Class + SMJK SAM TET IPOH. TRIAL EXAMINATION SEMESTER 2 UPPER 6 YEAR 2021 CHEMISTRY (962/2) PAPER 2 One and a half hours Prepared by : 1. En. Peter Paul Edward Certified by : Cik Tan Swee Imm 2. Puan Syawatul Yuslinda bt. Yusof Senior Assistant Form 6 Checked by Puan Carrie Lum Chemistry Panel Head Instructions to candidates: DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE ALLOWED TO DO SO. Answer all questions in Section A. een oP Answer all questions in Section B. SectionB | 16 Answer two questions only in Section C. 1 7 All working should be shown. For merical answers, units should be quoted RectionC whenever appropriate. Answer may be writien either in English or Malay Total ‘This question paper consists of 9 printed pages.Section A [15 marks] Answer all questions in this section. When 7.91 g NH4Cl is dissolved in 100 g water, the temperature of the solution decreased by 5.2 °C. What is the enthalpy of solution of NHACI? [Assuming that the specific heat capacity of the solution is 4.2 J g'°C"'; molar mass of NH,C1 is 53.5 2 mol") A 40.173 kT molt B +1.17kJ mol” C 42.18 kJ mol" 4 +148 kJ mol! C2Hp reacts with Cl) to form C7HsC1 and HC! under standard conditions. The standard enthalpies of formation of HC1 and CHsC1 are -92 kJ mol and -137 kJ mol” respectively. The standard enthalpy change for the reaction is -144 kJ mol. What can be deduced from the reaction? A GoHsC1 is less stable than CoH. “R. Standard enthalpy of formation of Cz is 0 kJ mot KJ mot" C Standard enthalpy of formation of C2Hsis| D Standard enthalpy of combustion of C:HsC1 is -85 kJ mol". ‘The standard reduction potentials of several species are shown below. Cr,07"(aq) + 14H"(aq) + 6c" 2Cr** (aq) + 2H2O(1) B® =+133V Cu” (aq) + 2e° sS Culs) E® =+0.34V Mg” (aq) + 2e Ss Mg(s) EB? 37 V Br(aq) + 2e S 2Br (aq) FE? =+1.07V Which statement ig(rup based on the data above? A, Mg(s) is a stronger reducing agent than Cu(s), B Cu(s) acts as the anode in Cu/Mg electrochemical cell. C Cu (aq) ion reacts with Cr** (aq) ion to form an orange solution. D NaBr reacts spontaneously with acidified Cr20;" (aq), Cu?" (aq) and Mg” (aq) ions. A Cu” (aq) | Cu(s) half-cell which contains 250 cm’ of 1.0 mol dm CuSO, is connected to a standard hydrogen electrode. The voltmeter reading is 0.34 V. What is the reduction potential of the cell if the concentration of CuSO,, is reduced to 0.25 mol dm"? A +030V B+0.32V C+0.34V D+0.36V'S In the industrial production of chlorine, diaphragm cells are gradually replacing mercury cells in order to reduce environmental pollutions. Which statement is true about diaphragm cells? A NaOCl is a usefull by-product. B Platinum gauze is used as a diaphragm. “© Hydrogen gas evolves at cathode. D The level of electrolyte is lower in the anode compartment. 6. The rusting of irod is an electrochemical process. The half-equations of the rusting of an iron nail are given below Cathode: O2(g)+2H:0 (1)+4e" = 4OH(aq) E°=+0.40V Fe™ (aq) + 2c = Fels) Ee=-044-V Which is‘not trig about the process? Anod A Itoccurs at the anode. B It involves the formation of Fe(OH) >. °G Ihoccurs faster in a solution with higher pH D The oxidising agent is O> gas, 7. The first-ionisatiow energy of Period 2 elements in the Periodic Table ingrease’ across the period. Which statement does not explain the trend? A. The distance between valence electron and nucleus decreases. RThe electronic repulsion effect increases. C The screening effect is almost constant. D Nuclear charge increases. 8. The properties of elements can be deduced from electronic configurations. Which statement emg about Na’ ion, CI ion, Ar atom and K* ion? / ‘A Na’ ion is bigger than CI’ ion. B The charge density of Na’ ion is lower than that of Cl Nn The ionisation energy of K* ion is higher than that of Na’ ion. QCT ion, K” jon and Ar atom have the same electronic configuration.9. The decomposition temperature for MgCOs, CaCO; and SrCOs is given in the table below. Compound MgCOs CaCOs ‘SrCO3 ‘Decomposition temperature/>C 7) 900 1890 The factor that explains the variation observed above is paarliiiy porer , eG , ‘A anionic size ©)polaridabitity of cation B lattice energy D polariging poWer of anion polorvaaity 10. One mole of each of the following compounds is strongly heated and the gas evolved is collected at room temperature and pressure. to be collected? rom which of the following compounds is 24.4 dm* of gas likely [One mole of gas occupies 24.4 dm’ at room temperature and pressure] A MgSO, B_ Mg(NOs)s © Mgcos D Mg(OH), 11. Solder is an alloy which is made of tin and lead. Which is the main role of tin in solder? A Lower the melting point B Resist corrosion & Increase conductivity D Increase lustre 12. Chlorine gas is bubbled into a concentrated solution of aqueous sodium hydroxide. The equations for the reactions are as follows: Cl +2NaOH — NaCl + NaClO+H,0 3NaCIO > 2NaC1 + NaClO; Which statement about the reactions is correct’? A One mole of Cl; forms one mole of NaClO}. B The anions formed are weak conjugate bases. “© The oxidation states of Cl changes from 0 to -1, +1 and +5. D The final reaction is fast at room temperature.Which of the following statement about the Group 17 elements and their compounds is not correct? A The boiling point of the hydrides increases in the order: HC] < HBr < HI< HF B The redueing power of the halide ions increases D The H-Cl bond is more polar than the H-I bond din He goip The elements show a constant oxidation state of -1 in their compounds ‘The graph below shows the standard reduction electrode potentials for M’*/M and M**/M”* ions. 14 EM 2 Coto” Based on the graph, the ions that could be found when theCmetals titanium chromium, manganese, iron and cobalt are placed in an acidic solution containing oxygen would be cr", Mn, Fe, Co” c Ti*, Cr", Mn™, Fe”, Co “RTI, Cr*, Mn”, Fe* D Ti, cr’, Mn™, Fe", Co™ 15. Zn** ions form a white precipitate, Zn(OH)>, with an aqueous solution of ammonia, The white precipitate dissolves when a NH,CI solution is added to it Which statement explains the observation? 4A soluble ZnCls compound is formed. B_NHs, molecule is a stronger ligand than OH NH" C NHB, ions inerease the solubility product of Zn(OH) 2 D_ 4h, ions decrease the concentration of OH ions in the solution NH Objective Answer sheet Be Ee Bee Lar 5 <6. =A ve. 10. Lue 12. 4 ___ las)Section B[ 15 marks ] Answer all questions. Write the answers in the spaces provided. 16, Consider the following cell notation below ‘Sn(s) / Sn*"(aq) , y mol dm” // Cu” (aq), 1.0 mol dm?/ Cu(s) The cell is built from a tin electrode immersed in an aqueous solution containing y mol dm“ of tin (ions, in equilibrium with an aqueous solution containing 1.0 mol dm*of sulphates ions, and a copper electrode immersed in 1.0 mol dm* aqueous solution of copper (I) sulphate. "Theft at 25°C, [Standard reduction potential, B° su /so= - 0.14 V, B® ca icu= +0.34 V] (i) Write the redox equation for the reaction occurring in the electrochemical cell. uy) (ii) Calculate the molarity of tin (11 in the electrochemical cell. (4) (iii) Explain the effect of the cell potential if the concentration of Cu”" ion is decreased to 0.5 mol dm”*, (21Compound ¥ is a sodium halide. It reacts according to the following flow-chart, Mixture of brown | <— —{ vy _ | Precipitate white Fu ee mes | concentrated H,50, AgNO, sliced capamle me NH, (aq) Brown solution Insoluble | cet [ Woe orc (i) From the reactions above, identify the halide in Y. ul (ii) What is the colour of the precipitate formed with AgNO3(aq) ? i) (iii) Explain the role of the concentrated sulphuric acid in its reaction with compound ¥. [1] (iv) Write balanced equations for the reaction of Y with concentrated sulphuric acid. (3) (¥) Identify the anion in Z and state the type of reaction that Y undergoes to produce the brown solution . C2 Anion in ¥” Type of reaction is : m1Section C[ 30 marks] Answer two questions only. 18. (a) Describe the chemical reaction of Group 2 elements with water. [4] (b) Explain the solubility of sulphates of Group 2 elements, B3] (c) The decomposition temperatures of magnesium carbonate and and strontium carbonate are 540°C and 1890°C respectively. Compare and explain the relative thermal stability of magnesium carbonate and strontium carbonate, {8} 19. (a) Describe and explain how the volatility of Group 14 tetrachlorides changes when going down the group. B) (b) (i) Explain why the +2 oxidation state of lead is more stable than the +4 oxidation state. [3] (ii) Carbon burns in air to form carbon dioxide but lead burns in air to form lead monoxide. Explain. 2 (©) Nearly 95% of the earth’s crust is made up of silicate minerals and silicon compounds. It has a basic unit in all types of silicates that could exists as discrete units or polymerises into larger units linked together by oxygen atoms. Describe how the chain silicates are formed in pyroxenes [7](a) (i) What is meant by transition element’ iin (ii) Ti(1T1) compounds are coloured but Ti(IV) compounds are colourless. Based on the electron configurations, explain why both compounds have different colours. [5] (©) (i) Define the terms complex ion and ligand. 21 (ii) The structure of an aqueous complex ion which is pale blue in colour is shown below. Give the IUPAC name of this complex ion, and state its shape. Describe the type of ligand(s) present(s) in this complex ion [6] ° 2- (iii) Draw the structure of complex ion with formula of [Cu(H20)6]**. [1] End of question Paper ( Don’t give up , all the best