49 -Joyeal ofthe Korean Cermis Society ‘ol 13, No. 21976 Printed in Reoublic of Korea QAARM so Aol BAS! OTe ER MA atta AAR ETS ee) A Study on the Leadless Raw Glaze for Domestic Earthen Ware. Hee-Soo Lee, Young-Ki Jeong and Se-Yeang Choi Dept, of Ceramic Engineering, Yonsei University (Revered March 27, 1976) ABSTRACT. ‘The study is an artempt to prepare the raw graze can replace the lead glaze thet has been used for a long time as Korean Kimchi-jars, 1) The batch of the glaze that show the similar properties end sappearance of lead-glaze were 4056 of Yongin or Anseong Yalsto, 40% of Ash ond 209% of Anlydrous-Colemanite, {i's Seger Formula was 2650 | a.m at 0.98 SiO 0.02 MgO O12 KNeO | 0.0007 Fads 9.8 BO, 2) The Fring temperature of selected glaze was 950—L050°C, 3) As the content of anhydrous-Colemanite was inereased, the thetmal expansion coeficient was decreased. 4) The color of leadless raw glaze was translucent light yellow. It was possible to obtain the some colo: as lead glaze by FeO, and MnOs TAB At 9] AL MSY, IMRT. B uot RHI) GA aBol Be HORA AL 1 sta, Peet obs) HURT fell At Weer 1 ako ABR} alot Dk Pe] Uetel als. POR] SEB) se aegeatte} 157, 407% (STS EMSS BMS] oe Agee vale Baa VE + Me AE Jodens we Sh Ml REE SEO) Soke, sey ERE Sebel eeiims 2 ol =e HE MeABd oa Se) BE eS AR S Ems Le —i BURRS Raa? —age teareho} sleh, teh] Hm) HH SARS} RUE Le Ss eM ol is titbee deel Qe awk Hel wise U MSS BA ma Be HOE IAFL mee ae BA Aza Be] BMY wave, fk, MREILE at HIE eh) sled, sca FS MEG frie Hol BE Zo] Gon) -AHESARBel SMBEAb MA AS ob] opens ARE BH Rs SR) eda (17)50 pi» Midety - iB, 4 colemanite®2} wollastoniteP ots}, giv RUBS BE BAS Wiebe RE BIS MiRel SR PLEA o8 (45) (Ils LE RINE RES RE ame (ameter, Bal Al s00RHABFS] S712 ees. alt ARAN BCS Del ERS Re) SEH so] Hehe] TRAY HSI Tl A BSA) AS MRS AES ae) + THES) 014. Fable 1. Chemicel compositions and some physical properties of raw matertols, Sr 7 Tw [Bebe lees by. Po | $iog | ALO, | Fe, | CO | MgO [20 | Ned | toss | Te J eoiness materisis ~ i L | ee | 30) imchan quaste 99.085] @04ie) G9 0.55% owes] 209 | 3 | Hadong keolin 2 jee | 105 2.47 a Yeongiok wollte | sy.q3 | 2.18 | 0.94 ost to | 2e3 | Yongin yekio | 68,00 |17 80 | 5.05 net | oes | 229 | eas Anseong yalto [64.2 [163 | 5.75 aa i073 | 2a0 | eee ! | aa 2 | 2 s8s | 2 RBS BER 24) BEBE SL A TR isolin, EEE, HOME, MCL, Boe EEA wollastonite ()S ARTS ARIE HA FEST KARAS Table 19] miko 41S] MBL] SLE. ARIE, wol 2 ANGE Ak colemanites| Xray MERE Fig. 13} eh ANA BE RAGE Tyler sivev 200 mesh iil Shea HRT. AE sedi) ME BRS TAM YY splasiel SK ais] ARE HAYES Res MMs ged, CAIeR AE Fide 9ALSA RS BESS HAS A oiled eRReIS, 9A) EI MS RATIIE aps Benes IBA] §) MNT) BARA AZD. 58)S Goo} GUATUTSIAT 6] RILLEA 25X25XSam 9} By Beet He ZAR Heiwelal Bs aE feels, Table 2 Physical properties of the fired nonglazed bodies ‘ater absorption| Linear shrinkage Temp. °C $60 | a9 wu 2000 0.99 18. 31050 258 15.38 na0 5.13 11.88 1150 6.2 9.02 1200 8.98 4.06 (as) Larlher cthodaad Wig 1. ¥-ray diffraction pattorns of starting’ materials, meee24288) oY BR J 74 Rela ff ome Al #) 100°C9) HERERO "ES desiccatore) (RAPA) SL FA GS] GRRE] SE pk Table 29) aheh, 3 Ate TK RES BS} SARS eT Mel MnO, FeO. 22 fio] aeaNSs, 22 Bie S08 AMR eT) BENE cookie 46595) 0) aE POS Mi AL aio 4) tet) HR ToL Snot! HANA Re, ely — ARTOIS 448 GE mets tablet 3 (1. s3emé, D5 MME (100 psi 35—) ERS LS 23 AMES] Hot BBM BIER wolla 2 M8} Fly 2a Be] ERG Riel AES REIT FORNAS Held, Flux bbe) IRE AORN Be CRE Som. Uuiktee a IFIERAE 10 1H—Z ohh} SOMERS |e AES} BA SES Bey 22 40, OLS $obo] TICES Ae boy Tse TAREE Table 4, Physical prop wet M59] BR Ze wblet HS Su ea AAS arabe oe Fiz 2. Diagram fer batch cocspositions ‘Table 8, Batch compositions aw male) Yoxcin yakio | Ask 20 4 | 40 2» eanewe cf the fied samples [comme | ipenene | - Gotowr —Trwstucaee | ctss | Da Samples roa black nome end | 1. 25cm 0.086 | rounel mae | datk brown ” one ” ” hax browa ” ” ” ” ” light brown | a | a” 1.33 eo a dak pep | ” " ” ” eres jos » ” ” " | cae Beane. Gicss | Dio | Comet ope | Babble | oa | born wilh w | bad bed 231 ! =O. 98ers) spread ! none ! & | brown pee : 2. uh. ben sood | cood | act | ties | 7 |snntl, may | 5 j whitish broyra ” ” 3.69 | +2,36 ” a 4 disk boowa » | ow | aie [4205 | 7 |teruo, macy | 2 wwhtis, brows » |» | ase jssoo | none 2 : ae ee BBR BARE (19)62 Flux 8.2.24 wollastonite (Ws. S878)$] 8x cole- monite (C2 RA) F RZ Asher Fig 2 M9 2] 8 FORMERS floxed fade GF] wee IE ETS MAINE ARTIST. IRAE Table 4 3 at, 4] RAL] E + glEsTs Be) W RFE BHI 6] AS) somsl=| Sskew eld CATE AHO) AS) sea Whakslo] apes! eh Messen Ate Sees taxes RACLS 1s sesh eR «bay HEB YF (SRS) SELLA AGIA EMRE EE = WR} BH} Pe ONCE BURSA 22] RARE wT, 3 ASHE Tolele sa) steak ahs. 9] Rell B+ sl sh eo] MINH, BE SURCIRESE GA omOt 2 PRA) AH IAS eno ETS, Ua RE WAN HS we Wintel HTC SG alaeelal thy Beds HR Aol sea D Mie WE RB MEK ee A) DAR MAA GRIAEE 1060°CR TA FEHR, BY, 2 ER AE Toble 5d ett. Table 5. Physical properties of the fired samples. Order Colour tee | lose } D Contre: | Bubble | Annet fad. {Shon =| bows cow) ba [Leal Soma) mee red) es) ght brown » | oa [200 [sos | nme jo | 8 9503 whitish brown ” a” 243 +110 small, many ” a wie dark brown ” a” 280 +7 small, little ” | 2 a's bluish Tight brown | uw /3.45 [F212 | large, many | 1 ag whitsh brown ” none | 216 40.83 | large, Tite " | 3s wee! brown none | bad | 2.09cm| -+0,68em) small, Hite | rome | 6 we, Tht brown » | ow [aa | #088 | ame fw) 6 seiC’s whitish brown ” ” 250 +117 | small, many e | 4 aac dark brown ” "| 8 # ; ead none ” 2 mac's | bhaish he bros | | seer |e many fon fa jC whitish brown » | none | aos | tase [twee oy | on | 8 OLE FE RFIS Jeeta] ae RHE St ee SE 0} CTI ULL AME oC’ aA] RAR. web ARBRE HA Miod deRsebo] Bhd ol} 2 ame} Bir} Melee ae waa, @ wae See Avy Cob HMOAE sol svAnel Ate] — HAA SLA 900°C} 4 1. 1g0°CA}o]-F 50°C ae eee ee ‘Table Go) BARS. ERT Hi BRE REE AS ae ‘Table 6, Prose propertios of the fired samples, Trea ‘Order of T Samples a Colour | Gloss Diameter i Conrract | ‘adhesion Appearence Cs vbitish brown none | 1,.33em 8 a | 6 | sharp exo ” 1.50 017 5 round rood light black | 3.20 +1 4 | " 0eog light brown cot 4.00 287 | 3 ” wots ” versed | ane | 2 | a | see ” | asy seg | 1 nt aC, SC WY RSLZ IAS ARMA BD ALS RSG PPE CBA ATS Ae ea. Abo} oe WETS A] SEAL] LS seats ey @ masts) ee SUBEURIR 160°CE LMLos Be} G0°C FS QO 0) sain21050°C, 1000°C SX 950°CS] af ato al BaRLST SLT. o}=] lin RE BU SKS shel AS Taef a] UG oe BMS 4068 Heim Cy SASS SRSA IHRE TI Cy seek 2 63. SEM] Mela= 5O%Z sleh, oleh MATHS) He FE EF —Bomedhs] Ree wees. KATE DUG) BS HARE Least ei asked a a8 Table 7. Physical properties of che fred samples = Tes | 2 S| Binds of glaze Coleus Gloss | Bubble Remark | [Macuing Temp. a | I Lead G. dark black =| god small. little | 2, 059°C o Dlackish brown | ” large, many : cy ” ” volanle Lead G, | dork ved | bed cracking 000°C ce \ Backish brown ” many c% ” ” ” i | _| | Lead G. darle ved | bad racking { seatc Ge local, ” ssnall i cs ” ” ” Table 8 Physical properties of the fred samples Firing PEPE ; , / Temp oo | | ret cy GG brown with | brown with | wanslucence | translucence Colour. eb rows | whi Brown | with with blue | dask brown | dark brown Spot spot) blue spot Spot 100°C | Goss ‘geod ‘good ‘good ‘good very good } very good Bubble | none Bone none rrone none volatile Crating} none none | isle Title meny | mapy yellorish yellowish | translucent | translucent Gerk =| dark Color | "yeawn brown yellow) + yellow | brown brown osoc | Gos ‘goed good | goad good good good [Bubble | small, Tile ) smell, litte | none pone} Tezge, many | volatile [ering] nema none | —_Hie ldo my wong Colour | brown ‘brown | deep yellow | deep yellow | dark brown | datk brown ‘ Gloss bad ted bed bad bed bad 1,000°C |utble | small, many | large, Uitele | mpl vey ] smal ver | many | many Craving} none none | __none one | Tile | ittle Colow | deep red deep red | deep yellow | deep yellow dark brown | dark brown woo [8 bod wd | bad bad bad bad Bubble | small, litte / small, litte small. Title | small, tile | Pady tbsoppe | body absorp: | Coleus red | ed light red | fight xed | dark brown | daric brows [Sin one one none one Tiele litle 000% Bubble | craking none none one} bey absoret- | body abeorpt- Crezing) none one none one none none erste sp28ta976) (aryat RE SRST «| SUE GA AGS Toble 102 Oth. Table 10, Efiect of colourents for syo0"s lave ABE Table 7] eRe. © mk 9} SRE SS Meteo se MART aT Sh 24 She RWIS Bt BGME aves. al fo EAE HES MLE He esa coCe mw CUt RETA RS SINT RUG. FH LIB] SHS oR sao] LE Hawise] Sete. iB, etre Bei GL EAM EUS este oalsE Fez a eH AG BAe} wash ol = BIL craringBhts Bho] athe) SNIERO] HRN Ae RSS Boe Mea MET 6S Ga ee BRE] ax Rite Sb wae BRS use ELS} S29} Bee Geo] AaBStSKM. ot RHA He Sheil ©) HIRIBELAIRLS BYES 100°C LR 2A] °C BSS 900°Cr}2|9) AIS e515} o] ERE Table 89] Ame Baa Qed a aol & Bel BA Ae SRS Slo, MEHOE Fe BRE HE She MIE ONC}. 1ns0°Co| 4} sR Ho $e GES HEL AE Cy CL eIsLOM) HRN exezings} bubbles) Agel et HIS’ BEAR Cy C/E 9] PHA Hate] AAAI 1000°C BL 2) INES Stale AE ol FS) BE Ae WEA, taba) ABR orca ee alts HBSS © #8 Rises TEES Tish dae CURES Ge ton RRA eka we 19) ABE BF aS —-#y HERO] KSaEShe, Heb AMA ale ele] BROS Ade] HS Ber Flo} ke (ANS: MAL ae aor Bee sities ete Awls ae ‘Table O9 BE BGM SWS ok BIE iw’ SUILOO), 2 ERAS Table 92} abo] & Fed ae aR saga asda See aS AiR 1 Table 9, Recipe of colovsenis seis | A | T owsl MOS | Feoal 7] 1 [ 4 | ‘Atiitinal “| 555 | 1096 | 5% | 20% | [nn | (22) % vs} Qe] ol ely ES Fo Hi PAS} HO GEE HEL slash Muse} Pee Oss] & RF HSH BE HBS ae Fs ASR24, Hb SOM IE) Bae FF GE HS SE AR ‘HOE PEE MACE SAFO] ig. Se Lo) Stekal st OM BEM) MAMET MAES + ales Fig 3, Appearence the developed ie, AS Fol] RE HL OTESASS RAMS] IN BEE 55 Eel ASH felt aI HBR esol, TE 224 WEES 2 S58] SH Ne HER A Bets dee Pel STB BL eS a SH EOL POOL o] REE o] 9h S834] OEE S Qe Qe}al oe py 4S SH) tals. ee a oe He MAS} EE AL eo) BelS OROREMES BE WIRE AME We alot A HMB fool proof 6] 100°C PHAR AEE AU BBSLo1, ANGE AA este) So] okey Bh SIR] SERS SHERI SHE Aol Extech, wei & REE 9) 22 Rabel Sana AL IBS. FA SEL HRMS] uhh eat the) = QAP woilastonites} ge colemanie 2 Bata, = AGL, AUR RR, be soe FRNA URASS AS] Biel at A WHE LE Mok colomanitey =}, 25}u} Lime} 24 BIR GME OA Sst. AAS ABS wa HHO] TH BA Ae RAS ode CRG Me BeRe TIRES, a4 S72 58 Gee) Sti Le me = a) he Tol GRE = 4) Sd Bae settee 2 SERBIA Rofo} oa pio AiAe) Bo Mx, 29 Rust g a2 wae BA] At desea) shee, REE RES] REA] RH] | Bopap, ERE 2 RE A Es), ale WR, REBEL Rite, AMR) aol Bee tl Abele Be Sle ashy ol £ agersio] CMe RAS fame] MS) Mme) es Me > ERE RMU IO Sas] 2] Ae ste Mea ap BASSE Ao] oda atey, 6} w slow ArDaL(u976) SL alkali A #2] NesOzo] 42 Be zo] Bokeh, % MENS Bal Mate w alkalis ga 4] Sb Rake] Ge 1, 25 ARAt mrss SS ache Be) Ac cab alicligh $5] NOS el GE FS His) Aste Soe WE RA EF = BA Re] Hl | ES as ( vt SES SHS Ae HHS] et FE HEE Rte RRL 409 AEE 4095 4A oale- manite 20%) Ftste B85 O20 0.25 AMO] 0.92 Sie oe M0 oe naz KNaa } 00007 Faso, BOs @ Bed Shs Ree sO~ CRY 5] AR REE Les] 10S BE Sha) sso] (9) 7K colemanites Ho] BS +S SRB] Hite o] ast MSA UES ante] go} we ssh ee, mE ae, 1 BS eG ale] Meni % Glo) WA ARS Res vb ee, References, CMBMAS as: fi a as75). 2 Tae-Wool Kim snd Wseng-Sook Kina, *A Seudy on the Prevention of Lesd-Poison Glazed Surisees of Fanikern Waves". The Report of National Pottery Industriel Research Lustitute, Vol.1, 3-10(1975). 3 2S, JAS, ee F Fa FQEo| aelgq—, Fax, Al 197, 123 4 USS, ha Frit P4943) lz", 221] say, 78c1971). 5. RR Danielson ond D. Opaque Glezes at C Soc, 28, No.11 (1950). 6 CW. Meritt, “Raw Leadless Glaze for Pottery and Tile at Cose 02", J. of 4m, Cora, Soo. 19. No.1 (29836), 7. BRIG, “MemReriCH Be SIAMESE, Vol 14 (No.6 Van Gordon, “Lesdlees Je of ao, Ceram, ti 2514970).