Yes, we know it’s constant to a very high degree of certainty.

We know because we observe it in the chemistry of distant stars. Stars have distinctive
colors based on their temperatures, and specific bands of absorption caused by
chemicals. Both of these properties are calculated based on Planck’s constant. If the
constant were to vary, we’d see it shifts of the spectrum and absorption bands of those
distant stars11
Since looking farther away is looking back in time, this provides an excellent natural
experiment for verifying that when scientists say that something is constant, they’re not
just taking two measurements a week apart and then knocking off for a beer. Our
number for Planck’s constant revises over time, but that’s due to increasing precision of
calculation. Even if the constant were to somehow be drifting, it’s not something we
could detect over the trivial time-scales that humans get to work out. Only astronomy
gives us the ability to look far enough back into time: billions of years.

11 You do have to correct for redshift, since distant galaxies are moving away from us.
But that’s a very specific form of shift, different from the ones you’d get if Planck’s
constant were to vary, and it’s easily taken into account and corrected for.