Problamas tema 3. GOLUCIONES see @) g2mCe AT MBE T 3 159 Ge (2%6-22,3)"C => Ce aa Za 2A Le (5 (29.6 - 22,3, = b) gamce (Ig-Té) ad = 2,75 -108cal = 225 10" deal yc (1-231) 'C Ty(te)2= ——* — sn asrtc => Ty 2 2488°C get gaz my Cel HyO1(T-Te)y € mae [M20] (Tp -Te), 20 etsy my ceffol(4-Te) : mg cof (%-Tea) ma Ty-img Tet 2 Mg Ty + me Ten (ngema)tp = mTy + maT =p ys MTae mes myting Ty = FE180 t 100-20. pe ayn ¢ 457 [oo ie Respuesta correcta: apartndo 6 (46'c ) 3 Au =qtwl a) AU = +g-w = 6217-67720 b) AU eters 2 3565-592 = - 2365 <) AV s-gtu) 5-385 4IUT = 41337@) PM (CgHo) = 44.4 9 /mst Amel — 44g — xT | 'CaHs (root s- hI /mee 084g — ~214kT 2.2201 kJ /met Cig b) Pm (Cio ied } = 182,29 (mae A mot — J52,24 —— xT Deg tc 0 + - 4440, 4 Real Mme ttico 0.186 ¢ ——~ -4,26 keat SC eat —4SET => AleytyeO =~ 584.2 kT/mekagtleO ce) Pm (cgH¢ 0) 3 58.1 g Jost 674414 /ml + 2.35 mL = JB64 Ama® — 584g — xT AHes ico =~ 1824.4 kT /met MBq — - 58.8 a bit dmekgte® 5] (4)+2 2Halg) + Og) —2 Hy 2) AH 5716 kJ (2) C3 Ha(g) + 4944) ima acd)» ange) Abts -193# RT (3)« C4) 3<%q) * anor) mth aiglig fy) fats) Ane 22219 AT 24 (q) # GHalg) —* SHG) piercaenaee @) 2HL (9) + Coa lg) + O, (g) —> Cae Cla lt) # Hy Ole) AW*s-a18- KE ()C%) Clay) + Ha0 le) —> AHL (g) + 40g (g) — AH*= 4042k7 Catty (g\ + C0, (5) —® CaHy z(t) AW? 2-2 TRT[A] a) ans anf Teaneg] + AS Cetiegy]- any [estera)] - Any [ary] AH s = 84,68 RI fel — FA.BL kT fet — (-108.8) kT/rl = 0 255,69 kS ls b) An = 2Any [ 50, (lle 2 Any Cazote)]- 24H Cr. sig) ]- Bane [O209)] AH = 2+(-246.8)kI/mst +2 (- 285.8) kI/mst ~ 2 (-20.63) kJ mv 0 2-123, 74h Tit CHy-cH,~ oF (¢) + 5 0aty) —+ 2 C02(5) + 3 Ha 0/e) AN? = 2 aHy"Te0aig)] +3 AH [H20(e) | Auf Tecate ore)]- BAN; [024] AH® = 2 (-393.5) kT /met + 3(-285.8)kI fave ~ (= 2424) kT)mst ~ 0 5436 RI fst An = Ang [ecta(g)| + 4 Any [We@(gy]- Bry Cotalg)] ~ 4 Any Tetacg\] AH; ecta(all= an" Aap Laettg] + Auf Feb] + 4Auy [ebay] Any [ectyts)] =~ 344.3 hy fet -4(-92.34) hI Anal + (- HBA) kd fort + 0 any [ccluls)] 27402. 8t kT Inet, 40] a) Incorrect. 2H cube ser mayor gua cere ya. gue hay gue rmper entacs. b) Correct, Cambio de un ine le gas a deo meles oe fs ¢) Correct a ath temperatores AG = AH-TAS v AH70 , AS>a AG = AH-TAS a) BH 70; AS>O (Amd de gas + 2 mel de gas) 7 AG KO a atlas temperabme b) ANL0 ; AS BG <0 & bajas demperaturas c) AH<0 7 ASPO (Amst de gas >a mek de gas) —> AGo ; AS AG<0 nwncaAG*= AH®-TAS® ARs Ang [Nia ch (2j]- At [wea (g)]- BAY Lee] AW? == B44.4 kT /met = (-4G.41) kT /onet = (= 12.31) kT foe = = 15-98 kT mee AG? = 46; [wi ¢s)] - 464 INHs (9) - Ag [hag] AG" = ~ 202.9 kI/meb = (- 16.48) hI lne€ ~ (-95.30) kT net = - 94.44 kT fmol Ast: AWDAG? 195.98 kT fet = (- 1,42) kT /mel Tv 292 K AS° = - 294.8 T/nel-kK [45] a) 2 Hele) + £02 ig) —e HaOGy) + Lacy) Ae? = AG THsO(g) 1+ 467 [ete (g)]- 2A6/ [Heb0y)]- % AG 4 [02G)] AG" ~228,6 kT /mel + 0 bS/met ~ 2-46. 3)kI met ~ 4.0 A Thee 2 -B8AT/mee AG*= - RTL Keg Ce ba key = AGL. £8-10 Thnee 4 bn T 45.3386 RT BBL T/mat.K - 298K Ker = elf — 457-108 b) 3 Feg03¢s) + Ha (g) == 2 Fez04(s) + H2.0(9) tomando to4 dates correspendientes o& far tablas vy fesstviendo ole manera andloga al apartado anterior: AG? 2 -32kJ fst 5 bn Keg 24242 5 Keg = 4.4105 <) 2 Ay” (ag) + S0,?" (ag) == Ag2SO4(s) AG’ = -284kT fst 5 tn Keg 2 44.34 j Keg 5 %4. 104a) (5)-(4) Na 0 (q) — dq) +(4 0219) AG" = -A04,.2k1 (4) Ng/G) + 2.02 (3) + 2NO2(5) AG" = 102.6 AG? 2 -aokT N20(g) +3 02 —> 2 NOa(3) (casi en equitibrio) +3 Oxi) 4 poly) + 2tx0 (e 46% 3369 kT AG? 2 -22kS 4) (2)-(§) 4 pha) (4):(3) 2 Aleta) + 2 Hal) —+ $ hats) (3) (3) 4 Aioy) re 3 Wis) + 3 626)) AG*s-145,4 kT AG °2-424.24T Ge prodoce per complete) Haig) + Oz fy) —» 24, 0(c) ) (5) (4) Wa(g) +4 O2 2G) —> A204) AG°s 1042kF (2) (4) 2 NH3 (9) + E batg) ) + 29064) + au.0l6) Ae? = 505,25 br (3)- 1) ) 266) — Ny) #026) AG" 3-1 tht AG? s -SH2kT 2 NHs(g) + 2 Oa (g) > N2O(g] + 342 0/e) [se prodoce pet complefe) AG = AG? + RTA P 505 2 AG*+ RT Ln V0," Po, AG =2 46; [sai |- 2hG; [so2(4)1- 4G; [oat | AG: 2-(-st1.4) kSlmet ~ 2(- 300.2) kT fnct =O kS/met = 144.8 k I fuk AG 2 -dAdS +103 Ffonet + 3145 T/mot-K- 248 K Ln Oot - AG =~ 403.5 kIT fmt ae do. feaccidu es espontinea. en e€ sentido que estd esecthaAG 2AG*+ RTIM@ ez a1 cH3600"(ag]] alHjor(ag)] — [cugcoo J [#;0°] @ [cH3c00H (ag) | a [H,0(e)] Let coo] Tc,coo][H,0°] AG = AG*+RT4n [cH,coou] “8 pt AG 2 24.0810 TF /met + 9.3145 T/met. 248K bn OIE od AG 2-446 ko /mot fa reaccion es esponttnea en e¢ sentido qua esta escrita., [A] tn Aes AWE 4A “RG k OR a) Like 54.2: 10° T/met 4 4\4 OMS — 8.3445 T/mot-K | 298 24] K % 429 An Ky = bn 0443 22.40 5 ba Ky 2-429 5 Kye” 2 0044 B4a-10rtAnet (4 4\4 ae TR] kK b) tn Ae OMB 8.3445 T /mot K 4d 4 BAF 0 = A — —— Ta =327.4K gk lk) 7{@] Los vatores oe AH" y ol AG ok cada. componente oe te reacdta pe toman ote dar tabtas correspondiente ot apdndice det Libro Petrucci -A 298 K AH= AH/ [et ony] ~ Any [6 0(3)] ~ 24Hy' [H2(9) ] AM? = - 90,24S/mst AG’ = AG [eHs6H ig)] - 4G,Ico gl - 246/[He ig] AG? = -24.9kS/mot Per otra. parte: AG°=-RT4n kp An Kp = AE, ans w*That __ go RT 33445 T/ ot. 278K Kpze” 22.204 —A 500k dn Ee AME 1-4) Ky R\% & bn Ke. 790.2:107 Hint _ fA -£)4 2.210" 9.3445 T/metig \21F 9%) K bn Ke 3 = 44,401 4.210 An kp 2-H, 707 tn 22-104 An kp 2-4 4! = kp ze 48 40a. 40?