UBNDTINHBACNINH = BETH. $6 GIAO DUC VA DAO TAO eee Mon thi: Hoa hee yb CHINE THC ‘Thi ian lm bis 150 PI (Dé thi'cé 02 trang) 1=35,5: K-39: C8 =40: Ba= 137. rhea hoe: Cho: H= 1; C= 12; N= 14; O= 16: Na= 23: Mg = 245 Al= 276 Fe=56; Cu 64; Zn = 65; Br= 80; Ag = 108: Thi sink King diege sit dung bing tui hodn ede nguvert Cau 1: (2,5 diém, 1. Mot s hop X gdm ede chit: K20, KHCOs, NHACI, BaCl: &6 6 mol mbi eit bing nhau, Hea tan hdn bop X vio nude, dun nhs, si khi phén ing xdy ra hon todn thu duge khi ¥, dung dich Z vi ket tia M, Vide prong trink da hoe ella eae phin mg xy ne va ‘ic dinh efic chat trong Y, Z, M. 2. Chi duge ding thém | thube thir vi eée éng nghigm, hity trinh bay phuong phap hoa hoe dé nbgin big cde dung djch riéng bigt bj mdt nhin sau: NaHSO;, Na.CO;, NaCl, BaCh, NaS. Cau 2: (1,3 diém) 1 Tir tink bt vi eleschlé wt ox (shdng: shifa nguyén (6 cachon) can thiét khie, diéu Kign c6 di, hy viet ede phuong trink héa ge digu ché regu etylic, axit axetic, etyl axetat, 2, Xa phng hoa hoin toin a gam mot este don. chife, mych hérE bing 28 gam dung dich KOH 28%. C6 egn hn hop sau phin img thu duge 25,68 gam chit Iéag X va. b gam chit rin khan Y. DOt hy hod oda b gam Y, thy due sin phim gbm COa, Hh0 va K:co; trong dé téng khdi Jugng cla CO} va H:0 13 16,18 gam, MBC khie, cho 25,68 gam X the dung wii Na dir thu duge 13.888 li khi Hs (@ ea gid uj eda.avab, BEG RES, 85 ih ng tec goon ih Cin 3: (2,0 diém) 1 Mgr Min op Xbl glen Nr-vi Hi 66 1 kb so-vdi ideo 183.6 Sau kt binhop X moti gan 078 Hethik bp i th igen hp RLY ln Hace SHEDS s0 vi hide Ih 4.5. Ce Kido Seite eis en nhiee da, ol NH 4) Tinh think phin % vé thé tch ota mBikhi trong tin hop X.¥. b) Tinh higu sudt phin img xiy ra, 2. Nguyén tir cia nguyén 5A cb ting 58 bat co bin (et ‘ lectron, proton, nguyén tir khoi oda A khéng vugt qué 40. Neguyén tr eta nguyy Rotron) fa 60, 8 38 tg sh ateg tgs Trangvik tn thi sinh; Sé bio danh: 7 SO GIAO DUC, KHOA Ht VA CONG NGHE BAC Chir ky widen thi ts " NH LOP 10 THPT NAM HOC 2021 - 2022 * Mon thi: Hoa hoe (Chuyén) * Nighy this 34¢s/2021 * Thirt gia: 180 phat (Addn hi thot whan pelt el) DE (Cho biét; Ca = 40; Al= 27; Mg © 24; Fe = 56; Na = 23; Cu= 64; Ba 37; Zn = 68; C= 12;.0 = 16; H = 1; Cl= 35,5, Br = 80; Clu 1240 diem) od bgt (proton, clectr = 32). . va nutron) tromg nguyen tir nguyen 1 X bani 58, Trong db, 36 hat mang difn nhitu hon sd ht khong mang din bling 18. Xe djnh dign tich hgt nhin eda nguyén ti nguyéa td X. — (1.2.30) Neu high neg quan wit duge khi cho | ‘git dung dich jot vio dng nghiém dmg hé tinh bot, ssi d6'dun ndng phin dng nehigm (chim KO tinh Yr vi jot) trén ngon déy edn mde thoi gian rhi dé ngudl. — (b) Thue higa thi nghigm nhu hinh sau Ho ~_ & [ J-eaey s) bliny cde phitn img héa hoe nay ra vl nae djnh khi ¥,— thay thé. Rein (CaCs, AlsCy) boi rin (CaCO), Nag$O)), Nuc trén phdu chiét qui-lé bing dung dich axit clohidric. Vidt, odin bing cic phin Ong xay en wa xde dinh khi¥. (C)Hai bink khi Cle vb O; déw ed Un hoi nude: Cho bié. CaO (riin) lam kho binh khTndo? Tal sao? + (Caw 23(4.0 diém) ‘ Q,)) Hoan thanh chudi phin émg hoa hoc sau (mit mi tén 1A mot phan éng = ghi v8 id c hig é tal coy as) hoa hoc, ghi rd diéu kige thye hign phiin dng met eo). > 2 Fe(OH, ——>xC6 ede chit rin mau tring trong ete Ip Feng bigt gam: CaCO; BaSOa, NayCO} vi NaCl. Chi ding nude vi mt thude thi khiie hay trinh bay céch nhan cde chit trén, Viet va cin bing cle phurong trinh phan img xay ra néu co. 2 (4,0 diém) Aly Phin dng hon toan 4,17 gam hon hop gém Fe va kim logi R ed 11 mol eee img 2: | trong dung dich axit clohidric (ding du 10% so vi lurgng phan img), het thie ede phan ima hoa hye thu duge dung dich ¥ v4.0,105 mol Ha. — (a) Vide wa cin bing phin tmg hoa hoe xy ra. X8c dinh kim logi R. — 6) Dé phan img dung dich Y can thé tich dung dich NaOH 0,5M lon nhat 1a Y. Viét.va cain biing efe phin img hoa hoe xay ra dong thai tinh gid’ tr] Y, Tién hinh dign phan adng chay 1,02 tin nhdm oxit bing dign cye cachon 6 criolit vei higu sudt 28% dime m ke nhom. Viet va can bing phuong. trinh phan img ddng thoi tinh iid tr] mn. Cau 4: (4,0 diem) 4.1. Nhiét phan m gam mau dé voi chia 85% canxi cacbonat (con lei ‘ep chat tro) voi higu suit 90%, khi sinh ra hap thy hoan toan vao nude voi trong, tien hinh toe duge dung dich Z va 2,0 gam két tha. Cho lung du dung dich Ba(OH)2 vito Z duge 8,91 gam két tha, Viet va can bang ede phuong trinh phan img hoa hoc xay ta. — Tinh m. 7% 4.2, Cho tir tir dén hét V ml dung dich H2SOs 0,1M vao coc thiy tinh dymg dung dich co 0,05 mol BaClh, loc bé phan ket tha duge nude Ioe Z. Trung hoa Z edn dung dich c6 0,35 mol NaOH. (4) Viet vacan bling cde phuong trinh phan tmg héa hoc xay ra. —— (by) Tinh V. ; CAiu 5: (4,0 diém) !) Bét chdy hoan ton 2,08 gam hén hgp T gim (metan, etilen va axetilen) trong khi oxi vi dd, thu duge 0,15 mol CO2. Néu phan (mg hodn toan 0,045 mol hon hop T can t6i da dung djch ¢6 hoa tan § gam Bro. Tinh phan tram khéi lugng etilen cee hon hop. + Dét chay hodn toan 6.9 gam hin hop X g6m CyH2.-\OH (n> 1) va Cin-lanei COOH (m = 0) trong khi oxi vira di, thu durge 0.24 mol CO: va 0,33 mol Cau 1:0. Xie djnh e6ng thire cau tgo thu gon hai chat hitu eo trong hén hyp X. — g Thue hign phan img este hoa Inong hén hop X trén (xtie tée H2SO% dc) — voi ie suat phan Ge dat 55%, thu due m gam este, Viét phurong trinh phan img este héa va tinh m.— — HET Liew ¥: Hoe sinh khang diege ste dung bang tidn hoan ede nguyén 16 héa hoe,KY-THI TUYEN SIN LOP 10 THPT SO GIAO DUC VA DAO TAQ TAS Hoe Dual =a oA Mén thi: HOA HOC Ney tie 14/6/2021 (Ba thi gdm 02 rang) ‘Thoi gian Jim bai; 120 plait iim) i. cme jo targris va viet phuong trink héa hoe eda phin img xy ra trong ede thi nghigm sau: CC Nycho mot dink sit vio dung dich CuSO, x : wir 'b) Nh vai giot dung dich phenolphialein vio ce d\mg dung dich NaOH loting, sau d6 nh tir & dirdung dich HCI vdo ede va khuly du, cane p 2)Cho: X 1a kim foal phé bién trong v6 Tri Bilt va c6 tinh nhiEm tir, ¥ ld oxit c& chita 72,41% X ve Eh6i lugmg; Z va T IA céc mudi khan cba X. Phan tir khdi cia cdc chit Y, Z, T thda min diéu kign: My+M 38-4 val Mr— Mz = 248, a) Xie dinh cing thire héa hoc cia X, Y, Z, T. 6) Véi cde chit X,Y, Z, T 6 trén, vide ede phurong trinh hdathoe thyc hign so dé chuyén hoa sau (ghi r0 didu kign néu e6): Yepox—957-057 Cau (2,0 diém) xe dinh xem thyre vit.c6 hé hép hay khdng, mGtban maw wr pas ee hoe sinh 43 lama thi nghiém nhur sau: Cho ede hat ny mam = vio binh dirgc néi véi Ong din khi ahwr hinh ve bén, Dan Khéng khi-vao éng nghiém 1 dymg dung dich KOH du. Khi thoutrakhdi ng nehiém I dure din qua éng nghigm 2 dung nude v6i trong dur. Kbf thoat rakhoi Ong nghiém 2 duge din feel acter > tiép vio binh chia hat nay mim. Dé khi thodt ra khdi binh TT i Te Ae 7 ima més th gian ri moi cm du 6ng din khi vio dng nghiém 3 dung nue vi trong it Ket thie thi nghigm, ¢ éng nghiém 2 khong 6 hign tugng gi cn Ong nghiém 3 thiy xudt ign vin duc mau tring. #) Gidi thich vi sao phai din khong khi qua dng nghigm 1 vi i iin vi pike ta ae phi 1g Khi qua Ong nghifm 1 vi éng nghigm 2 true khi din vio ,__ ,0) Gil thich vi sao phi dé khé thost ra khéi binh chita hat ‘ny mim m6t thoi gian ri moi cim dau Sng din khi vao ng nghiém 3, ¢) Dyn vao két qua thi nghigm trén, két lun the vit 66 hd hip kshOng, Tir d6 cho biét e6 nén 48 nhiéu chu ngim hat giéng trong-phong ngit khong, vi sao? 2. Tai mt phong thi nghiém, dé kiém tra him lugng hidro sunfua 6. trong mau khf Ay tir mot Khu dan cu, nguéi ta.cho miu khi dé di vio dung dich déng(tt }) sunfat dur v6i téc d9 2,5 livphit trong 400 phiit (gia thiét chi c6 phan dng: HaS + CuSO, > CuS + SOx, phin img xy ra hoan ton). Loc ly Két tha, lim kh6 thu duge 1,92 me chit rin mau den. Biét tai thoi diém nghién ciru, theo tiéu chudin Viét Nam 46i v6i khu dan ew, him lugng hidro sunfue trong khong khi ‘Khong duge vurgt qué 03 mg/m?. Xée-dinh him Iugng hidro sunfua e6 trong mfu kititrén vi cho biét khdng khi tai khu din eu dé ¢6 bj 6 nhiém khong. Cau TM (2.0 diem) Hop chit X.cé céng thite ABs. Téng s6 hat proton, notron ya electron trong: mgt phin tir X 1a trong 6 sé het mang dign nhiéu hon s8 hat khang mang dign la 70. Nguyén tir A c6 s6 hat proton bling 86, hal notron. Nguyén ti B ¢6 tng s6 heal trong hat nhin nhidu hon 56 het 6 lép vo 1a 18. Xée dinh 36 higu nguyén treba A va B, 2. Hip this hét 4,928 gam khi CO, bang dung dick ehita hon higp x mol Ba(OH)y vay mol NaOH thiu dirge 5,91 gam Ket tia vardung dich chi chita 8,708 gam mu6i, Tim gid tj cua x vay.@kibaiaa hon ton m gam ha hop X-gbm FeO, FeO, FesOu bing 350 gam dung di HCI 146% inrduve dang dieh Y. Dé trung hoa luong axit dur trong Y cin ding 140 ml dung dich KOH 2M. Mat hic, dé Khir hodn todn m gam X think kim logi cain ti thiéu V It (kte) Khi CO, Tim gié t cia V. Caw IV 2,0 aiém) : @ ‘Cho 22,62 gam hdn hgp X gbm NaOH, NazCOs, CaCOs, Ca(OH)2 the dung hét voi dung dich HCI dir thu duge 3,36 lit (dkte) khi CO: va dung dich Y. CO can ¥ thu duge 18,72 gam NaCl va m gam CaCl. Viét phurong trinh héa hoc ctia ede phiin img xy ra vA tim gid trj cia m. 2. Héa tan hét m gam hdn hop X gm Zn, S, FeS2, FeS, CurS, MgS bing dung dich H2SQ, dc, néng thu duge dung dich ¥ chi chia ge gam hén hgp céc mui sunfat trung hoa va 8,4 lit (dkte) ‘chi SO2 ld sin phim khirduy nit. Thém tirtir dung dich Ba(OH)2 vao Y thu duge t5i da 33,165 gam ‘eét the. Tim gif tr) ctiam. Cau V (2,0 diém) 1, Cac chit hitu co X, Y, Z, T déu o6 céng thire dang CxH2xO, (Mx= My < Mz = Mr < 100). Bi ~ Chat X phin img duge vai dung dich NaHCOs; ~ Chat Y phan img duge véi dung dich NaOH (dun néng) nhumg khéng phan img duge véi Na; - Chat Z phan img duge v6i dung dich NaOH (dun néng) va phan img duge voi Na nhimg khéng phan img duge v6i dung dich NaFCOs; ~ Dung djch chat T lam 40i mau quy tim thanh d duge bing sé mol T tham gia phan img. Xe dinh céng thite edu tao ca X, Y, Z, 2. Hén hyp X gém hai hidrocacbon mach hé ¢6 céng thie CuHzee2 va CaHoa:2; hbn hop ¥ gdm CulLN va CsHON. Tr)n X véi Y theo ti 18 mol tuong img 182 : 1 dupe hn hyp Z. Bét chéy hon (oan 10,28 gam Z bang O2 vita di thu duge sin phim ehéy chi gdm CQ2, HO va Nz. Diin toan bo san phil chy vio bin dumg nuge voi trong du. Sau khi phan tg xiy ra hodn toin thy o6 kh thot ra khoi binh, kh6i rong bin dymg nuéc voi trong ting 41,56 gam va c6 56 gam két tla. Mat khéc, din X qua dung dich brom du thi 6 t6i da 0,04 mol Br tham gia phan img va khi lirong binh brom tang 1,12 gam: Xéc dinh cOng thire phan ti eta eée hidrocacbon trong X. = 12; N= 14; O = 16; Na=23; Mg = 24; Al =27; P= 31; $ = 32: c} = 35,5; = 56; Cu= 64; Zn= 65; Br= 80; Ba= 137. G Thi sinh duege dung méy tink dm tay khéng c6 chie nding tha, phe vas luew trie de Tig Géin 6 coi thi khong gidi thich gi them. f ; Ho va tén thi sinh, wee $6 bdo danh:....... 2 va chir ki ciia edn b§ co} thi s6 1: Ho, tén va chiki cia cin b6 coi thi s62:>VADAOTAO —_ KY THI CHQN HQC SINH GIOL THPT CAP TINH. BO GIAO DUG YEN WRN ge Bic aee MON: HOA HOC be Ngiy thi: 30/3/2022 i ‘Thot gian: 180 phut (thdng ké thot gian giao da) (We thi cd 02 trang) - — INH THUC| Cho khdt long nguyen tie trung bin (g/mol) cdc nguyén 16: H = 1; He = 4; C= 12; N= 14; 0 = 16; Na= 23; Mg = 24; Al = 27, S = 32; Cl = 35,5; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137 vi ditu kign tiéu q chiukn duage vidt tit I dkte, R'= 8,314 J.mot“)K"! = 0,08205 Latm.mol-!.K-" | (2,0 diém) Khi A co ti kh6i hoi so véi khOng khi bling 3. Khi téc dung voi nude Ignh trong béng ti, khi A {go nén axit B. Axit B niy e6 kha nang chuyén thinh hai axit C vA D. Sin phiim nhiét phén cla khi A, Khi di qua dung dich KOH, tiy diéu kign, c6 thé tao nén mudi cia hai axit B va C hay mu6i ea hai axit C va D. Cho biét mudi kali cua axit D chia 31,8%K va 39,1%0. Hoi A, B, C va D 1a nhting chat ét phiong trinh héa hgc cia nhting phan img xay ra 2,0 diém) . Néu hign tugng va viét phuong trinh héa hoe cla cfc phan ting xay ra trong mdi tal nghigm sau: 8) Héatan hén hgp gbm AliCs vA CaC> vio nude lay du. ) Cho tir tir khi $02 dén dur vao dung dich KMnO. ©) Din khi sinh ra ti phan img gitia Ca(OH), va NH1Cl (dun néng) vao dung dich CuSOx 4) Cho dung dich AICI; vio éng nghigm dyng dung djch NaxCOs. Cau 3: (2,0 diém) tan hodn toa m gam hn hop chit rin X gdm Bs, BaO, Na va Al:Os vio nuée chi thu duge i dung dich Y va 6,72 lit khi He (dtc). Nh tr ti dung dich H»SOs vo dung dich Y thu durge két ta hu d8 thi duéi day, tinh m, hi lugng Két tha 6 mol H,80. loing | 03 oe Cin 4: (2,0 diém) : "Hoa tan hon hgp gdm ba mudi: MgCh, FeCh va CuCh vao nude dé duge dung dich X. + Ly ra mot Iugng ahd dung dich X, sau 6 thém dung dich NaS di, thu duge mot Iugng két tia gap 2,51 lan kh6i lugmg cba két ta cuge tgo nén khi syc dur khi Ha$ vao cling mot Ivong nhé nhu trén cia dung dich X. ee = Néu thay FeCls trong hdn hgp ba mudi trén bing cing mot khéi lugng mu6i FeCl va lip lai qua tinh thi nghigm hr tren, thu duge k&t qua ld iugng két ta tgo nén ki téc dung voi lugng du Nax$ gap 3,6 lan lugng ét tia tao ra khi syc du khi HLS, _Xée dinh thanh phin % vé khOi Iugng cla méi mudi trong hén bgp. Go ee hndn hop X gdm Mg, FesOy va Fe(NOx) cin vira du dung dich hin hop gdm 1,12:mol HCI va 0,08 mol HNOs, dun abe thu duge dung dich ¥ vi 2.24 lit hén hop kh Z. (Ake) 06 ti kk6i hoi 461 oa Ha bing 10,8 gdm hai khi khong mau trong 46 c6 mot khf héa néu agoai khong khi. Cho dung dich ¥ thc dung voi mOt long dung dich AgNOs vita di thu duge m gam két tia vi dung, dich T. Cho dung dich T the dang voi mt lugng dur dung dich NaOH, 1oc két tia nung dén Khoi hugng ‘khong di thu duge peppates \ ‘rin, Cc phan ting xy ra hoan toan, Tinh m. = quye’Chu 6 (0 diém) ~ hi crackinh butan go ra hn hgp ankan vi anken trong dé e6 hai chét X va Y. Ti khdi hoi cia X 80 voi ¥ biing 4/7. a) Tim X, Y. b) TWX tim duge 6 trén, viét cde phan img chuyén hoa theo so d® sau: X RUE > a tat 4g thot yy yy j Xa. yp 00", p_ wear gy Chu 7: 2,0 aidm 4 2 ‘Mi binh Kia chita hn hop khi A gdm: axetilen, vinylaxetilen, hidro (0,6 mol) va mét it b6t niken ita 2 » ; (bieE ALG 9S. = =). Nung néng binh mot thoi gian, thu duge hén hop khi X c6 ti kh6i so véi He bing 9,7. Khi X phin img vita dit véi dung dich chia m gam AgNOs/NEG, thu durge 0,2 mol hn hop két {ta va 6,72 it hbn hop kif Y (dktc) c6 kh6i lugng 11,48 gam, Khi Y phan tmg ti da v6i 0,16 mol Bry rong dung djch, Tinh m. Cau: (2,0 diémy Chia 0,06 mol hn hop gbm hai ancol dom chite mgt lién két doi) thanh 2 phan bang ahau: “Phan 1: Bem oxi héa béi CuO du, nu AgNOs/NH; du thu duge 11,88 gam Ag. "Phan 2: Cho vio binh kin ¢6 dung djch 5 Iit, sau 46 bom Or vio, nung néng binh dén 136,5°C 48 ‘hoa hoi hét thi 4p suét trong binh hic nay 1 0,8736 stm. Bét tia lia dign 48 d6t chay ancol an ting Oz vin cn du) rbi dua vé nhit d6 binh & O°C th 6p sudt trong binh lie nay 1a 0.3584 hong ding ké), a) Tim cdng thite cua ancol X, ¥ b) Tir CaCa va cde chit v6 co cin thids, lp mot sor 48 phin img ditu ché ¥ (c6 mach C kh6n, phin nbant). Cau 9: (2,0 diém) | Hidrocacbon A (CsHia) téc dung voi HCI thu dupe B va C déu e6 cdg thite phan tir la Ce#ysC Dun néng B véi KOH trong ancol dugc chit D li méi dng phin cu tgociia A. Khi ozon phi D' thu dupe chit E, biét rng B c6 phan Ung iodoform nhung khong cho phin tg véi (Gung die AgNOs trong NFL). Czon phan A duge F vi G, ci hai déu cho phan tmg vei thude the Tollens. Trong mi truéng kiém NaOH, F va G phin Gag véi nha tgo HCOONa va met ancol ba, mgt H. a) Xéc din cfu tric phin ti cia tt cd cdc chit A, B, C, D,£, F, G va H. b) Viet phin img cia A v6i HCI, giithich r sy tgo thdah B vi C blag C4n10: 2,0 diém) . Gas duge ding khé phd bién ding im nbn itu dun nu 6 nhidu gia dinh ethan phn chinn Bropan va butan, 020°C, gas tn tu trang thi kh, Tuy nhign gas duge héa long 8 tien Ig ens bio qin, vin chuyin vis ding. Kh hin aién(ihinh phn chi It metas) duge ing lk ahien fo nha may nhigt dign khi va cung edp cht d6t 6 nhidu h6 gia diah ving én d6i, Bién thién enthanpy chuin eta phda img d6t chy 1 mol metan va I mol gas (v6i tile mot CH, y, (CaHio turong tig 1a 2:3) duge tinh théng qua céc gia tr ning hromg lién két: . Litnkét | CH [cc 0-0 C=O On E,(dimol) | 418 346 494 732 459 So sinh nhigt lugng gidi phéng ra khi dt chy 1 mol gus va I mol metan? th ha X, Y (Mx < My) (no hole khOng no, ¢6 néng cho toan b6 sén phim di qua dung djch 8 phan tmg. HH CBCT hing iat unten gh tay ‘$6 bio dank areKY THIETUVEN SINIELOR 10 NAM HQC 2021-2022 BND TINE THAD NGUYEN $0 GIAO DUC VA DAO TAO % aoe ee ia tine ee Dee a ke thd gina gina aE ‘Thi gglan tam bai: 180 phot, leh FT eee tag gb 12) ca 1(2,0 did): Seat A nee! itn. Fipp chit khi ca A vel bidro va oxit cao ——phitretis A of efing thie hia hye 1 lugt 1A HA (B) va AxOx(T)- ‘a, Tim nguyén (6 A. Biét khot Iugng mol phiin tir etka T php 5.0137 in knit iurong tol phiin tir ofa Bs tb, Biét phn tt Ax 1A don chit tao bol nguyen (6 A. Xie dinh ebag thie hod hoe otis cde chit: X, ¥E, F, G, Hh D (chdog edn gidi thich) vi viéx PTHH cia cde phin img xdy ra theo so 0 sau (mbi mii 1én tuong, (mg vei mot PTH): “yf yop ig A MEG Epo ae ot Clu 2 (1,0 diém): Cho 3 hidrocacbon A, B vi D du o thé khi trong diéu kign thutme, “phiin ti cila ching c6 cling s6 nguyén tir cacbon.. a, Xie dinh cng thite cfu tao ede chit A, B vi D, Bit B vi D déu tam mbt mau dung ich brom, tir D co thé diéu ehé axit axetic bling 2 phin img. ‘Vidi PTHH otis ede phan img xy ra ae b. Trong phomg thf nghiém, qué trink diéu che khi D thuéng bi lin $02, Bé loai bd $0, ra kidi hn bgp khl gam D vA SOx, 06 thé ding dung djch chim chit nio trong, cic chit (riémg bige) stu diy: BaCls, Ca(OH), Bry v4 KaSOs. Gili thich va viet PTHH cba vée phan tg xiy ma. Clu 3 (1,0 didm): Xho dinh céc chit Xs, Xe... Xe, Xo vie hodn thinh PTHH cha ede phin mgr sau. Bidt Xe 18 mpi mudi trung hoa. (1) Xa + Xa— Xp + HO. (2) Xs+Xa+ HO —> HCL +H:S0x (3) X4+Xs—+ Fex$Ou)s + FeChy (4) X+Xa-+HsSO«—* + Xe+ NaSOs + K2S04+ MnSO, + 10 (5) Xu+ Xi—s NwSOy + (NH4):50. + CO2+ H20 Chu 4 (1,0 diém): Cho e&c Io mit nhan chia ede dung dich vi chlt long riéng bigt sau: “penian, dung dich glucozo, ety! axetat, ancol etylic, dung dich axit axetic, Trinh bay, phiromg phdp hoa he phan biet cde dung djch vi chit ling trén, viét PTHH eda cde phn img xfy ra. Cau 5 (1,0 diém): Nung a gam bOn bgp A gom KCIOy va KMnO., thu dupe On va. chdt Fin B gim KCI, KaMnOs, MnOz, KMnO4, Trong B 06 2,98 gam KCI chiém 19,893% theo khdi lugng. Tréin toan b> ig. On 8 trén vai khéing Ichi theo ti 16 thé tich lin lugt 1a 1: 4:thu durge én hop khi D. Bét chdy hét 1,056 gam cacbon bing hin hgp D, thu duge Hse BAPE den SHA On Ny Oa AB. cin so vl la 1605, Bit rong hg Wni 66 80% No vi 20% Oa theo thé tich, cdc khi déu do & cling diéa kién nhigt 4} va tp "suds. Vidi PTHH cia cde phan tmg xity ra va tinh gid tr] ota a ee 1* Cin 6 (1,0 didn): Cho dang kht co du él qua bog str ning nding chem earn Bla BT, Cae te a Kim iol A, (eons 8 on, Hint c g? 1 day sil, saa phan iin} ci eb fo Xr bang dog sr yk hoe ep KALI i aM ig 3 sn pi oe oy dng ch Be ts ve 5.61 we RM dung voi dang dich H2S0( 10% visa a, Kehna dhily 6 kh thedt ra, cba 193 1,92 gam Klin sume vd Se Jang wich Xs oO ui OD 1148 BE eke 8B SY odin tolit, ‘a. Vide PTEDH oa cic phim ting xy ra Nie dink tén kim Tog A, Bova ceding thite. boit boc cia ede oxit a8 dng. b, Hoa tan bet X ylo dung dich HCL Sau phin img, nbng 46 % cha bai madi trong. dung dich thu duge bing haw ‘Tinh in va % thea kh Jugng mi oxit trong % Cha 7 (h0 diém): Bé chiy hoda toln bidrocackon ‘A mech BS, thé khi ¢ dia Biga nie bg nd lagen, 4 el il thu dye thd fel Rew at WA Ft he vfs ee Kul tao ia phd tg (thé tie ee kh va hot dba do d cing didu kiga abit 66 vid 1). a. iGjnh dng thie phita te vi cling thie ou tuo cia A, ‘b, Cracking hoin toan 3,3 gam-A thu duge hin hep B (chi gom 2 hidrocacbon). Din tote bin hop Bt Gr qua Dinh chia 62,5 ml dung dich Br ‘aM, phiin tmg xoag, thy dung dich brom maf miu boda todn, Ehi D thodt ra Khdt binh chia brom 06 tf hb! hoi so ‘vi Hy 1a 9.5, Niko inh gia tr] cha a, Saree aden): Hén bop A gim 2 chit had eg 21, X:. Cho m gam NBs top A BSE ‘me vim di vii 250 ml dug djch NAOH 2M. Sau phim tg dm duge 2 rmubl CHae|COON®, C)Hsy+)COONA va mgt ancol C-Ha-+i\OH. ‘Lly tin bo lurgng aneol cho fg bat vei Na, thu ize 3.36 I SH Mit kh, Wt ee, Ra ES hén-hop A can ding vira hét 6,496 1it Ox, this dirge §,824 lit COs. Biét thé tich cde khi dia do 6 dite. Mile dinh cbng thite cd tao cla Xt, Xo. Cin 9 (1,0 diém): CdS ig thu tinh ring bigt due dink 26 thi ny tt (1) 4B (5), mii lo gna Ot trong cic dung dich su: NuSOs, (CHCOORHA, Ab(SOuh, NaOH vA BuOK): Neuiri ta tidh hninh ede thi ngbifm smu day: = Thinnghitm 1: Rot dung trong lo (4) vio Io (3) bode To (3) dé tao ra ket ti, - Thi nghigm 2: Rev ti th 6 ‘der dung dich trong io (2) vio lp (1) thi e6 Et tha, san a6 két tir tan din to dung dich trong, = Thi nghigm Ret arta dim dis dung dich trong lo (5) vido 1g-(1) thi ed #t tis, vant 6 ita tn tp. ‘Stie dich chit tong img trong mbit , viét PTHH oda cdc pin tng xhy ra Chu 10 (1,0 did); Ngudi ta dieu ‘uncol etylic ta tinh bOt bing phiroug phip 1én ‘men, vei higu suit toan b) qué tinh 1a 90%4, Hip thy toln bp jung hi COs sinh rm chi is men x gan ch two ae 8 ong, hts 165 gan Bn eS Cho dung dich Ca(OH), vio ding dich A. du, thu thém éreg 60 arn Sls tha. Ti i cia x va thé tich ancol viylio 37,3° thu durge, Bit Khbi tugng ring cia ancol oe iron 8 PTI po = Cie e trong de tk: PTHH: ‘rink ha bo sn tid ch (Cha: Hol; C12) Nalds OnI6; Sad2s PST, Sears even Al=27; Mgo24 Fe=36; om ‘Mine55; dg~108; B= 137). (lige sink = sik dung tid | Ho vil thm thi80 GIAO DUC VA DAO TAO. KY THI TUYEN SINH VAO LOP 10 CHUYEN TINH DONG THAP NAM HQC 2021 - 2022 Mon: HOA HOC pb CHINH THUC Ngay thi: 10/6/2021 (é gdm cé 02 trang) Thai gian lam bai: 120 phil, Khéng ké thoi gian phdt dé Cho nguyén tie khdi: H=1; C=12 K =39; Ca =40; Fe CAw'1, (2,0 diém) 1) Cho go d0 chuyén héa sau: «oy Oy Natri hidroxit > Cacbon dioxit Viét cdc phuong trinh héa hoe xéy ra, ghi r0 didu kign phan sing (néw 0). 2) Thye hign cic thi nghiém sau: ~ Thi nghiém 1: Cho CH3COOH vaio CaHsOH (tle tde H28O, dic) rdi dun néng. ~ Thi nghiém 2: Din khi CoH, vao dung dich Bra. sm 3: Din khi C:H2 vao dung dich AgNOs/NH3. - Thingh 4: Cho (C1s1131COO)xCsHs vio dung dich NaOH rbi dun néng. ‘Viét phuomg trinh hda hoc xay xa tro c thi nghiém trén. ‘Cau 2. (2,0 diém) 1) Nhic dén gimg, dan gian c6 clu ca dao: Tay ndng chén mudi dia gitng, Gig cay, mudi mén xin dig quén nhau. Gimg la m6t loai thye vit thén cd, vi cay, trong gimg chia nhiéu hgp chat ha hoc ¢6 the dung dutoc ly hitu {ch cho sire khde, cla con newdi, Hay ké ten B cong dung clia ging. te gu Tg barb abon teagan finan gig ve | Pde aso oe 'S) Bling kién thite héa hge, &m hay giai thich mot sO hign tome thre tign sav: , din nhiét t6t, nhe, bén... Nhiéu d6 ding sinh hoot, dung oy néu an Lim tirnhOm duge str dung rOng ri trong gia dinh. Theo em, ching ta cé nén ding ndi nhom dyng canh chua dé qua dém khdgg? Vi sao? \b) Trdi cy 1a mot trong nbting loai thye phim bo sung mhiéu vitamin 6 Igi cho site hie cia con ngudi, Sau khi Sn trdi ody nhur tho, cam, nho, chiing ta e6 mén- dnh rang ngay khong? Vi sao? beeentr ‘/c) Mt $6 loai rau, of nlur rau muéng, t5i, kigu... thurimg duge bao quan bing céch ngam vao lo giim, day kin, Em bay giai thich ¥ nghfa cla céch lam trén? 2 0 be OF i ONES dla gicaen cu’ veh 42+ __ 3) Trong phong th nghiém, khi Z dug cen x29 140 gach dig ché nhu hin ve bén (Hinh 1). V a) Ki Z c6 thé 1a khi ndo trong s6 edo i sau; Ha, Ch, Calla, COn, O2. Ub) Viet phuong trinh héa hoe xay ra. \ A) Nhém Ia kim logi ¢6 tinh din diCau 3, (2,0 dim) 11) Hoi thanh ofc phuong trin hoa bog sau,» ¢ a) BaCh + NaHSO; —> A+B+C (ii ié mol BaCls : NaHSO«= 1), jwo Ht + +a b) Ba(HCO;): + NaOH —> X+¥+Z (ti lé mol Ba(HCO;)2: NaOH = 1:1). Le) Hoa tan hén hyp AlzOs va NaxO vio ‘HO du. 2) Cho eée hop chét hau co X, ¥, ZT cb cdng thie phn tir C40, C20, CoHsONE. Big: Qtigon -X, ¥ tde dung duge voi NaOH 6 diéu kign thudng. (8 43 0CHs > -X,T tée dung duge véi Na. - Z tac dung véi NaOH (cb mat CaO) ki dun néng thu due chit Kht 12 thanh phn chinh cia khf thign nhién, 2 : 7 Xée dinh cong thite edu tao thu gon eta X, Y, ZT. CHROCH, +d, vorNavhed ctl, Cau 4. (2,0 diém) phat de #o ? Clg (OOH \/1) Khir hoan toan 19,2 gam mt oxit kim loai ping 16,128 li CO & nhiét 49 cao (trong B va Biét dibu kién khing cb khéng khi) thu durge hén hyp Khi_X o6 ti khéi hoi so vei hidro 18 1 chit rin Y. Cho toin 66 ¥ tée dung véi dung dich HCI du, thu duge 5,376 it khi Ha. ce phan img xéy ra hodn tod, thé tich ede Khi do 6 digu kign tiéu chudin ( | a) Viét cde phuong trinh héa hoc xy ra. Oe aes +) Xie dinh cdng tite héa hoc oxit kim log. £25 ar Y 1/2) Dét chy hoa toan 0,06 mol hn hgp khi A g6m C2Hz va mot anken, thu duge 0,16 mol CO? va 0,12 mol HzO. Mat khdc, cho m gam hén hgp khi A Ii qua dung dich brom dur thi c6 0,05 mol Bro tham gia phan img. a) Tim c6ng thite phan tir cia anken. Cp b) Tinh gid trj cia m. -/ (OY Cf 5. (2,0 diém) 1) Nhé tir tir 200 ml dung djch HCl 1M vio 200 ml dung dich chéra NazCOs 0,5M va NaHCO: 0,5M dén khi phiin img hodn todn, thu duye V lit khi CO2 (do 6 dtc) va dung dich n aaa es 1018 xo dane eX foc yng eh th dem od 3. Tim gi tri ci V vam. 2%, 25 o Y cin 18,256 lit O (do & dktc), din san pham