—
a4)
et)
| 4
ih) Asuring
Wn Over
Py = 0°36 ro Pa
Reaction a
Pu, afm
9°86
0°36
O0F
0-24
vr
on the veactor
constants
the
0,
&S Here,
My
0-3” PL
Ena ij gerential reacor at 315%,
5 A sere raqenation ap wa, ee poe aluens GWA ahd
measuréd with
veying partial precsun .
exon? 5 Tydrgen Rae "4 Fou: _Pratures 94 tne thy! cyclo
4,» ofm 7,7 mel _tolune
SKgeat
da 0-042
80 012
14 6100.86
4 0-014
a4 o-a13
Write down ‘the doichiometrlc mm oq? § deseribe the method of
Kinetic hay with the dij ijookd
DVeseribe the
reactor.
egects 04 mabye gy “yee igen ee pracures
rate veering -le the data inthe ta
Propose a rote ee that Gits experimental data 4 deternine the
ma in the equation.
iL The eee of plotinury ota is0-S, calculate
ee ger th reaction ole ot
eens T
0:34 PIAL O,
aS
Aruming qmwad mm?
—% =k-G? k =k-emp [e-(1- £))
Far gaa phase ae
M@) Tq) +34,
ate = kf” Rw“1k. (A-% ” C1-kd-ta)
I
ax = -(y) x 105
OY
kx105 (% eh") (1-ka td)
whee y= for SW
fro
Finally,
Ye =k Po
Vk” Pa
eS ae reypomible in the gord sav the
change > = ordw % tan. When, the concn o Hy divgg
Tracom, hore wen midximam m7 in geod - f a
a peduc of rm suppab as q promoter tha hay
pasitive ect der" townda Kineks 4?
Mhough the partial presure op His dnt game and
the’ McH partial pressure Inureates the -xale % tw? gor
qermatin ‘nea 99 gm the table
43) he model $4 the vate @:
y, = KY py
14 Kew fea
Voniable trial ques Vol 95Y. congderce
k 4 12:25 21S
k 2 3-005 1°80
0
Precisisy
2 = 0.g¢
KR" 2 adj = 0.978
Rmsd = 0-044 k= 12-2
Voslowe = 0:00 42ig xo melt == f, x
{woe 9 S+kq cal
bee Beery
os ml yy 602x107 Sabon
total atws Py QA atem (may 3
x ayn PE XOO08 gPh
acrernys g total