kanes 7 Also ~~ avant aie Feloalones 2 Ako | = Halogen olerivatives alkane. It has _ four types s _ 2 Monohalealkanes “(cus —x) © Dihaloalkanes (CHi—%3) e Tthaloalkares (CH—X3) 2 Tetrahaboalkanes (CX) -oxe alkylhelides and then by Ce _____Wonohateatkanes ane callegl ln we aot ——— Scanned with CamScannera -Colbon 78 Cltvectly attached with one or 70 edstbon. zi ie Ehtchiride (Chloreethane) =a nm hloromethane) Ts g ky habicle fn which — =e deal atone with two Conbons Ji 2-chloro propane (Bo peopylchlovide ree eh eT Type oh Amy bhabitle in which & me flere ye aha che a to THC Ch (2 Chlow- A--methy! p90) eh neo butyl chioride) p> Sl Scanned with CamScannerCH3—CH,-OH + HCL WO CH3CHacl+ H—OH | iL) FROM THIONYL CHLORIDE _ (Best_methoc!) CHy—CH— OH + SOC, PREPS cH,—cHy—cl + St! Thiak{chtovide Gases. Sime, 30, ancl HCL axe gases . They evolve by memselves no seperation fs epee regi 4 noe a, cee - ae Fin PHOSPHORUS PEN aoSPaBRaS PENT FACHIOROE 4 CHCl - OH + Pls — — ‘CH=CH, -Cl + FOCI i sae oe pa errr tanlneiaslaae anita eel | Scanned with CamScannernn ne iy) FROM PHOSPoRUSTRc HLORIOE H+ Pd; —> 3 3CHs —cHh,~ c+ TPO, a a —_pplons Om ft 8 OK ~atocling Subs Tate “1 Bad leaving i. 2 Good. atlackin ap. (strong bo} ) 9t's la & dle, : be altome size) Ler goed. atto chit as well as good ng te ~ lets ‘da “¢ - Fone | Ny? Bb nether a nucleophile ay een oy ~ ¢ Substitution K © Elimination | = ees se Subst TUuTioNn. SE — rr ee undergo Nuckophilice bubstitution. MO Kw No Ted Scanned with CamScanner(Wwe) ————<~-_o,,. NN , —_SN, ee "ole DEFINITION — | — Nucleophillic substifion ‘Nucleophillic tb sHltlon | by molecular _"eaction untmolecutert 7eaction "| AiKVE HALIDE 7 Primary alltyt halide _Tertiosey alkyl halide STEPS - Single_stepped Reactions consist of vedcHion two_Ssteps. MOL”ECULARITY Gmoeudan___——srimcecula | _ ORDER OF REACTION Second! ovcley feet order __4 MEDIUM favoured! b las medium. —HYBRIOIZATION Sp -sp'ssp? $p2-5 sp3sp? | Spospissp’ __sp>-ssp3sp?_ CONFIGURATION — Cannan gemeni ————) 100 > Inversion 5Oyp Invension onstqunatton “50%, retention +2 \ ston ot 1 oX 7 7 Net chy Slow alep ts Hale Scanned with CamScannerq ———__+ Ct. + 0h —> ch c~ nh oo ai ot _ CHa a ee — p-Eurmin nee : rs i ie product _ Y v B-« ‘elim OP mation “ts abwous Y Produce Alkene x re (h—CHy— Ch + KOH——> Cha = CH + KCL + he tl e ao No. “elimination ch, OEFINITION . [ee oy oS — ‘ueeulon yaadin ___- moleculant veatbn aire HAE ~ ALKYC HO ay aie Scanned with CamScanner~ MOLECULARITY Brmolecularc — Unimolecul ‘RDER_OF REACTION ; St oydley nd ones MEDIUM non - pole _ HYBRIOIZAT# IN: p3_ Spe sp* “?- —~ EXAMPLE a o_| CHy-CHa-CL_+ KOH Ho—C— hl ca-€* +a] CH3 - cH Cty et CH, = CH, +kC+H,0 et + ON ee tp +H20 canbocaiio oj” Step 4 Su, is Same 4 ee eee __ Scanned with CamScanner