et Page air} CEN VIE AP Chemistry Buffer/Titration Question (1982) @ Aart sotcion contains 0.40 mote of formic acid, HCOOH, and 0,60 moe of sodium forma HICOONa, in 1.00 liter of solution. The ionization constant, Ka, of formic acid is 1.8 X 10-4 (a) Caleulate the pH of this solution. ()__1£ 100. mL of this buffer solution is diluted toa volume of 1.00 liter with pure water, the Bl does nochange. Disus why the pH does eins conan on don, (© 'S00mL sample of 1.00 molar HCI is added to 100. mi of the original buffer solution, Calculate the [H0*] ofthe resulting solution. (@) A800, milliliter sample of 2.00 molar formic acd is mixed with 200. iniliiters of 4.80-molar NaOH. Calculate the (H30*] of the resulting solution. @ Reo ogy Wap © Ory hex we¥, (040 +x) () I oso 0m M0 = x Wo —« te “ £2 DJs 1a. c10-4 Py EF oso-x x K+ O.bo pis log (uaxions « (ad) Hen, - Hass, pH= plea t Log ond 5 pl ley (Mt810™) + fog 2g «EAD @ The pl dbes wat “charge because the amamls of coon { cool do wt change. We Nene of (e001) Citcoont) is constant. The ions are simply “spread out! (©) Ned WoUUME = [05 mee Goow]= th CO. MOCO 6.654 m4 coon” OOS LE Chow] = ME = (ost el2t0) 9 561 m4 coon wel Oost + (ue) = BE Comrdtact509 © gown n Her ous C COOH 5) + H* cag) —o HOH © bete am” goa 0.381 i vat lg i) Dd - aor 0.04% + 0.0N% gis -log ene + log Sane omy Atler 0,503 ° ona (3B) wr" one a ae om t BY Le teoot © 0.060" o.0500 055 S -pese ESS BB we Ig(htaes\e lng Soe de: After 9.055 0 0.045: : pacislsl LR ee @ (oo). sa [acon]. wl. Cave m)lo.900 0 _ Leo M W@OH 1c HCOOH cagy + Of cy —v COOH cap) + HHO UY Tiel bom 0.460 m ° Ab -0.%0mM — - 0.400 m + 0.860 M O64m ° 0.460 pi pke + leg geo = log (8 xt0-4) 2. P= tog (h8xto-m) ly 2 or WeoOM cap) xe Wop + comers pea pe ” “6 T A t Cr Oe x re Ka= konto’. (ose + — (x)(0.400) ee ato 0.4 -K Oy X= (CH= ha x10 ag pit= -teg (b xt0-4) =Er irae pitts my jt a a Ha) @redo | OOF + no = tena « derenAP? CHEMISTRY 2002 SCORING GUIDELINES ‘Question 1 ‘Total Score 10 Points HOB4(ag) 2 H'(aq) + OBr(a9) 3x10 1. Hypobromous aid, HOBr, sa weak acid hat isoiates in water, a represented bythe equation above. (@) Calculate the value of [H"] in an HOBr solution that asa pH of 4.95, reer oi wl pont eane rane eon tie = boosie (©) Writ the euirium constant expression forthe ionization of HOBr in wate, then ealeuat the concentration of HOBr(ag) inn HOBr solution that has (H'] equal to 1.8% 10-SM. 1 point eared for amet, Ke expression for Ky {point cared for 1F (HF) = 18107 a then (OBF) = 18% 104 me see Substating, fee a3 xo? = HUOBE) _ [8x10 se.8x107 af) (HOB HOB] (8x10 ag). 8x105 M1) 23x10” 1 point earned for comect [HOB [Hose =o Cory ©2002 Cale: Ene Een oad A igh ee -Aence Place! Popt nd AP eee ara othe Cog mere xan Bard 2‘AP® CHEMISTRY 2002 SCORING GUIDELINES ‘Question 1 cont) (©) Asoluton of Ba(OM) is itated into a solution of HOB. (© Caeulate the volume of 0.115 M Bu(OH,(aq) needed o reach he equivalence point wien tiated into a 65.0 ma. sample of 0.146 M HOBe(ag. 6. mol Bx(OH), IL 1 point eared fo owe (Sis) rastsxom,) | Shen = 004131 0 41.3 mt 1 point cared fo comect subaiton Azote posible comet method fr clung the volume starts with nd calelaton theexpression “Me 2 1 Vey 2 (i) Indiate whether the 9 atthe equivalence point is ess than 7, equal t,o greater tha 7, Explain ‘The pis grater than 7. HOBris a vesk aid and OB isa weak base. ‘A he equivalence point, the OB” in solution i the pH-detemining Seen ais is pote iyooe OB + 140 2 Howe + oF pe cl pan yon = (gfe) = (LOO) annie on eee = 107 Cony © 2002 Calg EnaceExaminton Deal ph ese Adan Place Propa nd AP ie epsom a te ange ce xainton Ba 3AP® CHEMISTRY 2002 SCORING GUIDELINES ‘Question 1 (cont) (@) Calculate the numberof molet of NsOPBr(s) that would have tobe added 19128 mL of 0.160 §¢ HOB to produce buffer solution with (H"] = 5.00. 10-9, Assume that volume change is nelle. xq ~ Hger} 1 pin eared for (OB the sep, nd the substation (0.160 64,2.3x10) (oss 500x107 1 pat eamed for el NaOBr (opr) = 0074 ror = ors (22z4nelone (© HOBs is «weaker acid than HB*Os. Account fortis ct in emns of molecular structure. “The HO bond is weakened or increasingly polarized bythe ditional onygen | Pai cams toms bonded tthe cenl bromine tam in HBO}, bankas Cop © 2002 y Cee Enns Exminsoe Boa Al ight eve Ato Pent Pog and A eid ademas he Coleg notes Eaton Bete ‘