January 2013

Material Safety Data Sheet

Cyper 100 – MAPP 15936
Material Safety Data Sheet: CYPER 100
1. Identification of the Substance/Preparation and Company/Undertaking:

MAPP Number: MAPP 15936

Trade Name: Cyper 100
Recommended Uses: Insecticide

Manufacturer/Supplier: AgChemAccess Limited

Cedar House
41 Thorpe Road
Norwich
Norfolk
NR1 1ES
Telephone number: +44 (0) 845 459 9413
E-mail: enquire@agchemaccess.com

Emergency Telephone Nos: 01865 407333 [Carechem]

0870-600-6266 [UK National Poisons Control

Information Service (NPIS) Centre]

01-8379964/66 [Poisons Information Centre,

Beaumont Hospital, Beaumont, Dublin 9, Ireland]

2. Hazards Identification

Classification of the substance or mixture

Xn – Harmful
N – Dangerous for the environment

Label elements
Labelling according to Directive 67/548/EEC or 1999/45/EC

Hazard symbols:
Xn - Harmful
N - Dangerous for the environment

Hazardous ingredients:
Cypermethrin cis/trans +/- 40/60, Solvent, anionic surfactants

R-phrases:
R10 Flammable
R22 Harmful if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed
R67 Vapours may cause drowsiness and dizziness

S-phrases:
S2 Keep out of the reach of children
S13 Keep away from food, drink and animal feeding stuffs
S20/21 When using do not eat, drink or smoke
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the
manufacturer)
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S29/35 Do not empty into drains; dispose of this material and its container in a safe way
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S51 Use only in well-ventilated areas
S61 Avoid release to the environment. Refer to special instructions/safety data sheets

Other hazards
Not known

3. Composition/Information on Ingredients

Mixtures
Emulsifiable concentrate

Cyper 100 MSDS Page 1

January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936

Hazardous components

according to Regulation according to Directive

Product Conc. (EC) No. 1272/2008 67/548/EEC
Component
identifier % w/w H Risk Hazard
EUH Phrases
Phrases Phrases Symbol
(CAS No.)64742-95-6 Flam. Liq. 3, R65
H226
(EC no)265-199-0 STOT SE 3, R37
H335 Xn
(EC index no)649- STOT SE 3, R51/53
Solvent ≤80% H336 Xi
356-00-4 Asp. Tox. 1, R10
H304 N
(REACH-no)01- Aquatic R66
H411
2119455851-35 Chronic 2, R67
Acute Tox. 4
(Inhalation),
H332 Acute Tox. 4
(CAS No.)52315-07-8
H302 (Oral), R20/22 Xn
Cypermethrin (EC no)257-842-9
10 – 15% H335 STOT SE 3, R37 Xi
cis/trans +/- 40/60 (EC index no)607-
H400 Aquatic Acute R50-53 N
421-00-4
H410 1,
Aquatic
Chronic 1,
Flam. Liq. 3,
H226
Skin Irrit. 2, R41
H315
Eye Dam. 1, R37/38
anionic H318
≤3 STOT SE 3, R10 Xi
surfactants H335
STOT SE 3, R67
H336
Aquatic R52/53
H412
Chronic 3,

4. First Aid Measures

Description of first aid measures

First aid measures general: If medical advice is needed, have product container or label at hand.
First aid measures after inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. In case of breathing difficulties administer oxygen. In case of irregular breathing or
respiratory arrest provide artificial respiration. In all cases of doubt, or when symptoms persist, seek medical advice.
First aid measures after skin contact: After contact with skin, take off immediately all contaminated clothing, and
wash immediately with plenty of water and soap. If skin irritation occurs: Get medical advice/attention.
First aid measures after eye contact: Rinse immediately carefully and thoroughly with eye-bath or water. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First aid measures after ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Do not
induce vomiting. Immediately get medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation: respiratory complaints. Gastrointestinal complaints. Nausea. Dizziness.
Excessive concentrations may cause nervous system depression, headache, and weakness leading to
unconsciousness.
Symptoms/injuries after skin contact: Tingling/irritation of the skin. Erythema (reddening).
Symptoms/injuries after eye contact: Tears. Conjunctival redness.
Symptoms/injuries after ingestion: gastrointestinal complaints. Abdominal pain, nausea. Vomiting. Central nervous
system depression.
Chronic symptoms: Irritating to eyes, respiratory system and skin. Symptoms of overexposure to vapours include
drowsiness, weakness, headache, dizziness, nausea, vomiting, dimming of vision.

Indication of any immediate medical attention and special treatment needed

Treatment: Treat symptomatically

5. Fire-fighting Measures

Extinguishing media
Foam. Dry extinguishing powder. Carbon dioxide (CO2). Water fog.
Do not use a high-powered water jet as it will scatter the flames

Special hazards arising from the substance or mixture

Flammable. May decompose on heating to release toxic components

Advice for fire-fighters

Precautionary measures fire: No naked lights. No smoking.
Firefighting instructions: Evacuate and limit access. Use water spray jet to protect personnel and to cool
endangered containers.
Protection during fire-fighting: Wear full chemical protective clothing. If technical exhaust or ventilation measures
are not possible or insufficient, respiratory protection must be worn.
Other information: Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface
water.
Cyper 100 MSDS Page 2
January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

When leaks or spills occur, only properly protected personnel should remain in the area.
Protective equipment: Wear suitable protective clothing, gloves and eye or face protection. In case of insufficient
ventilation, wear suitable respiratory equipment.
Emergency procedures: Evacuate area. Eliminate ignition sources. Provide adequate ventilation to minimize dust
and/or vapour concentrations. Call in an expert.
Protective equipment for emergency responders: Wear a self-contained breathing apparatus and chemical protective
clothing.

Environmental precautions
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
Notify authorities if product enters sewers or public waters.

Methods and materials for containment and cleaning up

For containment: Prevent spreading in sewers. Impound and recover large spill by mixing it with inert granular solids.
Methods for cleaning up : Collect spills and put it into appropriated container.
Other information: Special danger of slipping by leaking/spilling product.

Reference to other sections

Refer to section 7 and 16

7. Handling and Storage

Precautions for safe handling

Precautions for safe handling: Handle in accordance with good industrial hygiene and safety procedures. Keep away
from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow to enter into surface water or drains.
Handling temperature: at room temperature
Hygiene measures: Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash
before reuse. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when
leaving work.

Conditions for safe storage, including any incompatibilities

Technical measures: Ground well. Use explosion-proof machinery, apparatus, ventilation facilities, tools etc.
Storage conditions: Protect against direct sunlight.
Incompatible products: Strong acid. Strong bases. Oxidizing agents, strong.
Maximum storage period: 2 year(s)
Storage area: Keep container tightly closed in a cool, well-ventilated place. Provide for retaining containers,
eg. floor pan without outflow.
Packaging materials: Keep only in the original container. Keep locked up.

Specific end use(s)

No additional information available

8. Exposure Controls/Personal Protection

Control parameters

Solvent (64742-95-6)
Limit value (ppm): 19 ppm
Short time value (mg/m³): 100 mg/m³
VME (mg/m³): 150 mg/m³

Exposure controls
Personal protective equipment: Gloves. Gas mask. Safety glasses.
Hand protection: Wear suitable gloves resistant to chemical penetration. NBR (Nitrile rubber). For special purposes, it
is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the
supplier of these gloves.
Eye protection: Face protection umbrella. Chemical goggles or safety glasses.
Skin and body protection: Skin protection appropriate to the conditions of use should be provided.
Respiratory protection: If technical exhaust or ventilation measures are not possible or insufficient, respiratory
protection must be worn.
Environmental exposure controls: Notify authorities if product enters sewers or public waters.
Other information: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of
any potential exposure.

9. Physical and Chemical Properties

Information on basic physical and chemical properties

Physical state: Liquid
Colour: yellow

Cyper 100 MSDS Page 3

January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936
Odour: Aromatic
Odour threshold: No data available
pH: 5,3 (1%)
Relative evaporation rate: (butylacetate=1): No data available
Melting point: No data available
Freezing point: No data available
Boiling point: No data available
Flash point: 44.2 °C
Self ignition temperature: 465 °C (+/- 5 °C)
Decomposition temperature: No data available
Flammability (solid, gas): No data available
Vapour pressure: No data available
Relative vapour density at 20 °C: No data available
Relative density: No data available
Density: 0,912 g/ml
Solubility: Water: Emulsion
Log Pow: No data available
Log Kow: No data available
Viscosity, kinematic: 1,24 mm²/s (40 °C)
Viscosity, dynamic: No data available
Explosive properties: No data available
Oxidising properties: No data available
Explosive limits: No data available

Other information
None

10. Stability and Reactivity

Reactivity
When exposed to heat, may decompose liberating hazardous gases.

Chemical stability
Stable under normal conditions.

Possibility of hazardous reactions

None under normal conditions. Refer to section 10.1 on Reactivity.

Conditions to avoid
Protect against direct sunlight. Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Incompatible materials
Strong acid. Strong bases. Strong oxidizing agents.

Hazardous decomposition products

When heated to decomposition, emits dangerous fumes. Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides
(NOx).

11. Toxicological Information

Information on toxicological effects

Harmful if swallowed. Harmful: may cause lung damage if swallowed.

Acute toxicity:
LD50 oral rat 1850 mg/kg
LD50 dermal rat > 2000 mg/kg
LC50 inhalation rat (mg/l) > 3.37 mg/l/4 h

Information on active substance only

LD50 oral rat 287 mg/kg
LD50 dermal rat > 2000
LC50 inhalation rat (mg/l) 3.28 mg/l/4 h

Information on solvent only

LD50 oral rat 3492 mg/kg
LD50 dermal rat > 3160 mg/kg
LC50 inhalation rat (mg/l) > 6193 mg/m³

Irritation: Irritating to eyes, respiratory system and skin.

pH: 5.3 (1%)

Corrosivity: Not classified

pH: 5.3 (1%)

Cyper 100 MSDS Page 4

January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936
Assessment repeated dose toxicity:
Not classified

Assessment Mutagenicity
Not classified

Assessment Carcinogenicity
Not classified
.
Assessment Toxicity to Reproduction
Not classified

Assessment developmental toxicity

Not classified

Assessment of teratogenicity:
Not classified

Other relevant toxicity information

Not classified

12. Ecological Information

Toxicity
LC50 fishes < 1 mg/l (96 h)
EC50 Daphnia < 1 mg/l (48 h)

For active substance only

LC50 fishes 0.0028 mg/l (96 h; Salmo gairdneri)
EC50 Daphnia 0.0003 mg/l (48 h; Daphnia magna)
ErC50 (algae) > 0.1 mg/l (96 h; Selenastrum capricornutum)
NOEC (chronic) 0.00003 mg/l (34 d; Pimephales promelas)

For solvent only

LC50 fishes 9.2 mg/l (96 h Oncorhynchus mykiss)
EC50 Daphnia 3.2 mg/l (48 h Daphnia magna)
ErC50 (algae) 2.9 mg/l (72 h Pseudokirchneriella subcapitata)
NOEC (chronic) 2.14 mg/l (21 d Daphnia magna)

Persistence and degradability

Cypermethrin is not readily biodegradable.

Information for solvent only

Easily biodegradable (concerning to the criteria of the OECD).
Biodegradation 78 % (28 d OECD 301F)

Bioaccumulative potential

For active substance only

BCF fishes 1204 mg/l (Salmo gairdneri)
Log Pow 5.3 – 5.6 (25 °C)

Mobility in soil
Surface tension 30.6 mN/m (25 °C)

Results of PBT and vPvB assessment

No additional information available

Other adverse effects

No additional information available

13. Disposal Considerations

Waste treatment methods

Regional legislation (waste): Disposal must be done according to official regulations.
Waste treatment methods: Dispose of this material and its container to hazardous or special waste collection point.
Additional information: Do not contaminate water with the product or its container (Do not clean application
equipment near surface water/Avoid contamination via drains from farmyards and roads). Notify authorities if product
enters sewers or public waters.

Cyper 100 MSDS Page 5

January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936
14. Transport Information

ADR/RID/ADN
UN-No: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.
Class (UN): 3
Hazard labels (UN): 3
Packing group (UN): III
Tunnel restriction code: D/E
Limited quantities (ADR): LQ07
Excepted quantities (ADR): E1

IMDG
UN-No: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.
Class (UN): 3
Hazard labels (UN): 3
Packing group (UN): III
EmS-No. (1): F-E
EmS-No. (2): S-E
Marine Pollutant: Yes

IATA
UN-No: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.
Class (UN): 3
Hazard labels (UN): 3
Packing group (UN): III
Instruction "cargo" 366/220 L
Instruction "passenger" 355/60 L
I Instruction "passenger" Limited quantities (ICAO): Y344/10L

UK 'Carriage' Regulations
Hazard identification number (Kemler No.): 30
Classification code: F1

Special precautions for user

None

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

15. Regulatory Information

Regulatory information
Risk phrases and Safety phrases can be found in section 2 of this safety data sheet.

No REACH Annex XVII restrictions

Contains no REACH candidate substance

To avoid risks to man and the environment, comply with the instructions for use. The data should be considered when
making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related
guidance, for example, 'COSHH Essentials' (United Kingdom). This product is classified under the Chemicals (Hazard
Information and Packaging) Regulations, (CHIP) (United Kingdom). This product may be subject to the Control of Major
Accident Hazards Regulations (COMAH), and amendments if specific threshold tonnages are exceeded (United Kingdom).

Chemical Safety Assessment

For proper and safe use of this product, please refer to the approval conditions laid down on the product label.
Risk phrases and Safety phrases can be found in section 2 of this safety data sheet.

16. Other Information

Health and Environmental Hazards:

Harmful
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Text of the hazard statements mentioned in Section 2

Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1
Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
Cyper 100 MSDS Page 6
January 2013
Material Safety Data Sheet
Cyper 100 – MAPP 15936
Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3
Asp. Tox. 1 Aspiration hazard Category 1
Eye Dam. 1 Serious eye damage/eye irritation Category 1
Flam. Liq. 3 Flammable liquids Category 3
Skin Irrit. 2 skin corrosion/irritation Category 2
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H226 Flammable liquid and vapour
H302 Harmful if swallowed
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H318 Causes serious eye damage
H332 Harmful if inhaled
H335 May cause respiratory irritation
H336 May cause drowsiness or dizziness
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
------
R10 Flammable
R20/22 Harmful by inhalation and if swallowed
R22 Harmful if swallowed
R36/37/38 Irritating to eyes, respiratory system and skin
R37 Irritating to respiratory system
R37/38 Irritating to respiratory system and skin
R41 Risk of serious damage to eyes
R50 Very toxic to aquatic organisms
R50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic
environment
R51/53 Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic
environment
R52/53 Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic
environment.
R53 May cause long-term adverse effects in the aquatic environment
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
--
N Dangerous for the environment
Xi Irritant
Xn Harmful

Date of issue: January 2013

Disclaimer: The information contained in this MSDS is designed to give general health and safety guidance
on the storage and transport of the substance/preparation to which it relates. Requirements arising from a Risk
Assessment of the substance/preparation in a particular working environment should take precedence over any of
the guidance contained in this MSDS where there is a difference in the information given. The information contained
in this MSDS is accurate at the date of publication and will be updated as and when appropriate. Liability will not be
accepted for any injury, loss or damage resulting from any failure to take account of information or advice contained
in this MSDS.

Compiled in accordance with EC Directive 91/155/EEC and subsequent amendments EC Directives 93/112/EEC and
2001/58/EC.

Cyper 100 MSDS Page 7