5. cit ‘Temperature, T Tempe. T Calculation of entropy: 1, In Ideal gas in cylinder systems Q, As = Sm L 3 I, 2, AS,, 2300; a{ i AS, =2.308nCp 3 & 7, i) Calculation in Isothermal process: ii) Calculation in Isobaric proces ™ Isobarle Proce TY, ‘ondition; 7P*Ogh= st Condition: 7 PO AS _| Reversible expansion Irreversible expan soonn( 8) | spon Soy co" | 9 owcsoa(¥) seme il ) i, “acl | @ 7 y, Sra ° 85 + MSwr = spontaneous 2 he, +2.303nR. el 7 } (on) . B + 2.303nRlog| Ft m 2 } ZS Calculation in Igothermal Process 7 BY, Condition; AT =0,AE=0,40=-W,5-= fH ay Tafinite ree expansion Finite free expansion as __| Reversible expansion | Irreversible expansion AE =0,W =0,0=0, | AT=0,AE =0,W =0,0-, 0,P,, =0 V, #00,P,#0,P,, =0 2.303nRlog| 2 2.308nlog{ 22 2.303nRog{ ¥2 | ¥, K ; v) Sy (or) (or) tye (on) 2303iRlog| 2 A Bi 303nRlog| 2.303nRlog| 2 2.303nRlog| A , ?, P, eee 2003) v aE na PaalYeM) : i T B, -2.303nRlog{ : (2) 2sosnnleg ¥] 28 : 49, ?Sy, 78S cap vi) rot tye ( (for spontaneous process) * 2senenie Scanned with CamScannera Calculation in Adibatic process: . ‘AS Calculation in Adiabatic Process Condition : AT # 0,Q=0,W = nC,AT Tnfinite free expansion | Finite free expansion Pecan i WV =0,0=0, | AT =0,06 =0,17 =0,0=0, AS | expansion Irreversible expansion . pe 2.303nCyloe{ 2 +2 303nRtog{ YE 2303nRlog{ Y2 era vy v, Son 0 (or) te (or) p, 1nC,tog{ = \42 303nRlog{ Pe 2.303nRlog| <> 2c oF} 2s000eg( 2) (2) Sn] 0 ° ° o = +e, (for spontaneous process) a t BR 2.303nRlog) 2:303nC, Toe : }aamnn2) v, 7 ®, P? Sraat a (or) ve (or) BR =2. 303nC,le{ 3} 203Rel %) 2a 8) Calculation in Isochorie process: Arathi AS Calculation in kggtric Process Condition: ?V-0,2= 4 TW AS | Reversible expansion Irreversible expansion T, Tt 2.303nCylog| 2 .303nCylog| 22 nC y log] T ) 2.303nC, al Z ) 2S, (or) (or) P, P, 2.303nCy log] ry 2.303nC,log| = 2anance($) T 7 Scar. (or) -0sncy{F) > 28. AS + AS uy, = te for spontaneous process ra 0 ) Calculation of As for Isothermal mixing of two ideal gases or ideal sol Sainte sme fenmta) = ~2.303.m.Rlog X, + (~2.303.n,Rlog X,) =-2.303En, 0g X, (ming of idea gates for mole) 2.303.X,Rlog X, +(-2.303.X,Rlog X,) =-2.3032X, log X, Scanned with CamScanner