EC of A Co.

M/s. Benzo Chem Industries Pvt. Ltd. Dahej SEZ-II, Bharuch.
FORM – 1
(I) BASIC INFORMATION
Name of the Project. : M/s. Benzo Chem Industries Pvt. Ltd.
Location / site : Plot No. Z-103/D,
alternatives under Phase II,
consideration. Dahej SEZ Area,
Taluka: Vagra,
Dist: Bharuch,
Gujarat.
Size of the project * : Existing : 600 MT/M and
After EC Amendment : 600 MT/M
Expected cost of the : ₹ 225 Cr
project.
Contact Information. : M/s. Benzo Chem Industries Pvt. Ltd.
26/28-A, Cawasji Patel Street,
Fort, Mumbai 400 001.
Screening category. : Project Activity – 5(f) & 5(b)
Category – A
*capacity corresponding to sectorial activity (such as production capacity for
manufacturing, mining lease area and production capacity for mineral
production, area for mineral exploration, length for linear transport,
infrastructure, generation capacity for power generation etc.,)
Sr. Item Details

No.
1. Name of the Project M/s. Benzo Chem Industries Pvt. Ltd.
2. S. No in the schedule 5(f) & 5(b)
3. Proposed capacity/ 600 MT/Month
area/length/tonnage to be Plot area: 47613.19 m2
handled/command area/ lease area
/ numbers of wells to be drilled
4. New/ Expansion/ Modernization Modernization
5. Existing Capacity/ Area etc. Existing Capacity: 600 MT/Month
Plot Area: 47613.19Sq. m.
6. Category of the project i.e. ‘A’ or A
‘B’
7. Does it attract the general No
condition? If yes, please specify
8. Does it attract the specific No
condition? If yes, please specify
9. Location Dahej SEZ
Plot/ Survey/ Khasra No. Z-103/D, Phase II,
Village Tehsil Vagra,
District Bharuch,
State Gujarat
10. Nearest Railway station / Airport Bharuch about 50 Km.
along with distance in Kms. Nearest Airport: Baroda: 100 km
11. Nearest Town, City, District Bharuch around 50 Km.
M/s. Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 1

.
Headquarters along with distance

in Kms.
12. Village Panchayat, Zilla Parishad, Luvara Village
Municipal Corporation, Local Taluka : Vagra
Body (complete postal addresses District: Bharuch
with telephone numbers to be
given).
13. Name of the Applicant M/s. Benzo Chem Industries Pvt. Ltd.
14. Registered Address Plot. No. Z/103/D,
Dahej SEZ-II,
Tal: Vagra,
Dist: Bharuch.
15. Address for Correspondence:
Name: Mr. Sunil Shantilal Nawal
Designation(Owner/Partner/CEO): Director
Address: M/s. Benzo Chem Industries Pvt. Ltd.
26-28-A, Cawasji Patel Street, Fort,
Mumbai
Pin Code: 400 001.
E- mail: nawal@benzochem.co.in
Telephone No.: 91-22-43555851 / Mobile:
Fax No. : +919892203750
+91-22-40057327
16. Details of alternative sites No alternate site is examined
examined, if any. Location of these
sites should be known on the Topo
Sheet.
17. Interlinked Projects NIL
18. Whether second application of the NIL
interlinked project has been
submitted?
19. If yes, Date of submission Not Applicable
20. If no, Reason Not Applicable
21. Whether the proposal involves No
approval/clearance under: if yes,
details of the same and their status
to be given.
The Forest (Conservation) Act,
1980?
The Wildlife (Protection) Act,
1972?
The C.R.Z Notification, 1991?
22. Whether there is any Government Not applicable, as the project is
Order/ Policy relevant/ relating to located in
the site? Dahej SEZ-II.
23. Forest Land involved (Hectares) No
24. Whether there is any litigation No
pending against the project and/ or
land in which the project is

.
proposed to be set up?

Name of the Court
Case No.
Orders/ Directions of the Court, if
any and its relevance to the
proposed project
(II) ACTIVITY
1. Construction, operation or decommissioning of the Project involving
actions, which will cause physical changes in the locality (topography, land
use, changes in water bodies, etc)
Sr. Information / checklist Yes / Details thereof (with approximate
No. conformation. ` No. quantities/ rates, wherever
possible) with source of
information data.
1.1 Permanent or temporary change No Proposed project site is within the
in land use, land cover or Phase II, Dahej SEZ.
topography including increase
in intensity of land use (with
respect to local land use plan.)
1.2 Clearance of existing land, Yes Minor site clearance activities
vegetation and buildings? already carried out to clear shrubs
and weed to conduct soil
survey.
1.3 Creation of new land uses. No Land is for industrial purpose.
1.4 Pre-construction investigations Yes Soil testing and analysis is already
e.g. bore house, soil testing? done for detailed engineering before
construction.
1.5 Construction works? Yes The construction work includes
process plants, utility blocks &
other infrastructure which will be in
different Stages. Plant layout is
given as Annexure - II.
1.6 Demolition works? No --
1.7 Temporary sites used for No --
construction works or housing
of construction workers?
1.8 Above ground buildings, Yes All the process plants will
structures or earthworks have structures & will require
including linear structures, cut excavation.
and fill or excavations. Other buildings, godown, stores,
tank farms, weigh bridges, etc. also
require some excavations work.
Plant layout is given as Annexure -
II.
1.9 Underground works including No --

.
mining or tunneling?
1.10 Reclamation works? No --
1.11 Dredging? No --
1.12 Offshore structures? No --
1.13 Production and manufacturing Yes Manufacturing process,
processes? Chemical Reaction and Mass
Balance is given as Annexure -III.
1.14 Facilities for storage of goods or Yes Raw material storage area, Tank
materials? farm area & finished products area
will be developed for proposed
project.
1.15 Facilities for treatment or Yes Full Fledged Effluent Treatment
disposal of solid waste or liquid Plant and MEE will be installed
effluents? to treat the effluent so as to
achieve the GPCB norms. The
treated effluent shall be drained
into underground pipe line of SEZ.
The MEE Salt will be disposed off
in the approved TSDF site.
Domestic Waste water will be
disposed in biological treatment of
ETP or by septic tank/soak pit.
Hazardous waste shall be
disposed to approve TSDF Site.
Details of water consumption
& waste water generation are
given as Annexure IV.
Details of proposed Effluent
Treatment Plant and proposed
MEE system to be installed are
attached as Annexure V.
Details of Hazardous waste
generation and disposal is attached
as Annexure VI.
1.16 Facilities for long term housing No Local operational staff of shall
of operational workers? be employed for the proposed
plant.
1.17 New road, rail or sea traffic No The project is ideally situated in
during construction or Dahej SEZ-II, Dahej. It is
operation? having well connectivity of
Road as well as Railways.
Industrial town of Ankleshwar, a
well developed place having all the
required engineering, industrial
services and easy availability of
raw materials is 60 K.M.
away. The Ankleshwar industrial
area is having well accessibility
by Western Railways. The nearest

.
Railway Station is only 60 K.M. It

is well accessible by Road transport
and The National Highway is 60
K.M. away from the project site.
1.18 New road, rail, air waterborne No The GIDC Industrial Estate, Dahej
or other transport infrastructure (SEZ) has well developed road
including new or altered routes facility.
and stations, ports, airports etc?
1.19 Closure or diversion of existing No Proposed project is located in
transport routes or infrastructure Notified Area.
leading to changes in traffic
movements?
1.20 New or diverted transmission No The GIDC Industrial Estate, Dahej
lines or pipelines? (SEZ) has well developed road
facility.
1.21 Impoundment, damming, No Not Applicable.
culverting, realignment or other
changes to the hydrology of
watercourses or aquifers?
1.22 Stream crossing? No No such activity is involved in the
proposed Project.
1.23 Abstraction or transfers of water No No ground water shall be used. The
form ground or surface waters? raw water shall be supplied by
Dahej SEZ-II/GIDC authority.
1.24 Changes in water bodies or the No Site is located in Dahej SEZ-II,
land surface affecting drainage Dahej. There is no water body
or run-off? within the proposed project
premises. Storm water drainage shall
be provided & diverted to existing
natural storm water drain.
1.25 Transport of personnel or Yes Transportation of personnel or
materials for construction, raw material and products will be
operation or decommissioning? primarily by road only.
1.26 Long-term dismantling or No There is no dismantling of any sort.
decommissioning or restoration Not applicable.
works?
1.27 Ongoing activity during No Not applicable as no
decommissioning which could decommissioning is required.
have an impact on the
environment?
1.28 Influx of people to an area in No This is a well-developed Industrial
either temporarily or Area.
permanently?
1.29 Introduction of alien species? No Not applicable.
1.30 Loss of native species or genetic No Not applicable.
diversity?
1.31 Any other actions? No Not applicable.

.
2 Use of Natural resources for construction or operation of the Project (such

as land, water, materials or energy, especially any resources which are non-
renewable or in short supply):
Sr. Information / Checklist Yes Details thereof (with approximate
No. conformation. / quantities / rates, wherever possible)
No. with source of information data.
2.1 Land especially undeveloped No The proposed project is located in
or agricultural land (ha) notified GIDC Industrial Estate, Dahej.
2.2 Water (expected source & Yes Details of water consumption and waste
competing users) unit: KLD water generation are attached as
Annexure – VII.
2.3 Minerals (MT) No List of raw material is attached as
Annexure-V.
2.4 Construction material – Yes Material Qty. Source
stone, aggregates, sand / soil Bricks 1614000 From
(expected source – MT) no. local
Cement 207000Bags supply
Sand 67000 m3
TMT Steel 2250 MT
Kapchi 83160 m3
2.5 Forests and timber (source - No No forest and timber products are used.
MT)
2.6 Energy including electricity Yes Details of Energy & fuel consumption are
and fuels (source, competing attached as Annexure –X.
users) Unit: fuel Electricity: From Torrent Power Ltd.,
(MT),energy (MW) Proposed 5600 KVA
2.7 Any other natural resources No No other natural resources will be used.
(use appropriate standard Bio Coal usage proposed- 80 MT/Day. In
units) case of non-availability of bio coal, unit
will use imported coal.
3 Use, storage, transport, handling or production of substances or materials,

which could be harmful to human health or the environment or raise
concerns about actual or perceived risks to human health.
Sr. Information / Checklist Yes / Details thereof (with
No. conformation. No. approximate quantities / rates,
wherever possible) with source of
information data.
3.1 Use of substances or materials, Yes List of raw materials and products
which are hazardous (as per as per MSIHC rules is attached as
MSIHC rules) to human health or Annexure-XII.
the environment (flora, fauna, and
water supplies)
3.2 Changes in occurrence of disease No No change in occurrence of disease
or affect disease vectors (e.g. due to the proposed project.
insect or water borne diseases)
3.3 Affect the welfare of people e.g. Yes New employment will be created in
by changing living conditions? the area.
3.4 Vulnerable groups of people who No There will be no such effects due to

.
could be affected by the project the proposed project.

e.g. hospital patients, children, the
elderly etc.,
3.5 Any other causes. No No other cause.
4. Production of solid wastes during construction or operation or

decommissioning (MT/month).
wherever possible) with source
of information data.
4.1 Spoil, overburden or mine waste. No No such waste will be generated
from the proposed project activity.
4.2 Municipal waste (domestic and or Yes Some garden waste and canteen
commercial wastes) waste will be generated. Details
are given in Annexure-IX.
4.3 Hazardous wastes (as per Yes Details of hazardous waste
Hazardous Waste Management generation are attached as
Rules) Annexure –IX.
4.4 Other industrial process wastes No No such waste will be generated.
4.5 Surplus product No No surplus product will be
generated.
4.6 Sewage sludge or other sludge Yes Details are attached as Annexure-
from effluent treatment. IX.
4.7 Construction or demolition wastes Yes Any waste will be utilized in road
construction.
4.8 Redundant machinery or No Not Applicable
equipment
4.9 Contaminated soils or other No No such waste will be generated.
materials.
4.10 Agricultural waste. No No agriculture waste will be
generated.
4.11 Other solid wastes. Yes Details are given in Annexure-IX.
5. Release of pollutants or any hazardous, toxic or noxious substances to air

(Kg/hr)
information data.
5.1 Emissions from combustion of Yes Bio coal will be used as fuel. The
fossil fuels from stationary or usage will be 80 TPD of bio-coal.
mobile sources
5.2 Emissions from production Yes HCl is generated and scrubbed in 3
processes. stage water scrubber. HCl
generated is sold in market.
Unreacted Chlorine is scrubbed in
caustic scrubber for manufacturing
weak sodium hypochlorite

.
solution. Sulphur Dioxide gas is

liberated in some reactions which
are scrubbed in caustic scrubber to
make dilute sodium Sulphite
solution.
5.3 Emissions from materials No Chlorine handled from tonners /
handling including storage or through pipeline. All safety aspects
transport. observed.
5.4 Emissions from construction Yes Adequate measures will be taken to
activities including plant and control emissions from
equipment construction activities including
plant and equipment.
5.5 Dust or odors from handling of Yes Adequate measures will be taken to
materials including construction control emissions of dust.
materials, sewage and waste.
5.6 Emissions from incineration of No No such activity will be carried out
waste. by the unit.
5.7 Emissions from burning of waste No No burning activity will be done in
in open air (e.g. slash materials, the unit.
construction debris)
5.8 Emission from any other sources. No No other emissions from any other
source.
6. Generation of Noise and Vibration, and Emissions of Light and Heat:

No. conformation. No approximate quantities / rates,
information data.
6.1 From operation of equipment e.g. Yes Boiler, vacuum pump. Adequate
engines, measures will be taken by the unit.
ventilation plant, crushers. The noise level will be within the
prescribed limit.
6.2 From industrial or similar No Adequate measures will be taken
processes. by the unit.
6.3 From construction or demolition. No Adequate measures will be taken
by the unit.
6.4 From blasting or piling. No No such activity is involved.
6.5 From construction or operational No Adequate measures will be taken
traffic. by the unit.
6.6 From lighting or cooling systems. No Adequate measures will be taken
by the unit.
6.7 From any other sources. No No emission from any other
sources.

.
7. Risks of contamination of land or water from releases of pollutants into the

ground or into sewers, surface waters, groundwater, coastal waters or the sea:
information data.
7.1 From handling, storage, use or No Storage of raw materials and
spillage of hazardous materials. finished products is done in proper
HDPE, PP/FRP & SS storage
tanks. All storage tanks are above
ground with acid proof brick lined
dyke walls. The flooring will also
be acid proof brick lined. Major
quantity is of acetic acid and HCl.
Spillages are not anticipated.
Spillages if any will be collected in
dykes, from where the contents
will be transferred to spare storage
tanks through dedicated PP
glandless pump.
7.2 From discharge of sewage or No Domestic waste wills be sent to
other effluents to water or the land soak pit / GIDC sewage line.
(expected mode and place of Wastewater after neutralization
discharge) will be sent to GIDC discharge
line.
7.3 By deposition of pollutants No All the air emissions will be within
emitted to air into the land or into the permissible limit.
water
7.4 From any other sources. No No other sources will be there.
7.5 Is there a risk of long term No There will not be any long term
buildup of pollutants in the buildup of pollutants in the
environment from these sources? environment from these sources.
8. Risk of accidents during construction or operation of the Project, which could

affect human health or the environment.
information data.
8.1 From explosions, spillages, fires Yes There will be risk of accident from
etc. from storage, handling, use or the proposed activity. Adequate
production of hazardous control measures will be provided.
substances. Proper on site and off site
emergency plans will be prepared.
8.2 From any other causes No No risk of accident from any other
causes.
8.3 Could the project be affected by No All structures and buildings will be
natural disasters causing earthquakes proofs. Safe building
environmental damage (e.g. codes and other controls built will
.
floods, earthquakes, landslides, consider at the site design level.

cloudburst etc)?
9. Factors which should be considered (such as consequential development) which

could lead to environmental effects or the potential for cumulative impacts with
other existing or planned activities in the locality.
Sr. Information / Checklist Yes Details thereof (with
No. conformation. / No approximate quantities / rates,
information data.
9.1 Lead to development of supporting Yes Employment generation.
localities, ancillary development or
development stimulated by the
project which could have impact on
the environment e.g.:
• Supporting infrastructure (roads,
power supply, waste or waste water
treatment, etc.)
• housing development
• extractive industries
• supply industries
• other
9.2 Lead to after – use of the site, which No There will be no significant impact
could have an impact on the on environment.
environment.
9.3 Set a precedent for later No The Notified area is already well
developments. developed.
9.4 Have a cumulative effect due to No There will be no cumulative effect

proximity to other existing or from the proposed project.
planned projects with similar effects.
(III) ENVIRONMENTAL SENSITIVITY.

Sr. Area. Yes / Aerial distance (within 15
No No km.)Proposed project
. location boundary.
1 Areas protected under international No --
conventions, national or local
legislation for their ecological,
landscape, cultural or other related
value.
2 Areas which are important or Yes The Narmada estuarine zone
sensitive for ecological reasons - is approximately 8 km away
Wetlands, watercourses or other from project site.
water bodies, coastal zone,
biospheres, mountains, forests.
3 Areas used by protected, important or No _
sensitive species of flora or fauna for
breeding, nesting, foraging, resting,
over wintering, migration.
.
4 Inland, coastal, marine or No _

underground waters
5 State, National boundaries. No _
6 Routes or facilities used by the public No _
for access to recreation or other
tourist, pilgrim areas.
7 Defence installations. No --
8 Densely populated or built – up area. Bharuch Approximate distance 40
city km.
9 Areas occupied by sensitive man- Yes Academic institutes and
made land uses (hospitals, schools, hospital are approximate 7
places of worship, community km away from project site.
facilities)
10 Areas containing important, high No _
quality or scare resources (ground
water, surface resources, forestry,
agriculture, fisheries, tourism,
minerals)
11 Areas already subjected to pollution No _
or environmental damage. (those
where existing legal environmental
standards are exceeded)
12 Areas susceptible to natural hazard No _
which could cause the project to
present environmental problems
(earthquakes, subsidence, landslides,
erosion, flooding or extreme or
adverse climatic conditions)

.
“I hereby given undertaking that the data and information given in the
application and enclosures are true to my best knowledge and belief and I am
aware that if any part of the data and information submitted is found to false or
misleading at any stage, the project will be rejected and clearance give, if any to
the project will be revoked at our risk and cost”.
Date:
Place: Mumbai
Signature of the applicant

MR. SUNIL SHANTILAL NAWAL
26/28-A, Cawasji Patel street,
Fort, Mumbai 400 001.
Director.
(Project Proponent/ Authorized Signatory)
NOTE:
1. The projects involving clearance under Coastal Regulation Zone Notification,
1991 shall submit with the application a C.R.Z map duly demarcated by one of
the authorized agencies, showing the project activities, w.r.t. C.R.Z (at the stage
of TOR) and the recommendations of the State Coastal Zone Management
Authority (at the stage of EC). Simultaneous action shall also be taken to obtain
the requisite clearance under the provisions of the C.R.Z Notification, 1991 for
the activities to be located in the CRZ.
2. The projects to be located within 10 km of the National Parks, Sanctuaries,
Biosphere Reserves, Migratory Corridors of Wild Animals, the project
proponent shall submit the map duly authenticated by Chief Wildlife Warden
showing these features vis-à-vis the project location and there commendations or
comments of the Chief Wildlife Warden thereon (at the stage of EC).
3. All correspondence with the Ministry of Environment & Forest including
submission of application for TOR/Environmental Clearance, subsequent
clarifications, as may be required from time to time, participation in the EAC
Meeting on behalf of the project proponent shall be made by the authorized
signatory for the specific project

.
ANNEXURE I
Terms of Reference
This is EC Amendment application. The production quantity is remaining the same.

There is change in name of products, water consumption and waste water generation.
There is also change in fuel consumption as well as power consumption. This has
happened after working out detailed engineering and market feedback.
As per Notification issued by MOEF & CC, New Delhi No. F. No. J-11013/12/2013-
IA-II (I) (part) dated 25th January, 2016, project will not require carrying out
Environment Impact Assessment Report.
The earlier report was carried out in year 2015 and EC was granted on 29th October,
2015 File No. J-11011/132/2014-IA II (I).
Unit has obtained CTE No. 70398 on dated 30/06/2015.

.
ANNEXURE II
List of Directors
Sr. Name of Designation Address Mobile No. and

No. Directors E. Mail ID
1. Mr. Surendra Managing Floor 15 & 16, +919821210007
kumar Mohatta Director Plot No. 85, smohatta@hotmail.com
Mittal Grandeur,
Khatau Road,
Cuffe Parade,
Mumbai – 400
005
2. Mrs.Vimladevi Director Floor 15 & 16, +919821222182
Mohatta Plot No. 85, gcpl@bom3.vsnl.net.in
Mittal Grandeur,
Khatau Road,
Cuffe Parade,
Mumbai – 400
005
3. Mr. Gaurav Whole Time Floor 15 & 16, +919821509654
Mohatta Director Plot No. 85, gaurav@benzochem.co.in
Mittal Grandeur,
Khatau Road,
Cuffe Parade,
Mumbai – 400
005
4. Mr. Sunil Director H/2, Flat No. +919892203750
Shantilal Nawal 804, Highland nawal@benzochem.co.in
Garden, Dokali
Chitalsar,
Manpada,
Balkum, Thane
400608

.
ANNEXURE III B
PLANT LAYOUT & SITE PLAN

.
Plant layout area bifurcation:

Sr. Locations Area in sq. m Area in %
No.
1. Production Plants 5800 12.18
2. Admin 625 1.31
3. Research & 400 0.84
Development
4. Engg. Store and 500 1.05
Scrap yard
5. Effluent Treatment 1000 2.10
plant
6. Utility 1400 2.94
7. Raw Material 600 1.26
Storage
8. Finished Products 700 1.47
Storage
9. U.G. Tank area 400 0.84
10. Tank Farm 250 0.53
11. Green Belt & other 15000 31.50
open space
12. Parking Area 4800 10.08
13. U.G. Water Tank 1000 2.10
14. Occupational Health 100 0.21
Centre
15. Security Cabin 200 0.42
16. Coal Yard 800 1.68
17. Canteen 500 1.05
18. Road & Open Area 13538.19 28.43
Total 47613.19 100.00

.
ANNEXURE IV
List of Products
Sr. Name of Products Quantity as per Addition/ Quantity
No. EC No. F. No. J- Deletion after
11011/132/2014- of proposed
IA II (I) and products Product
CTE No. 70398 with Profile in MT
in reference / Month
MT / Month to EC
1. 2-Amino Benzo Nitrile 10 -9 1
2. 2-Amino-5-Bromo 5 -5 0
Benzo Nitrile
3. 2,4,6-trimethyl 20 -12 8
Benzaldehyde
(Mesitaladehyde ) / or
2,4,6-
TrimethylBenzaldehyde
84%in 16% Aceton
(Mesitaladehyde 84%
in 16% Aceton)
4. Indoline 20 -20 0
5. 2,4-Dichloro Phenyl 25 -25 0
Acetic Acid
6. 2,4-Dichloro Phenyl 25 -12 13
Acetyl Chloride
7. 2,4,6-Trimethyl Phenyl 20 +1 21
Acetyl Chloride
8. 2,4 Dichloro Meta 4 -3 1
Cresol
9. Pivolo nitrile (Tri 10 -10 0
methyl acetonitrile )
10. 4,4-dihydroxy Benzo 25 -25 0
phenone
11. 2-chloro-4,6 25 -17 8
dimethoxy-1,3,5-
Triazine
12. 2-Coumaranone 170 +38 208
30%,Acetic
Anhydride70 %
13. 4-Bromo-2-Hydroxy 4 -4 0
Anisole / 5-Bromo-2-
Methoxy Phenol
14. 5-Propionyl-2- 2 -2 0
Thiophenyl acetic acid
(PPP) /
2-Phenyl Thio-5-
Propionyl Phenyl

.

11011/132/2014- of proposed
MT / Month to EC
Acetic Acid
15. 2,3,4,5-tertrachloro 17 -17 0
Benzoyl chloride
16. 3,4,5 tri methoxy 25 -17 8
Toluene
17. 3,4,5 tri methoxy 2 -2 0
Benzyl chloride
18. 3,4,5-tri methoxy 2 -2 0
benzyl cyanide
19. 3,4,5-tri methoxy 2 -2 0
phenyl acetic acid
20. 3,4,5-trimethoxy 4 -3 1
benzoic acid
21. 3,4,5-Trimethoxy 17 -17 0
Benzaldehyde
22. 4,4-dimethoxy-2- 17 -17 0
Butanone
23. R-2-(2,4- 40 -40 0
Dichlorophenoxy)
Propionic Acod
24. Para Methyl 25 -25 0
Benzaldehyde / 4-
Methyl Benzaldehyde
25. 2-5 Dimethyl Phenyl 25 +0 25
Acetyl Chloride
26. 2-Amino 2 Phenyl 4 -4 0
Butyric Acid
27. 1-(2,6 Dichloro 4 -4 0
Phenyl)2-Indolinone
28. 2-(3-Benzoyl Phenyl)- 8 -8 0
propio Nitrile /
Ketoprofen Nitrile
29. N-Methyl-1- 2 +0 2
Naphtahlene Methyl
Amine Acetate
30. N-Methyl-1- 2 +0 2
Naphtahlene Methyl
Amine Base

.

11011/132/2014- of proposed
MT / Month to EC
31. Para Chloro Phenyl 5 -5 0
Ethyl Amine / 2-(4-
Chloro-Phenyl)-
Ethylamine
32. Ortho Chloro Phenyl 5 -5 0
Ethyl Amine
33. 2-Dimethylamino- 4 -4 0
2Phenyl Butanol/2-
(N,N-Dimethylamino)-
2-Phenyl-1-Butanol
34. Methyl- 2- 4 -4 0
Dimethylamino-2-
Phenyl butyrate /2-
(N,N-Dimethyl
Amino)-2-Phenyl-2-
Butyrate
35. 2-Phenyl Butyric Acid 4 -4 0
36. 5-Chloro-2-Hydroxy 5 -4 1
Benzo phenone
37. 5-(1- Carboxy Ethyl)-2- 2 -2 0
Phenyl Thiophenyl
Acetic Acid (DIACID)
38. N-Methyl 1-Napthalene 5 -2 3
Methyl Amine
Hydrochloride
39. 7-Methoxy 1 Tetralone 5 -5 0
40. 2-Amino 4 Hydroxy 0 +3 3
Acetophenone
41. 3-coumaranone 0 +8 8
42. 3, 3 Dimethyl Butyrl 0 +16 16
Chloride
43. 4-bromo Anisole 0 +16 16
44. 4-Cyano Benzoic Acid 0 +1 1
45. 7-Hydroxy 1 Tetralone 0 +1 1
46. Atropic acid 0 +2 2
47. 4-chloro Benzaldehyde 0 +6 6
Glycol Acetal
48. 2,2-Dichloro-2 Phenyl 0 +16 16
Acetic Acid Ethyl Ester

.

11011/132/2014- of proposed
MT / Month to EC
49. Para Chloro Meta 00 +25 25
Xylenol BP
50. Pivaloacetonitrile 0 +3 3
51. 3-Chloro2- Methyl 0 +25 25
Anisole
52. 2-Dimethyl 2 Methyl 1 00 +8 8
Propanol
53. 4-Hydroxy 3 5 00 +2 2
Dimethyl
Benzaldehyde
54. 2 Ethyl 2 Methyl 00 +8 8
Butanoic Acid
55. 2 2 Dimethyl Butyrl 00 +8 8
Chloride
56. DV Acid Chloride 00 +5 5
(60:40 Cistrans)
57. Ortho Benzyl Para 00 +7 7
Chloro Phenol
58. 4-Isopropyl Catechol 00 +1 1
59. 1-Adamantyl HCL 00 +8 8
60. 1-Bromo-2-(3-Chloro- 00 +11 11
4-Ethoxyphenyl)-2-
Methyl Propane
61. 4-Chloro 2,6 Dimethyl 00 +8 8
Phenyl Acetic Acid
62. 4-Hydroxy Benzyl 00 +3 3
Alcohol
63. 2-Methoxy Phenyl 00 +1 1
Acetone
64. Methyl-2-Dimethyl 00 +2 2
Amino-2-phenyl
butyrare
65. Meta Phenoxy Benzyl 00 +4 4
Alcohol
66. 4-Bromophenyl Acetic 00 +1 1
Acid Methyl Ester
67. 4-Hydroxy 00 +16 16
Acetophenone
68. 2-(1-Admantyl)-4- 00 +2 2
Bromo Anisole

.
Sr. Name of ProductsQuantity as per Addition/ Quantity

11011/132/2014- of proposed
MT / Month to EC
69. 2-(3-Hydroxy-2-Methyl 00 +10 10
Propionyl)-aminol-2-
methyl-propanol
70.0 4-Bromophenyl Acetic 00 +1 1
Acid
71. R & D Products 00 +70 70
Total 600 00 600
Sr. By-Products Quantity as per EC

No. and NOC
1. HCl (30%) (MT/Month)
126
2. H2SO4 (70%) 50
3. Liqour Ammonia (24%) 45
4. HBr 70
5. NaBr 76
6. Phosphoric Acid 60
7. Copper Sulphate 80
8. Sodium Chloride 80
9. Sodium Sulphate 60
10. Sodium Acetate 5
11. Sodium Sulfite 30
12. Potassium Chloride 5
13 Potassium Carbonate 12
14. Ammonium Sulphate 4
After change in product list:
Sr. Name of Products CAS Quantity in Quantity in End Uses

No. No. MT/Month (MT/Annum)
A. SPECIALTY CHEMICALS
1. 2-Amino Benzo 1885- 1 12 Agrochemical
Nitrile 29-6 /Pharmaceutical
Intermediate
2. 2,4,6-Trimethyl 487-68- 8 96 Agrochemical
Benzaldehyde 3 intermediate
(Mesitaladehyde ) /
2,4,6-Trimethyl
Benzaldehyde 84% in
16% Acetone
(Mesitaladehyde
84%in 16% Acetone
)

.

3. 2,4-Dichloro Phenyl 53056- 13 156 Agrochemical
Acetyl Chloride 20-5 intermediate
4. 2,4,6-Trimethyl 52629- 21 252 Agrochemical
Phenyl Acetyl 46-6 intermediate
Chloride
5. 2,4-Dichloro Meta 17788- 1 12 specialty
Cresol 00-0 chemicals
6. 2-Chloro-4,6 3140- 8 96 Agrochemical
Dimethoxy-1,3,5- 73-6 intermediate
Triazine
7. 2-Coumaranone 553-86- 208 2496 Agrochemical
30%,Acetic 6 intermediate
Anhydride70 %
8. 3,4,5 Trimethoxy 6443- 8 96 specialty
Toluene 69-2 chemicals( Fire
retardent)
9. 3,4,5-Trimethoxy 118-41- 1 12 Pharmaceutical
Benzoic Acid 2 Intermediate
10. 2-5 Dimethyl Phenyl 55312- 25 300 Agrochemical
Acetyl Chloride 97-5 intermediate
11. N Methyl 1- - 2 24 Pharmaceutical
Napthalene Methyl Intermediate
Amine Acetate
12. N Methyl 1- 14489- 2 24 Pharmaceutical
Napthalene Methyl 75-9 Intermediate
Amine Base
13. 5-Chloro-2-Hydroxy 88-19-8 1 12 speciality
Benzo phenone chemicals
14. 2-Amino 4 Hydroxy 19745- 3 36 speciality
Acetophenone 72-3 chemicals
15. 3-coumaranone 7169- 8 96 Agrochemical
34-8 intermediate
16. 3, 3 Dimethyl Butyrl 7065- 16 192 Agrochemical
Chloride 46-5 intermediate
17. 4-bromo Anisole 104-92- 16 192 Agrochemical
7 intermediate
18. 4-Cyano Benzoic 619-65- 1 12 Pharmaceutical
Acid 8 Intermediate
19. 7-Hydroxy 1 22009- 1 12 Pharmaceutical
Tetralone 38-7 Intermediate
20. Atropic acid 492-38- 2 24 speciality
6 chemicals
21. 4-chloro 2403- 6 72 Pharmaceutical
Benzaldehyde Glycol 54-5 Intermediate
Acetal
22. 2,2-Dichloro-2 5317- 16 192 Agrochemical
Phenyl Acetic Acid 66-8 intermediate

.

Ethyl Ester
23. Para Chloro Meta 88-04-0 25 300 Biocid
Xylenol BP
24. Pivaloacetonitrile 59997- 3 36 Agrochemical
51-2 intermediate
25. 3-Chloro2- Methyl 3260- 25 300 Agrochemical
Anisole 88-6 intermediate
26. 2-Dimethyl 2 Methyl 75-84-3 8 96 Agrochemical
1 Propanol intermediate
27. 4-Hydroxy 3 5 2233- 2 24 Pharmaceutical
Dimethyl 18-3 Intermediate
Benzaldehyde
28. 2 Ethyl 2 Methyl 19889- 8 96 speciality
Butanoic Acid 37-3 chemicals
29. 2 2 Dimethyl Butyrl 5856- 8 96 Agrochemical
Chloride 77-9 intermediate
30. DV Acid Chloride 52314- 5 60 Pharmaceutical
(60 : 40Cistrans) 67-7 Intermediate
31. Ortho Benzyl Para 120-32- 7 84 Agrochemical
Chloro Phenol 1 intermediate
32. 4-Isopropyl Catechol 2138- 1 12 Pharmaceutical
43-4 Intermediate
33. 1-Adamantyl HCL 665-66- 8 96 Pharmaceutical
7 Intermediate
34. 1-Bromo-2-(3- - 11 132 Agrochemical
Chloro-4- intermediate
Ethoxyphenyl)-2-
Methyl Propane
35. 4-Chloro 2,6 39944- 8 96 Agrochemical
Dimethyl Phenyl 18-8 intermediate
Acetic Acid
36. 4-Hydroxy Benzyl 623-05- 3 36 Pharmaceutical
Alcohol 02 Intermediate
37. 2-Methoxy Phenyl 5211- 1 12 Pharmaceutical
Acetone 62-1 Intermediate
38. Methyl-2-Dimethyl 39068- 2 24 Pharmaceutical
Amino-2-phenyl 93-4 Intermediate
butyrare
39. Meta Phenoxy 13826- 4 48 Pharmaceutical
Benzyl Alcohol 35-2 Intermediate
40. 4-Bromophenyl 41841- 1 12 Pharmaceutical
Acetic Acid Methyl 16-1 Intermediate
Ester
41. N Methyl 1- 65473- 3 36 Pharmaceutical
Napthalene Methyl 13-4 Intermediate
Amine Hydro
Chloride

.

42. 4-Hydroxy 99-93-4 16 192 Pharmaceutical
Acetophenone Intermediate
43. 2-(1-Admantyl)-4- 104224 2 24 Pharmaceutical
Bromo Anisole -63-7 Intermediate
44. 2-(3-Hydroxy-2- - 10 120 Pharmaceutical
Methyl Propionyl)- Intermediate
aminol-2-methyl-
propanol
45. 4-Bromophenyl 1878- 1 12 Pharmaceutical
Acetic Acid 68-8 Intermediate
46. R & D products - 70 840 Pharmaceutical/
Agrochemical
Intermediate
Total 600 7200
AFTER CHANGE LIST OF BY PRODUCTS:
Sr. List of By Quantity as Generated from Quantity after

No. products per EC in Products proposed
MT/Month product profile
(MT / Month)
1. HCl (30%) 126 2-Amino Benzo Nitrite, 126
2,4-Dichloro Phenyl
Acetyl Chloride, 2,4,6-
Trimethyl Phenyl Acetyl
Chloride,2,5-Dimethyl
Phenyl Acetyl Chloride,
5-Chloro-2-Hydroxy
Benzo Phenone, 3 3
Dimethyl Butyrl
Chloride, 7-Hydroxy 1
Tetralone, 2,2-Dichloro-
2-ohenyl Acetic Acid
Ethyl Ester, Para Chloro
Meta Xylenol BP,
Pivalacetonitrile, 22
Dimethyl Butyrl
Chloride, DV Acid
Chloride, Ortho Benzyl
Para Chloro Phenol, 1-
Admantyl HCL, Meta
Phenoxy Benzyl
Alcohol, 4-Hydroxy
Acetophenone, 4-Bromo
Phenyl Acetic Acid.
2. H2SO4 (70%) 50 -- 50
3. Liqour 45 2-Coumaronone 30%, 55

.

(MT / Month)
Ammonia (20- Acetic Anhydride,
24%) Pivaloacetonitrile, 2,2
Dimethyl Butyrl
Chloride,
4. HBr (35-40 %) 70 3,4,5 Trimethoxy 70
toluene, 3,4,5-
Trimethoxy benzoic
acid/ ester
5. NaBr (20-22 %) 76 3,4,5 Trimethoxy 76
toluene, 3,4,5-
Trimethoxy benzoic
acid/ ester, 4-Bromo
Anisole,
6. Phosphoric 60 7-Hydroxy 1 Tetralone 60
Acid
7. Copper 80 2-Coumaranone 30%, 40
Sulphate/ Acetic Anhydride 70%
Copper Oxide
8. Sodium 80 -- 00
Chloride
9. Sodium 60 -- 00
Sulphate
10. Sodium Acetate 5 -- 00
11. Sodium Sulfite 30 2,4-Dichloro phenyl 40
(20-22 %) acetyl chloride, 2,4,6-
Trimethyl phenyl acetyl
chloride, 3,4,5-
Trimethoxy Benzoic
Acid/ ester, 2-5
Dimethyl phenyl acetyl
chloride, 3,3 Dimethyl
Butyrl Chloride, 2,2-
Dichloro-2 phenyl acetic
acid ethyl ester, 2,2
Dimethyl butyrl
chloride, D V acid
Chloride,
12. Potassium 5 -- 0
Chloride
13. Potassium 12 -- 12
Carbonate
14. Ammonium 4 -- 0
Sulphate
15. Mix Chloro 0 Para Chloro Meta 6
Xylenol Xylenol BP

.

(MT / Month)
16. 2-Hydroxy 0 4-Hydroxy 1
Acetophenone Acetophenone
17. Methanol 50% 0 2-Chloro-4,6 40
Dimethoxy-1,3,5-
Triazine.
18. Poly Aluminum 0 2,4-Dichloro Meta 20
Chloride Cresol, 5-Chloro-2-
Solution 25% Hydroxy Benzo
Phenone, 2-Amino4
Hydroxy Benzophenone,
7-Hydroxy 1 Tetralone,
Meta Phenoxy Benzyl
Alcohol, 4-Hydroxy
Acetophenone,
ANNEXURE V
Product wise Raw Material Consumption Quantity:
Sr. Name of Products Quantity Name of Raw Quantity Quantity in

No. in MT/ Materials in T/T MT/Month
Month
1. 2-Amino Benzo 1 Toluene 0.42 0.42
Nitrile Phosphorous 2.60 2.60
Penta chloride
Sodium 1.50 1.50
Hydroxide
2-Amino 1.54 1.54
benzamide
Total 6.06 6.06
2. 2,4,6-Trimethyl 8 Mesitylene 0.84 6.72
Benzaldehyde Choral 1.13 9.07
(Mesitaladehyde ) / Titanium 1.46 11.68
2,4,6-Trimethyl Tetrachloride
Benzaldehyde 84% Soda Ash 0.67 5.38
in 16% Acetone Acetone 0.16 1.28
(Mesitaladehyde
Tetra Ethyl 0.01 0.08
84% in 16%
Benzyl
Acetone)
Ammonium
Chloride
Total 4.28 34.21

.

Month
3. 2,4-Dichloro 13 2,4-Dichloro 1.10 14.30
Phenyl Acetyl Phenyl Acetic
Chloride Acid / 2-4,
Dichloro Benzyl
Alcohol
Sodium 0.48 6.24
Hydroxide
Toluene 0.05 0.65
Thionyl Chloride 0.70 9.10
Total 2.33 30.29
4. 2,4,6-Trimethyl 21 2,4,6-Trimethyl 1.06 22.26
Chloride Acid / Mesitylene
Toluene 0.08 1.58
Sodium 0.53 11.03
Hydroxide
Total 2.53 53.15
5. 2,4-Dichloro Meta 1 2-Tert-Butyl-5- 1.00 1.00
Cresol Methyl Phenol
Sodium 0.60 0.60
Hydroxide
Aluminium 0.40 0.40
Chloride
Toluene 0.10 0.10
Chlorine Gas 0.30 0.30
HCL 30% 2.50 2.50
Total 4.90 4.90
6. 2-Chloro-4,6 8 Cyanuric 1.89 15.10
Dimethoxy-1,3,5- Chloride
Triazine Methanol 0.70 5.60
Sodium Bi 2.00 16.00
Carbonate
Total 4.59 36.70
7. 2-Coumaranone 208 Ortho Chloro 0.43 88.61
30%, Acetic Benzyl Cyanide
Anhydride 70 % Caustic Soda Lye 0.88 183.04
48%
Toluene 0.08 15.60
HCL 30% 0.97 201.55
Copper Sulphate 0.03 6.03
Acetic Anhydride 0.70 145.60
Total 3.08 640.43
8. 3,4,5 Trimethoxy 8 Para Cresol 0.80 6.40

.

Month
Toluene Hydro Bromic 2.68 21.44
Acid 48%
Hydrogen 1.03 8.26
Peroxide 50%
Methanol 1.03 8.20
Sodium Metal 0.36 2.88
Toluene 0.84 6.72
Copper Chloride 0.03 0.20
Dimethyl 0.16 1.28
Formamide
Sulphuric Acid 0.80 6.40
Total 7.72 61.78
9. 3,4,5-Trimethoxy 1 Para Cresol 0.80 0.80
Benzoic Acid Hydro Bromic 2.69 2.69
Acid 48%
Hydrogen 1.03 1.03
Peroxide 50%
Methanol 0.40 0.40
Sodium Metal 0.36 0.36
Toluene 0.84 0.84
Dimethyl 0.16 0.16
Formamide
Total 7.13 7.13
10. 2-5 Dimethyl 25 2,5-Dimethyl 1.00 25.00
Chloride Acid
Toluene 0.05 1.25
Sodium 0.57 14.13
Hydroxide
Total 2.46 61.38
11. N-Methyl 1- 2 Dimethyl 0.08 0.15
Napthalene Methyl Formamide
Amine Acetate Sodium Hydride 0.28 0.57
60% in Paraffin
N-Methyl 0.52 1.05
Formamide
1-Chloro Methyl 1.05 2.09
Naphthalene
98%
Caustic Soda Lye 2.30 4.60
48%

.

Month
Acetic Acid 0.29 0.58
Toluene 0.32 0.65
Total 5.89 11.78
12. N-Methyl 1- 2 Dimethyl 0.09 0.17
Amine Base Sodium Hydride 0.32 0.64
60% in Paraffin
N-Methyl 0.60 1.19
Formamide
Naphthalene
98%
48%
Toluene 0.32 0.65
Total 6.32 12.64
13. 5-Chloro-2- 1 Para Chloro 0.72 0.72
Hydroxy Benzo Phenol
phenone Ortho Dichloro 0.05 0.05
Benzene
Aluminium 0.80 0.80
Chloride
Benzoyl Chloride 0.85 0.85
HCL 30% 0.50 0.50
Methanol 0.07 0.07
Total 2.99 2.99
14. 2-Amino 4 3 3-Amino Phenol 1.05 3.15
Hydroxy Nitrobenzene 0.15 0.45
Acetophenone Acetyl Chloride 1.60 4.80
Sodium Sulphate 0.05 0.15
Aluminium 1.72 5.16
Chloride
HCL 30% 1.88 5.64
Soda Ash 0.10 0.30
Sodium 0.60 1.80
Methoxide
Toluene 0.09 0.27
Total 8.54 25.62
15. 3-coumaranone 8 Ethyl Chloro 0.70 5.60
Acetate
Potassium 0.70 5.60
Carbonate
Methyl Salicylate 0.70 5.60

.

Month
Dimethyl 0.30 2.40
Formamide
Sodium 0.80 6.40
Methoxide
Toluene 0.40 3.20
HCL 30% 2.70 21.6
Potassium 0.55 4.40
Hydroxide
Methanol 1.80 14.40
Carbon 0.05 0.40
Total 8.70 69.60
16. 3, 3 Dimethyl 16 1,1,2 Tri chloro 1.97 31.52
Butyrl Chloride ethane
Sodium 1.18 18.91
Hydroxide
Carbon 0.01 0.16
Ter. Butanol 0.74 11.79
Total 15.19 243.10
17. 4-bromo Anisole 16 Anisole 0.75 12.00
Bromine 0.70 11.20
Hydrogen 0.30 4.80
Peroxide ( 50%)
Sodium 0.05 0.80
Hydroxide
Solution
Sodium Thio 0.05 0.80
Sulphate
Total 1.85 29.60
18. 4-Cyano Benzoic 1 Para Chloro 1.10 1.10
Acid Benzoic Acid
Sodium Cyanide 0.34 0.34
Potassium Iodide 0.11 0.11
Dimethyl 0.17 0.17
Formamide
Sodium 0.10 0.10
Hypochloride
Total 1.82 1.82
19. 7-Hydroxy 1 1 Anisole 0.86 0.86
Tetralone Ethylene 0.11 0.11
Dichloride
Aluminium 1.93 1.93
Chloride

.

Month
Succinic 0.80 0.80
Anhydride
HCL 30% 2.05 2.05
Hydrazine 0.29 0.29
Hydrate 80%
Potassium 0.40 0.40
Hydroxide
Diethylene 0.04 0.04
Glycol
Poly Phosphoric 0.66 0.66
Acid
Toluene 0.11 0.11
Total 7.26 7.26
20. Atropic acid 2 Phenyl Acetic 0.97 1.93
Acid
Para 0.21 0.43
Formaldehyde
Potassium 0.98 1.96
Carbonate
HCL 30% 0.87 1.74
Toluene 0.18 0.36
TBAB ( Cat. ) 0.00 0.00
Total 3.21 6.43
21. 4-chloro 6 4-Chloro 0.90 5.40
Benzaldehyde Benzaldehyde
Glycol Acetal Toluene 0.06 0.36
Ethylene Glycol 0.43 2.58
Total 1.39 8.34
22. 2,2-Dichloro-2 16 Phenyl Acetic 0.90 14.40
Phenyl Acetic Acid Acid
Ethyl Ester Thionyl Chloride 0.90 14.40
Catalyst 0.01 0.14
Ethanol 0.40 6.40
Total 2.51 40.14
23. Para Chloro Meta 25 Meta Xylenol / 3- 1.00 25.00
Xylenol BP 5 Xylenol
HCL 30% 0.12 2.88
Cupric Chloride 0.01 0.25
Per Chloro 0.18 4.38
Ethylene
Chlorine 0.58 14.50
Total 1.88 47.00
24. Pivaloacetonitrile 3 Pivaloyl Chloride 1.30 3.90

.

Month
Methanol 0.35 1.05
Toluene 0.18 0.54
Acetonitrile 0.57 1.71
Sodamide 0.57 1.71
HCL 30% 1.42 4.27
Total 4.39 13.18
25. 3-Chloro2- Methyl 25 2,6 Dichloro 1.25 31.25
Anisole Toluene
Dimethyl 0.35 8.75
Sulfoxide
Sodium 0.46 11.50
Methoxide
HCL 30% 0.22 5.50
Total 2.28 57.00
26. 2 Di methyl amino 8 Acetone 1.30 10.40
2 Methyl 1 Sodium Cyanide 1.30 10.40
Propanol Methanol 2.60 20.80
Ammonium 1.50 12.00
Bicarbonate
HCL 30% 1.00 8.00
Sodium 2.40 19.20
Hydroxide
Sodium 0.55 4.40
Borohydride
Tetrahydro Furan 0.50 4.00
Para 1.20 9.60
formaldehyde
Solution
Formic Acid 1.00 8.00
Total 13.35 106.80
27. 4-Hydroxy 3 5 2 2,6-Xylenol 1.00 2.00
Dimethyl Toluene 0.16 0.32
Benzaldehyde Acetic Acid 0.05 0.10
Hexa methylene 1.16 2.32
Tetramine
Total 2.37 4.74
28. 2 Ethyl 2 Methyl 8 2,2 Dimethyl 0.85 6.80
Butanoic Acid Butanol
Firmic Acid 0.75 6.00
Ice 1.00 8.00
Total 4.20 33.60
29. 2 2 Dimethyl 8 2-Methyl2- 1.00 8.00
Butyrl Chloride Butanol

.

Month
HCL 30% 2.50 20.00
Sodium 0.40 3.20
Hydroxide
Total 5.40 43.20
30. DV Acid Chloride 5 D V Ester 1.05 5.25
(60:40 Cistrans) Sodium 1.38 6.88
Hydroxide
Toluene 0.10 0.50
N-Methyl-2- 0.0005 0.0025
Pyrolidinine
Total 3.37 16.85
31. Ortho Benzyl Para 7 Benzyl Chloride 1.00 7.00
Chloro Phenol Para Chloro 1.00 7.00
Phenol
Toluene 0.10 0.70
Total 2.10 14.70
32. 4-Isopropyl 1 4-Isopropyl 1.25 1.25
Catechol Phenol
Hydro Bromic 1.66 1.66
Acid 48%
Hydrogen 0.73 0.73
Peroxide 50%
Sulphate
Caustic Soda 0.50 0.50
Flakes
Cupric Chloride 0.03 0.03
N-Butyl Alcohol 0.25 0.25
HCL 30 % 1.40 1.40
Total 5.84 5.84
33. 1-Adamantyl HCL 8 Adamantane 1.00 8.00
Methylene 1.00 8.00
Dichloride
Catalyst 0.05 4.00
Acetonitrile 2.40 19.20
Methanol 0.50 4.00
Sodium sulphate 0.05 0.40
HCl 30% 0.50 4.00

.

Month
Total 8.53 68.24
34. 1-Bromo-2-(3- 11 Ortho Chloro 0.80 8.80
Chloro-4- Phenol
Ethoxyphenyl)-2- Zinc dust 0.05 0.55
Methyl Propane Sodium 0.28 3.03
Hydroxide
Diethyl sulphate 0.80 8.80
3 Bromo-2- 0.70 7.70
Methyl-1-
Propane
Toluene 0.10 1.10
Methanol 0.10 1.10
Total 2.83 31.08
35. 4-Chloro 2,6 8 3-5,xylidene 0.80 6.40
Dimethyl Phenyl HCl 30% 4.70 37.60
Acetic Acid Para 0.30 2.40
Formaldehyde
Solution
Sodium Nnitrite 1.00 8.00
Sodium 0.35 2.80
Hydroxide
Total 7.42 59.36
36. 4-Hydroxy Benzyl 3 Para Hydroxy 1.25 3.75
Alcohol Benzaldehyde
Flakes
Sodium Boro 0.35 1.05
Hydride
HCl 30% 1.15 3.45
Total 3.12 9.36
37. 2-Methoxy Phenyl 1 O-Anialdehyde 1.00 1.00
Acetone Methyl-2- 0.91 0.91
chloropropionate
Sodium 0.40 0.40
Hydroxide 50%
Sulpharic Acid 0.15 0.15
Total 2.45 2.45
38. Methyl-2-Dimethyl 2 Toluene 0.28 0.56
Amino-2-phenyl 2-Amino-2- 1.12 2.24
butyrare Phenyl Butyris
Acid
Sodium 1.06 2.11

.

Month
Hydroxide 50%
Dimethyl 0.62 1.24
Sulphate
Formic Acid 0.77 1.54
Formaldehyde 0.70 1.41
37%
Total 4.55 9.10
39. Meta Phenoxy 4 Aluminium 0.90 3.60
Benzyl Alcohol Chloride
Bromine 0.85 3.40
Benzaldehyde 0.55 2.20
Ethylene 0.10 0.40
Dichloride
Monoethylene 0.025 0.10
Glycol
PTSA 0.003 0.012
Phenol 0.50 2.00
Potassium 0.30 1.20
Hydroxide
Hydrogen 0.01 0.04
Tri ethyl Amine 0.00 0.01
Catalyst 0.01 0.04
Total 3.56 14.24
40. 4-Bromophenyl 1 4-Bromophenyl 1.07 1.07
Acetic Acid Acetic Acid
Methyl Ester Methanol 0.42 0.42
Soda Ash 0.03 0.03
Total 1.73 1.73
41. N Methyl 1- 3 Dimethyl 0.08 0.23
Amine Hydro Sodium Hydride 0.31 0.92
Chloride 60% in Paraffin
N-Methyl 0.57 1.70
Formamide
Naphthalene
98%
48%
HCl 30% 0.18 0.53

.

Month
Toluene 0.13 0.39
Total 5.99 17.98
42. 4-Hydroxy 16 Acetyl Chloride 0.90 14.40
Acetophenone Phenol 1.00 16.00
Mono Chloro 0.30 4.80
benzene
Aluminium 2.80 44.80
Chloride
Sodium 0.20 3.20
Hydroxide
HCl 2.00 32.00
Total 7.20 115.20
43. 2-(1-Admantyl)-4- 2 4-Bromo anisole 1.00 2.00
Bromo Anisole Adamantanol 0.63 1.26
Ethylene 0.50 1.00
Dichloride
Toluene 0.10 0.20
Total 2.68 5.36
44. 2-(3-Hydroxy-2- 10 2-Amino 0.75 7.50
Methyl Propionyl)- Isobutyric Acid
aminol-2-methyl- Methacrylic Acid 0.65 6.50
propanol Toluene 0.10 1.00
HCl 30% 0.50 5.00
Tetrahydrofuran 0.20 2.00
Sodium 0.25 2.50
Borohydride
Flakes
Total 2.70 27.00
45. 4-Bromophenyl 1 4-Bromotoluene 1.16 1.16
Acetic Acid AIBN 0.01 0.01
Bromine 1.00 1.00
Sulphate
Flakes
HCl 30% 0.76 0.76
Total 3.47 3.47
46. R&D Products 70 00 0.00 0.00

.
Raw Materials & Its CAS No.
Sr. Name of Raw Materials CAS NO.

No.
1. 1,1,2 Tri chloro ethane 79-00-5
2. 1-Chloro Methyl Naphthalene 86-52-2
3. 2,2 Dimethyl Butanol 75-85-4
4. 2,4,6-Trimethyl Phenyl Acetic 4408-60-0
Acid / Mesitylene
5. 2,4-Dichloro Phenyl Acetic Acid / 19719-28-9
2-4, Di chloro Benzyl Alcohol
6. 2,5-Dimethyl Phenyl Acetic Acid 13612-34-5
7. 2,6 Di chloro Toluene 118-69-4
8. 2,6-Xylenol 576-26-1
9. 2-Amino Iso butyric Acid 62-57-7
10. 2-Amino-2-Phenyl Butyric Acid 03-07-5438
11. 2-Aminobenzamide 88-68-6
12. 2-Methyl2-Butanol 75-85-4
13. 2-Tert-Butyl-5-Methyl Phenol 88-60-8
14. 3 Bromo-2-Methyl-1-Propane -
15. 3-5,xylidene 108-69-0
16. 3-Amino Phenol 591-27-5
17. 4-Bromo anisole 104-92-7
18. 4-Bromophenyl Acetic Acid 1878-68-8
19. 4-Bromotoluene 106-38-7
20. 4-Chloro Benzaldehyde 104-88-1
21. 4-Isopropyl Phenol 99-89-8
22. Acetic Acid 64-19-7
23. Acetic Anhydride 108-24-7
24. Acetone 67-64-1
25. Acetonitrile 75-05-8
26. Acetyl Chloride 75-36-5
27. Adamantane 281-23-2
28. Adamantanol 768-95-6
29. AIBN- Azobisisobutyronitrile 78-67-1
30. Aluminum Chloride 7446-70-0
31. Ammonium Bicarbonate 1066-33-7
32. Anisole 100-66-3
33. Benzaldehyde 100-52-7
34. Benzofuran-3-one-2(Carboxylate)
35. Benzoyl Chloride 98-88-4
36. Benzyl Chloride 100-44-7
37. Bromine 7726-95-6

.

No.
38. Carbon 7440-44-0
39. Catalyst -
40. Caustic Soda Flakes 1310-73-2
41. Caustic Soda Lye 48% 1310-73-2
42. Chlorine Gas 7782-50-5
43. Choral 75-87-6
44. Copper Chloride 7447-39-4
45. Copper Sulphate 7758-98-7
46. Cupric Chloride 7447-39-4
47. Cyanuric Chloride 108-77-0
48. D V Ester 61898-95-1
49. Diethyl sulphate 64-67-5
50 Diethylene Glycol 11-46-6
51. Dimethyl Formamide 68-12-2
52. Dimethyl Sulfoxide 67-68-5
53. Dimethyl Sulphate 77-78-1
54. Ethanol 64-17-5
55. Ethyl Chloro Acetate 105-39-5
56. Ethylene Dichloride 107-06-2
57. Ethylene Dichloride 107-06-2
58. Ethylene Glycol 107-21-1
59. Formaldehyde 37% 50-00-00
60. Formic Acid 64-18-6
61. HCL 30% 7647-01-0
62. HexamethyleneTetramine 100-97-0
63. Hydrazine Hydrate 80% 7803-57-8
64. Hydro Bromic Acid 48% 10035-10-6
65. Hydrogen 1333-74-0
66. Hydrogen Peroxide (50%) 7722-84-1
67. Mesitylene 108-67-8
68. Meta Xylenol / 3-5 Xylenol 108-68-9
69. Methacrylic Acid 79-41-4
70. Methanol 67-56-1
71. Methyl 2(2-Ethoxy-2- 22511-42-8
Oxoethoxy)Benzoate
72. Methyl Salicylate 119-36-8
73. Methyl-2-chloropropionate 17639-93-9
74. Methylene Dichloride 75-09-2
75. Mono Chloro benzene 68411-45-0
76. Monoethylene Glycol 107-21-1
77. N-Butyl Alcohol 71-36-3

.

No.
78. Nitrobenzene 98-95-3
79. N-Methyl Formamide 123-39-7
80. N-Methyl-2-Pyrolidinine 872-50-4
81. O-Anialdehyde 135-02-4
82. Ortho Chloro Benzyl Cyanide 2856-63-5
83. Ortho Chloro Phenol 95-57-8
84. Ortho Dichloro Benzene 95-50-1
85. Para Chloro Phenol 106-48-9
86. Para Chloro Benzoic Acid 74-11-3
87. Para Cresol 106-44-5
88. Para Formaldehyde 30525-89-4
89. Para Hydroxy Benzaldehyde 123-08-0
90. Per Chloro Ethylene 127-18-4
91. Phenol 108-95-2
92. Phenyl Acetic Acid 103-82-2
93. PhosphorousPenta chloride 10026-13-8
94. Pivaloyl Chloride 3282-30-2
95. Poly Phosphoric Acid 8017-16-1
96. Potassium Carbonate 584-08-7
97. Potassium Hydroxide 1310-58-3
98. Potassium Iodide 7681-11-0
99. PTSA( p-Toluene sulfonic acid ) 104-15-4
100. Soda Ash 497-19-8
101. Sodamide 7782-92-5
102. Sodium Bi Carbonate 144-55-8
103. Sodium Boro Hydride 16940-66-2
104. Sodium Cyanide 143-33-9
105. Sodium Hydride 60% in Paraffin 7646-69-7
106. Sodium Hydroxide 1310-73-2
107. Sodium Hydroxide 50% 1310-73-2
108. Sodium Hydroxide Solution 7732-18-5
109. Sodium Hypochloride 7681-52-9
110. Sodium Metal 7440-23-5
111. Sodium Methoxide 124-41-4
112. Sodium Nnitrite 7632-00-0
113. Sodium Sulphate 7757-82-6
114. Sodium Thio Sulphate 7772-98-7
115. Succinic Anhydride 108-30-5
116. Sulphuric Acid 7664-93-9
117. Sulphuryl Chloride 7791-25-5
118. TBAB ( Cat. ) 1643-19-2

.

No.
119. Ter. Butanol 75-65-0
120. Tetra Ethyl Benzyl Ammonium 56-37-1
Chloride
121. Tetrahydro Furan 109-99-9
122. Tetrahydrofuran 109-99-9
123. Thionyl Chloride 7719-09-7
124. Titanium Tetrachloride 7550-45-0
125. Toluene 108-88-3
126. Tri ethyl Amine 121-44-8
127. Vinylidene Chloride 75-35-4
128. Zinc dust 74406-66-6

.
ANNEXURE VI
BREIF MANUFACTURING PROCESS:
1. 2-Amino Benzo Nitrile
Manufacturing Process:
2-Amino-benzamide is dehydrated with phosphorus penta chloride. After reaction

completion, reaction mixture was quenched in water and pH was adjusted up to 6.5-
8.5 Separate the organic layer, Product was distilled off under reduce pressure after
distillation of solvent.
Chemical Reaction:

.
Material Balance:
Material Balance of 2-AMINOBENZONITRILE
2-Aminobenzamide 1539 Kg HCl Gas

Toluene 7700 Kg Dehydration reaction 825 Kg
phosphorus pentachloride 2600 Kg
11014 Organic layer
Water 5000 Kg
Sodium hydroxide 1500 Kg Aquous layer + Phosporic acid+ sodium choloride
(Quenching,hydrolysis and
Water (for sodium hydroxide) 1500 kg 10149 KgTotal Aq layer
workup
Toluene for extraction 700 Kg 1225 Kg Phosphoric acid
2185 Kg sodium Chloride
9565 Organic layer
Distilled Toluene 8365 Kg
Distillation
Residue 200 Kg
2-AMINOBENZONITRILE
1000 Kg
2. 2,4,6-Trimethyl Benzaldehyde (Mesitaladehyde ) / 2,4,6-Trimethyl

Benzaldehyde 84% in 16% Acetone (Mesitaladehyde 84%in 16% Acetone)
Chloral and mesitylene are reacted in presence of Titanium chloride. Product obtained
is isolated after quenching, mass is hydrolyzed with soda ash to make product
mesiatldehyde. Distilled mesitsldehyde is mixed with acetone to get 84 %
concentration.
Chemical Reaction:
O H
H3C CH3
H3C CH3
TiCl 4
+ Cl3CCHO + CH3OH
Na2CO3
Chloral Methanol
CH3 MW- 147.38 MW- 32.04 CH3
Mesitylene 2,4,6 Trimethyl Benzaldehyde( Mesitaldehyde )
MW- 120.19 MW- 148.20

.
Material Balance:
Mesitylene 3360 Kg
Chloral 1134 Kg
FC Reaction
TiCl4 1460 Kg
Methanol 302 Kg
6256 Kg
Water 2000 Kg
Quenching
Ti(OH) 2 + Water
Aq Layer
and
Ice 2000 Kg 882 + 5065 Kgs
Isolation
4309 Kg
Soda ash 672 Kg
Water 1680 Kg Hydrolysis CO2 275 Kg
TEBAC 10 Kg
6396 Kg
Water 840 Kg
Washing NaCl Salt layer
3696 kg
3540 Kg
Mesitylene(R ) + water
2520 Kg
Fractionation
Mesitaldehyde fractions 100 Kg
Residue 80 Kg
Mesitaldehyde 840 Kg
Acetone 160 Kg
Mixing
1000 kg Mesitaldehyde 84 % in Acetone
3. 2,4-Dichloro Phenyl Acetyl Chloride
2, 4-Dichlorophenyl acetic acid is chlorinated with Thionyl chloride, using toluene as

solvent to convert it to 2, 4-Dichlorophenyl acetyl chloride. The product is isolated
after recovery of toluene by doing high vacuum distillation and pure product is
collected separately.
Chemical Reaction:
CH2COOH CH2COCl
Cl Cl
Toluene
+ SOCl 2 + SO2 + HCl
Cl Cl
2,4-DCPAA Thionyl Chloride 2,4-DCPACl Sulfur dioxide
MW = 205.038 MW = 119 MW = 223.48 MW = 64

.
Material Balance:
2,4-Dichlorophenyl acetic acid 1100 Kg

SO2 HCl
Chlorination
Thionyl chloride 700 Kg 375 Kg 215 Kg
Toluene 1000 kg
1150
2200 Kg
Toluene 950 kg
Fraction 100 Kg
Distillation
Residue 150 Kg
1000 Kg 2,4-Dichlorophenyl acetyl chloride
4. 2,4,6-Trimethyl Phenyl Acetyl Chloride
2,4,6-Trimethylphenyl acetic acid is chlorinated with thionyl chloride to convert it to

2,4,6-Trimethylphenyl acetyl chloride using Toluene as solvent.
Chemical Reaction:
CH3 CH3
OH Cl
O
+ SOCl2 + SO 2 + HCl
O
H3C CH3 H3C CH3
2,4-6-Trimethylphenyl acetic acidThionyl chloride 2,4-6-Trimethylphenyl acetyl chloride
MW:178.22 MW:119 MW:196.67

.
Material Balance:
2,4,6-Trimethylphenyl acetic acid 1060 Kg

SO2 HCl
Chlorination
Tolene 1500 Kg
2695 Kg
Toluene 1400 kg
Fraction 71 kg
Distillation
Residue 125 Kg
1000 Kg 2,4,6-Trimethylphenyl acetyl chloride
5. 2,4-Dichloro Meta Cresol
In this process first monobutylated Meta Cresol in the presence of toluene to form
2,4- Dichloro Meta Cresol (Tertiary) is formed then this treated with Aluminium
Chloride obtained crude 2,4- Meta Cresol which is purified by salt formation and
distillation get pure 2,4- Di chloro Meta Cresol
2-Tert-butyl-5-Methyl phenol and Aluminum chloride are charged in chlorinator and
chlorine gas is purged at elevated temp.chlorination to make 2-tert-4,6-dichloro-5-
methyl phenol.Then in reaction mass again Aluminum chloride and toluene is charged
for dealkylation and Then Reaction mass is quenched in HCl+Water. Organic mass
after washing is distilled un reduced pressure to get pure 2,4-Dichloro meta cresol
Chemical Reaction:
CH3 OH CH3 OH
H3C H3C
Cl
AlCl 3
H3C + 2-Cl 2 H3C + 2 HCl
CH3 CH3
Cl
2-tert Butyl-5-Methyl Phenol 2-tert Butyl-4,6-Dichloro-5-Methyl Phenol
MW: 164.14 MW: 235.15
CH3 OH OH
H3C
Cl Cl
H3C
AlCl 3 + 2 HCl
CH3 Toluene CH3
Cl Cl
2-tert Butyl-4,6-Dichloro-5-Methyl Phenol 2,4-Dichloro meta cresol
MW: 235.15 MW: 179.04

.
Material Balance:
562 Hydrochloric Gas

Chlorine gas 900
Stage-1
Chlorination 1000 2-Ter Butyl 5-Methyl Phenol
Toluene 1000 (Mono Butylated Meta Cresol)
Degasing
2,4- Dichlro Meta

Cresol (Ter.)
2338 Crude 2,4- Meta Cresol (Ter.)+ Toluene

Stage-2
Aluminium Chloride 400 Reaction 1500 Toluene
500 Ice
Water 500 Quenching
2000 30 % Hydrochloric Acid
4000 Aqueous layer to ETP
Toluene + Crude 2,4-Dichloro Meta Cresol
200 Sodium Hydroxide

Salt Formation
1000 Water
2400 Toluene layer distilled and reused
Acidification 600 30% Hydrochloric Acid
1538 Aqueous layer to ETP

Crude 2,4- Dichloro Meta Cresol 1100
Distillation 100 Distillation residue to incinerator
1000
2,4- Dichloro Meta Cresol
Neutralization of Aqueous Layer
Acidic Waste 5538

Neutralization
Caustic Flakes 300
250 NaCl
Filtration
5588 Effluent

.
6. 2-Chloro-4,6 Dimethoxy-1,3,5-Triazine
Cyanuric chloride is reacted with methanol in presence of Sodium bicarbonate to

make 2-Chloro-4,6-dimethoxy-1,3,5-Triazine.After reaction mass is washed and
organic mass distilled under vacuum and flakes are made.
Chemical Reaction:
Cl Cl
N N NaHCO3 N N
+ 2 CH3OH + 2 NaCl
Cl N Cl H3CO N OCH3
Cyanuric Chloride Methanol 2-Chloro-4,6-Di Methoxy-1,3,5-Triazine

M.W 184.41 M.W. 32 M.W 175.57

.
Material Balance:
Methanol 3000 kg
Sod.bicarbonate 2000 Kg
Methylation Reaction CO2 Gas 900 Kg
Cyanuric chloride 1887 Kg
5987 Kg
Chilled Water 2500 Kg
Quenching
8487 Kg
Water for washing 200 Kg NaCl Methanol Water
Filtration
1100 Kg 2300 Kg 3507 Kg
Wet cake 1780 Kg

Water 580 Kg
Distillation Pitch 200 Kg
1000 Kg
Flaking
1000 kg Product
7. 2-Coumaranone 30%,Acetic Anhydride70 %
Ortho chloro benzyl cyanide (OCCN) is converted to ortho hydroxyl phenyl acetic
acid sodium salt in Autoclave. Autoclave mass is acidified with HCl to make Ortho
hydroxyl phenyl acetic acid (OHPAA).This OHPAA is then cyclized removing water
azotropically using toluene to make 2-Couraranone (2-C).
2-Coumaranone is blended with acetic anhydride to make 30 % 2-Coumaranonein
Acetic anhydride solution.

.
Chemical Reaction:
CH2CN CH2COONH2 CH2COONa
Cl Cl Cl
NaOH -H2O
+ H2O + NaOH + NH3
OCCN C.flakes OCPA-AMIDE OCPAA-Na

mw 151.6 mw 40 mw 185.6 mw 192.57
CH2COONa CH2COONa
Cl OH
H2O
+ NaOH
CuSO4
+ NaCl
OCPAA-Na OHPAA
MW:192.57 MW:174.12
CH2COONa CH2COOH
OH OH
+ HCl + NaCl
OCPAA-Na OHPAA
MW: 174.12 MW: 152.15
CH2COOH
OH
-H2O
Toluene
O + H2O
O
OHPAA 2 Coumaranone
MW: 152.14 MW: 134.13

.
Material Balance:
OCCN 476 Kg
48% NaOH 330 Kg Hydrolysis NH3,( Scrubbed 24% aq. NH3)
Water 257 Kg (1248 Kg) 53 kg 220 kg
Water 185 Kg
Na salt of OCPAA
(1195 Kg)
CuSO4 29 Kg
Autoclave
48% NaOH 550 Kg
(1806 Kg)
Water 32 Kg
Nutch Filtration CuSO4 sludge 16 Kg

(1790 Kg)
30% HCl 524 Kg Neutralisation CuSO4 sludge 32 Kg

(2282 Kg)
30% HCl 445 Kg Acidifier

(2727 Kg)
Belt filter ML 2227 kg

(2727 Kg)
Wet OHPAA (500 kgs)
Toluene 300 kg Cyclisation Water 165 Kg

(635 Kg)
Toluene (R ) 290 Kg
Distillation
Int cut 23 Kg
(635 Kg)
Residue 15 Kg
2-C DISTILLED (300 kgs)
BLENDING TANK 1000 KGS

Acetic Anhydride 700 Kg
30% 2C + 70% Acetic Anhydride
soln.

.
8. 3,4,5 Trimethoxy Toluene
Para cresol is brominated with Hydro bromic acid with help of Hydrgen peroxide to
produce 2, 6-Dibromo para cresol. Then this dibromo para cresol is converted in to 2,
4, 6-Trimethoxy toluene by using sodium metal and methanol. After washing material
is distilled to get pure 3,4,5-Trimethoxy toluene
Chemical Reaction:
CH 3 CH 3
+ HBr + H 2O 2
+ HBr
Br Br
OH OH
Para Cresol 2,6-Dibromo-Para Cresol
MW: 108.13 MW: 265.93
CH CH 3
3
Br Br
+ NaOCH 3 + CH 3 OH
CuCl 2
H 3 CO OCH 3
OH Sod.Methoxide OCH 3
2,6-Dibromo-Para Cresol 3,4,5-Trimethoxy toluene

MW: 182.22
MW: 265.93

.
Material Balance:
Para Cresol 800 kg
Hydrobromic Acid (48%) 2688 kg BROMINATION HBr + water 2000 kg
Hydrogen Peroxide(50%) 1032 kg
2520 kg
Toluene 3000 kg DISTILLATION Toluene ® 1000 kg
4520 kg
Cooper Iodide 25 kg
Sodium Metal 360 kg METHYALATION Methanol ® 1975 kg
Methanol 2370 kg
Dimethyl Formamide 160 kg
5460 kg
Sulphuric Acid 800 kg H2SO4 + water

WASHING 800 kg 1000 kg
Water 1000 kg NaBr sol. 2500 kg
Toluene ® 1600 kg
1800 kg
Intercut 600 kg
DISTILLATION
Residue 200 kg
3,4,5Trimethoxy Toluene = 1000 KG
9. 3,4,5-Trimethoxy Benzoic Acid
Para cresol is brominated with Hydro bromic acid with help of Hydrgen peroxide to
produce 2,6-Dibromo para cresol. Then this dibromo Para cresol is converted in to
2,4,6-Trimethoxy toluene by using sodium metal and methanol. After washing
material is distilled to get pure 3,4,5-Trimethoxy toluene. Then this Trimethoxy
toluene is converted in to 3,4,5 Trimethoxy Benzoic Acid by air oxidation in
Autoclave.

.
Chemical Reaction:
CH3 CH3
+ HBr + H2O2
+ HBr
Br Br
OH OH
Para Cresol 2,6-Dibromo-Para Cresol
MW: 108.13 MW: 265.93
CH3
CH3
+ + +
NaOCH3 CH3OH
CuCl2
Br Br H3CO OCH3
Sod.Methoxide OCH3
OH
2,6-Dibromo-Para Cresol 3,4,5-Trimethoxy toluene
MW: 265.93 MW: 182.22
CH3 COOH
Air oxidation
OCH3 H3CO OCH3

H3CO
OCH3 OCH3
3,4,5-Trimethoxy toluene 3,4,5-Trimethoxy Benzoic Acid

MW: 182.22 MW:212.20

.
Material Balance:
Para Cresol 800 kg
Hydro bromic Acid(48%) 2688 kg BROMINATION HBr + water 2000 kg
Hydrogen Peroxide(50%) 1032 kg
2520 kg
Toluene 3000 kg DISTILLATION Toluene ® 1000 kg
4520 kg
Cooper Iodide 25 kg
Sodium Metal 360 kg METHYALATION Methanol ® 1975 kg
Methanol 2370 kg
Dimethyl Formamide 160 kg
5460 kg
Sulphuric Acid 800 kg H2SO4 + water

WASHING 800 kg 1000 kg
Water 1000 kg NaBr sol. 2500 kg
Toluene ® 1160 kg
1800 kg
Intercut 600 kg
DISTILLATION
Residue 200 kg
1000 kg
Air
AIR OXIDATION
Cooper Iodide 25 kg
Methanol 500 kg AUTOCLAVE
1525 kg
Methanol ® 485 kg
RECOVERY
Copper salt 20 kg
3,4,5 Trimethoxy Benzoic Acid - 1000 kg

.
10. 2-5 Dimethyl Phenyl Acetyl Chloride
2, 5-Dimethylphenyl acetic acid is chlorinated with thionyl chloride to convert it to

2, 5-Dimethylphenyl acetyl chloride using Toluene as solvent.
Chemical Reaction:
OH Cl
O
+ SOCl 2
O
+ SO 2 + HCl
H3C CH3 H3C CH3
2,5-Dimethylphenyl acetic acid Thionyl chloride 2,5-Dimethylphenyl acetyl chloride
MW:164.20 MW:119 MW:182.65
Material Balance:
2,5-Dimethylphenyl acetic acid1000 Kg

SO2 HCl
Chlorination
Tolene 1000 kg
2131 Kg
Toluene 950 Kg
Fraction 31 Kg
Distillation
Residue 100 Kg
1000 Kg 2,5-Dimethylphenyl acetyl chloride
11. N Methyl 1-Napthalene Methyl Amine Acetate
1-Chloromethyl naphthalene is reacted with n-Methyl formamide in presence of

Sodium hydride and Dimethyl formamide to make N-(Methyl-formyl) methyl
naphthalene. This N-(Methyl-formyl) methyl naphthalene is then hydrolyzed with
sulphuric acid and neutralized with caustic solution to get N-Methyl -1-Naphtahlene
Methyl Amine base which is distilled under partial vacuum. Base is reacted with
Acetic acid in presence of toluene to make Acetate salt.

.
Chemical Reaction:
CH3
Cl
N O
O
NH H
DMF
+ H3C H + NaH
+ H2 + NaCl
Methyl Formamide
M.Wt:- 59.06 Sodium Hydride
1-Chloromethyl Naphthalene N-(Methyl-formyl)methyl Naphthalene
M.Wt:- 23.99
M.Wt:- 176.64 M.Wt:- 199.24
CH3 CH3
N O N
H
H
NaOH
+ H2SO4 + Na2SO4
Sulfuric Acid
N-(Methyl-formyl)methyl NaphthaleneM.Wt:- 98.07
N-methyl-1-(1-naphthyl)methanamine
M.Wt:- 199.24
M.Wt:- 171.23
CH3 CH3
N N
H H:CH3COOH
Toluene
+ CH3COOH
N-methyl-1-(1-naphthyl)methanamine N-methyl-1-(1-naphthyl)methanamine-Acetate
M.Wt:- 171.23 M.Wt:- 231.29

.
Material Balance:
DMF 2093 Kg
NaH 60 % 283 Kg
Coupling Reaction
NMF 523 Kg (4469 Kg)
1-CMN+Toluene 1047+523 Kg
4454 kg
Water 2093 Kg
Washing
Water + NaCl + DMF
(6547 Kg)
2093 421 2018
2015 Kg
Water 1570 Kg
Hydrolysis
H2SO4 1047 Kg (4632 Kg) Organic layer 968 Kg
Toluen+DMF
3664 Kg
50 % NaOH 2302 Kg
Neutralization
Aqueous layer 4947 Kg
(6174 Kg)
Toluene 208 Kg
1227 Kg
Toluene (R ) + water 264 Kg
Distillation
(1227 Kg) Residue 82 Kg
N-MAN Base 880 Kg

Toluene 5909 Kg
Acidiculation
Acetic acid 289 Kg
(7078 Kg)
Filtration
Toluene ML 6053 Kg
(7078 Kg)
Drying
(1025 Kg)
1000 kg
N-Methyl -1-Naphtahlene Methyl Amine Acetate
12. N Methyl 1-Napthalene Methyl Amine Base

Methyl Amine base.

.
Chemical Reaction:
CH3
Cl
N O
O
NH H
DMF
+ H3C H + NaH
+ H2 + NaCl
Methyl Formamide
M.Wt:- 23.99
M.Wt:- 176.64 M.Wt:- 199.24
CH3 CH3
N O N
H
H
NaOH
+ H2SO4 + Na2SO4
Sulfuric Acid
N-(Methyl-formyl)methyl Naphthalene M.Wt:- 98.07
M.Wt:- 199.24
M.Wt:- 171.23

.
Material Balance:
DMF 2378 Kg
NaH 60 % 321Kg
Coupling Reaction
NMF 595 Kg
5062 kg
Water 2378 Kg
Washing
Water + NaCl + DMF
2378 469 2293
2300 Kg
Water 1784 Kg
Hydrolysis
H2SO4 1189 Kg Organic layer 900 Kg
Toluen+DMF
4373 Kg
50 % NaOH 2616 Kg
Neutralization
Sod sulphate Aqueous layer 5823 Kg
Toluene 237 Kg
1403 Kg
Distillation
Residue 103 Kg
1000 Kg
N-Methyl -1-Naphtahlene Methyl Amine Base
13. 5-Chloro-2-Hydroxy Benzo phenone
Freidel craft reaction of Para chloro phenol (PCP) and Benzoyl chloride (BOC) with
Aluminum chloride is carried out in presence Ortho di chloro benzene (ODCB) as
solvent to make product 5-Chloro-2-Hydroxy benzo phenone (5-Cl-2-H-BP).
Chemical Reaction:
OH OH O
O
Cl AlCl 3
+ + HCl
ODCB
Cl Cl
Para Chloro Phenol Benzoyl chloride 5-Chloro-2-Hydroxy Benzophenone
PCP BOC
MW 128.56 MW 140.57 MW 232.66

.
Material Balance:
ODCB 1000 Kg
AlCl3 800 Kg HCl 217 Kg

FC Reaction
PCP 720 Kg
Benzoyl chloride 845 Kg
3148 Kg
Drowning
HCl 30 % 500 Kg AlCl3 + Aq Layer
Chilled Water 4000 Kg 800 Kg 5428 Kg
2220 Kg
ODCB (R ) 950 Kg
Distillation
Residue 150 Kg
1120 Kg
Methanol 1395 Kg
Crystallization
2515 Kg
Methanol ML
Filtration
1465 Kg
1050 Kg
Drying
1000 kg 5-Chloro-2-hydroxy benzophenone

.
14. 2-Amino 4 Hydroxy Acetophenone
3-Aminophenol’s, hydroxy and amino groups are protected with acetyl group by
reacting with acetyl chloride in presence of Soda ash. Thus 3-Acetamido phenyl
acetate forms is heated in presence of aluminum chloride for fries rearrangement to
make N-(2-Acetyl-5-Hydroxyphenyl) acetamide.
This then converted to 2-Amino-4-Hydroxyacetophenone by reacting with Sodium
methoxide in toluene.
The final product is fractionated under high vacuum to get 2-Amino-4
Hydroxyacetophenone.
Chemical Reaction:
Step 01: Preparation of 3-Acetamidopheyl acetate
HO NH2 CH3COO NHCOCH

3
Nitrobenzene
+ 2-CH3COCl
Soda ash
+ 2 NaCl + 2 CO2
3-Amino phenol Acetyl chloride 3-acetamidophenyl acetate

MW:109.12 MW:78.49 MW:193.19
Step 02: Preparation of N-(2-Acetyl-5-hydroxyphenyl) acetamide
HO NHCOCH
3
CH3COO NHCOCH
3 Fries rearragement
AlCl3
COCH3
3-acetamidophenyl acetate N-(2-acetyl-5-hydroxyphenyl)acetamide
MW:193.19 MW:193.19
Step 03: Preparation of 2-Amino-4-Hydroxyacetophenone
HO NH2
HO NHCOCH
3
NaOMe
Toluene COCH3
COCH3
N-(2-acetyl-5-hydroxyphenyl)acetamide 2-Amino-4-Hydroxyacetophenone
MW:193.19 MW:151.16

.
Material Balance:
Material Balance
Step 01 : Prepration of 3-Acetamidophenylacetate
3-Aminophenol 1050 Kg
Nitrobenzene 1050 Kg
Soda ash 1300 Kg Reaction
Acetyl chloride 1600 Kg
Nitrogen purging
5000 Kg
Water 1500 Kg Aq.Layer 3620 Kg
Washing
Water 500 Kg Water wash 500 Kg
Reaction mass 2880 Kg

Sodium sulphate 50 Kg
Dehydration
Org Layer 2930 Kg

Wet Cake waste 55 Kg
Filtration
Prod Step 01+Nitrobenzene 2875 Kg
Step 02 : N-(2-Acetyl-5-Hydroxyphenyl)acetamide
Step 01 +Nitrobenzene 2875 Kg

Fries Rearangment
Aluminum Chloride 1720 Kg
R.mass 4595 Kg
Ice+Water 2850 Kg
Quenching
HCl 30 % 1880 Kg
9325 Kg
5 % Soda ash wash 500 Kg Aq layer waste 6585 Kg
Separation
Water wash 510 Kg
Wet cake 2730 Kg

Soda ash dry 50 Kg Soda ash wet cake for reuse 55 Kg
Dehydration
Org layer 2725 Kg

Nitrobenzene (R ) 900 Kg
Nitrobenzene Recovery
1825 Kg Step 02 Bottom [Cr.N-(2-Acetyl-5-Hydroxyphenyl)acetamide]

.
Step 03 : Preparation of 2-Amino-4-hydroxy acetophenone
Step 02 Cr.bottom 1825 Kg

Toluene 1000 Kg Reaction
Sod Methoxide 600 Kg
Water 800 Kg Layer Separation Aq.waste 1973 Kg
Org Layer 2252 Kg

Toluene (R ) 912 Kg
Fractional Distilation Fractions 210 Kg
Residue 130 Kg
Prod: 1000 kg 2-Amino-4-Hydroxy acetophenone
15. 3-coumaranone
In first step Ethylchloro Acetate is added to Methyl Salicylate, Dimethyl formamide

and Potassium Carbonate after reaction Potassium Chloride salt is filtered then after
Dimethyl Formamide recovery product Methyl 2 (2-Ethoxy-2-Oxoethoxy) Benzoate
is obtained. In second step Carboxylation of Methyl 2 (2-Ethoxy-2-Oxoethoxy)
Benzoate the product Benzofuran-3-One-2 (Carboxylate) is obtained and Hydrolysis
of this product gives 3-Coumaranone

.
Chemical Reaction:
STEP I
COOCH3 O
OH Cl
K2CO3/Tolune
+
Catalyst
OC2H5
Methyl Salicylate M.W.=152 Ethyl Chloroacetate M.W.=122
COOCH3 O
O OC2H5
Methyl 2 (2-Ethoxy-2-Oxoethoxy) Benzoate
STEP II
O
COOCH3 O CH3ONa/Toluene
COOCH3
HCl O
O OC2H5
Methyl 2 (2-Ethoxy-2-Oxoethoxy) Benzoate Benzofuran-3-One-2 (Carboxylate) M.W.=192

STEP III
O O
COOCH3 KOH/Methanol
O O
Benzofuran-3-One-2 (Carboxylate) M.W.=192 3-Coumaranone M.W.=134

.
Material Balance:
Ethyl Chloro Acetate 700

Step-1 700 Methyl Salicylate
Potassium Carbonate 700 Reaction
3500 Dimethyl Formamide
Centrifuge 1000 KCl
Distillation 3200 Dimethyl Formamide Recovery for next batch
100 Residue to incinerator

Methyl 2 (2-Ethoxy-2-Oxoethoxy) Benzoate 1300
Step-2
Sodium Methoxide 800 Carboxylation 3000 Toluene Layer (D) 2700
Addition of Water= 3000
30 % Hydrochloric Acid 1200 Acidification 3000 Toluene layer
Benzofuran-3-One-2(Carboxylate) 5100 Waste water to ETP

1200
1200 Water
Hydrolysis 500 Potassium Hydroxide
1800 Methanol
30 % Hydrochloric Acid 1500 Acidification
5000 Waste water to ETP

Crude 3-Coumarnone 1200
Toluene 1100
Purification
Carbon 50
295 Waste Water to ETP
Filter
55 Carbon + Waste
Centrifuge 1000 Toulene distilled an reused for next batch
1000
Pure 3-Coumaranone

.
Acidic Waste 10195

Neutralization
Caustic Flakes 400
500 NaCl
Filtration
10095 Effluent
16. 3, 3 Dimethyl Butyrl Chloride
This is three step process. In first step hydrolysis of 1,1,2-Trichloroethane by using

sodium hydroxide solution in presence of carbon at low temperature to form
Vinylidene Chloride during reaction Vinylidene Chloride is collected in receiver. In
second step condensation is carried out by using (Vinylidene Chloride + Ter. Butanol)
mixture is added to H2SO4 at low temperature. After quenching crude 3,3- Dimethyl
Butyric Acid is formed after distillation pure material is collected and next reaction
takes place in Thionyl Chloride to produce 3, 3- Dimethyl Butyryl Chloride

.
Chemical Reaction:
ROS OF 3 3 DimethylButyryl Chloride
Cl
NaCl
+ NaOH
H 2C
C
Cl
+
CH 2 HC
Cl
Cl Cl
1,1,2-Trichloro ethane M.W.=133 Vinylidene Chloride M.W.=96.94
Cl O
H 2SO 4
OH + H2C Cl OH + 2 HCl
Tert. Butanol M.W.=88 Vinylidene chloride =96.94 3,3-Dimethyl Butyric acid M.W.=116
O
O O O
S Distill
Cl Cl
Cl + 2
OH So +HCl
Cl
Addslowly
(Crude) (Purematerial)
3,3-Dimethyl Butyric acid Thionyl Chloride 3,3-Dimethyl Butyryl Chloride M.W= 135
M.W.=116 M.W.=119

.
Material Balance:
Step-1 1182 Sodium hydroxide
1,1,2- Trichloroethane 1970 Hydrolysis 5900 Water
10 Carbon
7687 NaCl +Water to ETP
1375 Vinylidene Chloride
Ter. Butanol
Ter. Butanol 737 Step-2
Condensation 600 Hydrochloric Gas
Sulphuric Acid 10119
Ice 2000
Quenching 14601 Waste water to ETP
Water 2000
1030 Crude 3,3- DMBA
Distillation 50 Distillation Residue to incinerator
Thionyl Chloride 1176 980 Pure 3,3-DMBC

Step-3 540 Sulfur Dioxide Gas
Thionylation
Pure DMBC 980 300 Hydrochloric Gas
Vapour Loss 100 1250 Crude DMBC
1000 Pure DMBC
Neutralization of Aqueous Layer 14601 Acid Waste
Caustic Flakes 1500 Neutralization
2000 Na2SO4
Filtration
14101 Effluent
17. 4-bromo Anisole
This is single Step reaction. Anisole is Brominated by using Bromine and Hydrogen
Peroxide. After reaction Crude material of 4-Bromo Anisole is obtained. Crude
Material Washing by using Sodium Hydroxide solution. After distillation pure 4-
Bromo Anisole is formed.

.
Chemical Reaction:
OCH3
OCH3
Acetic acid/Br2
+ HBr + H2O2
NaOH + NaBr
Anisole M.W.=108
Br
4-Bromo Anisole M.W.=187
Material Balance:
Hydrogen Peroxide(50 %) 300

Step-1 750 Anisole
Bromination 250 Water
700 Bromine
500 Water
Washing
1200 Crude 4-Bromo Anisole

500 Water
Washing
50 Sodium Hydroxide Solution
550 Waste Water to ETP (NaBr)
Washing 500 water

100 Vapour Loss
Distillation
100 Residue to incinarator
1000
Pure 4-Bromo Anisole

.
18. 4-Cyano Benzoic Acid
To the stirred solution of 4-chlorobenzoic acid in DMF was added catalytical

amount of potassium iodide and sodium cyanide by lot-wise at 20-25oC. Reaction
maintain at 110-115oC for 12 hr. for completion. Recover the DMF and add water.
Filter the product, wash with plenty of water, followed by slurry wash with
cyclohexane. Recover the cyclohexane from the filtrate, to get back the un-reacted
4-chlorobenzoic acid and the residue is dry in oven to afford pure 4-Cyanobenzoic
acid.
Chemical Reaction:
NaCN
KI
Cl CN
DMF
+ NaCl + KI + DMF (R)
HOOC HOOC
4-Chlorobenzoic acid 4-Cyano-benzoic acid Sodium chloride Potassium iodide
C7H5ClO2 C8H5NO2 ClNa IK
Mol. Wt.: 156.57 Mol. Wt.: 147.13 Mol. Wt.: 58.44 Mol. Wt.: 166.00

.
Material Balance:
19. 7-Hydroxy 1 Tetralone
Anisole is reacted with Succinic anhydride in presence of Aluminum chloride to make

4-(4-Methoxyphenyl)-4-oxobutyric acid (MPOB).After washing/ isolation, this is
reacted with Hydrazine hydrate 80% in presence of Potassium hydroxide to reduce to
4-(4-Methoxyphenyl)-butyric acid (MPPB). 4-(4-Methoxyphenyl)-butyric acid is then
cyclalized to 7-Methoxy -1-tetralon by using Poly phosphoric acid. After isolation
/washing this 7-Methoxy -1-tetralon is demethylated in presence of Aluminum
chloride to make 7-Hydroxy -1-tetralon.

.
Chemical Reaction:
Step: 01 Preparation of 4-(4-Methoxyphenyl)-4-oxoburtyric acid

O O
O O
H3C H3C OH
+ O
EDC+AlCl3 + Al2O3 + HCl
O
O
Anisole Succinic anhydride 4-(4-Methoxyphenyl)-4-Oxobutyric acid Aluminium oxide
MW:108.14 MW:100.07 MW:208.21 MW:101.96
Step: 02 Preparation of 4-(4-Methoxyphenyl)-burtyric acid

O
O
O
H3C OH O
KOH , DEG H3C OH
+ NH2NH2 + N2
O 4-(4-Methoxyphenyl)-butyric acid
4-(4-Methoxyphenyl)-4-Oxobutyric acid
MW:194.23
MW:208.21
Step: 03 Preparation of 7-Methoxy-1-tetralone
O
O
O
H3C OH O
+ PPA H3C
+ H3PO4
4-(4-Methoxyphenyl)-butyric acid Poly phosphoric acid 7-Methoxy-1-tetralone

MW:194.23 MW:176.21
Step: 04 Preparation of 7-Hydroxy-1-tetralone
O O
O HO
H3C AlCl3
Toluene + CH3OH + Al2O3
7-Methoxy-1-tetralone 7-Hydroxy-1-tetralone Methanol Aluminium oxide

MW:176.21 MW:176.21 MW:32.04 MW:101.96

.
Material Balance:
Material Balance
Step 01 : Prepration of 4-(4-Methoxyphenyl)-4-oxobutyric acid (MPOB)
Anisole 864 Kg
Ethylene dichloride 1728 Kg HCl to scrubber 290 Kg
F.C.Reaction
Aluminum chloride 1065 Kg
Succinic anhydride 800 Kg
4167
Ice+Water 2000 Kg
Quenching
HCl 30 % 300 Kg

EDC Mother Liquor 1800 Kg
Filtration
Aq.Layer 3067 Kg
Wet cake 1600 Kg

Drying
Prod Step 01 MPOB 1497 Kg
Step 02 : 4-(4-Methoxyphenyl)-butyric acid (MPPB)
Step 01 MPOB 1497 Kg

Hydrazine hydrate 80% 288 Kg Nitrogen Gas 200 Kg
Reduction
Potassium hydroxide KOH 404 Kg
Diethylene glycol 749 Kg
Solvent recovery DEG (R ) for recycle 802 Kg
Bottom 1936 Kg
Ice+Water 1000 Kg
Quenching
2936 Kg
HCl 30 % 875 Kg
Acidification
3811Kg
Water 100 Kg Aq layer waste 2550 Kg
Filtration
Wet cake 1361 Kg

Water loss 34 Kg
Drying
Prod: 1327 kg 4-(4-Methoxyphenyl)-butyric acid

.
Step 03 : Preparation of 7-Methoxy-1-tetralone (7MxT)
Step 02 MPPB 1327 Kg

Cyclization
Polyphosphoric acid 663 Kg
R.mass 1990 Kg
Ice+Water 1327 Kg
Quenching
3317 Kg
Filtration
Wet cake 1244 Kg

Water loss 100 Kg
Drying
Prod: 1144 kg 7-Methoxy-1-tetralone
Step 04 : 7-Hydroxy-1-tetralone (7HxT)
Step 03 7MxT 1144 Kg

Toluene 1144 Kg Demethylation HCl Gas 710 Kg
Aluminum chloride 865 Kg
Layer Separation Toluene layer for recovery 1066 Kg
1377 Kg
HCl 30 % 875 Kg
Acidification
Water 1144 Kg
3396 Kg
Filtration
Wet cake 1050 Kg

Water loss 50 Kg
Drying
Prod: 1000 kg 7-Hydroxy-1-tetralone
Mother liquor distillation
Water for reuse 90 Kg

EDC Mother Liquor 1800 Kg Distillation EDC(D) 1620 Kg
Residue 90 Kg
Diethylene Glycol Recovery

DEG (R ) for recycle 802 Kg Distillation DEG (D) 712 Kg
Residue 40 Kg
Toluene Recovery
Toluene layer for recovery 1066 Kg Distillation Toluene (D) 1030 Kg

Residue 36 Kg

.
20. Atropic acid
To the stirred solution of phenyl acetic acid in toluene was added potassium
carbonate, para formaldehyde and catalytical amount of tetra butyl ammonium
bromide at 20-25oC. Reaction maintain at 105-110oC for 12 hr. After completion,
quench with water, acidify with HCl to pH 1-2 and separate the layers. Organic
layer, distil-off the toluene to afford the pure atropic acid / 2-phenylpropenoic acid.
Chemical Reaction:
para HCHO
K2CO3 / TBAB
Toluene
OH OH
HCl (30%)
+ 2 KCl + TBAB (cat.) + 2 H2O + CO2 (g)
O O
Phenyl aceticacid Atropic acid

C8H8O2 C9H8O2
Mol. Wt.: 136.15 Mol. Wt.: 148.16
MP: 76-78oC MP: 105-109oC

.
Material Balance:
21. 4-chloro Benzaldehyde Glycol Acetal
4-Chlorobenzaldehdye is reacted with ethylene glycol in presence of p-toluesulphonic

acid and toluene. Thus water formed is collected azotropically. After completion of
reaction toluene is recovered and rest is fractionated to get pure product.

.
Chemical Reaction:
CHO Toluene
OH Cl
+ HO PTSA
Cl
p-Chloro benzaldehyde Ethylene Glycol 2-(4-Chlorophenyl)-1,3-Dioxolane

MW:140.56 MW: 62.06 MW:176.64
Material Balance:
4-Chlorobenzadehyde 900 Kg
Toluene 1000 Kg
Reaction
Water 110 Kg
Ethylene Glycol (MEG) 430 Kg Toluene 100 Kg
Water 200 Kg Effluent 200 Kg

Washing

Toluene (R ) 840 Kg
Distillation Fractions 200 Kg
Pitch 60 Kg
1000 kg 2-(4-Chlorophenyl)-1,3-dioxolane
22. 2,2-Dichloro-2 Phenyl Acetic Acid Ethyl Ester
This is three step reaction. In first step Thionylation of Phenyl Acetic Acid form
Phenyl Acetyl Chloride obtained. In the second step phenyl Acetyl Chloride is
chlorinated to form Alpha Alpha - Dichloro Phenyl Acetic Acid in presence of
catalyst then esterification of Alpha Alpha - Dichloro Phenyl Acetic Acid to form
Alpha Alpha Di chloro Phenyl Acetic Acid Ethyl Ester (DCPAC).

.
Chemical Reaction:
CH2COCl
CH2COOH
+ Socl2 + SO2 + HCl
P.Acetyl Chloride M.W.=147

O
Phenyl acetic acid M.W.=136
Cl
CH2COCl Cl
C
Cl
+ Cl2 + 2HCl
P.Acetyl Chloride M.W.=147 Alpha alpha dichloro phenyl acetyl chloride M.W =223
O
O
Cl
Cl C2H5
C Cl
Cl C
Cl
-
+ C2H5 --OH
HCl
+
Alpha alpha dichloro phenyl acetyl chloride M.W =223Alpha alpha dichloro phenyl ethyl ester M.W =217

.
Material Balance:
Hydrochloric Gas 241 423 Sulfur Dioxide Gas
Step-1 900 Phenyl Acetic Acid

Thionylation
900 Thionyl Chloride
Chlorine Gas Passed 550 1136 Crude Phenyl Acetyl Chloride

Step-2
Chlorination 9 (Catalyst)
Hydrochloric Gas 500
Hydrochloric Gas 295 1195 Alpha Alpha Dichloro Phenyl Acetyl Chloride Crude
Step-3
Esterification 400 Ethanol
Washing 1000 Water
1000
Alpha Alpha Dichloro Phenyl Acetic Acid Ethyl Ester (DCPAC)
100 NaCl
Filtration
1200 Effluent

.
23. Para Chloro Meta Xylenol BP
Meta Xylenol is chlorinated with Chlorine in presence of Cupric chloride and

Hydrochloric acid (HCl) to make Para Chloro Meta Xylenol (PCMX). Reaction mass
is filtered to get brown colored PCMX and Mother liquor is recycled after top up
fresh meta xylenol , HCl 30 % and cupric chloride. Brown colored PCMX is purified
in Perchloro ethylene (PCE) to make BP grade PCMX.
Chemical Reaction:
OH OH
CuCl2
+ Cl2
HCl / Water
+ HCl
H3C CH3 H3C CH3

Cl
Meta xylenol Chlorine Para Chloro Meta xylenol
MW:122.16 MW: 71 MW:156.60

.
Material Balance:
Meta xylenol 1000 kg

HCl gas to scruber 300 Kg
Hydro chloric acid(HCl) 5000 Kg
Chlorination
Mother liquor for recycle
Cupric chloride 400 Kg 5285 Kg
Chlorine 585 Kg HCl 30 % 115 Kg + CuCl2 10 Kg for recycle make up
6685 Kg
Mother Liquor to Chlorination step for recycle
Water wash 200 Kg Filtration 5285 Kg
Effluent from wash
300 Kg
Wet Brown PCMX 1300 Kg
Drying
Dry Brown PCMX 1200 Kg

Purification of brown PCMX
Per chloro ethylene(PCE) 2600 Kg

Purification
Brown PCMX 1200 Kg
Wet cake 3800 Kg
PCE 25 Kg Filtration Mother Liquor 2775 Kg
1050 Kg
Drying
1000 kg Para chloro meta xylenol BP
Distillation of ML and top up for recycle
Solvent recovery
Vapour loss 100 Kg

Mother Liquor 2775 Kg Distillation PCE (R ) for recycle 2450 Kg
Chloroxylenols residue
225 Kg
24. Pivaloacetonitrile
Methyl pivalate is prepared by adding methanol in Pivaloyl chloride at low temp. This
methyl pivalate is then charged with toluene, acetonitrile in reactor and Sodamide is
added slowly. After reaction, mass is acidified and Pivaloyl acetonitrile is isolated
from toluene layer by recovering toluene, crystallization, filtration and drying.

.
Chemical Reaction:
CH3 O CH3 O
H3C
+ CH3OH H3C + HCl
CH3 Cl CH3 OCH3
Pivaloyl chloride Methanol Methyl Pivalate
MW: 120.57 MW: 32.04 MW: 116.15
CH3 O CH3 O
NaNH2
H3C + CH3CN H3C + CH3OH + NH3
CH3 OCH3 CH3 N
Methyl Pivalate Acetonitrile Pivaloyl acetonitrile Methanol Ammonia

MW: 116.15 MW: 41.05 MW: 125.57
Material Balance:
Methanol 350 Kg
Pivaloyl Chloride 1300 Kg Esterification HCl gas 390 Kg
1260 Kg
Toluene 3000 Kg
Acetonitrile 570 Kg Reaction Ammonia gas 210 Kg
Sodamide 570 Kg
Water 500 Kg
HCl 30% 1425 Kg Layer separation Aqueous waste 3045 Kg
Water 500 Kg Water wash 530 Kg
Cr PACN+Tol = 4250 Kg
Toluene (R ) 2000 Kg
Toluene recovery
Bottom 2250 Kg
Crystalization
2250 Kg
Mother liquor 1170 Kg
Filtration
Wet cake 1080 Kg

Drying
1000 Kg Pivaloyl acetonitrile
Mother liquor distillation

Toluene Mother Liquor 1170 Kg Distillation Toluene (D) 820 Kg
Residue (bottom) 335 Kg

.
25. 3-Chloro2- Methyl Anisole
2,6-Dichlorotoluene is methylated with Sodium Methoxide by using

Dimethylsulfoxide (DMSO) as a solvent. After conversion mass is acidified with HCl.
After isolation and washing, crude mass is fractionated under vacuum to get pure
product.
Chemical Reaction:
CH3
Cl O
CH3 CH3
DMSO
+ NaOCH3 HCl
+ NaCl
Cl Cl
2,6-Dichlorotoluene Sod.Methoxide 3-Chloro-2-Methyl anisole
MW: 161.03 MW: 54.02 MW: 156.60
Material Balance:

.
2,6-Dichlorotoluene 1150 Kg
Dimethyl sulfoxide 350 Kg

Methylation
Sod.Methoxide 460 Kg
1960 Kg
Water 800 Kg
HCl 220 Kg Acidification
2980 Kg
Separation
Water wash 520 Kg
Crude 1320 Kg
Fractionation Fractions 220 Kg

Residue 80 Kg
1000 kg 3-Chloro-2-methyl anisole
26. 2-Dimethyl 2 Methyl 1 Propanol
In Autoclave Acetone is reacted with Sodium Cyanide in presence of ammonium
bicarbonate along with methanol solvent to produce 5,5 Dimethyl Hydantoin
In Autoclave 5,5 Dimethyl Hydantoin safonification with caustic to produce to 2-
Amino Iso butyric acid.
2-Amino Iso butyric acid reduction with sodium borohydride along with THF solvent
to produce 2-Amino 2-Methyl propanol.
2-Amino 2-Methyl propanol reacted with formaldehyde & formic acid to produce 2-
Dimethylamino 2-Methyl propanol.

.
Chemical Reaction:
Material Balance:
Acetone - 1300 kg NaCN - 1300 kg
Water - 6500 kg Methanol - 2600 kg
NH4HCO3
1500 kg AUTOCLAVE CO2 - 800 kg
Waste - 10500 kg
HCl 5,5 - Dimethyl Hydantoin - 1900 kg
1000 kg
Water
5600 kg AUTOCLAVE Acidic Waste to ETP - 9400 kg
NaOH
2400 kg
NaBH4 THF -( R ) - 4500 kg

550 kg 2-Amino Iso Butyric Acid - 1500 kg
Water
1000 kg
THF GLR
5000 kg
Formaldehyde Waste water to ETP - 2350 kg

solution - 1200 kg 2-Amino-2-Methyl propanol - 1200 kg
Formic acid
1000 kg SSR H2O - 1000 kg
Waste material - 3350 kg to ETP

Residue - 50 kg
1000 kg
2-Dimethyl Amino-2-methyl propanol

.
800 NaCl
Filtration
10000 Effluent
27. 4-Hydroxy 3 5 Dimethyl Benzaldehyde
2,6-Xylennol is formylated with Hexamethylene tetra mine(Hexamine) in Acetic

solvent to make product 4-Hydroxy-3,5-dimethyl benzaldehyde. After washing Crude
product is purified in water.
Chemical Reaction:
OH
H3C CH3
Formylation
+ H3C CH3
Acetic acid
OH
2,6-Xylenol Hexamethylenetetramine 3,5-Dimethyl-4-Hydroxy benzaldehyde
MW: 122.16 MW 140.18 MW: 150.17

.
Material Balance:
2,6-Xylenol 1000 Kg
Toluene 2000 Kg
Acetic acid 50 Kg Formylation Reaction
Water 1000 Kg
Hexamine 1160 Kg

Cooling

Water for wash 500 kg Aqueous layer 1960 Kg
Separation
Water wash 530 Kg
Org Layer 3220 Kg

Toluene (R ) 1840 Kg
Toluene Recovery
Bottom 1380 Kg
Water 1000 Kg Cooking
Total mass 2380 Kg

Crystalization

Filtration
(For 2nd crop)
Wet cake 1060Kg

Drying
1000 Kg 4-Hydroxy-3,5-dimethyl benzaldehyde
28. 2 Ethyl 2 Methyl Butanoic Acid
2,2-dimethyl Butanol is interacted with Formic acid in presence of sulphuric acid to

produce of 2-Ethyl ,2-Methyl Butanoic acid

.
Chemical Reaction:
+ H2SO4
Formic Acid M.W.=98 2.2-Dimethyl Butanol M.W.=98 2-Ethyl,2-Methyl Butanoic acid M.W =130
Material Balance:
1600 Sulphuric Acid
Formic Acid 750

GLR
2,2- Dimethyl Butanol 850
1000 Ice + Water
Quenching
1100 Crude 2-Ethyl 2-Methyl Butanoic Acid
Distillation
100 Residue to Incinarator
1000
Pure 2-Ethyl 2-Methyl Butanoic Acid
Neutralization of Aqueous Layer 3100 Acidic Waste
Neutralization
Caustic Flakes 300
350 Na2SO4
Filtration
3150 Effluent

.
29. 2 2 Dimethyl Butyrl Chloride

This is 4 step reactions. In first step 2- Methyl 2- Butanol and HCl i.e SN1 reaction to
form 2- Chloro Butane. In second step 2- Chloro 2- Methyl Butane is reacted with
Sodium Cyanide to form 2- cyno 2-methyl butane and Hydrolysis of 2- cyno 2-methyl
butane to form 2,2- Dimethyl Butyric Acid after Thionylation 2,2- Dimethyl Butyryl
Chloride is obtained.
Chemical Reaction:
+
Step I
CH 3 CH 3
H 2O
H 5C 2 C OH + HCl H 5C 2 C Cl +
CH3 CH3
-
2,2 -DMBA M.W.=88
-
2,2 -DMBCl M.W.=77
Step II
CH 3
CH 3
NaCl
H 3C C Cl + NaCN H 5C 2 C CN +
CH3 CH3
-
2,2 -DMBCl M.W.=77 -
2,2 -DMBCN M.W.=97
Step III
CH 3
CH 3
NaOH
H 5C 2 C CN + H 2O
H 5C 2 C COOH + NH 3
CH3
CH3
- -
2,2 -DMBCN M.W.=97 2,2 DMBA M.W.=116
Step IV
CH 3 CH 3
H 5C 2 C COOH + SOCl 2 H 5C 2 C COCl + SO +

2 HCl
CH3 CH3
-
2,2 DMBA M.W.=116 -
2,2 DMBC M.W =150

.
Material Balance:
2500 HCl
2- Methyl 2- Butanol 1000 GLR
2400 Effluent to ETP
1100 Crude 2- Chloro 2- Methyl Butane

500 Water
Sodium Cyanide 500 Cynatation
1000 Effluent to treatment

Ammonia Gas 170
1000 Crude 2- Cyno 2- Methyl Butane
Sodium Hydroxide 400 Hydrolysis 1000 Water
1000 Crude 2,2- Dimethyl Butyric Acid

550 Sulfur Dioxide Gas
Thionyl Chloride 1000 Thionylation
1150 Crude 2,2 - Dimethyl Butyryl Chloride
Distillation 150 Residue To Incinarator
1000
Pure 2,2- Dimethyl Butyryl Chloride
Acidic Waste 2400

Neutralization
Caustic Flakes 150
200 NaCl
Filtration
2350 Effluent
For Cyanitation water special treatment use.

.
30. DV Acid Chloride (60 : 40Cistrans)
This is three step processes. In first step, D.V. Ester is added to sodium hydroxide
solution. After the reaction the aqueous layer containing sodium salt of D.V. acid is
taken to next step. In next step, Sodium salt of D.V. acid of previous step (in water
solution) is added to mixture of dilute H2SO4 and toluene. D.V. acid formed is
dissolved in toluene and sodium sulphate in water. After the reaction, the layers are
separated. The Toluene layer is concentrated and aqueous layer is sent to further
treatment in waste management plant. Crude D.V acid is reacted with Thionyl
chloride in presence of catalyst N-Methyl 2-Pyrrolidinone to form D.V acid chloride .
D.V acid chloride is further distilled in WFE.
Chemical Reaction:
Cl
Cl
OCH3 Hydrolysis
C CH OH
C CH
Cl O
Cl O
+ SOCl2
D.V. Acid Methyl ester M.W.=209.11 D.V. Acid M.W.=211.08
Toluene
N-Methyl Pyrollidine
Cl
C CH Cl + SO2+ HCl
Cl O
D.V. Acid Chloride M.W.=227.5

.
Material Balance:
DV Ester 1050 Stage 1 : Hydrolysis

NaOH 425
Water 2200
3675 Organic Mass to Stage-2
Toluene 3200 Stage 2 : Acidifacation 4800 Waste water to ETP

H2SO4 275
Water 1800 5 Toluene loss
4145 Organi Mass (D.V. Acid + Toluene) to Stage-3
Stage 3 : Concentration 3100 Toluene Recovery
60 Residue to Incinerator
985 Organic Mass to Stage-4
Water 2000 Stage 4 : D.V. Acid 3000 Wastewater to Evaporeator

NaOH 950 Preparation 185 Recovered HCl (By product)
N-Methyl 2-Pyrrolidinone 0.5 320 Sulfur Dioxide Gas
Thionyl Chloride 570 60 Process waste to incinerator
1084 Organic Mass (Crude D.V. Acid Chloride) to Stage-5
Stage 5 : Distillation 1000 D.V. Acid Chloride from DV Ester
84 Distillation residue to incinerator
800 Na2SO4
Water 100 Filtration
4500 Effluent
31. Ortho Benzyl Para Chloro Phenol
This is one step process. Benzyl Chloride is slowly added to Para Chloro Phenol to
form crude Ortho Benzyl Para Chloro Phenol and unreacted Para Chloro Phenol.
After reaction unreated Para Chloro Phenol and also Ortho Benzyl Para Chloro
Phenol are distilled out. The distilled material Ortho Benzyl Para Chloro Phenol is
crystallised in Toluene. After Crystallisation white crystalline powder is obtained.

.
Chemical Reaction:
OH CH2Cl OH
CH2
+ + HCl
Cl Cl
4-Chlorophenol M.W.=128 Benzyl chloride M.W.=128 Ortho Benzyl 4-Chlorophenol M.W.=202
Material Balance:

Benzyl Chloride 1000
Step-1
Reaction 4400 Para Chloro Phenol
5115 Crude Ortho Benzyl Para Chloro Phenol and Para Chloro Phenol
Distillation 3400 Para Chloro Phenol
200 Residue to incinarator
1515 Crude Ortho Benzyl Para Chloro Phenol
Crystallisation 100 Toluene
Centrifuge
1000
Pure Ortho Benzyl
Para Chloro Phenol
615 Mother Liquor Recovery and
Toluene reused
32. 4-Isopropyl Catechol
4-Isopropyl phenol is brominated to make 2-Bromo-4-Isopropyl phenol by using

Hydrobromic acid and hydrpgen peroxide. After washing this bromo mass is
hydrolysed with caustic soda flakes to make product
4-Isopropyl catechol. After acidification ,product is extracted in N-butyl alcohol.
Organic layer is fractionated to get pure product 4-Isopropyl catechol.

.
Chemical Reaction:
OH
OH
H3C + HBr + H2O2 H3C

Br
+ H2O
CH3
CH3
4-Isopropylphenol 2-Br-4-isopropylphenol
4-Hydroxy cumene MW = 215.08
MW = 136.19
OH
OH
H3C + NaOH H3C + NaBr

OH
Br
CH3
CH3
2-Br-4-isopropylphenol 4-Isopropyl catechol Sod.Bromide
MW = 215.08 MW = 152.19 MW = 102

.
Material Balance:
Material Balance
4-Isopropylphenol 1250 kg
HBr 48 % 1660 Kg
Bromination
Hydrogen peroxide 50% 730 Kg
3640 Kg
Washing
Sod.thio sulphate(STS) 20 Kg
Crude 2-Br-4-isopropylcatechol 1740 Kg

Water 4500 Kg
Caustic Flakes 500 Kg
Reaction
Cupric chloride 30 Kg
6770 Kg
NBA 2000 Kg
Extraction &
HCl 30 % 1400 Kg
Acidification
Total mass 10170 Kg
Layer separation Aq . Layer 7150 Kg
Org.Layer 3020 Kg
NBA (R ) 1750 Kg
Distillation Fractions 140 Kg
Residue 130 Kg
1000 Kg 4-isopropyl catechol

.
33. 1-Adamantyl HCl

This is three step reaction process. In first step Adamantane is chlorinated to form 1-
Chloro Adamantane in presence of catalyst. In Second step 1-Chloro Adamatane to 1-
Acetamido Adamantane in this step H2SO4 is slowly added to 1-Chloro Adamantane ,
Acetonitrile and methylene dichloride. In third step 1-Acetamido Adamantane is
converted into 1-Admantaneamine Hydrochloride by using sodium hydroxide solution
and methanol in autoclave.
Chemical Reaction:
Step I
Cl
Cl
+ 2
+ HCl
Adamantane M.W.= 136 1-Chloroadamantane M.W.=170
Step II
Cl NH-CO-CH 3
H 2 SO 4
+ CH 3 CN
1-Chloroadamantane M.W.=170 1-Acetamidoadamantane M.W.=193
NH-CO-CH 3
NH 2 .HCl
HCl
+ NaOH
1-Acetomidoadamantane M.W.=193 1-Adamantaneamine HCl M.W.=187

.
Material Balance:
Chlorine gas passed

50 Catalyst
Chlorination 6000 Methylene dichloride
1000 Adamantane
Reaction Mass
Quenching 5000 Water
Washing crude 1-Chloro Admantane + MDC
Crude 1-Chloro 2000 Water

Admantane + MDC
50 Sodium sulphite
2000 Methylene dichloride
Sulphuric Acid 2500 1000 Crude 1-Chloro Admantane
Reaction 2400 Acetonitrile
Upper organic
Layer Waste water to ETP
Separation
2500 Methylene dichloride recovered
Centrifuge Pure 1-Acetamido Admantane
750 Sodium Hydroxide
Autoclave
750 Water
Preassure 15 kg 3000 Methanol
Filtre Reaction Mass
Distillation 2500 Methanol Recovered
Acidification by HCl
Centrifuge Wash with water
1000
Pure 1-Admantaneamine Hydrochloride
34. 1-Bromo-2-(3-Chloro-4-Ethoxyphenyl)-2-Methyl Propane
2-Chloro phenol is reacted with Diethyl sulphate in presence of caustic to produce 2-

ethoxy chloro benzene.
2-ethoxy chloro benzene is reacted with 3-bromo-2-methyl-1-propane in presence of
Toluene & methanol by using catalyst zinc dust to produce 1-Bromo-2-(3-chloro-4-
ethyxo phenyl)-2-methyl propane.

.
Chemical Reaction:
OH
OC2H5
Cl
Cl
(C2H5O)2 SO4
+ + Na2SO4
Diethylsulphate M.W.=162 2-Ethoxychlorobenzene M.W.= 156

2-Chlorophenol M.W.=128
OC2H5
OC2H5
CH2 Cl
Cl
Br H3C
+
CH3
CH3 Br
1-Bromo,2-(3-Chloro,4-ethoxyphenyl )2-Methylpropane M.w.=291

1-Bromo,2-(3-Chloro,4-e
2-Ethoxychlorobenzene M.W.= 156
3-Bromo,2-Methyl,1-Propane M.W.=135

.
Material Balance:
NaOH - 275 kg Water - 800 kg
OCP
800 kg
DES SSR
800 kg
Zinc Dust - 50 kg
Water - 1000 kg Sodium sulphate water waste - 1875 kg to ETP
2- Ethoxy chloro Benzene - 800 kg
3-bromo-2-methyl-1-propane
- 700 kg
Toluene - 500 kg GLR
Methanol - 500 kg Toluene + methanol ( R ) - 800 kg
Waste water - 1750 kg to ETP

Residue - 50 kg
1000 kg
1-Bromo-2-(3-chloro-4-ethyxy phenyl)-2-methyl propane
Neutralization of Aqueous Layer 1875 Sodium Sulphate Waste Water
Chilling
700 Na2SO4
Filtration
1175 Effluent
35. 4-Chloro 2,6 Dimethyl Phenyl Acetic Acid

This is four step reaction. In first step 3, 5-Xylidene is converted into 4-Amino 2,
6-Dimethyl Benzyl Chloride by Para Formaldehyde solution and Hydrochloric Acid.
In second step 4-Chloro 2, 6-Dimethyl Benzyl Chloride is Obtained by Diazodisation
reaction. In third step 4-Chloro 2, 6-Dimethyl Benzyl Chloride is converted into 4-
Chloro 2, 6-Dimethyl Acetonitrile by Cynatation. In last step Hydrolysis of 4-Chloro

.
2, 6-Dimethyl Acetonitrile is converted into 4-Chloro 2, 6-Dimethyl Phenyl Acetic

Acid.
Chemical Reaction:
Step I
NH 2 NH 2
+ HCHO +HCl + HCl

H 3C CH 3 H 3C CH3
CH 2 Cl
3,5-Xylidene M.W.= 121
4-Chloromethyl ,3,5-Xylidene M.W. = 169
Step II
NH 2 Cl
+ H 2 SO 4 + NaNo 2
+ Cl 2 + Na 2 SO 4
H 3C CH3 H 3C CH 3
CH 2 Cl CH 2 Cl
4-Chloromethyl ,3,5-Xylidene M.W. = 169

4-Chloromethyl ,3,5-Dimethyl Chloro Benzene M.W. =189
Step III
Cl
Cl
+ NaCN
H 3C CH 3
+ NaCl
H 3C CH 3
CH 2 Cl
CH 2 CN
4-Chloromethyl ,3,5-Dimethyl Chloro Benzene M.W. =189 4-Cyanomethyl ,3,5-Dimethyl Chloro Benzene M.W. =179
Step IV
Cl Cl
+ NaOH
+ NH 3
H 3C CH 3 H 3C CH 3
CH 2 CN CH 2 COOH
-
4-Cyanomethyl ,3,5-Dimethyl Chloro Benzene M.W. =179 4-chloro,2,6 -Dimethyl Phenyl acetic acid M.W.=198

.
Material Balance:
3,5 Xylidene 800
Hydrochloric Acid (30%) 2000

GLR 500 Water
Para Formaldehyde Solution 300
1000 Crude 4-Amino 2,6-Dimethyl Benzyl Chloride
Sodium Nitrite 1000

Hydrochloric Acid (30%) 2000 Diazodisation 2000 Na2SO4 Solution
Copper Chloride 10
1020 4-Chloro 2,6-Dimethyl Benzyl Chloride
Sodium Cyanide 260 Cynatation 1400 Water

1000 4-Chloro 2,6-Dimethyl Acetonitrile
Sodium Hydroxide 350
Water 1800 Hydrolysis 700 Hydrochloric Acid (30%)
1000
Pure 4-Chloro 2,6-Dimethyl Phenyl Acetic Acid
600 NaCl
Filtration
4430 Effluent
36. 4-Hydroxy Benzyl Alcohol
PHB reduced with Sodium borohydride in alkaline condition. Mass is acidified and
filtered to get product 4-Hydroxybenzyl alcohol.

.
Chemical Reaction:
O OH
Reduction
+ NaBH4
Caustic soln HO
+ H2O
HO
4-Hydroxybenzaldehyde (PHB) Sod.borohydride 4-Hydroxybenzylaclohol (PHBL)

MW:122.12 MW:37.83 MW:124.13
Material Balance:
Material Balance
Water 1000 Kg
Caustic flakes 370 Kg
Reduction
Para Hydroxy Benzaldehyde 1250 Kg
Sodium borohydride 350 Kg
2970 Kg
HCl 30 % 1150 Kg
Acidification
4120 Kg
Water for cake washing 400 Kg Mother liquor 2545 Kg
Filtration
Wash 350 Kg
1625 Kg wet cake

Water 2500 Kg
Purification
4125 Kg
Filtration
(For 2nd crop)
Wet cake 1100 Kg

Drying
1000 Kg Para hydroxy benzyl alohol (PHBL)
37. 2-Methoxy Phenyl Acetone
Addition reaction of 2-anisaldehyde (2-Mehtoxybenzaldehyde), Methyl-2-

chloropropionate and Sodium methoxide to make epoxy ester. After conversion,
reaction mass is treated with dilute sulfuric acid to make 2-Methoxyphenyl acetone.

.
After washing, crude mass obtained is fractionated under high vacuum to get pure
product.
Chemical Reaction:
O
O O
H Cl O
NaOCH3 H CH3 OH
+HC O CH3
OCH3 3
OCH3
o-Anisaldehyde Methyl 2-Cl-Propionate (2CPME) Epoxy Ester
MW: 136.14 MW: 122.55 MW: 230
O O
O
H CH3 OH H2SO4 / H 2O
CH3
OCH3 OCH3
Epoxy Ester 2-Methoxy Phenyl Acetone (2MPA )

MW: 230 MW: 164.2

.
Material Balance:
Reaction
o-Anisaldehyde- 1000 Kg
Methyl-2-chloropropionate- 910 Kg
Condensation
Sodium methoxide- 395 Kg Methanol (R) - 250 Kg
2055 Kg
Sod. Chloride salt- 440 Kg

Filtration
1615 Kg
CO2- 320 Kg
Sulphuric acid - 145 Kg Aq Layer 780 Kg
Water for 20 % acid- 580 Kg Acidification (For neutralization)
Water for wash- 500 Kg Effluent- 530 Kg
2840
Crude 2-MxPA 1210 Kg
Water - 20 Kg (to ETP)
Crude 2-MxPA- 1210 Kg
SS Distillation Kettle Fractions 55 Kg
Residue- 135 Kg
2-MxPA 1000 Kg
Neutralization of Aqueous layer
Aq Layer 780 Kg
Neutralization
Caustic flakes 42 Kg
Na2SO4- 205 Kg
Water - 50 Kg Filtration
Effluent- 667 Kg
38. Methyl-2-Dimethyl Amino-2-phenyl butyrare
2-Amino-2-Phenylbutyric acid is converted to Dimethylamino-2-phenyl butyric acid

by reacting with formic acid and formaldehyde solution, After getting desired
conversion, caustic solution is added in reaction mass and sodium salt solution is
reacted with Dimethyl sulphate to make methyl ester i.e product Methyl-2-
Dimethylamino-2-phenylbutyrate.

.
Chemical Reaction:
CH3O
O
H3C N
H2N
OH
OH
CH3
+ HCOOH + HCHO -CO2
CH3
Toluene
2-Amino-2-phenylbutyric acid
Formic acid Formaldehyde 2-Dimethylamino-2-phenylbutyric acid
M.Wt:- 179.21 MW:- 46 MW:-30 M.Wt:- 207.26
CH3O
O
H2N H3C N
CH3 CH3
O O
Sodium hydroxide
CH3 + (CH3)2SO4 CH3
-Na2SO4
Methyl-2-Amino-2-phenylbutyrate
Dimethyl Sulphate Methyl-2-dimethylamino-2-phenyl butyrate
M.Wt:- 193.24 M.Wt:- 126 M.Wt:- 221.29
Material Balance:
Toluene 3000 Kg
2-Amino-2-phenyl butyric acid
Formylation
1120 Kg CO2 410 Kg
37%Formaldehyde Soln 770 Kg
Formic acid 704 Kg
5184 Kg
Water 500 Kg
Neutralization
&
NaOH 50 % 480 Kg Alkaline layer 500 Kg
Water wash
4500 Kg
Dimethyl sulphate 619 Kg
Esterification
Sodium Hydroxide 50% 576 Kg
5695 Kg
Water 500 Kg
Neutralization
&
HCl 30 % 910 Kg HCl wash 900 Kg
Water wash
Water 300 Kg Water Layer 305 Kg
4020 Kg
Toluene Water
2720 Kg 50 Kg
Fractionation
Low purity product fraction 150 Kg
Residue 100 Kg
Methyl-2-dimethylamino-2-phenylbutyrate
1000 kg 2-Phenyl butyric acid

.
39. Meta Phenoxy Benzyl Alcohol
This is four step reaction. In first step Bromination of Benzaldehyde to form Meta-
Bromo Benzaldehyde. In second step Meta-Bromo Benzaldehyde is converted into
Meta- Bromo Benzyl Acetal in presence of Monoethylene Glycol. In third step
Potassium Phenate is formed by Phenol and Potassium Hydroxide and Potassium
Phenate in turns react to Meta-Bromo Benzyl Acetal to form Meta-Phenoxy Benzyl
Acetate. Meta-Phenoxy Benzyl Acetate treated with water to form Meta-Phenoxy
Benzaldehyde and which is converted to Meta-Phenoxy Benzyl Alcohol by
Hydrogenation.
Chemical Reaction:
Meta Phenoxy Benzaldehyde
CHO CHO
2 + Br 2 + Cl 2 2 + 2 HCl
Br
Benzaldehyde M.W.= 106 Meta Bromo Benzaldehyde M.W.=185
CHO O
CH 2 OH O
HC
+ + H 2O
Br CH 2 OH
Br
Meta Bromo Benzaldehyde M.W.=185 MEG M.W.=62
Meta Phenoxy Benzyl acetal M.W.=229
O OH O
O O
HC
CH
+ KOH +
+ H 2O
Br
O
Meta bromo Benzyl acetal M.W.=229 Phenol M.W.=94
CHO Meta Phenoxy Benzyl acetal M.W.=242
CH 2 OH
O +
CH 2 OH
Meta Phenoxy Benzaldehyde M.W.=198 MEG M.W=62

.
Meta Phenoxy Benzyl Alcohol
CHO CH2OH
Catalyst
O + H2 O
Meta Phenoxy Benzaldehyde Meta Phenoxy Benzyl Alcohol

.
Material Balance:
Aluminium Chloride 900 370 Hydrochloric Gas
Bromine 850 375 Chlorine
Benzaldehyde 550 MBB 1100 Ethylene Dichloride

Reaction
Water 1000 Quenching 1000 Ethylene Dichloride

970 Crude Meta-Bromo Benzaldehyde
Monoethylene Glycol 325
PTSA 3
1200 Crude Meta Bromo Acetal
Phenol 500
Potassium Hydroxide 300
Copper Chloride 10
580 Potassium Bromide
95 Water
1335 Crude Meta-Phenoxy Benzyl Acetate
Water 100
393 Monoethylene Glycol + Water

1042 Meta-Phenoxy Benzaldehyde
Hydrogen 11
Autoclave
Triethyl Amine 2
Catalyst 10 Hydrogenation
55 Aqueous layer to Incenerator

Decantation
10 Recovery of catalyst
1000
Pure Meta-Phenoxy Benzyl Alcohol
300 NaCl
Filtration
2385 Effluent

.
40. 4-Bromophenyl Acetic Acid Methyl Ester

4-Bromophenylacetic acid is reacted with Methanol in presence of sulphuric acid to

methyl ester of 4-Bromophenylacetic acid.
Chemical Reaction:
COOH COCH3
H2SO4
+ CH3OH + H2O
Br Br
4-Bromo phenylacetic acid Methanol 4-Bromo phenylacetic acid methyl ester

MW:215.05 MW:32.04 MW:213.07
Material Balance:
4-BrPAA 1065 kg
Methanol 2130 Kg
Esterification
Sulphuric acid 215 Kg
3410 Kg
Methanol (R ) for recycle 1715 Kg
Recovery
1695 Kg
Water 300 Kg Dil H2SO4 915 Kg
Separation
1080 Kg
Neutralization
Soda ash 30 Kg
Cr Bromo ester 1050 Kg

Water 20 Kg
Distillation
Residue 30 Kg
1000 Kg Methyl-4-Bromophenylacetate
41. N Methyl 1-Napthalene Methyl Amine Hydro Chloride

Methyl Amine base which is distilled under partial vacuum. Base is reacted with HCl
gas in presence of toluene to make Hydro chloride salt.

.
Chemical Reaction:
CH3
Cl
N O
O
NH H
DMF
+ H3C H + NaH
+ H2 + NaCl
Methyl Formamide
M.Wt:- 23.99
M.Wt:- 176.64 M.Wt:- 199.24
CH3 CH3
N O N
H
H
NaOH
+ H2SO4 + Na2SO4
Sulfuric Acid
M.Wt:- 98.07
N-(Methyl-formyl)methyl Naphthalene
M.Wt:- 199.24
M.Wt:- 171.23
CH3 CH3
N N
H H:HCl
Toluene
+ HCl
N-methyl-1-(1-naphthyl)methanamine N-methyl-1-(1-naphthyl)methanamine-HCl
M.Wt:- 171.23 M.Wt:- 207.70

.
Material Balance:
DMF 2260 Kg
NaH 60 % 305 Kg
Coupling Reaction
NMF 565 Kg (4824 Kg)
4809 kg
Water 2259Kg
Washing
Water + NaCl + DMF
(7068 Kg)
2260 455 2178
2175 Kg
Water 1695 Kg
Hydrolysis
H2SO4 1130 Kg (5000 Kg) Organic layer 1045 Kg
Toluen+DMF
3955 Kg
50 % NaOH 2485 Kg
Neutralization
Sod sulphate Aqueous layer 5341 Kg
(6665 Kg)
Toluene 225 Kg
1324 Kg
Distillation
(1324 Kg) Residue 89 Kg
N-MAN Base 950 Kg

Toluene 5909 Kg
Acidiculation
HCl Gas 175 Kg
(7037 Kg)
Filtration
Toluene ML 6009 Kg
(7034 Kg)
Drying
(1025 Kg)
1000 Kg
N-Methyl -1-Naphtahlene Methyl Amine HCl
42. 4-Hydroxy Acetophenone
4-Hydroxy Acetophenone is synthesised from Friedalcraft’s reaction of phenol,

monochlorobenzene and acetyl chloride in the presence of aluminium chloride crude
4-Hydroxy Acetophenone is formed. After purification pure product is obtained.

.
Chemical Reaction:
O CH3
OH
Cl
AlCl3
+
O
MCB + HCl
H3C
OH
Phenol M.W. =94 Acetyl Chloride M.W.=78 4-Hydroxy Acetophenone M.W.=136
Material Balance:
Acetyl Chloride 900 386 Hydrochloric Gas
Stage-1 2700 Monochlorobenzene

Friedalcraft reactn
Phenol 1000 2800 Aluminium Chloride
Stage-2 1600 Ice

Water 1000 Quenching
2000 HCl 2500 Recycled Monochlorobenzene for next batch
Centrifuge
1200 Crude
Caustic Flakes 300 Stage-3 6914 Waste water to ETP
Salt Formation
Water 2400
Stage-4
Hydrochloric Acid 30% 500 Acidification
Centrifuge 3400 Waste water to ETP
1000
Pure 4-Hydroxy Acetophenone
Aqueous Layer 10314

Neutralization
Caustic Flakes 600
700 NaCl
Filtration
10214 Effluent

.
43. 2-(1-Admantyl)-4-Bromo Anisole
This is one step reaction process. Sulphuric acid is added to 1-Adamantanol, Ethylene
dichloride and 4-Bromo Anisole at low temperature. Crude product is isolated by
recovery of Ethylene dichloride and purified in Toluene. Pure 2-Admantyl-4-Bromo
Anisole is obtained.
Chemical Reaction:
OH
O CH3 O CH3
H2SO 4
+ + Na2So4
NaOH
Br Br
1-Adamantanol 4-Bromo Anisole 2-Adamantanyl-4-Bromo Anisole
M.Wt. :- 152.23 M.Wt. :- 187.03 M.Wt. :- 321.25

.
Material Balance:
Sulphuric Acid 450

2500 4-Bromo Anisole
Reaction 6000 Ethylene dichloride
630 Adamantanol

Lower organoc layer
seperated
Crude Product
+
EDC
5500 Ethylene dichloride
1500 4-Bromo Anisole
1400 Crude
Purification 1400 Toluene
1450 M.L. Distilled out use for next batch

(Toluene Recovery- 1300)
Centrifuge
350 M.L. Material used for purification
1000
Pure 2-Admantyl-4-Bromo Anisole
Acidic Waste 6180

Neutralization
Caustic Flakes 300
350 Na2SO4
Water 100 Filtration
6030 Effluent
44. 2-(3-Hydroxy-2-Methyl Propionyl)-aminol-2-methyl-propanol
In first step2-amino isobutyric acid reacted with Methylacrylic Acid to produce

Diacid Intermedaite after isolation of Diacid Intermediate ,In second step Diacid
utilised for reduction byusing sodium Borohydried along with solvent THF to
produce 2-(3-hydroxy-methyl propyl)amino) –2-methyl propanol

.
Chemical Reaction:
Material Balance:
2-Amino Isobutyric Acid 750

GLR
Methacrylic Acid 650
Water 750
Washing 1400 Toluene (R)
Toluene 1500
1450 Intermediate Diacid

Tetra Hydrofuran 2400
GLR
Sodium Borohydried 250
200 Vapour Loss
Water 1000 2200 Tetra Hydrofuran (R)

Washing
Hydrochloric Acid(30%) 500
Distillation 50 Residue to Incinerator
1000
2950 Acidic waste

Neutralization
Caustic Flakes 250
300 NaCl
Filtration
2150 Effluent

.
45. 4-Bromophenyl Acetic Acid
4-Bromobenzyl bromide is reacted with Sodium cyanide to make 4-Bromobenzyl

cyanide. 4-Bromobenzyl cyanide is then hydrolyzed with caustic to make 4-
Bromophenylacetic acid
Chemical Reaction:
CH3
Br
AIBN
+ Br Br + HBr
Br Br
4-Bromo toluene Bromine 4-Bromo benzyl bromide
MW:171.03 MW:160 MW:249.94
Br CN
+ NaCN
+ NaBr
Br Br
4-Bromo benzyl bromide Sod .Cyanide 4-Bromo benzyl cyanide
MW:249.94 MW:49 MW:196.05
CN Hydrolysis COOH
+ NH3
NaOH / water Br
Br
4-Bromo benzyl cyanide 4-Bromo phenylacetic acid
MW:196.05 MW:215.05

.
Material Balance:
4-Br toluene 2150 kg

Azo bis Butyronitrile 10 Kg HBr to scrubber
Bromination
Bromine liquid 1000 Kg 500 Kg
2660
Washing
Sod.thio sulphate(STS) 20 Kg
3680 Crude PBrBBr+PBT 2610 Kg
Sod Cyanide 270 Kg

Cyanation
Water 810 Kg
3690
Aq . Layer 1100 Kg
Water (w) 600 Kg Separation Water wash 650 Kg
Cr Cyanomass 2540 Kg
Crystalization
Cr Cyanomass 2540 Kg
Filtration PBT ML for recycle 1320 Kg
Crude 4-BrBCN 1220 Kg
NaOH flakes 250 Kg Ammonia 95 Kg

Hydrolysis
Water 1000 Kg
2375 Kg
HCl 30 % 760 Kg
Acidification
3135 Kg
Water 150 Kg Sod.chloride + Aq Layer
Filtration
360 Kg + 1875 Kg =2235 Kg
Wet cake 4BrPAA 1050 Kg
Drying Water loss 50 Kg
1000 kg 4-Bromophenylacetic acid

.
ANNEXURE VII
DETAILS OF WATER CONSUMPTION
Source of Water: GIDC water supply
Sr. Particular Water Consumption in KL/Day

No.
As per EC Addition Quantity
No. F. No. J- after
11011/132/20 proposed
14-IA II (I) Profile
and CTE No.
70398
1. Domestic 15 +10 25
2. Gardening 6 +24 30
3. Industrial
Process & 80 +140 220
Washing
Boiler 20 +60 80
Cooling 20 +160 180
Cleaning 3 +22 25
Scrubber 10 +20 30
Total(Indust 133 +402 535
rial)
Total 154 +436 590
(Domestic +
Industrial+
Gardening)
DETAILS OF WASTE WATER GENERATION
Sr. Particulate Waste Water Generation in KL/Day

No. As per EC No. F. Addition Quantity
No. J 11011/132/ after
2014-IA II (I) and proposed
CTE No. 70398 Profile
1. Domestic & 12 8 20
Gardening
2. Industrial
Process & 70 130 200
Washing
Boiler 5 40 45
Cooling 6 24 30
Scrubber 10 20 30
Cleaning 3 22 25
Total(Indust 94 236 330
rial)
Total 106 244 350
(Domestic +
Industries)

.
Existing Water Balance Diagram

.
Proposed Water Balance Diagram
Raw Water
590 KL /Day
Process / Boiler- Cooling Cleaning- Domestic- Gardening Scrubber-

Washing- 80 KL/Day Tower- 25 KL/Day 25 KL/Day 30 KL/Day 30 KL/Day
220 KL/Day 180 KL/Day
200 45 KL/Day 30 KL/Day 25 KL/Day 20 KL/Day 30 KL/Day

KL/Day Septic tank &
Soak Pit
150 KL/Day Primary

ETP
MEE Salt to
MEE TSDF
50 KL/Day MEE Condensate

135 KL/Day Effluent Treatment
Plant
315 KL/Day
GIDC Drain
315 KL/Day
.
ANNEXURE-VIII
Effluent Treatment Plant
EFFLUENT TREATMENT FLOW DIAGRAM

.
EFFLUENT TREATMENT PROCESS DESCRIPTION

First all non-toxic, low-medium COD, biodegradable streams of wastewater shall
passed through Screen Chamber where floating material shall be removed. Then
effluent shall be collected in Collection cum Equalization Tank-1 (CET-1). Pipe
grid shall be provided at bottom of the CET to keep all suspended solids in
suspension and to provide proper mixing 2 nos. of Air Blowers (B-01) shall supply
air through diffusers to pipe grid.
Then after, equalized wastewater shall be pumped to Neutralization Tank-1 (NT-1)
where the continuous addition and stirring of lime solution is done to maintain
the pH of wastewater from Lime Dosing Tank (LDT) as per requirement by
gravity. Then after, neutralized wastewater shall go to Flash Mixer (FM). Alum
shall be dosed from Alum Dosing Tank (ADT) by gravity into FM to carry out
coagulation by using a Flash Mixer. Then Polyelectrolyte shall be dosed from
Polyelectrolyte Dosing Tank (PEDT). Then after, coagulated wastewater shall be
settled in Primary Tube Settler (PTS). Clear supernatant from Primary Tube Settler
shall be passed in Aeration Tank (AT) in parallel.
Cooling and Boiler blow down waters shall be added to AT. Here, biodegradation of
organic matter of the wastewater shall be carried out by bacteria (suspended growth)
in the ATs. The aeration tank provides proper mixing and supplies oxygen to the
microorganisms in the dissolved form through the fine bubble diffusers. A constant
feed rate shall be maintained in the aeration tank. A sludge percentage of
around 25 to 30 % by volume shall be maintained in the aeration tank. Also
MLSS and MLVSS ratio shall be maintained to ensure active microorganisms
growth. Various nutrients like Urea and DAP shall be added from
Nutrient Dosing Tanks regularly so as to ensure proper growth of the
microorganisms. Oxygen shall be supplied by 2 nos. of air blowers (B-02) through
diffusers in ATs. Air blowers also keep MLSS in suspension.
Then the overflow of the Aeration Tanks shall be collected in the Secondary
Clarifier (SCL) for biomass separation. An appropriate retention time is given to
the effluent to ensure proper settling. The sludge settles down at bottom of the
SCL and required amount of settled sludge shall be recycled back into the
aeration tank to maintain desired concentration of biomass. Excess biomass shall
be pumped to sludge sump.
Then after, overflow (clear supernatant) of SCL shall collected in Intermediate
Sump (IS).Then effluent from the IS shall be pumped to the Pressure Sand
Filter (PSF) and Activated Carbon Filter (ACF) for tertiary treatment. The effluent
shall enter into the sand filter from the top and the filtered effluent shall be further
passed to the Activated Carbon Filter for color removal. A back wash facility shall
be provided to the sand filter and carbon filter to wash out the suspended solid
whenever required. For backwash, the effluent from the Intermediate Sump shall be
pumped at the bottom of the sand filter (and / or carbon filter) and the discharge of
the sand filter (and / or carbon filter) shall be diverted into the Collection cum
Equalization Tank.

.
The outlet of the carbon filter shall be collected into the Treated Effluent Sump
(TES). The treated effluent from the treated water tank shall be finally pumped to
GIDC underground drainage through magnetic flow meter and recorder system. We
will meet all the norms laid by Gujarat Pollution Control Board.
The primary and secondary sludge from the sludge sump shall be pumped to the filter
press (FP) for sludge dewatering. The sludge cake shall be collected and packed into
the plastic bags and stored in the HWSA and ultimate disposal to TSDF. The
leachate from the filter press shall be diverted to the collection cum equalization tank
for further treatment.
High COD Stream:

All high COD streams of wastewater shall be collected in Collection cum
Equalization Tank-2 (CET-2). Pipe grid shall be provided at bottom of the CET to
keep all suspended solids in suspension and to provide proper mixing 2 nos. of
Air Blowers (B-03) shall supply air through diffusers to pipe grid.
Then after, equalized wastewater shall be pumped to Neutralization Tank-2 (NT-2)
where the continuous addition and stirring of lime solution is done to maintain
the pH of wastewater from Lime Dosing Tank (LDT) as per requirement by
gravity. Then after, neutralized wastewater shall go to Flash Mixer (FM). Alum
shall be dosed from Alum Dosing Tank (ADT) by gravity into FM to carry out
coagulation by using a Flash Mixer. Then Polyelectrolyte shall be dosed from
Polyelectrolyte Dosing Tank (PEDT). Then after, coagulated wastewater shall be
settled in Primary Tube Settler-2 (PTS-2).
Then Clear supernatant from Primary Tube Settler shall be collected in ME Feed
Tank before feed to Multiple Effect Evaporator. Condensate of MEE will be sent for
further treatment to Collection cum Equalization Treatment-1(CET01).Concentrated
effluent from MEE shall be sent to Agitated Thin Film Dryer (ATFD) from
drying. Salt obtained from ATFD shall be collected and stored in HWSA and
ultimate disposal to TSDF.
121
Details of Effluent Treatment Unit ( As per Existing)

Sr. Name of units Size (m x m x m) Nos. MOC
No.
Low-Medium (100 M3/day) (60 +40) m3/day
1. Screen Chamber (SC) 2.0 x 0.8 x (0.1 LD+0.6 FB) 1 RCC with A/A
bk lining
2. Collection cum Equalization 5.5 x 3.6 x (2.5 LD +0.8 FB) 1 RCC with A/A
Tank-1(CET-1) bk lining
3. Neutralization Tank (NT-1) 1.5 x 1.2 x (2.5 LD +0.5 FB) 1 RCC with A/A
bk lining
4. Flash Mixer (FM)-1 1.5 x 1.3 x (2.2 LD +0.7 FB) 1 RCC M25
5. Primary Tube Settler (PTS-1) 3.0 x 2.5 x (2.2 SWD+ 1.0 1 RCC M25
HB +0.7 FB)
6. Lime Dosing Tank (LDT) 2000 lit 1 HDPE
7. Alum Dosing Tank (ADT) 1500 lit 1 HDPE
8. Poly Dosing Tank (PDT) 1000 lit 1 HDPE
9. Aeration Tank (AT) 12.0 x 8.0 x (4.5 LD+ 0.5 2 RCC M25
FB)
10. Secondary Clarifier (SCL) 3.75 dia x (3.0 SWD+0.5 1 RCC M25
FB )
11. Nutrient Dosing Tank (NDT) 1000 2 HDPE
12. Intermediate Sump 3.5 x 3.5 x (2.5 +0.5 FB) RCC M25
13. Pressure Sand Filter (PSF) 5 m3/hr 1 MSEP
14. Activated Carbon Filter (ACF) 5 m3/hr 1 MSEP
15. Treated Effluent Sump (TES) 5.0 x 2.5 x (2.5 LD +0.8 FB) 1 RCC M25
16. Sludge Sump (SS) 3.5 x 3.5 x (2.5+ 0.5 FB) 1 RCC M25
17. Filter Press (FP) 35 m3/day 1 PP
High COD Streams (40 m3/day)
1 Collection cum Equalization 3.5 x 2.5 x (2.5 LD +0.5 FB) 1 RCC with A/A
Tank-2 (CET-2) bk lining
2 Neutralization Tank-2 (NT-2) 1.0 x 1.0 x (1.7 LD +0.5 FB) 1 RCC with A/A
bk lining
3 Flash Mixer-2(FM-2) 1.0 x 1.0 x (1.5 LD +0.7 FB) 1 RCC M25
4 Primary Tube Settler-2 (PTS-2) 2.0 x 1.5 x (2.2 SWD+ 1.0 1 RCC M25
RCC = Reinforced
Cement Concrete
PCC = Plain Cement
Concrete
Bk. Mas. = Brick
Masonry
LD = Liquid Depth
122
FB = Free Board
HB = Hopper Bottom
Details of Effluent Treatment Unit (As per after proposed profile change)
Sr. Name of units Size (m x m x m) Nos. MOC
No.
Low-Medium
1. Screen Chamber (SC) 4.0 x 1.6 x (0.1 LD+0.6 FB) 1 RCC with A/A
bk lining
2. Collection cum Equalization 11x 7.2 x (2.5 LD +0.8 FB) 1 RCC with A/A
Tank-1(CET-1) bk lining
3. Neutralization Tank (NT-1) 3 x 2.4 x (2.5 LD +0.5 FB) 1 RCC with A/A
bk lining
4. Flash Mixer (FM)-1 3 x 2.6 x (2.2 LD +0.7 FB) 1 RCC M25
5. Primary Tube Settler (PTS-1) 6.0 x 5 x (2.2 SWD+ 1.0 1 RCC M25
HB +0.7 FB)
6. Lime Dosing Tank (LDT) 4000 lit 1 HDPE
7. Alum Dosing Tank (ADT) 3000 lit 1 HDPE
8. Poly Dosing Tank (PDT) 2000 lit 1 HDPE
9. Aeration Tank (AT) 24 x 16 x (4.5 LD+ 0.5 2 RCC M25
FB)
10. Secondary Clarifier (SCL) 7.5 dia x (3.0 SWD+0.5 1 RCC M25
FB )
11. Nutrient Dosing Tank (NDT) 2000 2 HDPE
12. Intermediate Sump 7x 7 x (2.5 +0.5 FB) RCC M25
13. Pressure Sand Filter (PSF) 10 m3/hr 1 MSEP
14. Activated Carbon Filter (ACF) 10 m3/hr 1 MSEP
15. Treated Effluent Sump (TES) 10 x 5 x (2.5 LD +0.8 FB) 1 RCC M25
16. Sludge Sump (SS) 7.0 x 7.0 x (2.5+ 0.5 FB) 1 RCC M25
17. Filter Press (FP) 70 m3/day 1 PP
High COD Streams
1. Collection cum Equalization 7.0 x 5 x (2.5 LD +0.5 FB) 1 RCC with A/A
Tank-2 (CET-2) bk lining
2 Neutralization Tank-2 (NT-2) 2.0 x 2.0 x (1.7 LD +0.5 FB) 1 RCC with A/A
bk lining
3 Flash Mixer-2(FM-2) 2.0 x 2.0 x (1.5 LD +0.7 FB) 1 RCC M25
4 Primary Tube Settler-2 (PTS-2) 4.0 x 3 x (2.2 SWD+ 1.0 1 RCC M25
RCC = Reinforced
Cement Concrete
PCC = Plain Cement
Concrete
123
Bk. Mas. = Brick

Masonry
LD = Liquid Depth
FB = Free Board
HB = Hopper Bottom
Effluent Quality before Treatment and After Treatment

Sr. Parameter Units Characteristics
No. Untreated Treated
1. pH – 2 to10 6.5 - 8.5
2. SS mg/lit 400 to 600 80 - 100
3. TDS mg/lit 1000 to 2500 1000-2500
4. COD mg/lit 4000 to 10000 < 250
5. BOD mg/lit 1000 to 2500 <100
6. Ammonical Nitrogen mg/lit 50 to 80 <50
124
Annexure-IX
Energy and Fuel Consumption Details
Sr. Fuel As per EC No. Addition As per after

No. F. No. J- proposed
11011/132/2014 profile
-IA II (I) and
CTE No. 70398
1. Bio Coal/Coal 40 T/Day +40 T/Day 80 T/Day

2. Natural gas 15000 Sm3/Day +00 15000 Sm3/Day
3. Diesel for D G Set 300 Lit/Day +300 Lit/Day 600 Lit/ Day
Flue Gas Emissions

Sr. Stack attached Fuel & Stack Stack APCM Probable Permissible
No to Consum Height Diame Pollutants Limit
ption in ter in
meter mm
As per EC No. F. No. J-11011/132/2014-IA II (I) and CTE No. 70398
1. Thermic Fluid Natural 25 1000 -- SPM 150 mg/NM3
Heater Gas SO2 100 ppm
NOX 50 ppm
2. Steam Boiler Coal/Briq 35 1000 Multi SPM 150 mg/NM3
(Coal Fired uette Cyclon SO2 100 ppm
FBC based e+ Bag NOX 50 ppm
system) Filter
6 TPH
3. D.G.SET Diesel 11 200 SPM 150 mg/NM3
(500 KVA) SO2 100 ppm
NOX 50 ppm
After Proposed profile change
1. Thermic Fluid Coal/Briq 45 1400 MDC + SPM 150 mg/NM3
Heater uette/Nat Bag SO2 100 ppm
ural Gas Filter NOX 50 ppm
2. Steam Boiler Coal/Briq 45 1400 Multi SPM 150 mg/NM3
(Coal Fired uette Cyclon SO2 100 ppm
FBC based e+ Bag NOX 50 ppm
system) Filter
8 TPH
3. D.G.SET(1500 Diesel 11 350 -- SPM 150 mg/NM3
KVA) SO 2 100 ppm
NOX 50 ppm
125
Process Emission
Sr. Stack attached Stack Stack APCM Probable Permissible
No. to Height in Diameter Pollutants Limit
meter
As per EC No. F. No. J-11011/132/2014-IA II (I) and CTE No. 70398
1. Reaction Vessel 12 300 Two Stage HCl 20 mg/Nm3
Water SO2 40 mg/Nm3
Alkali HBr 5 mg/Nm3
Scrubber
HBr
Scrubber

Alkali
Scrubber

Water SO2 40 mg/Nm3
Alkali
Scrubber
After Proposed profile change

1. Reaction Vessel 12 300 Three Stage HCl 20 mg/Nm3
Water SO2 40 mg/Nm3
/Alkali HBr 5 mg/Nm3
Scrubber

water/Alkali
Scrubber

Water SO2 40 mg/Nm3
/Alkali
Scrubber
4. Reaction Vessel 12 300 Three Stage NH3 175 mg/Nm3

Water
/sulphuric
Scrubber
126
DETAILS OF AIR POLLUTION CONTROL SYSTEM
DIAGRAM OF CYCLONE SEPARATOR
127
FLOW DIAGRAM OF TWO STAGE WATER SCRUBBER FOLLOWED BY

ALKALI SCRUBBER FOR PROCESS EMISSIONS:
reactor
Water
SCRUBBER
COLUMN
PACKED
SCRUBBER
VENTURY
DILUTE NaOH
NRV
PG
BLOWER
STACK
1
128
VOC CONTROL MEASURES
VOC Control Mechanism
129
ANNEXURE X
Details of Hazardous Waste:

Sr. Type of Categ Quantity Quantit Total Treatment &
No. Hazardous ory as per y as per Quantity Disposal
Waste No. EC propose after
d Mix proposed
Change
1. ETP Sludge 26.2 30 +20 50 Collection, storage,
transportation
,Disposal to
Nearest TSDF site
2. Residue from 28.1 65 +30 95 Collection, storage,
Distillation transportation ,Co-
processing in
Cement Industries
or send to Nearest
Common
Incineration Site
3. Discarded 33.3 1000 +2000 3000 Collection, storage,
Drum Nos. transportation ,Sell
to GPCB
authorized Vendor
after
decontamination
4. Discarded PP 33.3 2000 +2000 4000 Collection, storage,
Bags/Liner Nos. transportation ,Sell
to GPCB
authorized Vendor
after
decontamination
5. Used Oil 5.1 200 +300 500 Collection, storage,
Liters/Mo transportation, Sell
nth to GPCB registered
reprocessor.
6. Inorganic 28.2 100 -50 50 Collection, storage,
Salts transportation ,Sell
to end user
7. Carbon -- 5 -0 5 Collection, storage,
Sludge transportation
,Disposed at
Nearest TSDF Site
8. MEE Salt -- 25 +275 300 Collection, storage,
transportation
,Disposed at
Nearest TSDF Site
9. HCl (30%) D2 126 -0 126 Collection, storage,
transportation ,Sell
to end user
130
Sr. Type of Categ Quantity Quantit Total Treatment &

No. Hazardous ory as per y as per Quantity Disposal
Waste No. EC propose after
d Mix proposed
Change
10 H2SO4 D2 50 -0 50 Collection, storage,
(70%) transportation ,Sell
to end user
11. Liqour C1 45 +10 55 Collection, storage,
Ammonia transportation ,Sell
(20-24%) to end user
12. HBr (35- B26 70 -0 70 Collection, storage,
40%) transportation ,Sell
to end user
13. NaBr (20- B26 76 -0 76 Collection, storage,
22%) transportation ,Sell
to end user
14. Phosphoric D2 60 -0 60 Collection, storage,
Acid transportation ,Sell
to end user
15. Copper C1 80 -40 40 Collection, storage,
Sulphate/Cop transportation ,Sell
per Oxide to end user
16. Sodium -- 5 -5 0 Collection, storage,
Acetate transportation ,Sell
to end user
17. Sodium -- 30 +10 40 Collection, storage,
Sulfite transportation ,Sell
to end user
18. Potassium -- 5 -5 0 Collection, storage,
Chloride transportation ,Sell
to end user
19. Potassium -- 12 -0 12 Collection, storage,
Carbonate transportation ,Sell
to end user
20. Ammonium C1 4 -4 0 Collection, storage,
Sulphate transportation ,Sell
to end user
21. Spent Solvent -- 00 50 50 KL/Month Collection, storage,
KL/Mon transportation ,Sell
th to Cement Industry
22. Poly -- 00 +20 20KL/Month Collection, storage,
Aluminum KL/Mon transportation ,Sell
chloride th to end user
solution 25%
131
Details of Solid Waste

Sr. Waste Quantity Mode of Disposal
No.
1. Glass Waste ( Z 13) What so ever Land Fill site
2. Paper waste (Z44) What so ever Land Fill site
3. Cotton waste What so ever Land Fill site
4. Wooden Waste What so ever Authorized Scrap Vendors
ANNEXURE XII
List of Hazardous Chemical

Sr. Name of
No. Hazardous chemical
1. Acetone
2. Ammonia
3. Benzene
4. Benzyl Chloride
5. Benzyl Cyanide
6. Bromine
7. Chlorinated Benzenes
8. Chlorine
9. Chlorobenzene
10. Copper & Compounds
11. Cyclohexane
12. Di-Chloroethane
13. Formaldehyde
14. Hexane
15. Iodine
16. Methyl Alcohol
17. Methylene Chloride
18. Perchloroethylene
19. Phenol
20. Sodium Cyanide
21. Sulphuric Acid
22. Thionyl Chloride
23. Toluene
24. Xylene
132

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Headquarters along with distance

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proposed to be set up?

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Railway Station is only 60 K.M. It

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7. Risks of contamination of land or water from releases of pollutants into the

8. Risk of accidents during construction or operation of the Project, which could

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(III) ENVIRONMENTAL SENSITIVITY.

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This is EC Amendment application. The production quantity is remaining the same.

Unit has obtained CTE No. 70398 on dated 30/06/2015.

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Plant layout area bifurcation:

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Sr. Name of ProductsQuantity as per Addition/ Quantity

Sr. By-Products Quantity as per EC

After change in product list:

Sr. Name of Products CAS Quantity in Quantity in End Uses

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Sr. Name of Products CAS Quantity in Quantity in End Uses

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Sr. Name of Products CAS Quantity in Quantity in End Uses

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Sr. Name of Products CAS Quantity in Quantity in End Uses

AFTER CHANGE LIST OF BY PRODUCTS:

Sr. List of By Quantity as Generated from Quantity after

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Sr. List of By Quantity as Generated from Quantity after

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Sr. List of By Quantity as Generated from Quantity after

Product wise Raw Material Consumption Quantity: