Chemistry Electrochemistry Weightage = 8 Marks 1 Mark -1Q 2 Marks-1Q 5 Marks - 19 ONE MARK QUESTIONS : 1. 2. 10. be 12. 13. te Veo Write the overall cell reaction taking place in Daniel cell. Ans : Zn + Cu? Zn2*+Cu Write Nernst equation for Daniel cell. Ans : Beat = Boy ~ 220 tog Br] What is specific conductance or conductivity? Ans : The conductance of 1m? of electrolyte solution is called specific conductance What is molar conductance or molar conductivity? Ans : It is the conductance of all the ions produced by the solution containing one mole of electrolyte, What is the SI unit of specific conductance? Ans : Sm! What is the SI unit of molar conductivity? Ans :Sm?mol! Draw graph of dm v/s V¢ for acetic acid solution t Draw the graph of v/s V¢ for KCI solution i, NN veo Define limiting molar conductivity. Ans : The conductivity of electrolytic solution at infinite dilution is called limiting molar conductivity, ‘The resistance of a conductivity cell containing 0.001M KC! solution at 298K is 15002. What is the cell constant if conductivity of 0.001M KCI solution at 298K Is 0.146 x x10%sm1? Ans : Cell constant G*=kxR = 0.146 x 103x1500 G* = 219m? What happens to molar conductivity when one mole of KCI dissolved in one litre is diluted to five litres? Ans : Molar conductivity increases Write the mathematical expression for limiting molar conductivity of sodium chloride (NaCl). Ans : Afaci = Agathe What is the electrode potential value of SHE at 300K? Ans : Zero (or) 0 Scanned with CamScannerChemistry Electrochemistry 14. What happens to conductivity when one mole of KCl dissolved in one litre is diluted to five litres? Ans : Conductivity decreases. TWO MARK QUESTIONS : 15. Mention any two factors on which conductivity of an electrolyte solution depends. Ans : (i) Nature of electrolyte (ii) Concentration of the electrolyte solution 16. What is the effect of dilution on conductivity. Give reason. Ans : Conductivity decreases with increase in dilution. Because number of ions per unit volume decreases. 17. What is the effect of dilution on molar conductivity? Give reason. Ans : Molar conductivity increases with increase in dilution because total volume of solution containing one mole of electrolyte increases. 18. The conductivity of 0.025N solution of methanoic acid is 1.1525SM-!. Calculate its molar conductivity. Ans : hy = MOH = MARIE = 46100 Sm? mol! 19. 1.0M solution of a salt surrounding two platinum electrodes 2.1 Cm apart and 2Cm? in area was found to after a resistance of 50 Ohm. Calculate the conductivity of the solution. Ans : Given l=2.1cm, A=4.2cm? R=50 Ohm Specific conductance k=tx¢ =Hxt K=0.01 Scm 20. State Kohlrausch law of independent migration of ions? Write mathematical relation for limiting molar conductivity of CaCl2 Ans : It states that the limiting molar conductivity of an electrolyte is equal to the sum of the ionic conductances of respective cations and anions. Mace = Bea? + 2AS- 21. Name the gases liberated at anode and cathode when an aqueous solution of sodium chloride is electrolysed. Ans : At Anode — Chlorine gas At Cathode ~ Hydrogen gas THREE MARK QUESTIONS 22. Explain the construction and working of standard Hydrogen Electrode (SHE) OR Draw a neat labelled diagram of SHE, write the symbolic representation and write half cell reactions. Ans: SHE consists of a platinum foil coated with platinum black. Platinum foil is connected to the platinum wire with mercury. The other end of the platinum wire is connected to external circuit. The platinum foil is dipped in 1M HCI solution as shown in the figure. Scanned with CamScannerChemistry Electrochemistry Working : Pass pure and dry hydrogen gas at 1 bar pressure from inlet electrode reaction is ~ot Hig) Feo 7 Ae SHE is represented as S / He(g, 1 bar) / H+ (aq, 1M) Ese = 0.0V 23. Calculate the emf of the cell in which the following reaction takes place at298K Nica) + 2AB{o002my>Nigeacomy + 2AB) (Given E8y = 1.05V) : pO, 9.0591 9 fi?) Ans : Beet =Efqy - “> log (oat = 00501 4. (0160) © 1.05 = "5 108 ooze aso. =1.05= log (40,000) ea (20,000) 10/52 = 1.05- osbn0e 1) Ecc = 0.914V 24, Calculate the value of AG® at 298K for the cell reaction 2M ges) + 2ALRS) > 3M get) + 2Alce) 2.36V, Ef, = -1.66V and F = 96487C Given Efi, Ans: Efu= Et ~ Eltg £9, = -1.66-(-2.36)= -1.66+ 2.36 = 0.70V AG® = -nFE® = -6 x 96487 x 0.70 = -405245.4) AG° = - 405.2454KJ 25. The electrode potential for the Daniel cell given below is 1.1V. Znggy/ Znbt + Curt) / Cups) Write overall cell reaction and calculate the standard Gibb’s free energy for the reaction. (F-96487 C/mol) Ans : Zn) + Cushy >Zngihy + Cues AG° = - nFEO, = -2x96487 x 1. AG® = -212.271kJ 26. Calculate the emf of the cell for the reaction Mais) + 2AGiaqy May + ZAI) Ehytjag = 0-BOV, EXiy2s yy = -237V, [Mg’*}=0.001M, — [Ag*] = 0.0001M Ans: Ela = Etathode~ anode Scanned with CamScanner~hemistry 0 0 = Engt ing” Ema?*/mg = 0.80-(-2.37) Eo, = 3.17V {ag?*} lag? Bee = Foy — log =3.17- 2 log = 3.17 - “© tog 105 = 3.17 ~ (0.0295 x 5) = 3,17- 0.1475 Eee, = 3.0255V 27. Calculate the equilibrium constant for the reaction Eby = 0.46V Cus) + 2Aggoq) > Cutan) + 2AB() 0.059 Ans: ESy = 7 logKe 0.46 = jogk. 04622 0.059, logKe= 15.5932 Ke= antilog (15.5932) Ke= 3.92 x 10'5 logKe Electrochemistry Scanned with CamScannerChemistry Alcohols, Phenols & Ethers ee Unit weightage 2 MARK QUESTIONS 2 5S MARKS QUESTION 1 TOTAL MARKS 9 1 EACH QUESTION CARRIES ONE MARK. 1) _| Write chemical composition of Lucas reagent? Ans. | Cone. HCl and ZnCl: 2)_| Between primary and tertiary alcohols, which one does not produce turbidity at room temperature? ‘Ans. | Primary alcohol 3) 9 Give the IUPAC name of Heh ‘Ans, | Propan-2-one OR 2-Propanone OR Propanone 4) Lt Give the IUPAC name of 1 4 Ans. | Methanal 5) _| Between phenol & alcohol, which Is more acidic? Ans. | Phenol 6) | Phenol is more acidic than alcohol. Give reason, ‘Ans, | Phenols easily undergo ionization to give phenoxide fon and proton. Phenoxide ion is resonance stabilized where as alkoxide ion is not resonance stabilized. 7)_| Give example for trihydric phenol. Ans. | Pyrogallol 8) | Give example for mixed ether. ‘Ans, | Methoxy ethane ‘9)_| Write general equation for Esterification. ' W ' Ans. R-OH + R'-COOH ¢—> — ROCOR'+H,0 Alcohol Carboxylic acid Ester 10) | Write the reaction for the conversion of phenol to benzene. on “Phenol Benzene u EACH QUESTION CARRIES TWO MARKS. 11) | Explain the method of preparation of phenol from cumene? ‘Ans. | When cumene is oxidised in the presence of air, it gives cumenc hydroperoxide which on hydrolysis gives phenol. we ete ; CD mire CD it~ CB -encoom Commer Cummoue Phenol Autos: ne Scanned with CamScannerChemistry Alcohols, Phenols & Ethers 12) | Explain Williamson's synthesis with an example. ‘Ans. | When alkyl halides are allowed to react with sodium alkoxide gives ethers. R—X + R-O Na—PR—-O-R?* NN Alkyl Sodium Ether halide alkoxide 13)_| Write the equation for the preparation of t-butyl methyl ether by Williamson's synthesis. ‘Ans. | When sodium t-butoxide is reacts with methyl bromide in dry ether medium gives t-butyl methyl ether. cH, cH, CHy— G—O7Ne* + CHy— pr—> CH, — ¢ —OCH,+Ne Br Mest CHs Bromide CH ‘Sodium srt burma sre 14) | Explain Kolbe’s reaction, ‘Ans. | Phenol on reaction with COs in alkaline solution followed by acidification produces 2-hydroxy benzoic acid (Salicylic acid). = scstan Ponte Schyaoay tense ahd [ 15) [Explain Reimer-Tiemann reaction with an example. ‘Ans. | When phenol on treating with chloroform in presence of sodium hydroxide at 340K followed by hydrolysis gives salicyladehyde. Ht ou ag Naor or 10 }.CHCI, + ag NaOH, PHENOL SALICYLADEHYDE 16) | How anisole reacts with acetyl chloride (CHsCOCI in the presence of anhydrous AICL? Write the chemical equation for the reaction. ‘Ans. | When anisole reacts with acetyl chloride in the presence of anhydrous AICI, forms 2-methoxy acetophenone and 4-methoxy acetophenone. oom, ecm, foci, coon, + cnycoc: Amat A, . Acerst Anisole — Ghtonde thorgactntenone — Loe 4a acetophenone 17) | How is phenol prepared from Aniline? Write the equation. ‘Ans.| A diazonium salt is formed by treating an aromatic primary amine with nitrous acid (sodium nitrite and hydrochloric acid) at 273-278K. Diazonium salt is hydrolysed to phenol by warming with water. on Phenol Scanned with CamScannerChemistry Alcohols, Phenols & Ethers 18) | How does anisole react with methyl chloride? [Ans. | Anisole reacts with methyl chloride in the presence of anhydrous AICI to give 2-methoxy toluene and 4- methoxy toluene. zMethorictume — o-mettryl anisole 4 -Methosytolucne p-methyt anisole 19) | How do you differentiate between prima ; Secondary and tertiary alcohols using lucas reagent. Ans. |__ Experiment Observation Inference ‘Alcohol + anhydrous appears immediately Tertiary alcohol ZnCl; + conc. HCL appears afier 5 to 10 minutes Secondary alcohol (Lucas reagent) . n No Turbidity appears Primary alcohol ‘Complete the reaction: coon on 20) + (cH:Co,0 + HCOOH Sabiylic acid Ans. on coc + cnyco,0 ut EACH QUESTION CARRIES THREE MARKS. 21) | Write the three steps involved in the mechanism of acid catalyzed dehydration of ethanol to ethene. Ans. | Step-1: Formation of protonated alcohol: 4 1 Fast wt 4 oo Protonated alcoho! Emmanol (Ethy! oxonium ton) Step-2: Formation of carbocation: tO Slow Hoe 4 n Carbocation Step-3: Elimination of proton: " " iH. 4 n—éN ed Le Scac + T T Ho i ood Emene Scanned with CamScanner