| | 16 sf Na,CO,10H,0. (1-56 x 4,2, ber of oxygen atoms in 02 mole of Na,CO;10H,0. (1.56 x 1% he nur » gyCalculate # i 100 mL of 1 he number of moles of CuSO, contained in M caso, 6/Calculate the sot ions in it. 1 mole, 0. ution. Also, find the number of SO, fons int (04 mote, 0.6022 198 solution. Also, sent i £ °C atoms. (12 x 6.022 x 42 7 Find the total number of nucleons present in 12 g of ¢ 2102 2 Fin a Find (j) the total number of neutrons, and (ii) the total mass of neutrons in 7 mp 8/Find (i = a hydrogen atom) of a neutron = mass of a hydrog: of "Ge (Assume that the mass (2408810049) [Hint 1 ¥C atom contains 8 neutrons. 8 : 3 P? (Lm? = 10° litre 1 metre’ of any gas at NTI tres) 9. How many moles are there in 1 met en 10.3 g of a salt of molecular weight 30 is dissolved in 250 g of water. Calculate the : molality of the solution. (0-4 m) 11. Calculate the volume occupied by 5:25 g of nitrogen at 26°C and 74.2cm of pressure. | (4-71 litres) 12, Find the ratio of the number of molecules contained in 1 g of NH, and 1 g of N,, (28: 17) How many molecules of CO, are contained in one litre of air if the volume content of CO, is 0.03 % at NIP? (8:06 x 10") 14. Is the number of molecules in 1 kg of H, and 1 kg of O, the same ? What is the ratio of weights of H, and O, , the mixture of which contains equal number of molecuiles of each gas? (n0, 1: 16) 15. The measured density at NTP of a gaseous sample of a compound was found to be 178 g/L. What is the weight of 1 mole of the gaseous sample? (399 ) 16.If the concentration of a solution is 2 M calculate the number of millimoles present in 2 litres of the solution. (Hint: Follow Rule 5.] (4000) 17 How many moles of oxygen are contained in one litre of air if its volume content is 21% at NTP? (0.0093) 18. How many atoms do mercury vapour molecules consist of if the density of mercury “aPour relative to air is 692? (Hg =200). The average mass of air is 29 g/mole. (One) 19. Calculate the total number of atoms in 0-5 mole of K,Cr,0,. [Hint: Follow Example 19] (31x 10") 70. What is the volume of 6 g of hydrogen at 1 atm and 0°C? (672 litres) 21. What is the density of oxygen gas at NIP? (Hint: See Example 14] (1-429 g/L) 22. Calculate the total number of electrons present in 18 mL of water. a (10x 6-022 10")Elementary Problems Based on D n of Mole: The Mole Concep' 7 lems Based o1 finition of Me e: The Me 23. Calculate the ne number of electrons, protons and neutrons in 1 mole of "“O- n ‘ole of “O"? ions. pee : (10 x 6-022 x 10", 8 x 6.022 x 10, 8x6002% 10") aay Ona aoe the nitrogen contained in 1 kg of (i) KNO,, (ii) NH,NO,, and ; if ; a JNO, , an [() 1385 g (ii) 350 i 5 350 g and (iii) 212 2: a the mass of each element in 7-84 g of FeSO,. (NH,) , $0, O i e the volume of O, at NTP in this sample? st fier (3-136 litres) 26. The density of solid AgCl i ‘ BCI is 5:56 g/cc. The solid alternate Ag* and Cl” ions at a spacing of 277A toa maaan a data calculate the Avogadro constant, eet (6:04 x 10") 27. Three atoms of magnesium combi: a ine with 2 atoms of nitrogen. WI weight of magnesium which combines wi eo eee : °s ith 14 es with 1.86 g of nitrogen? j 4.86 g) 28. 600 mL of a mixture of O, and O, wei 00 il of sabes OE }, weighs 1 g at NTP, Galculate the pie Ee m 29. The vapour density (hydrogen = 1) of a mixture consisting of NO, and N,O, is 383 at 26:7°C. Calculate the number of moles of NO; in 100 g of the mixture. [Hint: Wt. of NO,=xg. ». obs. mol. wt. (wt./mole) = ET oles = S & a6t (0-437 mole) 30. A nugget of gold and quartz weighs 100 g. Sp. gr. of gold, quartz and the nugget '3, 2-6 and 6-4 respectively. Calculate the weight of gold in the nugget. 100 100 we . yi x= wt of gold) (686g) m of X is supposed to be a sphere with a radius of wucleus if the atomic are 19: 31. The nucleus of an ator 5x 10°" cm. Find the density of the matter in the atomic ni weight of X is 19. : __ mass of 1 mole(ie,, at. wt) [ Hint: Density = vol. of Imole | (602% 10" g/mL) copper, twice as much oxygen oxides. For the same amount of is the ratio the first oxide than to form the second one. What t and second oxides? (0, and Cu,O, and apply Rule 6} (2:1) NE, gas, producing a solution of of NH, by weight, calculate its Copper forms two was used to form of the valencies of copper in the firs [Hint: Assume that the oxides are Cuy water (4°C) is saturated with 33, 105 mL of pure .L. If this solution contains 30% density 09 g/m! volume. total mass__ 105 (H,0) + 45 (NH) [Hint: Density = total volume Vv 34. How many iron atoms are present in a stainless steel of 0-1 inch (1 inch = 2.54 cm)? The stainless steel cont has a density of 7-75 g/cc. } (166.67 mL) 1 ball bearing having a radius tains 85.6% Fe by weight and ~ — ag1x10")maa oo = 15 g/cc.) must be measured out to conta ow many litres of liguid CCl (a=15.8/ (61 Ly 5 CCI, molecules? ) votato starch was grou cular weight. The pro 10 contain one a 35. He 1x10" . ind in a ball mill to give a starchlike molecule duct analysed 0-086 % phosphorus. If each tom of phosphorus, what is the molecular (36 10" amu) 36. A sample of P of lower mole molecule is assumed | weight of the material? about one microgram. Assuming imate number of atoms of carbon (5 «10 atoms) The dot at the end of this sentence has a mass of that the black stuff is carbon, calculate the approx! needed to make such a dot. (1 microgram = 1x 10°°g) 37. S (0 M H,80, be diluted in order to make 2M 38. To what volume must 50 mL of 3.5 HS0,? [Hint: Use Rule 5] (875 mL) 39, Sulphur molecules exist under various conditions as Sy S, Sy S, and S. (a) Is the mass of one mole of each of these molecules the same? ‘ole of each of these molecules the same? (b) Is the number of molecules in one m {@)Is the mass of sulphur in one mole of each of these molecules the same? f atoms of sulphur in one:mole of each of these molecules the (@) Is the number o same? (No, Yes, No, No) Two minerals that contain Cu are CuFeS, and Cu,S. What mass of Cu,S would 40. contain the same mags of Cu as is contained in 125 Ib of CuFeS,? (642 b) 41, What is the maximum number of moles of CO, that could be obtained from the carbon in 4 moles of Ru,(CO,),? (12 mol) 42. What mass of NaCl would contain the same total number of ions as 245 g of MgCl? (225 g) 4B. ns — sample weighing 15 g was found to contain only Mn and S. The mple was completely reacted with oxygen and it produced 1.22 g of Mn (I) oxide and 1.38 g of SO,. What is the simplest formula for this compound? (Mins) “ i Beto sources of Zn, that is, ZnSO, and Zn(CH,COO), -2H,O, can be purchased sme price per kilogram of compound. Which is the most economical source of Zn and by how much? (ZnSO, 35.9%) My, SOF 45. How many moles of HO form solution rm whe x jon i fin ; A : en 25.0 mL of 0.10 M a ti . completely neutralised by NaOH’ (2.5 x 10 mole) 46. Which ; ; Sad Selon be deer an atomic mass unit based on the current standard or one rth 85 of a Be-9 atom set at exactly 9 amu? (latter) ‘co, tes icon anhydrase catalyses the hydration of CO,- This reaction: via the bloodstream, is involved in the transfer of CO, from tissues to the lungs Meee Hea team™ One enzyme wiblécile Kjdfais 0 maletulés of COs PX 1x10°M ny kg of CO, are hydrated in one hour in one lite by rte 4 (0.1584 kg) 48. An oxybromo compound, KBrO,, where x is unknown; is analysed and found to