SAFETY DATA SHEET Hydrogen Peroxide 50% Oxypure® SDS #: 7722-84-1-50-34 Revision date: 2015-05-08 Version 1 ‘AND COMPANY IDENTIFICATION Product Identifier Product Name Hydrogon Peroxide 60% Oxypure® ‘Other means of dentiication. CASINO 722844 ‘Recommended use of the chemical and restrictions on use. Recommended Use: Potable water treatment: Certified to conform to the requirements of the "NSF / ANSI ‘Standard 60 - Drinking Water Treatment Chemicals - Health Effects" by NSF Intemational Restrictions on Use: Use as recommended by the label Manutacturer'Supplier PeroxyChem LLC 2005 Market Streat Suite 3200 Philadelphia, PA 19103 Phone: +1 287/ 422-2400 (General Information) E-Mail: sdsinfo@peroxychem.com PeroxyChem Canada PG Pulp Mill Road Prince George, BC V2N2S8 ‘+ 250/ 561-4200 (General Information) For leak, fire, spill or accident emergencies, call 4/800 / 426 $300 (CHEMTREC - U.S.A) 4.703 / £27 3887 (CHEMTREC - Collect - All Other Countries) 1.613/ 896-6666 (CANUTEC - Canada) 1 908/ 389-1409 (Medical - U.S. - Call Collect) 1 281 / 474-8750 (Bayport, Texas Plant) 4.260 / 881-4221 (Prince George, 8C, Canada Plent) SEs 2 HAZARDS IDENTIFICATION Classification. OSHA Regulatory Status ‘This material is considored hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) sis toxilty - Oral (at te toxicity ~ Inhalation in corrosionvirtaton ious e iration, cific target organ tonicity (singleHydrogen Peroxide 50% Oxypure® 808 #: 7722-84-1-50-34 Revision date: 2016-05-08 Version 4 aang Haus oye .GHS Label elements, including precautionary statements. EMERGENCY OVERVIEW 1335 - May cause respiratory initation Precautionary Statements - Prevention P271 - Use only outdoors or in a well-ventilated aroa 260 - Do not breathe mist, vapours or spray. 280 - Wear protective gloves! protective clothing! eye protection’ face protection 210 - Keep away from heat/sparks/open flamesihot surfaces. - No smoking P220-- Keep/Store away from clothing/fammable materiais/combustibles P21 - Take any precaution to avoid mixing with combustibles/iammables Precautionary Statements - Response P05» B361 P38 -IF IN EYES: Rio cavtouty wth water for several inues, Remove conc anaes i presen and easy to do, Continue rinsing P3910 - Immediately call a POISON CENTER or doctor 303 + P361 + P353 - IF ON SKIN (or hair: Take off immediately all contaminated clothing. Rinse skin with water! shower 363 - Wash contaminated clothing before reuse 304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing 312 - Call a POISON GENTER or doctor if you fool unwell 301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting 310 - Immediately call a POISON CENTER or doctor 370 + P378.- In case of Fre: Use water for extinction Hazards not otherwise classified (HNOC)_ No hazards not otnarwise classified were identified, ‘Other information Keep container in_a cool place out of direct sunlight Store only in ventad containers. Do not store on woodsn palists. Do not return ‘unused material to its original container. Avoid contamination - Contamination could cause decomposition and generation of ‘oxygen which may result in high pressure and possible container rupture. Empty drums should be tripe rinsed with water before discarding. Page 2/9. Hydrogen Poroxide 50% Oxypure® SDS#: 7722-84-1-60-34 Revision date: 2018-05-08 ‘ Version 4 Eon a | COMPOSITIONIINFORMATION OW INGREDIENTS jneimoy UES er Formula HO-OH | ‘ ‘Chemical name, CAS-No ‘Weight Fiydrogen peroxide 7722-244 0 ‘Weier T3285, 80 Occupational exposure limits, i availablo, are isted in section & SEs Ce FIRST AID MEASURES are su team | 1 Eye Contact Rinse immediately with plonty of water, also under the eyelids, for al feast 15 minutes, Remove contact lenses, f prosont, after tho first § minutes, then continue rinsing. Seek immodiate medical atientonvadvice. ‘Skin Contact ‘Take off contaminated clothing. Rina skin immediately with plonty of water tor 16-20, ‘minutes. Calla poison control center or dacior for further treatment advice, inhalation Move to frash ai. If person is not breathing, contact emorgoney madical services, then give artificial rspietion, preferably mouth-1o-mouth if possible, Call « poison control center or dostor for further treatment advice. Ingestion Rinse mouth. Do not induce veriting. I eonselous, give 2 glasses of water. Get immediate medical alanion. Naver give anything by mouth 6 an uncenscious parson. I ‘Most Important symptoms and Hydrogen Peroxide initates respicetory system ond, if inhaled, may cause inflammation and ‘effects, both acute and delayed —_pusmonary edema. The offects may net be immediate. Overexposure symptoms are coughing, giddiness and sore throat.| in case of accidental ingestion, nacresis may resuit Irom mucous membrane bums (mouth, esophagus and stomach). Oxygen rapid reloaso may cause stomach swelling and hemorrhaging, which may product major, or even fatal, Injury to organs if a largo amount has beon ingasted. tn con ofstin contact may cause burs, erythema, ster or even neces Indication of immediate medical Hydrogen peroxide at those concentrations is a song oxidant. Direct contact wih the eye attention and special treatment i ikely to cause corneal damage especially f not washed immediately. Careful needed, If necessary cepthalmologie evaluation is recommenced and the possibilty of local cortiecsterold therapy should be considered. Because of tha likeihood of corrosive effects on the gastrointestinal tract afer ingestion, and the unikelincod of systemic effec attomps at evacuating the stomach via emesis induction or gasbie lavage should be avoided. There is a remote possibilty, however, that a nasogastric or orogastic tube may be required forthe reduction {Of severe distension due to gas formation. Si FIREFIGHTING MEASURES sous errant EN Suitable Extinguishing Media Weer. Donatus any ther substance. { ‘Specific Hazards Arising from the In closed unventilaled containers, risk of rupture dus to the increased pressure from ‘Chemical dscomposiion. Contact with combustible material may cause fre Hazardous Combustion Products On decomposton produc roleses yen which may nny fro Explosion data ‘Sensitivity to Mechanical Impact Not sensitive. Sensitivity to Static Discharge Not soncitive. Protective equipment and ‘Use water spray to coo! fre exposed surfaces end protect personnel. Move containors from precautions for firefighters fire area if you can do it without risk. As in any fre, wear celf-centained breathing apparatus ‘end ful protective geer. sy umions) 6 ACCIDENTAL RELEASEPersonal Precautions Other Environmental Precautions ‘Methods for Containment Methods for cleaning up SDS #: 7722-84-1-50-34 Revision date: 2015-05-08, Version 1 ‘Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Isolate and oat spl area. Keep people aay from and upwind of sp/ieak. Eliminate all sources of ignition and remove combustible materials, Combustible materials exposed to hytrogen peroxide should be Immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is rernoved Residual hydrogen peroxide that is allowed to dry (upon evaporalion hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, eather, wood or other combustibles can cause the material to ignite and result in fre. ‘See Section 12 for additional Ecological information. Dike to collect large liquid spilis. Stop leak and contain spil if this can be done safely. Small spilage: Dilute wit large quantities of water. Flush area with flooding quantities of water. Hydrogen peroxide may be decomposed by ‘adding sodium matabisulfte or sodium sulfite after diluting to about 5%. T.HANDLING AND STORAGE 5 Handing Storage Incompatible products Use only in well-ventilated areas. Keep/Store away from clothing/ combustible materials. Wear personal protective equipment. Never retum unused hydrogen peroxide to eriginal container. Contamination may cause decomposition and generation of axygen gos wich Could resuit in high pressures and possible container rupture, Emply drums should be tiple ‘insed with water bofore discarding. Utensiis used for handling hydrogen peroxide should oniy be made of glass, stiniess steel, aluminum or plastic. Pipes and equipment should be passivated before frst use. Hydrogen perexide should be stored only in ventad containers {and transferred only in a prescribed manner. Keep containers in ecol areas out of direct sunlight and away from combustibles. Provide ‘mechanical general andior local exhaust ventilation to prevent release of vapor or mist into ‘work environment, Containers must be vented. Keep/siore only in original container. Store rooms or warehouses should be made of non-combustible materials with impermeable floors. In case of release, spillage should flow to safe area. Containers should be visually Inspected on a regular basis to detect any abnormalities (swollen drums, increases in temperature, et.). ‘Combustible materials, Copper alloys, galvanized iron. Strong reducing agents. Heavy ‘metals. Iron. Copper alloys. Contact with metals, metalic ions, alkalis, reducing agents and ‘organic matier (such as alcohols or terpenes) may produce selt-accelerated thermal decomposition. _-8- EXPOSURE CONTROLS/PERSONAL PROTECTION ‘Control parameters Exposure Guidelines Ingredients with workplace control parameters. ‘Chemical name ACG TL ‘OSHA PEL, MOSH, Wexice Fiydrogen peroxide TWAT ppm TWA: T ppm TOLH: 75 ppm ‘Wexico: TWA 1 ppm 7722-844 TWA 1.4 mgim? TWA: t ppm | Mexico: TWA 1.5 mg/m? TWA: 1.4 mgien co: STEL 2 ppm Mexico: STEL 3 maim? ‘Chemical name British Columbia ‘Quebec ‘Ontario TWAEV, ‘Alberta, Fiydrogen peroxide TWA: 1 ppm TWA: 1 ppm TWA. 1 ppm TWAT ppm TH2B44 TWA: 1.4 mg/m? TWA: 1.4 gin? ince Engineering measures Ensure that eyewash stations and safety showers are close to the workstation location. Eneure adequate ventilation, Page 419. Hydrogen Peroxide 50% Oxypure® SDS #: 7722-84-1-50-34 Revision date: 2015-05-08, Version t Individual protection measures, such as personal protective equipment EyelFace Protection ‘Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures. General information Use chemical splastrtype monogoggles and a fullface shield made of polycarbonate, acolate, polycarbonate/acetate, PETG or thermoplastic, For body protection wear impervious clothing such as an epproved splash protective sult made of SBR rubber, PVC (PVC Outorehel wrPoyester Substrate), Gore-Tex Polyester ‘tilaminate wiGore-Tex), or a specialized HAZMAT Splash or Protective Suite (Level A, B, 0). For foot protection, wear approved boots made of NBR, PVC, Polyurathano, or neoprene. Overboots made of Latex or PVC, ae well as refghtar boots or specialized HAZMAT boots aro a's permitted, DO NOT var any form of oot or overbeot made of ‘nylon or nylon blonds, 06 NOT USE coton, wool er leather as these matriaisreectepidly “with higher concentrations of hydrogen peroxide. Completely submerge hydrogen peroxide: Contaminated clathng or olher materia in water porto crying. Resitual hycrogon Beronde, flowed to dry on materials such es paper, fabres, cotton, leather, wood or ‘ther combustibles, can causa the malarial to ighita and result in a fr. For hand protection, wear approved gloves made of ntl, PVC, er neoprene. DO NOT use cotton, woo! or leather for these materials react RAPIDLY with higher concentrations of ‘hydrogen peroxide. Thoroughly rinss the outside of gloves with water prior to removal Inspect regularly for leaks. | concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved self-contained breathing apparatus (SCBA) or other approved air-supplied respirator (ASR) equipment (e.g, 2 ful-feee airine respirator (ALR)). DO NOT use any form of air-purifying respirator (APR) or fiterng facepiece (dust mask), especially those containing oxidizable sorbants such as activated carbon, ‘Avoid breathing vapors, mist or gas. Clean water should be available for washing in case of ‘878 oF skin contamination. Protective engineering solutions should be implemented and in use before personal protective equipment is considered. 9. PHYSICAL AND CHEMICAL {Information on basic physical and chemical properties pearance Physical State Color Odor Odor threshota pH Melting pointifreezing point Bolling PointRange Flash point Evaporation Rate Flammability (soll, gas) Flammability Limitin Alr Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density, Density Specific gravity Water solubility Solubility in other solvents Partition coefficient ‘Autolgnition temperature Becomposition temperature Viscosity, kinematic Viscosity, dynamic Clear, colorless quid Liquid Colorless odorless Not applicable = 30 62°C 114 °C Not flammable > 4 (n-butyl acetate=1) Not flammable Not applicable 18 mm Hg @30 °C 'No information available 12 @20'C 12 completely soluble No information available log Kow= 1.6 @ 20°C Not combustible 100 °C (adiabatic) 4.47 eP @20°C 'No information available Page 5/9- Hydrogen Peroxide 50% Oxypure® SDS #2 7722-84-1-5004 Revision date: 2015-05-08 ‘Version 1 Explosive properties ‘No Information available Oxidizing properties: ‘Strong oxidizer ‘Molecular weight 34 Bulk density NNot appfcabie ig eee Se sey eG STABILITY AND REACTIVITY sche erage ee Reactvity Raatve and ovifzng gent. | ‘Chemical Stability ‘Stable under normal coneitfons. Decemposes en heating. Stabie under recommended storage conditions. Possibility of Hazardous Reactions Contact with organic substances may cause fir cr explosion. Contact with metals, metalic jons, alkalis, reducing agents and organic matter (such as alochots or terpenes) may produce soffaccelerated thermal decomposition. Muazardous poymetaion _—_Harrdouspalmarealan dos a ati | Conditions to avoid Excessive heat; Contamination; Exposure to UV-rays pH variations. Incompatible matertals ‘Combustible materials. Copper alloys, galvanized iron. Strong reducing agents, Haavy metals. lon. Copper alloys. Contact with metals, metallic ons, akals, reducing agents and Srgenc mater (euch a aleahol or epenes) may produce siheceleraed thermal decomposition. Hazardous Decomposition Products Oxygen which suppers combustion, Liable to produce overpressure in container. 1050 Oral 50% solution: LDSO > 225 mg/kg bw (ra) 35 % solufion:LDSD 1193. mgikg bw (rat) 70% solution: LDEO 1026 mg/kg bey (rat) LD50 Dermal 35% solution: LDSO > 2000 mig/kg bw (rabbit) 79 % solution: LDBO. 8200 mghkg Bw (rabbi) L650 Inhalation ‘60% solution: LSO > 170 mg/m! (rat) (4-hr) Hydrogen Peroxide vapors: LOD 400 rngfm® (mouse) (5 - 15 minutes) Hydrogen Peroxide vapors: LCEO > 2160. mgln? (mouse) Serious eye damageieye unitation Corrosive. Risk of serious damage lo eyes. Skin corresioniritation Corrosive to skin. Causes severe burs, Sensitization Did not caus genctization on laboratory animals, Information on toxicological effects Symptoms Vapors, miss, ot aerovcls of hydrogen peroxide can cause upper sicway lritaton, {inflammation of the nose, hoarseness, shortness of breath, and a sensation of buring or tightness in the chest. Prolonged exposure to concentrated vapor or to dilute solutions can ‘cause iffation and temporary bleaching of skin and hair, Exposure to vapor, mist, oF saroao can cause singing pin and iaring of eyo, exposure Carcinogenicity ‘This product contains hycrogen peroxide, The Intemational Agancy for Research on Gancer (ARC) has conculded that there is inadequate evidence for carcinogenicity of fpdrgan pooxide in humans, but ited evidence in expermarta animale (Group 3 nol claasifable as fo Rs eareinogenicly to humane). The Amarican Conference of Governmental Industria! Hygienists (ACGIH) has concluded that hydrogen peroxide is a ‘Confirmed Arimai Carcinogen with Unknown Relavenca fo Humans! (A3)..Hydrogen Peroxide 50% Oxypure® SDS #: 7722-84.1-50-34 Revision date: 2016-06-08, Version 1 ‘Chemical name ReGH TARE we OaRA, Fivcrogen peroxide a3 3 THA Mutagenicity Reproductive toxicity STOT-single exposure ‘STOT- repeated exposure ‘This product is not recognized as mutagenic by Research Agencies In vivo tests did not show mutagenic effects ‘This product is not recognized as reprotox by Research Agencies. No toxicity to ‘reproduction in animal studies. May cause respiratory iitation, Not classified. ‘Target organ effects Eyes, Respiratory System, Skin. Aspiration hazard ‘Aspiration risk: may cause lung damage if swallowed. 12, ECOLOGICAL INFORMATION iS Ecotoxic! Ecotoxicity effects Hydrogen peroxide is naturally produced by sunlight (between 0.1 and 4 ppb in air and 0.001 fo 0.1 mg/L in water). Nol expected to have significant environmental effects. Fiydrogen peroxide (7722-847 [Active ingredients) Duration Species alae [Unis Hydrogen peroxide fe hLCEO FFish Pimephates 16.4 [git as en peroxide antes Fish Leuciscus igus [55 Ingil jen peroxide Bh ECS [Daphnia pulex ba Ingit drogen peroxide baa hECEO [Dephnia magna: in Ino drogen peroxide [72 hECSO [Algae Skelstonema [1.38 Img/ lcostaturn jon poronde Bi aNoEc [Daphnie magna es est Persistence and degradability ‘Hydrogen poraxide in tha aquatic environment is subject to various reduction or oxidation ‘Bioaccumulation Mobiity Other Adverse Effects [processes and decomposas into water and oxygen. Hydrogen peroxide hall-ife in freshwater ranged from 8 hours to 20-days, in air from 10 ~ 20 hours, and in soils from ‘minutes to hours depending upon microbiological activity and metal contamination. ‘Material may have some potential to bioaccumulate but will ikely degrade in most ‘environments before accumulation can eccur. Wil Iikely be mobile inthe environment due to its water solubllty but will ikely degrade over time, Decompotas into oxygen and water. No adverse effects [3: DISPOSAL CONSIDERATIONS: See Waste disposal methods US EPA Waste Number Contaminated Packaging Dispose of in accordance with local regulations. Can be disposed as waste water, when in compliance with local regulations. D001 D003 Dispose of in accordence with local regulations. Drums - Empty as thoroughly as possible. Tripie rinse drums before disposal, Avoid ‘contamination; impurities accelerate decomposition. Never return product to original container. Page 7/9Hydrogen Peroxide 50% Oxypure® SDS #: 7722-24-1-60-34 Revision date: 2016-05-08 ‘Version 1 SET RAN PORT INFORMATION OEE AE) por NID no unzo14 Proper Shipping Name HYDROGEN PEROXIDE, AGUEOUS SOLUTION Hazard class PY Subeletary class 8 ' Packing Group q Is ‘UNIID nO UN 2014 Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION Hazard class BA ubeleiary class 8 Packing Group i (CAONATA Hydrogen peroxide (>40%) i forbidden on Pasesngar and Cargo Altera. Airreguaton permit shipment of Hydrogen Perenda (2-403) in non-reniodeertalner for Air Cargo ‘Only aircraft, as well as for Passenger end Cargo aircraf. HOWEVER, all Hydrogen Peroxide containers are vented and therefore, air shipments of H202 are net permitted. IATA air regutations state that venting of packagas coniaining oxidizing substances is not permitted for air transport. UNI no un 2014 Proper Shipping Name HYDROGEN PEROXIDE, AQUEOUS SOLUTION Hazard class 54 ‘Subsidiary Hazerd Class Bg Packing Group u OTHER INFORMATION Protect irom physical damage. Keep drums in upright position. Drums should not be stacked in wars, Do not stare drums on wooden pats. paar U'S. Federal Regulations: SARASI3 Section $13 of Tite Il of the Superfund Amendments and Reauthorization Act of 1986 (SARA), This product does net contain any ‘chemicels whieh are aubject to the reporting requirements of the Act and Tite 40 of the Code of Federal Reguletions, Part 372 ‘Acute health hazard Yes Chronic health hazard No Fire hazard Yes ‘Sudden release of pressure hazard Ne Reactive Hazard No ‘Clean Water Act ‘This product does no! contaln any substances regulated as pollutants pursuant to the Clean Weter Act (40 CFR 122.21 and 40 ‘CFR 122.42) CERCLA Chemical name Hazardous Substances R@s | Extremely Hazardous: ‘SARA RQ Substances ROS Fydrogen peroxide 16005 7722-844 Page 8/9_ Hydrogen Peroxide 50% Oxypure® spe; 772284-1.5034 Revision date: 2015-05-08 Version 4 Hydrogen Peroxide RQ is for concentrations of > 52% only International inventori Component | TSCA] DSL fEINEGSIEL| ENCS [China | KECL | Piece | Alce | Naioc (Unites | (canada) |" ines | (Japan) | (IECSC) | (Korea) |(PHHpPives| (austraiay] (New States) (Europe) y Zealand) IHygrogen peroxide) x x x x x x x x x T7z284-4(50) Mexico - Grade Serious risk, Gra CANADA WHMIS Hazard Class a z 46 OTHER INFORMATION, aaaE FPA jeaith Hazards 3 [Flammability 0 fstabuity 7 [Special Hazards OX Fis jelth Hazards 3 [Flammability 0 [Physicar hazard 1 [Personal Protection NFPATHMIS Ratings Legend Severe = Serious = 3; Moderate =, Sight = f; Minimal =O Special Hazards: OX = Oxidizer Protection = H (Safety goggles, gloves, apron, the use of supplied air or SCBA respirators ‘required in lieu of @ vapor cartidge respirator) Uniform Fire Code Oxidizer, Class 2—Liquid Revision date: 2015.05.08 Revision note intial Release Disclaimer PeroxyChem believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION. PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of PeroxyChem, PeroxyChem expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such Information. Prepared By: PerexyChem ©2015 PeroxyChem. All Rights Reserved, End of Safoty Data Sheet Page 9/9