conditions, for several months without considerable changes in quality FREEZING
change in the physical state of a substance from a
liquid to a solid, in which energy or latent heat has to be removed from the substance.
considered an excellent process for preserving the
quality of fish for longer period of time.
<-10oC- most microbial activities stop.
EFFECTS OF FREEZING
Ideally, there should be no distinguishable
changes between fresh and frozen products after thawing.
Biological changes are very minimal.
A series of chemical, physical and histological
changes occur in frozen fish during excessively prolonged cold storage at temperatures below –30 oC
Partial and mild dehydration
Stages of Freezing
1. Stage 1- REMOVAL OF HEAT
-denoted by the fall of temperature -temp falls fairly rapidly to just below 0oC
2. Stage 2- CONVERSION OF WATER TO ICE;
CRYSTALLIZATION OF WATER. -critical zone or period of thermal arrest at around -1oC
3. Stage 3- FURTHER COOLING OF FROZEN FISH
-frozen fish attains the desired temp. for storage at around -30oC. TYPES OF FREEZING SLOW FREEZING QUICK FREEZING (SNAP FREEZING)
Ice crystal Large Small
Thermal Arrest passes at a very passes at very
Period slow rate quickly
Rate of freezing -2mm/hr -5-30 mm/hr
- lowers the temperature of fish from 0 to - –5oC in 2 hrs or less METHODS OF FREEZING
1. AIR BLAST FREEZING
METHODS OF FREEZING 2. CONTACT OR PLATE FREEZING
3. SPRAY OR IMMERSION FREEZING
QUALITY ASSESSMENT OF FROZEN FISH 1. PROTEIN DENATURATION
2. FREEZER BURN QUALITY ASSESSMENT OF FROZEN FISH 3. LIPID CHANGES QUALITY ASSESSMENT OF FROZEN FISH 4. DEHYDRATION AND WEIGHT LOSS
5. DEVELOPMENT OF COLD-STORE FLAVOR
AND ODOR THAWING OF FROZEN PRODUCTS 1. THAWING IN AIR A. STILL AIR B. MOVING AIR (AIR BLAST THAWING) 2. THAWING IN WATER 3. VACUUM THAWING 4. ELECTRICAL METHODS -dielectric and electrical resistance heating for thawing or tempering (partial thawing or softening) HANDLING OF FROZEN FISH DURING THAWING FREEZING PROBLEMS 1. BROWNING OR BLACKENING OF TUNA AND BONITO MEAT – due to oxidation of hemoglobin in the blood and myoglobin in the meat. 2. GREEN DISCOLORATION OF TUNA MEAT – due to the presence of TMAO in the flesh 3. BROWNING OR BLACK SPOT IN SHRIMPS AND PRAWNS – due to oxidation of tyrosine into melanin SOME MANUFACTURED PRODUCTS
1. BONELESS MILKFISH
2. SQUIDS
(for the whole freezing
procedure, please see Espejo-Hermes’ FISH POCESSING TECHNOLOGY IN THE TROPICS, pp. 52-54 )