Centrestades No Signature... Ps2si CHEMISTRY Paper 1 July/August 2% hours WAKISSHA JOINT MOCK EXAMINATIONS ig Uganda Advanced Certificate of Education CHEMISTRY Paper | 2 hours 45 minutes Instructions to Candidates * Attempt all questions in section A and any six questions from section B, * All questions are to be answered inthe spaces provided. * A Periodic Table witheievat atomic masses supplied ct he eof he py os Molar gas volume at stp = 224 dm? (er Bane ae ay | | © WARISSHA Joint Stock Fxuminasions_? Turn Over re ~ Scanned with CamScanner — cen SiS TE peer* & S SECTION A 46 MARKS) Avempe all g cisulphate fons oxidise exit fons accord (aq) + 21-(aq) —> 2s03-(aa) + The rate equation for the redox reaction is Rate = k{S03°] {I-) a 2sc © Stxenwar above ¢2) yy which the rate of reaction 1g changes on the rate, In each ease give treason for (©) State the effect of your answer (Addition ¢ Iron (1) sulphate solution to the rea jon mixture. ~ (1% marks) ing 1g concentration of peroxodisulphe;e ians while the foncentratien of lodide ions is halved. ( (1% marks) ‘Complete the following eguations and in each case name the ) (2) CH C— NH, + HaOBr(aq) —NaOti(agy Name of the product. _Pusees NaBr(s)/ Conc. HpS0, @) CH CH Heat Hh Name ef the prgdiftevsvsessnrnenses ae KMn04/ HaSO, () (Cis) = CHCH Conc. oe ly Name of the provucl(s).. ‘ (1% marks} © WAKISSH Joins Mock tscamunation 2 Scanned with Camscannert Manganese is a transition clement which forms stable comy 82,4 and 47, (@) Write the formuta 42. (i) 44: Pounds in oxidation states of manganese in oxidation state; Fthe oxide (14 marks) () Write an equation for the (oxide eaction that takes place between; 2 and dilute sulphuie acid, Gi) hot concentrated hiyrochioric Gi) 4 Methanois acid in an organic solvent such ae benzene dimerises * (@) State the; 0) "ype of bonds between the ‘acid molecules in benzene, . © _ (@) above with the vapour pies Your answer, +> Cémpare your answer in 30°C. State the reason for + (V% marks) SS Niglaq) + 1,0" (aq) NHR + 1,00 == Ny saase The pH. sree solution Sfammonium sulphate was found to be 6.24 at Turn Over (CAKISSIA Joiat Mock Examinations?Cotoutate the; (8) (concentration of hydroxonin um ions in the solution. Re J’ in the solution. Gil) concentration of gdm? of ammonium sulphate in t (Kb for ammonia at 25°C is 1.78 x 107* moldm=?) *- (03 marks) (&) (i)... . State what would happen to the pH of the solution ja (a) if an equimolar _ solution of aqueous ammonia is added to it. (4 mark) 6 @ 4 oe C=0, N-H, CoNandO= Hee wos F 7 respectively, are 799, 391, 61S and Calculate the enthalpy of the reaction, Nou CHSCOCH, + H,NOH ——> CH C~CH, + 11,0 (03 mats) ‘©WAKISIA Jon eck Examination? ‘ | ie Scanned with Camscanter2 Orine forms oxo acids of the formulae f@) State how acid strength of the o * chlorine. ) Explain your answer in (a), (© A solution containing HCO, ‘was added to 1M sulphuric acid followed by Iron @) sulphate solution. @ State what was observed, (1% mark) 8. State what would be observed and write an equation for the tanc place when cach of the following substances sare mixed. (@) Dicthylamine and ice-cold: sodium nit hydrochloric acid, ‘Observation:... ) (©) Benzeite dinzoniy'n chloride and phenol in alkeline 3 © IAKISSHA Jolnt Mock Examinations_2 i} } | a4 Scanned with CamScanner bkTin and carbon belong (a) &) Equation: to group IV of the periodic table. Write the: ; (i formulae of stable chlorides of Tin and Carbon. (1Amarks) fes in (a)(i) nbove with water. (02 marks) for the reaction of the chlor ea Eros ciifed Tin (I) suphate solution was added to potassium dichromate solution, State what was observed. (01 marks) Gi) Weite an equation for the redox reaction that took place. (01 marks)SECTION B (54 MARKS) Attempt any six questions from this section, ‘What is meant by the term cell constant? ‘The molar conductivity of 0.05M of Magnesium chlaride placed between sleetrodes of cross sectional wea 1.25664 x10-%mn? and 0.12m apar is ~'m?mol-!. When 0.05M Barium chloride solution is placed in the maeeale the resistance was 93.929, Calculate the; (cell constant, (01 mark) qi) (© @_—_ Compare the molar conduct ites of he leery in) above at Gi) 2 rest being . 53.19% by mass of Q. the 78%, hydrogen 7.41 ‘of carbon, 77. ee Compound Q consists i Star ined at ‘at 95°C and 760mintlg, the di vapour pyzssure of water is 639mmHg, (0) Determing je: (o2 mars) “so () ~emplrical formula of Q. . a(8) State the trend in melting points of the chlorides in (a) above. Explain your answer. (2% marks) (© Desc ine weston of the chlorides of Na, Aland P wih water. (03 marks) (6) Use equations to show the following conversions can be effected. (1,1 —dichloropropene to CHsCH = CHOH (03 marks) 4 Bu-2-yne to CHyC- COOH fl CH,CH Turn Over OARESSIA Joon Mack Examination? ° Scanned with CamScannercan be synthesized # (8) Without using equations describe now 2-bromoethanol ea ion we + 3 may cethanoie acid, \ 4 14, Ethanol and cycloh 1¢ boil at 78.4°C and 80,8°C respectively at 760mmHg while an azeotropic mixture (43% ethanol and 57% cyclohexane) boils at 64,8°C, (9) (Define the term uzeotropic mixture. el Gi) (0 ©) @ Sketch a well-tabetie “ en cyclohexane saren C28 Poin composition diagram for ethonst. (2% marks) , | 4 - /: ‘State any twongen,, cyclohexane ar by Name the We the reagent that Pairs of can be used to dit : Substances. State what would bese sh between each ofthe lowing erved in cach case. oO m i) MCOX(s) and Bacoy) (@2 marks) Gi) -Kiq) ‘and NaBr(aq) * ona | © precipitates i formed in a brown solution hen potassivn fodie ‘aqueous solution of Copper (I) chloride. (2¥smarks) solution is added to an STE cect eange when hone tide FS pcidified Nickel (lt) sulphate solution. Ga scanned with Camscanteratbundant isetope of chlorine (01 mack) ate the average relative atomic mass of chlorine. (02 marks) why the mass spectrum of chlorine gas has three peaks, (04 marks) (©) State two advantages of using Ws the mass spectrometer to ¢ mass of elements, ‘© WARISSHA Join Mock E al saminations_2 ned with CamScanner uFV Different ma8565 ofa non-voaile CompoUnN X ye water at 101.325 Kpa and ine teeing pont Mass of X in 250g of wat Freezing point (°C) Non. int OF the resulta TY Separately dissolved in 250g of al Solution measured. ler (g) too [7 250 | 300 -054 | -065 st muss of X in 250g of water, (2% marks) Turn Over 3 A Eninaint? ‘e WARISSIA Join . © scanned with CamscanneUse your graph to determine the; * freezing point of pure water. (01 mark) ‘molar mass of compound X. (eryoscopic constant of water is 1.86°C Kg” mol") ©) % (1% marks) (ii) short chain carboxylic acids dissolve ~ CWAKISSHA Joint Mock Examinations >THE PERIODIC TABLE 39 m1 x | as Cr Ma 820] 549] ss| su9] sa7 726|749| 790] 739] 0.9 alolalas s43| ons] iot | 103 a[ ols nt] xe a Bl Bl ulslula|n " as | 6 w]e! os! | n at |e 859 | 103 | 139] ae | ans | ea | 6] 130 | 190 | 9s 204| aon|ct0)azy Fe \can| T1 a ” | ales| oslo o|w)n t So] Be] 1 | by) he | Fe | te] v0 | be 150) 482 159 | ter | 165 | 107 | 169 | 173 | 175} v6 | 95] 96 | 97 | 90 Pefam|cm| m| cr | 100] 101 | 02 | 103 Es | ra | nie Re | Low lace} ae]can| aan} 231 |eso|asn|asa| cso) END G WAKISSHIA Join Mock Examination 15 anned with CamScanner