16} a) Complex salt b) Basic salt ¢) Double salt (fares aaa) d) Acid Salt Gre aq) 7 17) German Silver is an alloy Same 2) a) Cu + Ag+ Cr ) o) Cu + Zn+Ni d) Ag: 18) Which one of the fol g pairs relationship in the periodic table. (Rtq CaTeAG re Aare ems eA): a) Li, AL C,S (d) B,Si 19) In the extraction of metal from Ore,ot i (2) (i y 9) Rearrangement reaction (eaucal fate ) 4) Decomposition reaction (Fara Fafitem ce oe in thermal « (NHajo GriOr is ANH fr/07 08 1" FATE Carte a) NH; (b) No (ce) NO, (d) NZO 3) Which of the following pairs are isotones osx Gm RCA 2 (a) C4, 7N'4 (b) C199, 170187 (C) ee, oi? (@) 2017 , oF 4) Rusting is an electro chemical reaction. During rasting iron acts as (AES ahr rr oath wise apna falcon 162 ieee eer re a) Cathode (It21G it) (b) Anode (inte Sz) ¢} Electrolyte (efts fever fee) d) None of these (07% 51 Corie #7 ) 5) How many water of crystallization present in common alum? cinas SYsiice afb ears oa Tea) a)16 (b) 20 (c) 24 (dj 28 6) Two colourless gases combine chemically to produce coloured gas. The gases are - ({’fo a2at 904 Sas Se rn aeth afBat amr Geen Sta | HP YTS SA - a) O2, Ne (b) NO, O2 (c)CO2,O2 (dj) CO, Os 7) Which of the following pairs react with each other aqueous solution to produce a yellow precipitate (#m5q) corer ome Yai walt Hata amis ieal Som See Seca es =a) a) AICl;, NHsOH (b) BaCl, CuSO; (c) AgNO: NaCl d) Pb(NOs)2, KI wales Which one of the followin; ions i , ao fe g reactions is not (roa cary Fefinantt carewr far aul a redox a) MnO, + HE] —___ b) CuO + Hq, lL: a ——*» CuCh + H20 2) A gaseous substi(3) c) Zn + H2SO, ———=* ZnSO, + Ha d) HaS'+ Cy —<—=s cl 9) Correct increasing order of atomic size is - TTA WENA WH Gears Zt -) a) Na> Al>Mg>P>S$ (b) NaMg>Al>P>S — (d) MgO HN —BF3 a) Itisanacid b) In this reactiona ¢) Itisaredox d) NH3isa lewis iestreaeaon co-ordinate bond is reaction base : formed a) PBaemws — b) a fee eat c) ae we — od) NH Pea PE se Cel ee Frere Fate afb ei ts 11) The compressibility factor for a real gas at high pressure Is BHO eal seq MTOR ATTIC! oF aD aR - a), 1+Pb/RT b) 1-Pb/RT oo 148t da Pb PAGE 20F 621) 22) 23) 24) 25) 26) 27) ° : _ Os 2 (pee c) : 2 hen a mintur of NHsSO4 and 50% H:S04 selec anode are- ; a Masur 0% HS, Fe of MARE PAA ENS ES aie a) Heand 0b) Heand (NHahS:0s o) te au Net i : Which alkaline earth metal jon plays a vita role in contraction of muscles | anya eco cs HRT SAR TTF a) Bat b) set Qo Me Which of the following is pyrosilicate ? Reva cant Rca & a) (S103). b) (Si03),7" SiOW* Carbon does not form complex because - ae eB CRI Me AA, FH — a) Vacant d- b) Iisnotametal —_¢)_Its atomic radius is orbital’s are small absent in it f a) apeid-trse b) sateaT <) oa ‘Arrange the following carbanions in order of their decreasing stability . Doon aromas “eficer ARETE AITO | ) © QO i)H2C=CH ii) H-C: iii) CHs — CH a) i)>if)> ti b) ii)>i)> ii iil)>i)>i Ph—CH,—CN and Ph-CH Ph—CH> - CN and Ph - Ct a) Geometrical —-b)- Metamers ©) Tautomers d) none isomers. a) Sifigievaims by) THAR Bom d) hy (CH3 — oe (CH, - CH3 + Cl, ————> CHs How many isomeric monochloroderivative will be formed 2 MORE FOE AATATA FART GOR ZIP a 4 b) 3 ) 6 4 The product of the reaction - fafuftos Geng fefaerers te — fireees — 20% HaS0, ad 60°CRar a2 mee 2 is 14) For silver, Cp (Jk*mol) = 23 + 0.01, If the temperature (T) K to 1000 k at 1 atm pressure, the value of AH will becloseto- Fiera Cp (iK*mol%) = 23 + 0.01 T 3 orm Berg oy 1000 K SEO AH cr SH Cea IT a) 62K b) 16K ©) 21K) 15) _ For which of the following reaction AH = AU Toa Ret oy AH = AU a 3) N2O.(e) © 2NOX(g) b) 2S02(g) + 0.() <=> ©) Hele) + Chale) <> 2HcI(g) 4) Hole) +205) <> 16) The sum of PH and PX fora basic buffer solution is 13, the ratio of the coi that of salt is - s oR rte at TPH « Pky ox 7h 13 (eR ws em EA me eRtS aR a) 10 b) o1 ©) 0.05 d) 0. 17) K; for CHsCOOH is 1.8 x 10 and Ky for NHOH is 1.8 x 10°. The py of ammonium will be- a CHsCOOH <4 k= 1.8 x 105.4 NHAOH oy Ke 351.8 x 10° eran apt we a) 7.005 b) 4.75 7.00 48) "If dissociation of PC\s is 20% at 1 atm Pressure. The value of ky for the rea Wt 1atm Phi PCls 3 Riemer en 205% SPC; S PCy + Cl Fefteria k, ait ey — a) 0.04 6) 0.05 <) 0.07 49): Vin thereattion : 3Br2+6CO;" +3H,0-+ 58,74 Br0;"+ HCO,” 38r2 + 6CO,” + 3H.0 > 58," 4 Br; + HCO, ~ a fafaoate a) Bromine is 5) Bromine is reduced c) oxidized and and water is carbonate is oxidised reduced ‘ a) Bee men b) a Rents ea ore ¢ TAGE Rao Bi wite ay ‘i PAGE 3 OF 538) 39) 40) ie ey the Newman projection formula for two principal conformations of ethane and ind dihedral angle . TS a ca a ee Explain why : TRS i) Hs can not be produced by the product by the reaction of dil Hel with fi) 020 is not suitable for drinking purpose . i) Capea (pb) Fie ay Hel a Fae HP seat TT AT | Tl) DO "tera weary 1 Complete the following reactions : Frosa Pafermeln eel ats a) BiHls + 2NH; + AS B+ 12H, b) Na,SiO;.H,0 > C+D29) 30) 31) 32) 33) , AlCl a + CHs CHa CH,Br. |= ————» x? Xis— Xe a) CHs ~CH2— CH ~ CoH ©) CHs~CH2—CéHs Which of the following is a secondary pollutant ? Aaa CoA ta Ts a) CO, b) N20 ) SO, Answer the following questions (Teaeenfaa 8cl, is more acidic than BF; ~ why ? Bch, am enftrret BF; acre! cal can & Megclzis linear but Sncl, is angular~ Explain. Magel rseteferr Fey Src cet - are a | calculate equilibrium temperature for a chemical reaction at 1 atma 30 KI mol* Latm vies caf amare Fefteaa ea AS = 75 JK? molwax AH = 30K) mo‘common salt: itions of Ure® 2) The ratio of freezing point depression values of 0.03(M) soluti a ve gerne HI AT 0.01(M) BBFR, meter eve cat cours arreerD wees Pa 4) 228 a) tata b) 224 Be aes: cmtequy? at infinite 4 ind 762 3) The equivalent conductance of Ba’? and el are respectively 127 “a infinite dilution will Be « 1 eiaaeett dilution, The equivalent conductance ( in a" equiv) of Bach, at i a a ‘ mn? equy Ba? eat cl Ga ePtia eyTla went afaatlote ai water 127 ak 769° Back, em prone "RET Bra - ae a) 1395 b) 203 279 4) The optical isomerism ts not shown by the complex, [ Ficwa cart efba cet IFA AAAS waa] a) fer(ox)s}? b) [co(€oTA)) ¢) [Colen)(NH3)cl]’ 4) penlshead 5) Rate of reaction with aqueous ethanol follows the order ( BaTT BQlace ica MAferat Fas SH] Qe e i oO a (P) (Q) (R) (s) a) P>Q>S>R b) Q>P>R>S c) P>R>Q>S d) R>P>S>Q 6) HI Product. Identify the major product. [ain fafeeat 4181 Grats | a) ey b) Z ¢ 4) CHs Cf: Oro Cke 1 oe 1 1 D order of basicity of the following component is -[ficwa Gilat se leee Abe =a ae] NH ao i CHs— CH2— NH, (CHs)NH CH CC NH NH i i Vv a) l>i>>i>IV by) Lom >t oty <) ill t >i ow a) > >iew 8) What should be the final product in the following reaction ? [ FICS Rfeatto mal aie, ay] }NHz + 21C| ——> Main product 6) °) NH d) No reaction 2|Page of 621) The Key of Cul is 1.1 x10” Détermine emf of the cell represented 4 {logi.1=0.041) 7 2) 0.502v b) 1.28v 9) 0.705v A certain current liberates 0.504g of hydrogen in 2 hr. How m by the same current flowing for the same time in aqueous cusos a) 127 b) 16 d 318 F's the fraction of molecules having energy greater than Ea, it will be 23 a) x=2 8) inx=-28 er 74) The ty of a\resction is hilved as the ited concentration of the re: order of the reation ? a) 4 b) 0 9 3 25) _Flocculation value is expressed in terms of 3) Millimole L* b) MolL* ‘} gt 26) _ In which pair of ions both contain s-s bord 3) Si0,* 5:05? b) 5:0;785.0;* a) 5.0441 27) The state of hybridization in anionic part of solid ClO; is a) Spd? b) Spd 28) The mass average molecular mass and number 4 a) <1 -b) >2 4[Page of 6) Co 10) 14) 12) 43) 44) 1s) 16) 17) [Pag The fllowing compound is used as [exch aye ey ~ [ a a) Ananti- b) Analgesic C) ro inflammatory, compound ) Sodium metal crystallizes in a body centred cubic lattice Sele of sodium atom Is approximately .(cnfeam ang orate watateta a 1 ‘eres FR tee 4.29 A fear ea anata a — ° ° a) 186A b) 322A ) S724 ‘Among the following, the coloured lanthanide ion is (Ferner sear age mma a) b) Gd ¢] Ce” The total number of fone pair of electron in izis. (Ij x 3005 Risen 2) 0 b) 3 ) 6 The structure of Iclz is (ICI, si +1121) 2) Trigonal b) Trigonal bipyramial c) Octahedral Which of the following is an intrinsic colloid ? (Ficoa tig Sofas =H ) a) Rubbersolution b) Soap solution ©) Sol of gold The main products formed in the reaction of phenyl acetate with hydrolysis are (Pratt wnfhndba aca afeite CHsMeBr aa ema Sern a f a) Phenol and b) Phenol and acetone c¢)’ Phenol and aceti t-butanol acid One mole of a coordination complex of the empirical formula excess of AgNos , precipitates two moles of AgCl. The coordinat 7c FAfSRR A CoCls SNHs & -geraecerw Fafa wafbar et xe enter A a) Pentaammine b) Penta ammine °) cobalt dichloride cobalt (ill) chloride (IN!) chloride e of 6 of ie(3) PaSsaa 39 fy 1 (CHs)2NH Ha / Ni § area ex B eee 308 (Q.No. 31-40) (SA) en erg meneame saat ) - All questions are to be answered, (sca eca Bex ee 2k | ) For each Multiple Choice Questions ( MCQ) four options are given as answers. The correct option is to be shaded in the appropriate box of the answer script with a ball point pen. Multiple options shading for answer of an MCQ would liable the answer to be cancelled. Wrong answer for each MCQ would invite a deduction of 0.25 marks, (MCQ. scezererof nf Sar zou etx (fea Sanity we Sameer FRG cee arcane BnipTw) ‘ b) Acetylene — B ceurtatoier)Reals Axe A colourless lead salt ~ residue (Y) and brown AR GY ae Sage Segee TT 39) ; What is the advantage of using common acid-base indicator ? Write one equation oxidant. Mention reduced in that reaction oe POI TAS AS Fonte VaR wl Cer +) Three elements.25) Which one is the Ore of iron a) Magnesite (anemrr85) b) } cc) Calamine (TAT) — d) 26) What is the percentage of ‘22 Carat gold’ ? (‘22 4 aes “ee AfsaT FS 2) a) 92.2% b) 92.4% 94.6: 27) Which one is not a heterocyclic or; (Ros cmt ecbcarrate tea a)Pyridine (Mie) b) Nephthaline (4 c)Furan (f*tar) — d) Pyrrole (*8cara) 28) Number of sigma (0) and Pie (x) bonds present is — (algcn Prom 6 91 eacra zen Za a) 12,3 (b) 3,12 (9) 96 (@) 6,9 29) 30) ‘SR’ policy means ~ (‘3R’ Gag za -) if a) Reduce @), Reuse (42m), Refuse b) Recycle (7rfateay, Re c) Reduce, Reuse, Recycleappropriate space of the answer script ( ben teas RB a PACS ee) . Candidate shall use ball point pen (blue, (sera <4 tar ears (sra/Aer) Gece . The last page of the answer script be “7017 Rough Work «4% Be |) ae 4 NHN A 40-0 @) Addition reaction b) Substitution reacti