CENTRAL BOARD OF SECONDARY EDUCATION. CHEMISTRY INVESTIGATORY PROJECT. IDENTIFICATION OF ANIONS AND CATIONS PRESENT IN THE TOOTHPASTE For session 2015-2016 ewes ) 4 mi [ il a} 4 ‘al | re a iar sree 3 p2CHCOONa+ Ca204 «¢ NaHPO4+MgCl2+NHsiOH— Mg(NH4)PO4+2NaCl +H2O0 ¢ 1+AgNO;—>NO3+Ag1 (YELLOW PPT).¢ (COOH)2+2CH3COONA— NO REACTION e Pb+2KI— NO REACTION e MgClo+ NH.sOH(NH3)2HPOs—Me(NH4)PO4+ 2NH4 +20 TESTON COLGATE COLOUR OF PASTE: - WHITE EXPERIMENT OBSERVATION | INFERENCE TAKE A PART OF FORMATION OF | CO37 THE SOLUTION AND | WHITE PPT CONFRIMED ADD MgSOsSOLUTION TAKE A PART OF FORMATION OF | Ca** SOLUTION AND ADD | WHITE PPT CONFRIMED AMMONIUM HYDROXIDE. TAKE A PART OF FORMATION OF | POg SOLUTION AND ADD | WHITE PPT CONFRIMED MAGNESIA MIXTURE(MIXTURE OF NHsOH) AND ALLOW TO STAND ACIDIFY A PORTION |A YELLOW PPT |I CONFRIMED OF AQUEOUS IS FORMED SOLUTION WITH WHICH ISDILUTE HCL.BOIL AND COOL AND ADD AgNO3 INSOLUBLE IN NHsOH TAKE A SMALL QUANTITY OF SOLUTION AND ADD OXALIC ACID SMELL LIKE THAT OF VIEGAR CH3sCOO ABSENT PREPARE THE PASTE OF IT WITH FEW DROPS OF WATER RUB AND SMELL TAKE ONE PART OF SOLUTION ADD KI NO REACTION PB ABSENT TO ONE PART OF THE SOLUTION ADD SOLID NH‘OH IN SLIGHT EXCESS THEN ADD AMMONIUM PHOSPHATE. A WHITE PPT IS FORMED. Mg PRESENT IONS PRESENT.-Mg, I, POs, Ca, CO3 CHEMICAL REACTIONS.- © CO3+MgSOs—MgCO3+S047© C03+2CH3COOH-— (CH3COO)2Ca+H2O © (CH3COO)2Ca+(NH4)2C204—2 CHCOONH4+ CaC204 © NaHPOs+MgClo+NHsOH—Mg(NH4)POs+2NaCl+H2O e [+AgNO3—NO3+Agl (YELLOW PPT) © (COOH)2+2CHsCOONa—NO REACTION e Pb+2KI— NO REACTION e MgCL2+NHs0H+(NH3 )2HPOs—Mg(NH4)POs+2NHs+H 20 TESTON CLOSE V®, COLOUR OF THE PASTE: - RED GEL EXPERIMENT OBSERVATION | INFERENCE TAKE A PART OF FORMATION OF | CO3* THE SOLUTION AND | WHITE PPT CONFRIMED ADD MgSOsSOLUTION TAKE A PART OF FORMATION OF | Ca** SOLUTION AND ADD | WHITE PPT CONFRIMED AMMONIUM OXALIC (1-2ML) AMMONIUM HYDROXIDE. TAKE A PART OF FORMATION OF | POs SOLUTION AND ADD | WHITE PPT CONFRIMED MAGNESIAMIXTURE(MIXTURE OF NHzOH) AND ALLOW TO STAND ACIDIFY A PORTION OF AQUEOUS SOLUTION WITH DILUTE HNO3.BOIL AND COOL AND ADD AgNO; FORMATION WHITE PPT IT CONFRIMED TAKE A SMALL QUANTITY OF SOLUTION AND ADD KI FORMATION WHITE PPT CH3COO PRESENT TAKE ONE PART OF SOLUTION ADD KI FORMATION WHITE PPT PB ABSENT TO ONE PART OF THE SOLUTION ADD SOLID NH*OH IN SLIGHT EXCESS THEN ADD AMMONIUM PHOSPHATE. A WHITE PPT IS FORMED. Mg PRESENTIONS PRESENT. - Mg, I, POs Ca, CO3 CHsCOO CHEMICAL REACTIONS.- © COs+MgSOu>M gCO3+SOu(WHITE PPT) © CO3+2CHsCOOH—(CH;CO0)2Ca+H20 © (CH3COO)2Ca+(NH1)2C204—2 CHCOONHs+ CaC204 «¢ NaHPOs+MgClh+NHsOH—Mg(NH1)PO01+2NaCl+H20 © I+AgNO;—NO3+Agl (YELLOW PPT) ¢ (COOH)2+2CH3COONa—NO REACTION e Pb+2KI— NO REACTION °¢ MgCL2+NH:OH+(NH3)2HPOs—-Mg(NH4)PO4+2NHs+ H20 CONCLUSION.- HENCE AFTER TESTING DIFFERENT SAMPLES OF TOOTHPASTE, WE FIND THAT COLGATE HAS ALL NECESSARY FOR STRONGER AND WHITER TEETH.ANIONS: - CATIONS:- OH Ht SO? Ca** CO; Cu?* CL’ Fe3* Br- Fe?* I- NH NOx SAFETY TIPS WHILE DOING THIS EXPERIMENT:- e WEAR EYE PROTECTION. AMMONIA SOLUTION CAUSES BURNS AND GIVES OFF AMMONIA VAPOURS WHICH IRRITATES THE EYES, LUNGS AND RESPIRATORY SYSTEM. e¢ SODIUM HYDROXIDE CAN CAUSE BURNS AND IS DANGEROUS TO THE EYES. e HYDROCHLORIC ACID CAN CAUSE BURNS. ¢ BARIUM CHLORIDE IS HARMFUL BY INHALATION AN IF SWALLOWED. e NITRIC ACID CAUSES BURNS.Bibliography:- 1. PRADEEP’S CHEMISTRY 2. BRITANNICA ENCYCLOPEDIA 3. NCERT CHEMISTRY 4. GOOGLE 5. CHEMISTRY TODAY