Scribd Logo
Upload

Welcome to Scribd!

  • Reactor Sizing Notes

    Uploaded by

    Yash Choraria
    34 views40 pages
    Reactor sizing

    Original Title

    Reactor sizing notes

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    Reactor sizing

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    34 views40 pages

    Reactor Sizing Notes

    Uploaded by

    Yash Choraria
    Reactor sizing

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 40
    F \6 0B 2099. He ae = moles i trned, Cnlume of fd time? KINETIes Of HomMoneNntous REACTION deal _veachor types “Batch Pua Plow Mixed flow YN i Hee | a Bs pn Fluide pastes Cat Uniform cone ben wt de. Uniform mixed, everywhere ih wise game compasition se suackor,bub no mex of every drut ait inee cfeourse Mie Loder ond earxdier enlestirg Rt) and punofor & of combinolion = ; en vara tine we. no overtabii erat. ee I is oo “Pta foal o moved Zn singe Fie Need not be an Rrogerencer __- Seolated syste Steady state fle Diff behween Laminar & orbuloxt Flovs - a Tn pl flows no vasaatien ef Plato velocity _B [ete Equablion aA+bB ——F cel +dD —% = -_l dN = oiss Ye _Wolume dima) The vates_of 7xn_ove EE Se ee al ooo ef P) che vate of - reaction 2° Inefluanced by _* | Composition — $$ —________________| ney 4 te pal frog, yctemb (random Kineb'e enongy of xan) + Bi tght_ 2atensity within her Systm —_ + Mag a =% = KG = Ke GS Ke peche oxo vate | KAA) = pre exponenciall ; factor a frag backer _£ = Activation. energy i ] J Ear Activation evergs mac Cneentrakion - per term et yote eqyichien + When @ gingle hocliomehfe equatian ond o a Zrale xate equokion ase deren, Sr az eck won to again ‘Yefreseut dtu. \pregress of Hr sucction , 5s eats ae Single reactien, iy hon Mote Shae ous hoo Jomebrie. equatien ord more Shan oe Kinshe embreasion »J¢ Cotlked Kindle sunchion. 1% 08 20822 Multiple reactions Soutes wn A PRPS _ Rayelted 1x0 ao and AR ide Competitive B—-+s gi Complicated sale mes A+B —-R Rt Bor S ste. Elementary ard avn-clementory yeoctieng A+B FR tho “ote of disiopeaxonce of A ~Vy = kKCaCe * GeRenchtions Gn tel, dita. safe eayaltion ole Lernentary soodisn. * non- elementary osadten Ho+ Gy, —P QB Ko +Bid6.) | m1Qar Molecular ty} 0 Reasttsn —. The no-6f molecuted Snvolved Zn a reackien ds tte moleculayity of, a reactsa he powers to Wilh di concenbotions asa volsed!- tte owlese of tite seaacddion. Tus is tt Lavo ef moss acten ef Toke pHa ok (oradluct oF eone of eool-verctoud bbe ci = en K= (ime) Gone) n= ordex of Ten. - “Representation af an elementary RN ~ |, MEK GSC elementary ron ore cPten rebreendial by an eqtoGi en roving, ba. die wolecuQascty eke eode coustauk . Date js C aA th b) y “Ta = REKCR - - : cae nesesany fo eheoi Fy Ge 7 : . Reece clstancte —___.aenstant is offered ___ Bee H Qe 2D —P ST ee 7 . ree eee oe \ a = Kees ae el eee 700 —— =—Ye - —% . eee 2B = aniaia = & a t t See t= ———. 2n_ gubstitde |- i a ut [esaauesaaa ae aaa < ]\Nonelementary Recllion Whose stiockiometyy does not matelh tts Kinatics Stivcbiomebry Ay+ Stl, <— ANHy i,” K GIDEA Kee fH) “ee @ide= vate of Pamation — robe of dussofeannce ef osnmone, & OMnAo Kier © Kin Sieg non- elamento: f,4 = ON - OP His Kineticg of the steeacttion anda tthiat Hie reo.ckion GS on ~ elementary we may postulahe a gelice of clomontam, Bteps de explain the Knahe fs <=> ant +8, = — AQ+ & t+ eS AB uncbseived) ateveredinSes 1D Gime steditaafla : Clee Co bg-r Tas Bo oSShy: 4) Sion andl Polar Substances: Ss pea wy, NY cHpH, jit 3) Molecules ArR—>s RSdlernadiateis weaall, reacfive - LD, Transition compexes. Nine Que —— Grtermadiotiay? > Reduobe ae 7 a 1 Reaofant —?(Ziter madrobe) Paglia (6lator madeadS! +Reochau —>Clabempadliote) : : + \roduk | ” S: fee voLiaad Veen oA media wien 3 + Ry, <> arr \ Treen ey Dalf ed ae te fen 5 "2. BW, SQW Lanattennns Teriuhy Bee Hy == Bar +H” Pedpagain Wor Gy << SHBy + By Probupho- BEY ron alin Rem (piso ante) A ang — meee deen = KCatLe) Mi= constant (Me) he Atenas cs Gerad CA a enzyme) —e R + eneyre Qk enzyme - din credaion, ! 3) Trancitien onmpler ,o% “4 w @ugd2No > Coe 7M crn aA — R*S ere fone | ne p +A > AF +A cendtion of energie molecule ' \ Ane" A+A Poimakien +o stale fore, | by cell gion ph —PR+S_ Shotancous ducmlpesitten | nko Yoroducks. (9 0g 2092 TESTING KINETIC MODES Anhese elementary swactions we hystese dia exlctence a} eitier of 2 types of intermediates. Type -1 = Unseen and unmeaawwad nkexmadods ? Cd is gral and 403 ~o this js eat steady stati afpproximakien. “Wpe-2- saneeerias catalyst of anitial cone. GJ =(el+e) Site Ossie eitfeble au = =0 ov dint @ as fn | Quilibrium eee Neon) ut) romney hoe K=O Ke Calle) 45 Tembrokure dependank berm F arake equobien 7 = BCemprtwe) - & (eompesitien) =k § Concentration) Prehenius lavo ~/R Ke toe 2 £(+- Lot = Jn ve E(+ +) = (nk Vex Sud Yr wa straight ae et | % large for Sooge valuos Of Oe ten te igh activation enegy veg ne - aoruitive. an - Readtion ig more tomprabee senfitive af a “ee SEARCHING cor a Thee axe 3 axcos d Syuealligettion al a sunckion, | dts thodlgomuby , te Kindics ancl dhe | machari sac. MECHANISM | 1). qoupliated sbioddiomabry or enc Stat foie. suaction cenlitiens or extent ct *Us alsase evidence of multiple reactions. & Btiodlometn, Pon Quoged wfPose ; | veackion O¢ cto eee a Peer 4B OOOO No ebrnen} suactions wit. mole culasity cc tin cthree hove Jean obsowed te 3). The Combasdigon of th utioddiomatric, eapotien Leis. tha exbestimental Kinetic exprestion con Suggest iflitor or not webe daaling waist. _ Ghvichly Sheaking the seaction softs Mould be. Lauitten Sn tex og ¢ ths acbivities A= Yue; Ulsa y; se dhe activity Coefficont. Yer Kate = Ki Gata? (BE - PD xeackion fay a storclhiometria equafien A+8 =2R Overall orci is 2,/ wrt A & ‘vort @ = bpiven dtu swactien, collaf us bth, slafiien f dic suaction compnin. eng tJe =O om oe Gaath; Se Date (——!= a pA + B.'= = Sote exressi on | a _—%n =< 7 oth stn sp i tbh A+2B =2R+S — _ | of clissopeaxnce of dttbstonce— os_given by _ -% = 1360 [A] [£e) pol 7 7 7 6+ frar ms : : L mol ye fot = Gnots x4 a . fal also he 2 Contant, — rP-3 ms x mol Seo LC CerFaln wxeaction has a vate given by i. = 2 005 2 mol/ems- min if a ne 4s to Ge exbressed un mole/Liter and “he bee wien fixes fours hak usill be tte, Value and anifs of ete. constort. => -% =o [05 Oy > 6-019 I K= ol), (liter) ee Gitex). Lime Gmorye eamwicneca ram li se c= 5x60 _mol b (literX hy) ~% = 300 mol _ Fr 30065 Gter)Cnr) — New value of K= Soo hter) @el)(time ) dh - 2:66Fh elena ate | 7 2 | nels: ‘ — dR = = Bs “oR _ aE po ape kB — Ge Ce "Coe The rode $e peel. — Ht be a aR = Co RT van tee ae - AG, = AKG of mote constant oe 4 {| alt | ; a = AG = i : 120-829 J a a | deg = 0: ie xX Yoox 8. Ha a OX B66 — | ot _ _ mol!l-h | Date — /— /—__ sae _—}— — tee oy en ae = i eta ee Steet | k 5120-2 W/melsh “| Ke 1w0.9 x el Boxe) — a opus oe ke 8.38 x15 Yard: se 4 ee I aa =i ianaseisssaae eee n ol umn ex eld hi oe =a Hee oak Aun 5 elo » Soe by dhe Sn Gksen— Pn 189%, BF Dlbear al Pot dies. ofa clestng se waa, ——____ dapentlonk on Tite fembratue an given by | Gumbo of links 20 pis) +40 bourbon ee Gani nk _ — ao Sp, dhat dha alta - “tia mushalesRic hata oe “adiedion-ensigy 2m S/mnot_of Suase | F __ adote 39 temp range Go—8O—____| ate |r no dud 0 Ver r _ 88 460 20 9.995% YR ee oe Ce _ BY age Bo B-WOII + O41 AU args a 85583 4 OF x16 at 4-8 Be opag 02 Lp 1 | yor i a = | ie, ae ae yh — + N20 wt No + Vo Tye = Ki Los [+ kKCn,o) [>> Ko [nod =P Qnd order \<< Ko PNG) =p ley ovder NO, zat NO + uh x Ne Sy io, [NPs Pate + Ip O0 Sager Bue. chee! 28 coniistont Je sand eon Loin athe “Vist ovdex droowbeirtion nee ° wbexton -2 [aes] = ki (a,05]- & [Noe] no¥| ~a Lees] = eLuog ]+ Ke [wos l[wes a -a Ose] = #4 (ue) - Cae | Gx stent stale ae seers so _|- —_=«iss “cn let] —Kolvest] =0 -@ (NO™] = Kes/ic, 8 ne + + vate Wor) = — | on -_ "coat AT SL pel * atid enbaray ejeo el eisei = “elu Coes] ___ Bg t to wog) [——————— when Kg>> Ko we can neglect The Bo Cito.) —.o AEah KeCNoy) TA voint become {st Oder 2)2 The ecompesi ten rawr heirs, ore sate 8) ST a mechorPem sivfloy db azomettiane dreoupesie Hf veactant A at Gode 2£en 1 and ioatm Plows a fret lauo A+ pe AF a p* EP Rag SB consistent Loe tha cboseved) Kinsticn Difbrent mecharfems can be Ysopeted do eublain \St ord Kinabicn Co Cain at tig medloutyw dg correct Sn ¥he Coo A thie ont albernal ves deaquines odldiitional evidence. , ~A TAD = KiCal — Ko [oA )(0) at ~ACet] = QC] - Y Laks ve Cet (A) at Sor steady wake ~ at =< gl a -ucAl -O- a7 [tere CA) = Hela)” b= ao | =) = cel = ae = All _ ele Ta ge uf "e +*2CA ye > fa atigh nd odbiden es ae ae a) TE ee > Kg = TE uth Ve conn roy, Sap = a CA” : Ae Tee +t a pdms GkeCa) a : ~ OO. EER) won brevet e Ahad en? wal AYE & 2X fie unatoduad curye 2 xX SS RVE ~ ahd - _ylalce) +46 + 6b Ae). ay, (OLE DS - 603 KBE age = reemiced eb} ee 2 ce ee el ee ~¥5 (03 Char Scientis A+e oS x wit 20 on x Se BE 7 (e)\-(+05 fra the sete fem Ya in terms of ca S(Esl vy % and ¥, does Q) Ist mechanigrn given and mechanism gren n - SX = Gd= 4K) ia Ore Ke, €-€d -& Gd= 4 (eI(e.- x3 a=" 60s aan — 4 Disndharkap eo a a AY: Date __ /—_ /— Bah Rk Design Copalien for = + Sati-Sanle cberalion ‘ rl -Lesting new | prccesses Shor ave wid been Filly + The mmonufocke of “exhonsive paduch, asd «| Roceases thal aso “ffl do Conved to conkingw. : _orpouien. oe — Best re of dh) con convesSong_tthak can be ebbcired Shee seoaant tin the swockor | im long i oan “Hi labor © casts per pax bate, 2 via Bally ef ee Rom bald te dhate, ond) ita defy & loxge gede production! = rag gona nde balance enpafion, : ye fey! ot fy NV - . AN = — at A re. Be = =YpV => dt = _aNa Vay += N, = Nor Nox = = Nyol (5%) oe eee | —Yav | | Nai ~My SSE —_ > | = O-e=Nao AX 1 | ae a ae i { Mods = = Ah = Yay ae — dts = —thefas _ 3 Continous-Flow reactors re * Continous — Stived Lank yea: * Bug - Plow veackor : baciy ~ bed suactor, (ar) Class notes Bote Reaclov clesign Equadiion ~ Srnalt salle ovperakion ‘ testing new \prece ates Gal oo. not been (at, Dovdlped : - The manufackuxe 4 expensive frwducts ~ Processes hak axe. Ja PRiowtt +o convert to conkinews orperoHior g. ~ Advantages Of Reef, eonvenion Rat aon be obkereal Qearfing dea veackiwk Snthe tecnofsy Por long pena of tiene, —Disadvankages ef BL (abor ceate he vasiads ty vets Boe bat. aces BiGierdty of lange scale \produchlen. AY Continous Sfirred Sank veachor STP) Also Known as vob , or back min yeackor Vereoily uackt for Diguid plane sanctions . Normally Crpouitid at steady state. “Pesumed de he pedectly erixal. “Consequendby tase 28 no ine dofperdonce ox ecivan Suberdonce af tompredwu, ,concenkmbion ,of reaction rite Gncido ke CSTR. Samo ads Whe ert poral. Design custige fora. ese y,av = aN 7 «fy : fi Bic fuav= V4 rsa stab te - Ve Volume of content ie quid oh Kn. y V % C= Aloo wate \VO= Vo Cpo -Vln Th tt Design equations fer £ Flove Teaco x Holor nalit al lice fetees poe Sach Ais at er A a in tla Syste fed. oR syslem et en (fe) - fos ® fhe Fr Ae *) = for aad syste , Shir vausrabic flow vote , Vv, $6 constant and eqpal te \, - for gpa aytlern , Cho Can be catieuttiBas! How! fa enkesting ode Rrction, Yro. ~ (Me foubrabuce Fo and dtu Sac gas Sow of Save ORex gan lar. Cro = Po Yo, RT Rt. CSTR desgn eqcblion ~ Well nfined sulla Hh ace no eadQ Vastiabions, dn tthe veaclor, fox Oa gene) Veacths.. At o,® —» oe « ay V= Gof G2 ive “th Tedeg-venaked Y= Fo (Fay Fac) Se Vea Fa% & Wek HW lub ose Plows “‘Rooatoy (TT RP) = A oyfendbiical pipe aS Nowme 044 ohporollad) ak ead Sehr . - Treat of fen Rx gon pore wwooklons E Concentimiion and Conce quorily jhe ceoalen Tobe A asy Conbinowly Sle anciad hireobion Horousl . xeadey Brall but tte Zexo ordlan sea kon, ~ Theve 28 no vadRal vasSation an veadtion vals, And Ra Teaakox ue Toa flag- How ys Va av Molay Plow + Mielaw Ploworalt| eos abs. Welaoe woe 25) 6} shecies.) [a | Ob Spectea J 2 j In ak v out ak Viav * termi Mohortinne Mdes/ om ri In + Greruxatione Te Filv 7m ac ee | ~ ag | =X filvae - Flv Gon 9 av Sb af, av “* Cangicten, +f Leomotadlion -f\ Se A fo (i B, fo, 7 vy ve D Ve ‘ Ath iy ( ho % coal) fro a | \ * F229 68 04 Anan D2ing Continous flow eaclors = Ky = Key (I-74) pe #kls) | L Siztng - delernine te reactor volume fer Shecified comersion. i reackton is cossied ae oe oe ey week te denhabign of | | te gveataat Lie 1S san a | 2 niftle sansa * Hence resiprocald ate Chr) wa Foy ryeverible an A —POQ+c as XL, Vy —eO The oe Gain Pre Veto Y Caathi — fa, = Gye Foe — a Hide balance on eather 2.2. s A mole balance en reads \ gives In — Ouk + Lenwation =o fo - Al + “Yay, =o Fo = Feo — Fach Me Fok, Yay ae ed Qn Macher Q a ee a eee ee v= "a =F The hee Ene = Fao Xe -%1) Me G(% x) HEL oR on 6s 48 L 4, - et eee ee oo Abbvoximadiin a umber CSTR'S din a "a me | Ve — y || Date 6 , el 22 _Gaarhiy —— | [te ‘thes -more_number of staaslors Loe use | ond ite volume _2e -acroaiing, So ‘Aha ot ee te ao shlrlrmrmC—C—C : fm Gane ha 00a Aci Ye too snuck ax. each | Yeachoy JB req Pies a. Seber _selulp SN L 102 dbtinmige a == Pee CER tn gevfog | We sow Rat 2 Cste’s § Sn seston gow E _ total valune > fon a_i CST R foe ta —_||Same_conversien . TV8s Case Moca | net Cold) trug | o dor Ro 2 _ lug Plovo Teachors Pn geruen. = lly. 2 C87 eye loss vane? | © || When the. fined conc soy Bred Sn bot | aig at elie nenabe iS samo __| Land) ucQon Gaathi) y af ae rate ga ouplace 2. gf ere _ Continous?! FR —Requined to ad)8ve : ems [Reootor a > Vy [ee Ya jee al ‘Rexckor Qa Ve = eZ) De Fniti ona & Shoce time Chddiing time oy_mean, vrecidunce sin co VAL Fora PER yo | t= fe = Cn di ak Ye % | oe lh aCSTR B4+c O! 62 63 o& of 0G oF OF OF _ eas dh 7 — “heeeforiyhe 1 Nelume cee ese cB wy eal CSTR ‘ Y -- Sao00 PER 8 4 {ire CSte Bf Yoo -egtR 3 (b dor Pre Q 2 MMe FH bono On duty the fovenshizal lot Salo Ixoe

    You might also like