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~ ct ae ee ee oe " XN nucleophile H ‘ Nem Haclaaphilie spbeaietion ¥ (po adil cuych tole A> chctac ne ve Subs 488) —$£$—_—_ chscthcl ——>| ciretC¥] — Cihemc 4p, (EA) Chas th tid > eB ehael cA (eathouoh) boas der Hef lax Mcaaphilie pbetinations © cHemel + Moor eat adr fx chcH20H + Mack “ent, Shere thee ethanol, C- eb hos hiyh DE att y ry Eni igh, semed heat fo Cog tine, . host mer refx CiscHs ol + Koff Cethanos) Memes vhs epate site uth ree: CH CHCl gy _exass als in ete cthef dite + nel bent in sealed tele = —— eben anine q “ detain fed My __, csc <1 - Hees [ov al ae 4 chy CH =~ cH 5 men - et a ; Cony? oe che) + chet c ; chek = - cnet et ete cl Tene conpovad Mechanism: So SM +g SN2 cnn -a L > [re a tf] —— cwepot ta- » of” OO ——— cevivated conplx (rot rel) Primary in ta 0sition st ate he eh 5M ots - oP sls slew, cw- iG + be cs oy se ‘oarpo cation vertiory (intermediate) (rel) on ——— (ch)scoy + o> fost A: SN 2 “primera OM, ( tertiary) one -Step te steps E transition Stete VY ) pethwoy geo fertinry corbe cation has 3 electron dora ety genps to veduce the positive charge, mabing it more stable So SM mechonigm ‘6 fovoured © steric find ance: betty a nyt ynan block +t he as tack of nucleophile from backside of CCl. So 5M neckonisn i¢ favoured: Maol cag) peat under reflex ch ore I" Milos ocitigied Has. Ay or Cream ppt Age white ppt pores dissolve dilate Hl conpletely diss dre cone: iy conpletely diseae conpletely disse “ FS chscty —O—> cen or Q Giz - ols £——— ca = ff AVE (fom forme) yellow ppt K x > CsCl cy (|) Jo 2 > chee how br oF /@ \X® Hao (H- oH) cts ~ cha CO: tho cise pao ot A nt reagent ond condition type Ha Mi heat elect rophilic add ton Ala 03. high T cracking Bre Aelegrattion oxidation. cold dilate £ma09(oH-) 2S aela0 toe combustion /rsidatin H20 cold cone. Has04 feltoused by wan Jo ch her EA Graig) er light BS WoW (0g) heat under reflux SGe@c0e. ECM (entionsl) heat cader reflux [bimination — D. pec bas Hf we iv i af ‘ Heol tens) POE y -CC-H + Nacl + H0 vim refx c . bey eliningti oH ee ‘ “§ vel 1 Meell (ethene) che = é-¥ + Mel tHpo H a 4 Hy 4 ! as cP bp be es + Waot (ethanol) ———>(Chb)p¢ -c = -H oS peony) tal +o beat onder ney lax Chrchol + Yacy Kew (ethanol) 3c see etal enced ket H chhoce popenenierie * cee th the ClpcHzWH2 + Heb heat it saied tale (toa heat under ep 4x CH= ca + Mad + ho oO rep one nitrile Hs JW) Inat scl prepone Ta dy exer CHa ChecHMf2 (reduction) dilate Msoeleg) heat 1- C eit Ch va) ops Teaqr Chchetl FWY hy dragas) Maoh (og) hat cH of coo Mat + Wh Chydrelgeis). “J che cach face ® \ CH cia Che He prepriys tens fammeble ow = toxic casy te be condensed liquid use refrigerant. solvent cect). propellawt Harm break O3 bayer CS tan Joremate chloring fore radiey andor u-V lpht. Os tcl ——» 62 +clO° a a: catalyst ClO +03 ———? 702 * ob" 03 —> 02 20; Hs 502

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