
IS
Q •H
100.0
0 2B 0 30 0 40 0 s^ 13 9? ASE (MJt)
•id
' 160 120
— 3 0"C-
40'C-
50'C -
60*C - GEOrHERMAL
GRADIENT
7 0*C -
ASSUMED
z eo'c- CONSTANT
THROUGHOUT
\ 90°C- GEOLOGIC PAST
lOO'C-
0 0
1 10'C -
120'C-
OIL
130"C - GENERA
WINDOW
0
140*C -
0
150*C-
—
0 0 ieo"C -
0
170"C -
n 09, -Iso-TTI lines on geologic model
0
Figure 12—Iso-TTI lines on geologic model. Oil generation >
dowis shown in cross-hatched area (from Waples, 1980).
ae.a
TTI 55 e ffl ? i5e p le .3 se e i-
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