WORKSHEET AH-03 Tor JEE (MAIN+ADVANCED) 2021 ENTHUSIAST COURSE rssiing CE ALKYL HALIDE & ARYL HALIDE SECTION - |: SINGLE CORRECT TYPE QUESTIONS 1. Consider the following reaction, a SOC CH,—CH, — b 1— CH, In the above reaction which phenomenon will take place: (A) Inversion (B) Retention (C) Racémisation (D} Isomerisation OH CHy—CH, — ba —CH, 2. Ph—C—O—CH, I (P) + 1 J Absto! Abide CH; (P) & (Q) respectively is: H (A) Ph— t — OH,CH,—Br (B] Ph—CH,=0H, CH,—CH,—Br CHy (C) CHy—OH, P= CH CH, (0) CH,—OH, Ph—CH,—CH,—Br 3. CH,(CH,),CH,OH HE, x, 1-butanol Identify X and the type of mechanism of the reaction? (A) CH, —CH, CH, &CHp—=Br & $1 (B) CH, —CH, —CH, —CH, —Br & Sy2 (c) ck A 1CHy—Chy & 81 (D) Cr to 1CH,—CHy & S,2 Br Br 4. Consider the féllowing reactions carvied outat the same temperature. One OO Which of the following statement is correct about these reaction. (A) Both the reactions take place at the same rate (B) The first reaction takes place faster than second reaction (C} The second reaction takes place faster than first reaction (D) Both the reactions take place by $1 mechanism WORKSHEET (AH-03)(CHEMISTRY) 1CHyOH OCH, The product (A) and (B) ate respectively: oF oe CH,Br CH,Br 1 Br Be ° . or oe Ok CHBr Br HOH tls SECTION - Il : ONE OR MORE THAN ONE CORRECT TYPE QUESTIONS H 6. A XK SEY Kand ¥ are CHy OH an Br wx a Vx OY ov OY CHy OTs CH Br 7. Identify correct steps representing S¢Tinechanisin for the cleavage of ether with HI R-O-R + HI we Boas®? H int 2. | slow (Ps REQ he ier RI+ HOR (R81) H Rw ay? RP Ris 3°) +ROH (C) R° +1? RI (p) RP sae WORKSHEET (AH-03)(CHEMISTRY)agHi (eq) >———— 8+) Reaction (I) 8. Anhya.HI (1 64.) Reacion ty” (O*F) Which ofthe following statements isfare correct? (A) The compounds (B) and (C) are MesC—I and MeOH and reaction (I) proceeds by Sy1 mechanism (B) The compound (B) and (C) are MeC—OH and Mel and reaction (I) proceeds by $2 mechanism (C} The compound (E) and (D) are MesC—I and MeOH and reaction (Il) proceeds by Sxl mechanism (D) The compound (E) and (D) are Me,C—OH and Mel and reaction (ll) proceeds by S,2 mechanism SECTION - Ill : NUMERICAL ANSWER TYPE QUESTIONS (SINGLEIDOUBLE, THREE & FOUR DIGITS ANSWER INCLUDING DECIMAL) 9. Most reactive position inthe given reaction, CH, a { 4 8 NBS cH, cH. CH, =CH ———* 10. When trans-2-butene reacts with BrJOCly)X slumber of products are formed. Whereas when trans-2- butene 3 reacts with HBr, Y nuiber of products are formed. Report your answer as [¥ |X ]. oe ek ANSWER KEY 1B) eee) 3. B) 4. @) 5. (A) 6. (AB) 7. (BC) 8. (AD) % 2 10. (21) WORKSHEET (AH-03)(CHEMISTRY) 3