Page 1 Safety Data Sheet ace. to OSHA HCS Printing date 05/01/2015 Reviewed on 0510/2015 (ee iter ‘Trade name: Penetrant BY-LUX 1.2 Relevant identified uses of the No further relevant information available Application ofthe substance the mixture NDT Inspection penetrant stance oF mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Sherwin Incorporated 5530 Bomtick Ave South Gate, CA 90280 Phone: ($63) 861-6324 Fax: (582) 823.8370, hits Jaw sherwinine.com! Information department: Product safety department 1.4 Emergency telephone number: Chemtrec +1-800-£24.9900 in U.S.A; outside U.S.A. 001-703-527-3887 | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 | Asp. Tox 1 H304 May be fatal if swallowed and enters airways, Eye Dam. 1 H318 Causes serous eye damage. | Skin iit, 2 H315 Causes skin iritation, 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labeled according to the CLP regulation, Hazard pictogeams ros GHSo8 Signal word Danger Hazard-determining components of labeling: ‘Secondary alcohol ethoxylates Distlates (petroleum), hydrotreated light Hazard statements 315 Causes skin initation, 1318 Causes serious eye damage. 1304 May be fatal f swallowed and enters aways Precautionary statements 280 ‘Wear protective gloves, P301+P310___ifswallowed: Immediately calla doctor. 'P305+351+P396 If in eyes: Rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing 321 ‘Specific treatment (see on this label. aos ‘Store locked up, (Conta on page 2)ove ne 3 22 Coe Safety Data Sheet vV ace. 0 OSHA HCS Pring date 5012018 viewed on 0/01/2015 Trade name: Penetvant BY-LUX “| (Corts. of page *) 501 Dispose of contentsicontainer in accordance with localiragionalinationalinternations! regulations. Classification system: NEPA ratings (scale 0 -4) Heath Fie =" Reactivity HMIS-ratings (scale 0-4) =o ReAcTury a] Reactivity 2.3 Other hazards [Results of PBT and vPvB assessment PBT: Not applicable. PB: Not applicable ae | 3.2 Chemical characterization: Mixtures Description: Mixture ofthe substances listed below with nonhazardous additions Dangerous components: | ‘CAS: 64742-47-8 Distilatos (petroleum), hydrotreated light ‘s0-100% | ~ CAS: BBTST-AOS | Secondary alcohel ethowyates (3) 25-50% 4.1 Description of first aid measures After inhalation: Supply rash air. If raquired, provide arificial respiration. Keep patent warm. Consult doctor if symptoms persist in-case of unconsciousness place patient stably in side postion fo transportation ‘Take affected persons into fresh ait and Keep quiet. After skin contact: Immediately wash with water and soap and rinse thoroughly Ifckin iitation continues. consult a doctor. After eye contact: Rinse opened eye for several minutes under running water, Then consult 2 doctor. ‘After swallowing Do not induce vomiting: immediately cal fr medical help ‘A person vomiting while ying on their back shouldbe turned onto thelr side (Contd on pap8 3)ot wee = GC Safety Data Sheet ace, to OSHA HCS- Printing date 05/01/2015 Reviewed on 08/01/2015 (Cont of page 2) 42 Most important symptoms and effects both acute and delayed No furthar relevant information available 443 Indication of any immediate medical attention and special treatment needed [nie ume Penta SY-LUK | 45; Fire-fighting measures | For safety reasons unsuitable extinguishing agents: Water spray | 5.2 Special hazards arising from the substance or mixture Carbon monoxide and carbon cioxise | | “5.1 Extinguishing media Suitable extinguishing agents: Water haze Foam ABC powder | 5.3 Advice for firefighters | Protective equipment: ‘Wear sell-contained respiratory protective device. Wear fully protective su Ee ‘Wear protective equipment. Keep unprotacied persons away Ensure adequate ventiation 6.2 Environmental precautions: Ditte wth plenty of water [Do not allow to enter sewers! surface or ground water. 6.3 Methods and material for containment and cleaning up: ‘Absorb with iquid-binding material (eand, clatomite. acid binders, universal binders, sawdust), Dispose contaminated material as waste according 1a iiem 13. Ensure adequate ventiation Collect iquid in an appropriate container or absorb wth an inert material such as vermiculite, dry sand, or earth: DO NOT use combustib materals. Place ina chemical waste container 6.4 Reference to other sections ‘See Section 7 for information on safe handling. | See Section 8 for information on personal protection equipment See Section 12 for depot information Puli ns 7.1 Precautions for safe handling Prevent formation of aerosols | Information about protection against explosions and fires: | Use explosion-proot apparatus tings and spark-poat tool | ‘Containers may be hazardous when empty since residue Iqud and vapors may be present | | | 6.1 Persona precautions, protective equipment and emergency procedures | 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements Information about storage in one common storage facility: Not required, Further information about storage conditions: None _ (Conta on page 4)i. we 5 reek Safety Data Sheet — ace. to OSHA HCS 12015 Reviewed on 05/01/2015 Printing date 05 Trade name: Penetrant BY-LUX (Conta of page Additional information about design of tech 8.1 Control parameters Components with limit values that require monitoring at the workplace: ‘The product does not contain any relevant quantities of materials with crcal values that have to be monitored atthe workplace Additional information: The lists that were vald during the creation were used as basis | 82 Exposure controls | Personal protetive equipment: General protective and hygienic measures: Keep away trom foodsut, beverages and fed. Immediately move ti soled ond eonoranaid cthing, Week hands before Breas ond atthe end of work ‘old contact wih the eyes Breathing equipment in ase of oe expose o low pollaon use repratoy iter device. in case of intensive orionger exposure | Use resto potcive deve fate independent of Sreatng a | | | | Ventiation System: A system of local or general exhaust i recommended to keep | trrployeeexpoure ber the avoome esperar ins. enposue ete orcad lee trganie vapor resprotor (ype Al or Sef online breathing apperas. For ry powder | ‘ulsance exposure use type P96(US) or type PiEU EN143 particle respirator. For higher level protection use type OVIAGIPER|US oF ABEK-PZ(EU EN 143) respirator carvioges. | Protection of hands: ‘The glove material has to be impermeable and resistant to the product’ the substance preparation Selection ofthe glove material on consideration f the penetration times, rates of diffusion and the degradation Material of gloves “The selection ofthe suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is @ preparation of several substances, the Fesistance of the glove material cannat be calculated In advance and hae therefore to be checked prot to the application. Penetration time of glove material ‘The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Bye protection: Safety glasses Tighty sealed goggles Body protection: Use protective suit ‘on page 8)G Page 5 op Safety Data Sheet ace. to OSHA HCS Pringng date 05/01/2015 Reviewed on 05/01/2015 “Trade name: Penetrant BY-LUX Eins 9.1 Information on basic physical and chemical properties an General Information Appearanee: Form: Liquid Color: Rea Odor: Characteristic Odor threshold: Not determined pitvalue Not determined ‘Change in condition “Melting point/Melting range Undetermined. 240°C (484 °F) Decomposition temperature: Not determined Auto igniting: Product isnot seignting Danger of explosion: Product does not present an explosion hazars Explosion limits: Not determined Not determined, Vapor pressure Not determined Density at 20 °C (68 °F): (0.88 gic (74 bsigal) (ASTM D-1298) Relative density 0.874 20°C), ‘Vapour density Not determined __Evaporation rate Not termined. ‘Solubility in / Miseiblity with Water: Not determined Partition coefficient (n-octanoliwater): Not determines. Not determined Kinematic a 40 °C 45) mation avaliable, 33 Other information (Contd of page #) 10.1 Reactivity 10°2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition i used according to specifications 10.3 Possibility of hazardous renetions No dangerous reactions known, (Condon pane 6)Page 6 Safety Data Sheet ace, to OSHA HCS Printing date 05/01/2015 Reviewed on 05/01/2015 “Trade name: Penetrant BY-LUX (Cont of page 5) 10.4 Conditions to avoid No further relevant information avaliable. 10.5 Incompatible materials: ‘Avoid contact witn acetaldehyde, acids, chlorine, ethylene oxide isocyanate and strong oxidizing agents 10.6 Hazardous decomposition products: No dangerous decomposition products known. 11.1 Information om toxicological effects Acute toxicity: Information on hazardous ingredients Primary ievitant effect fon the skin: No iritant effect fon the eye: rong irtant with the danger of severe ay injury Additional toxicological information: ‘The product shows the folowing dangers according to intemally approved calculation methods for preparations: Iritant Carcinogenic categories 1 “Group 1 Careinagani to humans Group 2A _—_—Probably/carcnogeni¢ to humans Group 2B. Possibly carcinogenic to humans Group 3 Not classifiable as tots carcinogenicity to humans Group 4 Probably not carcinogenic to humans No component ofthis product present a levels greater than or equal to 0.1% i identified as probable, possible or canfirmed human carcinogen By IARC NIP (National Toxicology Program) None ofthe ingredients is iste ‘OSHA-Ca (Occupational Safety & Health Ad Aquatic toxicity: Information on hazardous ingredionts 68131-40-8 al ethoxy CEO! 48H). 1 mail (daphne) LC50V 96h 1-10 mgi Fish) 12.2 Persistence and degradabiliy No further relevant information available 12:3 Bioaccumulative potential No furner relevant information avaiable, 12-4 Mobility in sol No further relevant information avaiable. Ecotoxical effets Remark: Secondary alcohol ethoxylates: This surfactant complies withthe biodegradability criteria as laid down in Regulation (EC) No. €48/2004 on detergents ‘Additional ecological informati General notes: Water hazard clas 1 (Self-assessment: sight hazardous for water Do not alow undiluted product or large quantities of it to reach ground water, watercourse or sewage system. (Coma. on pog6 7)ace. to OSHA HCS Printing date 08/01/2015 Reviewed on 05/01/2015 wee _ sa Safety Data Sheet " Trade name: Penetrant BY-LUX Results of PBT and vPvB assessment PBT: Not applicable. -yPVB: Not applicable. 12.6 Other adverse effeets No futher relevant information avaiable 13.1 Waste treatment methods Recommendation: ‘Must not be disposed of together wih household garbage. Do not alow product to reach sewage system. Waste! unused products Collect all waste sutable and labeled containers and dispose according to local legislation Uncleaned packagings: Recommendation: Waste / used products Waste products and empty packages dispose of in accordance with local regulations. Emply containers may contain flammable residue and vapors Recommended cleansing agent: Weer, i necessary with cleansing agents RSs | bot Bulk: UN3082 | bor a | Rbk. impo, 1aT0 pot ppteate | atl. ASS | Se | DoT Bulk 14.4 Packing group bor Bulk th ADR, IMDG, IATA 14.5 Environmental hazards: Marine pollutant: No 1146 Special precautions for user Not appicabie (Contd on page 8) | | | I | 2, 1.1 UN-Number |-a Page 8 C Safety Data Sheet ace, to OSHA HCS. ringing date 05/01/2015 Reviewed on 059012015 “Traude name: Penetrant HM-1, HM-20 HM.3A, HM-408 (Com of pape 7) 14-7 Transport ta bulk according t Annex To? MARPOL73/78 and the IBC Code Not applicable ~ Not dangerous according othe above specications. | Quantity limitations. & gee ree YH oonccargo alreratt any: Na iit | Special marking with the symbol (ish and tee) 15.1 Safety, health and environmental regul Sara Section 385 (extremely hazardous substances): "None of the ingredients sted = Section 313 (Specific toxic chem legislation specifi forthe substance oF mixture ee ‘Chemicals known fo cause cancer: ~ None of the ingredients i sted, Chemicals known to cause reproductive toxicity for males: lone ofthe ingredients is listed — Chemicals known to caus developmental oxic jane ofthe ingredients ie lsted, oo | “TLY (Threshold Limit Value established by ACGIH) [None ofthe ingredients is listed = ears apaLe were ase op Safety Data Sheet ace. to OSHA HCS Printing date 05/01/2015, Reviewed on 051012015 ‘Trade name: Penetrant BY-LUX (Con. otpage 8) {MOSH Ca (Wational Toatitte for Oceopatnnal Safety and Health) [None of ie ingreions toa = ‘15.2 Chemical safety assessments A Chemical Safety Assessment has nol been carried out “This information is based on our present knowledge. However, this shall not constitute @ guarantee for any pectic product features and shall not estabish a legally vali contractual elatonehip, Contact: Sherwin Incorporated Date of preparation / last revision 05/01/2015 /- Abbreviations and acronym: 208 Recer epeen reaver a marchanes sangre pa Rave (uepen fae {HD trnatoa’ atone Cave or Dangerous Goods 150r U8 Deparment ef ansportan {G5 honyrarrantaed Spey of Cseeson an Labtog ot Comeat cont amercan Content of Commer accra gens EENEGS. European iano fxg Commer Choma Sunlonces Lincs European Uso! hes names! uacane ES Cheri uate Seen axon ne marcan Charl Say) Sera nator te rectn sasosson SX) Sint Stn cortsonin, nae Cah Eye Dom Sofa eye araplee anton Naar Category # 1p Tort Asaton haar ard Slory = Data compared to the previous version altered.