MSDS Cloruro de Niquel - MSDS (En 10.04.17) - Anders Peru S.A.C.

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Safety Data Sheet

acc. to Regulation 1907/2006/EC (REACH), Article 31
Printing date 04.10.2017 Version number 122 Revision: 04.10.2017
* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name:&+/25,'(1,&.(/+2
· Article number:
· CAS Number:
7791-20-0
· EC number:
743-0
· Index number:
011-00-6
· Registration number01-2119486973-20-[[[[
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixtureChemicals for synthesis
· Uses advised againstRestriction under Regulation 1907/2006 (REACH), Annex XVII
· 1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
$03(5(,1'8675,(
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· =$,GHV%pWKXQHV
· 6DLQW2XQHO
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· 1.4 Emergency telephone number:25),/$,156
· 8.
* SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS06 skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.

Acute Tox. 3 H331 Toxic if inhaled.
GHS08 health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350i May cause cancer by inhalation.
Repr. 1B H360D May damage the unborn child.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
(Contd. on page 2)
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GHS09 environment
Aquatic Acute 1 H400 Very toxic to aquatic life.

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.

Skin Sens. 1 H317 May cause an allergic skin reaction.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS06 GHS08 GHS09
· Signal word Danger

· Hazard-determining components of labelling:
nickel(II) chloride hexahydrate
· Hazard statements
H301+H331 Toxic if swallowed or if inhaled.
H315 Causes skin irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
· Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
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* SECTION 3: Composition/information on ingredients

· 3.1 Chemical characterisation: Substances
· CAS No. Designation:
7791-20-0 nickel(II) chloride hexahydrate
· Identification number(s):
· EC number: 231-743-0
· Index number: 028-011-00-6
· Dangerous components: Void
· Additional information For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information
Remove contaminated clothing.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing Do not induce vomiting; instantly call for medical help.
· 4.2 Most important symptoms and effects, both acute and delayed
· 4.3 Indication of any immediate medical attention and special treatment needed
* SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Hydrogen chloride (HCl)
- Chlorine (Cl)
- Nickel oxides (NiOx)
· 5.3 Advice for firefighters
· Protective equipment: Put on breathing apparatus.
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures Not required.
(Contd. on page 4)
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· 6.2 Environmental precautions:
Inform respective authorities in case product reaches water or sewage system.
· 6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
* SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Open and handle container with care.
Prevent formation of dust.
· Information about protection against explosions and fires: Keep breathing equipment ready.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Storage class LGK 6.1 D
· 7.3 Specific end use(s) No further relevant information available.
* SECTION 8: Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or
longer exposure use breathing apparatus that is independent of circulating air.
· Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
(Contd. on page 5)
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· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Safety glasses
· Body protection: Protective work clothing.
* SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Solid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value at 20°C: 4.5
· Change in condition
Melting point/freezing point: Not determined
Initial boiling point and boiling range: Not determined
· Flash point: Not applicable
· Inflammability (solid, gaseous) Not determined.
· Ignition temperature:
Decomposition temperature: Not determined.
· Self-inflammability: Product is not selfigniting.
· Explosive properties: Product is not explosive.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not applicable.
· Density at 20°C: 3.55 g/cm³
· Bulk density at 20°C: 1.15 kg/l
· Relative density Not determined.
· Vapour density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Soluble
· Partition coefficient: n-octanol/water: Not determined.
(Contd. on page 6)
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· Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
· 9.2 Other information No further relevant information available.
* SECTION 10: Stability and reactivity

· 10.1 Reactivity No dangerous reaction known under conditions of normal use.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Possible in traces.
Hydrogen chloride (HCl)
Chlorine
In case of fire: see Section 5.
* SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity
Toxic if swallowed or if inhaled.
· LD/LC50 values that are relevant for classification:
Oral LD50 200 mg/kg (rat) (Acute Oral Toxicity)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity
Suspected of causing genetic defects.
· Carcinogenicity
May cause cancer by inhalation.
· Reproductive toxicity
May damage the unborn child.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure
Causes damage to organs through prolonged or repeated exposure.
· Aspiration hazard Based on available data, the classification criteria are not met.
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(Contd. of page 6)
* SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity:
LC50/96 h 17.1 mg/l (Oncorhynchus mykiss (rainbow trout))
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Very toxic for fish
· Additional ecological information:
· General notes:
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Harmful to aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation Must be specially treated under adherence to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleaning agent: Water, if necessary with cleaning agent.
* SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN3288
· 14.2 UN proper shipping name
· ADR 3288 TOXIC SOLID, INORGANIC, N.O.S.
(NICKEL CHLORIDE), ENVIRONMENTALLY
HAZARDOUS
· IMDG TOXIC SOLID, INORGANIC, N.O.S. (NICKEL
CHLORIDE), MARINE POLLUTANT
· IATA TOXIC SOLID, INORGANIC, N.O.S. (NICKEL
CHLORIDE)
(Contd. on page 8)
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· 14.3 Transport hazard class(es)

· ADR
· Class 6.1 (T5) Toxic substances.

· Label 6.1
· IMDG
· Class 6.1 Toxic substances.

· Label 6.1
· IATA
· Class 6.1 Toxic substances.

· Label 6.1
· 14.4 Packing group
· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Product contains environmentally hazardous
substances: NICKEL CHLORIDE
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Toxic substances.
· Kemler Number: 60
· EMS Number: F-A,S-A
· Stowage Category A
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· Transport/Additional information: Not dangerous according to the above
specifications.
· ADR
· Limited quantities (LQ) 5 kg
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· Transport category 2
· Tunnel restriction code E
(Contd. on page 9)
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· IMDG
· Limited quantities (LQ) 5 kg
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· UN "Model Regulation": UN 3288 TOXIC SOLID, INORGANIC, N.O.S.
(NICKEL CHLORIDE), 6.1, III,
ENVIRONMENTALLY HAZARDOUS
* SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· EU regulations/legislation
· Regulation (EC) No 1907/2006 (REACH), Annex XIV not applicable
· Regulation (EC) No 1907/2006 (REACH), Annex XVII
Restrictions must be observed for:
Nickel and its compounds (no. 27)
CMR substances (no. 28, 29, 30)
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I Substance is not listed.
· Seveso category
H2 ACUTE TOXIC
E1 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 27
· National regulations
· Water hazard class:
Water danger class 3 (German Regulation) (Self-classification): extremely hazardous for water.
· Chemical safety assessment: A Chemical Safety Assessment has been carried out.
SECTION 16: Other information

The information contained herein is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
(Contd. on page 10)
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PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 3: Acute toxicity – Category 3
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 2: Germ cell mutagenicity – Category 2
Carc. 1A: Carcinogenicity – Category 1Ai
Repr. 1B: Reproductive toxicity – Category 1B
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered.
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EC number: Nickel Chloride CAS number:
231-743-0 Generic Exposure Scenarios 7718-54-9
Nickel Chloride
Generic Exposure Scenarios
(as presented in the Nickel Chloride Chemical Safety Report)
September 2010
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TABLE OF CONTENTS
1. Generic exposure scenario for nickel chloride production ...................................................................... 3
1.1 GES 1: Production of nickel chloride from nickel matte .................................................................. 3
1.1.1 Summary of the secondary poisoning exposure and risk characterisation assessment for the
production of nickel chloride from nickel matte ............................................................................ 12
1.1.2 Porewater concentrations in the soil compartment for the production of nickel chloride from
nickel matte .................................................................................................................................... 12
1.1.3 Atmospheric compartment for the production of nickel chloride from nickel matte ..................... 13
1.1.4 Exposure concentrations in on-site waste water treatment plants (WWTP) and sewage
treatment plants (STP) for the production of nickel chloride from nickel matte ............................ 13
1.1.5 Man via the Environment exposure and risk characterisation assessments for the production
of nickel chloride from nickel matte............................................................................................... 13
2. Generic exposure scenarios for downstream users of nickel chloride .................................................. 14
2.1 GES 2: Metal surface treatment – nickel electroplating, nickel electroforming and
electroless nickel plating ................................................................................................................... 14
use of nickel chloride in metal surface treatment ........................................................................... 19
2.1.2 Porewater concentrations in the soil compartment for the use of nickel chloride in metal
surface treatment ............................................................................................................................ 20
2.1.3 Atmospheric compartment for the use of nickel chloride in metal surface treatment .................... 21
2.1.4 Exposure concentrations in on-site waste water treatment plants (wwtp) and sewage treatment
plants (stp) for the use of nickel chloride in metal surface treatment ............................................. 21
2.1.5 Man via Environment exposure and risk characterisation assessments for the use of nickel
chloride in metal surface treatment ................................................................................................ 21
2.2 GES 3: Use of nickel chloride for the production of nickel hydroxycarbonate............................. 22
use of nickel chloride for the production of nickel hydroxycarbonate ........................................... 28
2.2.2 Porewater concentrations in the soil compartment for the use of nickel chloride for the
production of nickel hydroxycarbonate .......................................................................................... 29
2.2.3 Atmospheric compartment for the use of nickel chloride for the production of nickel
hydroxycarbonate ........................................................................................................................... 29
treatment plants (STP) for the use of nickel chloride for the production of nickel
chloride for the production of nickel hydroxycarbonate ................................................................ 29
2.3 GES 4: Use of nickel chloride for the production of nickel metal - Electrolytic refining of
nickel matte via a nickel chloride solution (Hydrometallurgical process) .................................... 30
use of nickel chloride for the production of nickel metal ............................................................... 36
2.3.2 Porewater concentrations in the soil compartment for the use of nickel chloride for the use of
nickel chloride for the production of nickl metal ........................................................................... 37
2.3.3 Atmospheric compartment for the use of nickel chloride for the production of nickel
treatment plants (STP) for the use of nickel chloride for the production of nickel metal ............... 37
chloride for the production of nickel metal .................................................................................... 38
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1. GENERIC EXPOSURE SCENARIO FOR NICKEL CHLORIDE

PRODUCTION
1.1 GES 1: PRODUCTION OF NICKEL CHLORIDE FROM NICKEL MATTE
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(&
:
; 6 3 $ .0$ .0.. 3( (&
!
; 6 3 .09 .0$ .0$9 3(
(& !
1 5 6 3 .0.- .0.4 .0 9- &
& (&
&
1 5 6 3 .0.- .0.4 .0 9- &

& (&
&
$< ! & ! ' ' 0

H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
'
# %2 & ! 0
= "1 "(& # #
(&
=
; 6 6 5 # 5
SDS : 040292 8 18/48

; 5 # 5
6 6
1 5 6 6 5 # 5
1 5 .0...44 .0...3 .0 ). &

6 6 (&
+ #
'
D + 6
7 -8,
'
5 & !
! ,
:
; 6 3 $ .0.$ .0..$ 3( (&
!
; 6 3 .09 .0.$ .0. -9 3( (&
!
1 5 6 3 .0.-$ .0.. .0$ #
&
(&
& ! &
&
&
0
1 5 6 3 .0.-$ .0.. .0$ #
&
(&
& ! &
&
&
$H & ' & D ! +;"=, ' $. I (& + *H;,

& ' & .0.$ 6 30
4
# % 0 ! & '
= "1 "(& # #
(&
=
; 5 # 5
6 6
; 5 # 5
6 6
1 5 5 # 5
6 6
1 5 .0...44 .0...3 .0 ). &
6 6 (&
+ #
'
& ' + 6
7 -8, '
5 & !
! ,
SDS : 040292 9 19/48

:
; 6 3 $ .0$4$ .0..) 3( (&
!
; 6 3 .09 .0$4$ .0 3( (&
!
1 5 6 3 .0.-$ .0.49 .0)4 ' &
(&
& /
&
1 5 6 3 .0.-$ .0.49 .0)4 ' &
(&
& /
&
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
5
# )%
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 5 # 5
6 6
1 5 6 6 5 # 5
1 5 .0...44 .0.. )9$ 09- + , 9- &
6 6 (&
&
0 0
"(&
.04 3.
+J.0-,
'
' 0
:
; 6 3 $ .04 - .0.3 $.(
(& ! 0;
$. '
& '
& 0
; 6 3 .09 .04 - .0 $ $.(
(& ! 0;
$. '
& '
& 0
1 5 6 3 .0.- .0.4 - .0 9- & !
&
(& &
0 &
1 5 6 3 .0.- .0.4 - .0 9- & !
&
(& &
0 &
$< ! & ! ' ' 0
H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
SDS : 040292 10 20/48

6
# .%
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 5 # 5
6 6
1 5 6 6 5 # 5
1 5 .0...44 .0....3 .0. ).
6 6 &
(&
+ # $.
'
5 & !
! 4
(
& ,
:
; 6 3 $ .0$$$ .0..9 3( 5 !
; 6 3 .09 .0$$$ .0$ 3( 5 !
1 5 6 3 .0.-$ .0.39 .094 >
& (&
1 5 6 3 .0.-$ .0.39 .094 >

& (&
$H & ' & D ! +;"=, ' $. I (& + *H;,

& ' & .0.$ 6 30
5 - # & &
#
% " " :* + ' % &%66'''0 5 0 6 5 ;5 (6 5 5 ,
' ! %
# ' ' 6 ' '
0
" D ! && !
+ && ,0
" & && !

+ && ,0
/
D
& 0 & / ' ! && &
= "1 + K$.8 & ,0
SDS : 040292 11 21/48

1.1.1 SUMMARY OF THE SECONDARY POISONING EXPOSURE AND RISK

CHARACTERISATION ASSESSMENT FOR THE PRODUCTION OF
NICKEL CHLORIDE FROM NICKEL MATTE
The methodology applied to assess secondary poisoning is extracted from the European Union Risk Assessment
for Nickel (2008/2009).
. & , " 7 (
$! % $ ! %
" 6 " ;D
" 6 " ;D
"
" ' + " + , +" &
+ 6 '
61, ' + 61, " L$ 03 6 F , " L 03
,
#;2L$ 6 F
#;2L.0. -
.0..33 .0.. ) .0 4 .0.9 .0..)
. ' + , " 7 (
$! % $3 % .&
" 6" ;D " 6 " ;D
" + , + ,
+ 6 ' , " L$ 03 6 F " L40 6 F
" " #;2L$ #;2L.0. -
' + 61, ' + 61, 0 0 0 0 0 0
& & &
>;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9.
6 6 6 6 6 6
.0...9 .0...3 .0 3 .0$4 .0.9 .0.$ .0..- .0..
. 4 . " & 7 (
" " 6 "

" 6 "
" * M
" 6 "
# * M + ',
" > + ',
3.8 3.8 '
& + , $..8 '
$..8 ' 9.8 &
+ 6 , " L 0- " L.0$
+ 6 , ' 9.8 " L.0$
6 #;2L$ 6
+ 6 '', & 6
#;2L.0.3
+ 6 '', #;2L.0. -
04$ .0)
$ 03 $ 0 . .0 .09 .0 $
1.1.2 POREWATER CONCENTRATIONS IN THE SOIL COMPARTMENT FOR

THE PRODUCTION OF NICKEL CHLORIDE FROM NICKEL MATTE
The derived PECporewater for the generic scenario is 0.026 mg Ni/L (with sludge application).
SDS : 040292 12 22/48

. 5 ) $ % &
" & ' + 61,
.0.
1.1.3 ATMOSPHERIC COMPARTMENT FOR THE PRODUCTION OF NICKEL

CHLORIDE FROM NICKEL MATTE
An overview of the local air concentrations and PEC in the air compartment are provided in Section 1.1.5 Man
via Environment exposure and risk characterisation.
1.1.4 EXPOSURE CONCENTRATIONS IN ON-SITE WASTE WATER

TREATMENT PLANTS (WWTP) AND SEWAGE TREATMENT PLANTS
(STP) FOR THE PRODUCTION OF NICKEL CHLORIDE FROM NICKEL
MATTE
. 6 reports the calculated Ni concentrations in the effluent of the on-site WWTP. For the generic exposure
scenario it is assumed that the wastewater is not connected with an STP.
. 6 7 & &
5
(& HH* + 61,
" 2 ' .0 4
" .0 4
1.1.5 MAN VIA THE ENVIRONMENT EXPOSURE AND RISK

CHARACTERISATION ASSESSMENTS FOR THE PRODUCTION OF
NICKEL CHLORIDE FROM NICKEL MATTE
For each sector, an overview of the range of operational conditions (OC) and predicted Clocal air and PEC air are
given below. To assess whether a site is compliant with the GES, the predicted Clocal needs to be compared to
11.5 ng Ni/m3 or the measured PEC needs to be compared to the DNEL of 20 ng Ni/m3.
. 8 # # &
" N " O
+* 6 ,
+ 6 , + 6*, & + 6 , + 6 3, + 6 3,
$-... $ 4 33. 3 $
*: based on IFDM air model
$: based on Clocal predicted + regional background.
SDS : 040292 13 23/48

2. GENERIC EXPOSURE SCENARIOS FOR DOWNSTREAM USERS

OF NICKEL CHLORIDE
2.1 GES 2: METAL SURFACE TREATMENT – NICKEL ELECTROPLATING,

NICKEL ELECTROFORMING AND ELECTROLESS NICKEL PLATING
' + 9 (" ( (
" P=
P &
&
3:
!
"# -% : (
!
# %* & & + 6 ,
6 ! 6 5
# %* & & + 6 ,
6 ! 6
# $3% * && &
# $-%
# .%
5 & 0
" " # #
Q 5 &R &
$ # %
&
(& " 0$%
" " # # & ! !
$& % (& " 0 %
& '
' ! (
' # )
# P &
"# -% : (
$ # %
5 & 0
" " # #
Q 5 &R &
$ # %
0
"
# * +
"
%= && ( $.. 8 -5-.8

*
+ ) 304 +-. 8 -. 8 ,
+ ) $$ $ +-. 8,
,
H % 33) & & +-. 8,
#
; % . & & +-. 8,
# (
" $= * % $) ... 36
# ( & &
" = % 3 4 ... 36
" $% = * % $..
- " &
" %= %$... + (,
- " $.. + ,
! (# ( # )
. # $ % #
SDS : 040292 14 24/48

. ( "
/ &
" $= * %
5 ' ' & &
" ))0)8
5 ' ' & *
" 4.8
# 5 % $03 6* +-. 8,
" = %
5 ' ' & &
" ))0)8
# 5 % $03 6* +-. 8,
*
* 0
# 5 % $409 6* +-. 8,
!( 0 # 1
# && ! 5 0
& (
+ & ( . $ . % S " $= *
- ( + . ... 36 + ,
2 ( +
* &&
.
) &
' / ' ! ' ! &
0
) # &
&&
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& ! !
P &
/
&
# %* & & + 6 ,
6 ! 6 5
# %* & & + 6
#
6 ! 6
# $3% * && &
# .%
# '
" " # # &
" (&
* + 0" (&
(& * $
%= && ( $.. 8 -5-.8

*
!
, 1 )
; & ! 3'
3 (
# & ! 1 ! ' $. 36
# / ! !
; '
) .
> ' 9.
SDS : 040292 15 25/48

! (# (& )
&& & 0; & (& 0
' & & ! & ' 0 ' ! ' " ;
& ' ' 0
%< ' & &
. # $ % #
; & ' &
. & &
1"C D & ! ! & ' & ' & && && '
( & '
!( # 1 " )
" ( #
: % # " +2 3F ; 2 L ., D
= %< ! & ! D
'4 & ) ( ) ''
& '
P &
/
&
# %* & & + 6 ,
6 ! 6 5
# %* & & + 6 6
# ! 6
# $3% * && &
# $-%
# .%
;
= &&
# !
" " # # #
# ! & 6 '
H ' P '
" (&
* +
0
% -5-.8
*
!
, 1 )
0
= D & ' % & &&
0
3 (
# & ! !
# / ! !
; '
!
> ' !
! (# (& )
& 0 & ! ! & & '
& 0* & & & -59.A 0
! !
& & 0
' & 0
%< ' & &
. # $ % #
; & ' & 0
SDS : 040292 16 26/48

5 %
& 5& &
5 & 5& T ! ' !
; & P 5 & ( & T !
: 1"C ' & D %; & +

& & , && ! & & +& ,0
* ! + ! ,0 ! &
&& 0
. & &
1"C D & ' & &&
! & & +& ,
!( # 1 " )
" ( #
: % # " +; 2 ., D & 0
= %< ! & ! D ' + ,
4 )
#
"# -
P &
& " " # " # #
!
"
2 ' G 61 30-- 0) .0$ 30. .0 ! * 35#H
" $
=
*
2 ' G 61 30-- 0) .0$4 30.4 .0 ! * 35#H
" =
G 61 0 .03 $03 $0 .0$) ! * 35#H
* 6 )0) $ 0 .0 ) $ 0 ) .0- ! * 35#H

" $
=
* 5
&&
* 6 )0) $ 0 .0.. $ 0 $ .0-4 ! * 35#H
" =
/
'
# - # # # $3 # .% & ! !
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 6 6 5 # 5
1 5 6 6 5 # 5
1 5 6 6 .0...44 .0....3 .0. "(&

"; " 0
1"C & &
!
0
SDS : 040292 17 27/48

:
; 6 3 $ .0- .0.3 " 9-
&
(&
4 & ' '
1"C & 0:
(&
40
; 6 3 .09 .0- .09$ " 9-
&
(&
4 & ' '
1"C & 0:
(&
40
1 5 6 3 .0.-$ .0.33 .0 "(&
"; " 0
1"C # " +; 2
., & &
!
0
1 5 6 3 .0.-$ .0.33 .0 "(&
"; " 0
1"C # " +; 2
., & &
!
0
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
''
# # # $3 # $- # .% & '
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 6 6 5 # 5
1 5 6 6 5 # 5
1 5 6 6 .0...44 9($.5- .0$ " 9-
& (&
& !
&
:
; 6 3 $ .0. .0..4 " 3(
9- &
(&
; 6 3 .09 .0. .0.) " 3(

9- &
(&
1 5 6 3 .0.-$ .0. .04 " 9-

& (&
& & '
SDS : 040292 18 28/48

! 1"C &
1 5 6 3 .0.-$ .0. .04 " 9-
& (&
& & '

! 1"C &
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
5 - # & &
#
% " " :* + ' % &%66'''0 5 0 6 5 ;5 (6 5 5 ,
' ! %
# ' ' 6 ' '
0
" D ! && !
+ && ,0
" & && !

+ && ,0
/
D 0
& 0 & / ' ! && &
= "1 + K$.8 & ,0

CHARACTERISATION ASSESSMENT FOR THE USE OF NICKEL
CHLORIDE IN METAL SURFACE TREATMENT
. : & , " 7 (
$! % $ ! %
" 6 " ;D
" 6 " ;D
"
" ' " & +"
"(& + 6 ' + ,
+ 61, ' + 61, , " L 03
, " L$ 03 6 F
6 F
#;2L$
#;2L.0. -
(&
$5 .0..3. .0.. ) .0 . .0.9 .0..)
'
*
(&
.0..3. .0.. ) .0 . .0.9 .0..)
' 5
'
SDS : 040292 19 29/48

. ; + , " 7 (
$! % $3 % .&
" 6
" ;D " 6" ;D
+ , + ,
"
" L$ 03 6 F " L40 6 F
+ 6 ' ,
#;2L$ #;2L.0. -
" "
' + 61, ' + 61, 0 0 0 0 0 0
& & &
>;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9.
6 6 6 6 6 6
.0..$ .0...3 $0- .0 - .0$ .0. . .0.. .0..$
. < . " & 7 (
"
" 6 "
" " 6 "
* M
# + ',
"
* M " 6 " + ', 3.8 '
"(& & 3.8
> $..8 ' 9.8 &
+ 6 , '
+ 6 , $..8 + , " L.0$ " L.0$
9.8
' " L 0- 6 6
&
+ 6 6 #;2L$ #;2L.0.3 #;2L.0. -
+ 6
'',
'',
(&
$5
$ 0 ) $ 0 . 04- $0.. .0 ) .093 .0 $
*
&&
(&
P $ 0 $ $ 0 . 04. .0) .0 .09 .0 .
&&

THE USE OF NICKEL CHLORIDE IN METAL SURFACE TREATMENT
. = ) $ % &
" & ' + 61,
.0.3
SDS : 040292 20 30/48

2.1.3 ATMOSPHERIC COMPARTMENT FOR THE USE OF NICKEL CHLORIDE

IN METAL SURFACE TREATMENT

(STP) FOR THE USE OF NICKEL CHLORIDE IN METAL SURFACE
TREATMENT
. reports the calculated nickel concentrations in the effluent of the on-site WWTP. A summary of the
exposure concentration in the STP is presented in . '. A PEC for the effluent of the STP of 0.022 mg Ni/L
is calculated and taken forward for risk characterisation.
. 7 & &
5
(& HH* + 61,
" $2 ' P * .0.

" 2 ' P ' .0.
" .0.
. ' ) $ % & (
# # *
< "
: & " * + 61,
" 6 "
" L.033 61
" $2 ' P * .0. .0.9
2.1.5 MAN VIA ENVIRONMENT EXPOSURE AND RISK CHARACTERISATION

ASSESSMENTS FOR THE USE OF NICKEL CHLORIDE IN METAL
SURFACE TREATMENT
. 4 # # &
"
N " O+
+* 6 , &
+ 6 , + 6*, + 6 3, 6 3,
+ 6 ,
$$ $ .0. $- . 4 )
( $-.. .0. $- 4- 4 $
*: based on EUSES Model
$: based on Clocal predicted + regional background and monitoring data
SDS : 040292 21 31/48

2.2 GES 3: USE OF NICKEL CHLORIDE FOR THE PRODUCTION OF NICKEL

HYDROXYCARBONATE
4 )
" P=
& (
3:
)
!
"# %:
+ ,
! # * & &
+ 6 , 6 ! 6
# % & '
(&
# .
: & ( %# '
" " # #
+& ( ,
$ # %
' & && 0
(& " 30$%
# %# '
(& " 30 %
" " # #
# % & ! + , '
$& %
(
(& " 303%
# .%
' ! (
' # )
# & (
"# % "# %:
$ # % + ,
: & ( %# '
" " # #
+& ( ,
$ # %
' & && 0
"
# * +
"
&&
( ( & ' + @ -G , +
@$-. G , 0 & ( 0
*
+ ) 4
+ ) $-...
,
# 33. & &
# (
# ( & & ... ... 36
- " & $... + (,
- " $...
! (# ( # )
. # $ % #
. ( "
/ &
5 ' ' & & 0" 7))0 80
# 5 % 0. 6*
SDS : 040292 22 32/48

*
# ! ' 0
# 5 % 309 6*
!( 0 # 1
& (
+ & ( . $ . %
- ( + . &&
2 ( +
&&
.
) &
' / ' ! ' ! &
0
* 5 & & + ,0
) # &
&&
'' & ) ( ) 4
# '
/ & (
# %* & & + 6 ,
#
6 ! 6
" " # # # '
" (& (& * $
* +
&&
*
!
, 1 )
( 4 (& &
3 (
# & ! 1 ! ' $. 36
# / ! !
; '
4 .
> ' 9.
! (# (& )
& ' ! 0
;&& & 0
' & & ! & ' 0
%< ' & &
. # $ % #
: % & & ! (&
0
= %; & ' & D 0
. & &
1"C D & ! ! !
&
!( # 1 " )
" ( #
: % # " +22 3 ; 2 ., ? && ! ' " $4)F ..$ B D & '
(& 5 & ' & 0
= %< ! D & ! D ' '
0
'4 & ) ( ) 4'
SDS : 040292 23 33/48

& ! + , ' (
/ & (
# % & + ,' &&
#
(&
& ' ( 0
2 ' & & & & &
( & &
" " # #
( ! ! (& 0* &
! # ( <" &
( 0
" (& 0"
* +
(& * $
&&
*
!
, 1 )
( $ (& &
3 (
# & ! !
# / ! !
; '
4 .
> ' !
! (# (& )
" & & ( (
! & & ' + '
! , ' ( & && & 02
' ! & ( 0
' & & ! & ' 0
%< ' & &
. # $ % #
: %; & ( & !
(& 0 & (
& ! 0
= %< ! & ' & ! D ' '
( 0
. & &
1"C D & ! ! ( ! 5
!( # 1 " )
" ( #
: % # " +22 3 ; 2 ., ? && ! ' " $4) 3 )33 5 & 6 6
! ! & B D & & (
& 0
= %< ! D & ! D ' '
( 0
'8 & ) ( ) 44
/ & (
# # .%
" " # #
" (& (& * $
* +
& 5 (
*
SDS : 040292 24 34/48

!
, 1 )
3 (
# & ! 1 ! ' $. 36
# / ! !
; '
) .
> ' 9.
! (# (& )
& ' ! 01 &
' 0
' & & ! & ' 0
%< ' & &
. # $ % #
. & &
' ! ' " ; ! & ' 0
!( # 1 " )
" ( #
: % # " +2 3 ; 2 ., & ' (& P
& ' & 0
= %< ! & ' & ! D & !
' 0
4 )
#
"#
& (
& " " # " # #
!
"
2 ' G 61 30-- 0) .04 303 .0)- ! * 35#H
G 61 0 .03 .04 .09 .0.) ! * 35#H
* 6 )0) $ 0 .0$ $ 03 .0-- ! * 35#H

/
4
# %# '
= "1 "(& # #
(&
=
; 5 # 5
6 6
; 5 # 5
6 6
1 5 5 # 5
6 6
1 5 .0...44 .0...3 .0 +4 , "; " + #
6 6 '
+ 6 8 7 -8,
'
5 & !
! 4 (
&
'
'
SDS : 040292 25 35/48

:
; 6 3 $ .0..3 J.0..$ 3( (&
!
; 6 3 .09 .0..3 .0..4 3( (&
!
1 5 6 3 .0.-$ .0..$ .0. ). &
(& ! '
"; " + #
& ,
1 5 6 3 .0.-$ .0..$ .0. ). &
(& ! '
"; " + #
& ,
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
4'
# % & ! + , ' (
= "1 "(& # #
(&
=
; 5 # 5
6 6
; 5 # 5
6 6
1 5 5 # 5
6 6
1 5 .0...44 .0...$ .0 9 +$ , (&
6 6 "; " + #
!
+ 6 8 7 -8,
'
5 & !
! $ (
&
+ &
& &
! ,
'
' 0
:
; 6 3 $ .0. .0..3 3( (&
; 6 3 .09 .0. .0. 3( (&
1 5 6 3 .0.-$ .0.$) .03 (&
1 5 6 3 .0.-$ .0.$) .03 (&

0
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
44
# .%
= "1 "(& # #
(&
SDS : 040292 26 36/48

=
; 5 #
6 6
; 5 #
6 6
1 5 5 #
6 6
1 5 .0...44 .0....3 .0. (&
6 6 "; " + # $.
'
5 & ! ! ,
:
; 6 3 $ .0 - .0.$ 3( (&
!
; 6 3 .09 .0 - .039 3( (&
!
1 5 6 3 .0.-$ .0. $09 ( 0 ). &
# " (& ! '
"; " + # $.
.0. ' '
# " +; 2
., 5 & ! !
# " +; 2L ., 4
(
& ,
1 5 6 3 .0.-$ .0. $09 ( 0 ). &
# " (& ! '
"; " + # $.
.0. ' '
# " +; 2
., 5 & ! !
# " +; 2L ., 4
(
& ,
$H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 30
" (& & ' & ( = "1
&& & # " ' 3 & (& = "1 & !
& ( & & & ! 02 & ! ! 5
& ' = "1 ' ( 0
5 - # & &
#
% " " :* + ' % &%66'''0 5 0 6 5 ;5 (6 5 5 ,
' ! %
# ' ' 6 ' '
0
" D ! && !
+ && ,0
" & && !

+ && ,0
/
D
& 0 & / ' ! && &
5 = "1 .0.- 6 3 + K$.8 & ,0
SDS : 040292 27 37/48


CHLORIDE FOR THE PRODUCTION OF NICKEL
HYDROXYCARBONATE
for Nickel (2008/2009).
. 5 & , " 7 (
$! % $ ! %
" 6 " ;D
" 6 " ;D
"
" ' + " + , +" &
+ 6 '
61, ' + 61, " L$ 03 6 F , " L 03
,
#;2L$ 6 F
#;2L.0. -
.0..33 .0.. ) .0 4 .0.9 .0..)
. 6 + , " 7 (
$! % $3 % .&
" 6" ;D " 6 " ;D
" + , + ,
+ 6 ' , " L$ 03 6 F " L40 6 F
" " #;2L$ #;2L.0. -
' + 61, ' + 61, 0 0 0 0 0 0
& & &
>;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9.
6 6 6 6 6 6
.0...9 .0...3 .0 3 .0$4 .0.9 .0.$ .0..- .0..
. 8 . " & 7 (
" " 6 "

" 6 "
" * M
" 6 "
# * M + ',
" > + ',
3.8 3.8 '
& + , $..8 '
$..8 ' 9.8 &
+ 6 , " L 0- " L.0$
+ 6 , ' 9.8 " L.0$
6 #;2L$ 6
+ 6 '', & 6
#;2L.0.3
+ 6 '', #;2L.0. -
04$ .0)
$ 03 $ 0 . .0 .09 .0 $
SDS : 040292 28 38/48


THE USE OF NICKEL CHLORIDE FOR THE PRODUCTION OF NICKEL
HYDROXYCARBONATE
. : ) $ % &
" & ' + 61,
.0.

FOR THE PRODUCTION OF NICKEL HYDROXYCARBONATE

(STP) FOR THE USE OF NICKEL CHLORIDE FOR THE PRODUCTION OF
NICKEL HYDROXYCARBONATE
. ; reports the calculated Ni concentrations in the effluent of the on-site WWTP. For the generic exposure
. ; 7 & &
5
(& HH* + 61,
" 2 ' .0 4
" .0 4

ASSESSMENTS FOR THE USE OF NICKEL CHLORIDE FOR THE
PRODUCTION OF NICKEL HYDROXYCARBONATE
. < # # &
" N " O
+* 6 ,
+ 6 , + 6*, & + 6 , + 6 3, + 6 3,
$-... $ 4 33. 3 $
*: based on IFDM air model
SDS : 040292 29 39/48

2.3 GES 4: USE OF NICKEL CHLORIDE FOR THE PRODUCTION OF NICKEL

METAL - ELECTROLYTIC REFINING OF NICKEL MATTE VIA A
NICKEL CHLORIDE SOLUTION (HYDROMETALLURGICAL PROCESS)
5 7 ( #
$3 ( %
" 5=
& 0" !
+ & ,
% $4%
% !
"# % "# %:
+ ,
# % # % & '
(&
# 3% & + ,
# % & & '
6 ! &
# .%
: & %
1 ' + , +:::,
&& 6 F" ' +
" " # #
' , &
$ # %
T 0
+ , & '
0
(& " 40$%
# %1 ' + , +:::,
&& 6
(& " 40 %
" " # #
# # 3 # %" ' +
$& %
' , &
(& " 403%

# .% & ( &
' ! (
' # )
# : &
"# %: +
$ # % ,
: & %
1 ' + , +:::,
&& 6 F" ' +
" " # #
' , &
$ # %
T 0
+ , & '
0
"
# * +
"
0
D - $.. $ 5$- $
$ 5$- Q ' R +3.5 . ,0
*
+ ) 4-
+ ) $-...
,
# 33. & &
# (
SDS : 040292 30 40/48

# ( & & ... ... 36

- " & $... + (,
- " $...
! (# ( # )
. # $ % #
. ( "
/ &
5 ' ' & & 0" 7))0 80
# 5 % 0. 6*
*
# ! ' 0
# 5 % 309 6*
!( 0 # 1
& (
+ & ( . $ . %
- ( + . &&
2 ( +
&&
.
) &
' / ' ! ' ! &
0
* 5 & & + ,0
) # &
&&
'' & ) ( ) 5
1 ' + , +:::, && 6
& 0" !
/
+ & ,
# % & '
#
(&
1 ' + , +:::,
" " # #
&& 6
* + " (&
*
!
, 1 )
0
= (& 0
= (& .0- 6 9 6 0* & (&
! ' ! && ! 0
3 (
# & ! !
# / ! !
; '
!
> ' !
! (# (& )
1 0; & & !
+@$$. A , & & & ! 0
2 & & & 0
. # $ % #
1 & ! 0* &
SDS : 040292 31 41/48

0
* & ' & & & 0
. & &
1"C & + ' ! ,0
1"C & 0
!( # 1 " )
* ' ' & & & & ! '
! ' & & 0
" ( #
: % (& & ! & D # " && ! ' "
$ )4$ +& ' ! ' , " $ 49 +& ' ! '
D , " $4. + , " $43 + , & 0
" 3 9... & 3 E & ' ; * && ! ' " $ )496
+; 2 L ., && ' D 5
& ! 0* ! D ' ' 1"C
! 0
= %* (& D & & & &
' ! 0
'4 & ) ( ) 5'
" ' + ' , &
& 0" !
/
+ & ,
# % & '
(&
# # 3% & + ,
# % & & ' 6
! &
" ' + ' , &
" " # #
* + " (&
'
D - $.. $ 5$- $
$ 5$- Q ' R +3.5 . ,0
*
!
, 1 )
0
= (& 3 0
= (& .0- 6 9 6 0* & (&
! ' ! && ! 0
3 (
# & ! !
# / ! !
; '
!
> ' !
! (# (& )
' ' & ! 0
* & ! ! ! %
0 & F
0 # ! 5 && F
0 & + , 0
" ' & ! ' & & ! ! & 0*
& ( & 0
; & + & & , &
+Q R, 0
. # $ % #
SDS : 040292 32 42/48

" ' ! ! & ' 0

. & &
1"C + ' ! , ( 0
2 ' 1"C (
!( # 1 " )
* ' ' & & & & ! '
! ' & & 0
" ( #
: %= ! ! & (&
D # " && ! ' " $4. + , " $43 + ,0 "
3 9... & 3 E & ' ; * && ! ' " $ )496 +; 2 L .,
&& ' D 5
& ! 0* ! D ' ' 1"C ! 0
= %= (& D & + ,
D ' ! 0
'5 & ) ( ) 54
& ( &
& 0" !
/
+ & ,
# # .P
" " # # & ( &
" (& 0"
* +
(& * $ 0
'
D - $.. $ 5$- $
$ 5$- Q ' R +3.5 . ,0
*
!
, 1 )
( 4 (& &
3 (
# & ! !
# / ! !
; '
) .
> ' !
! (# (& )
"( & & '
0 "( & ' & !
& + ', '
0
. # $ % #
. & &
!( # 1 " )
* ' ' & & & & ! '
! ' & & 0
" ( #
: %: D & # " & ' &
3 9... && ! ' " $ )49$ +& ' ! ' , " $ 49
+& ' ! ' D , " $4. + ,
5 & ! 0
= %# ! D (& & D 0
4 )
#
"#
: &
SDS : 040292 33 43/48

& " " # " # #

!
"
2 ' G 61 30-- 0) .04 303 .0)- ! * 35#H
G 61 0 .03 .04 .09 .0.) ! * 35#H
* 6 )0) $ 0 .0$ $ 03 .0-- ! * 35#H
/
5
# %1 ' + , +:::, && 6
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 6 6 5 # 5
1 5 6 6 5 # 5
1 5 6 6 .0...44 .0... -$ .0-9 + , #
9-
&
(&
:
; 6 3 $ .0$ .0.. 3(
(&
; 6 3 .09 .0$ .0$9 3(
(&
1 5 6 3 .0.- .0.4 .0 9- & !
!
1 5 6 3 .0.- .0.4 .0 9- & !
!
$< ! & ! ' ' 0
H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 3
5'
# # 3 # % " ' + ' , &
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 6 6 5 # 5
1 5 6 6 5 # 5
1 5 6 6 .0...44 .0...-)$ $034 + , " 9-
&
(&
.0-. +J3 , "(&
3
'
' 0
:
; 6 3 $ .0$ .0.. 3(
SDS : 040292 34 44/48

9- &
; 6 3 .09 .0$ .0$9 3(
9- &
1 5 6 3 .0.- .0.4 .0 9- &
1 5 6 3 .0.- .0.4 .0 9- &
$< ! & ! ' ' 0
H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 3
54
# .% & ( &
= "1 "(& # #
(&
=
; 6 6 5 # 5
; 6 6 5 # 5
1 5 6 6 5 # 5
1 5 6 6 .0...44 .0....3 .0. +4 , ).
&
(&
+ # $.
'
5
& !
! 4
(
& ,
'
'
:
; 6 3 $ .03 .0. 3(
(&
; 6 3 .09 .03 .043 3(
(&
1 5 6 3 .0.-$ .0.99 $0-4 ( 0 9- & 0
# "
.0.99 ' &

# " &
+; 2 . !
&
1 5 6 3 .0.-$ .0.99 $0-4 ( 0 9- & 0
# "
.0.99 ' &

# " &
+; 2 ., !
& 0
$ H & ' & D ! +;"=, ' $. I (& + *H;,
& ' & .0.$ 6 3
5 # & &
#
% " " :* + ' % &%66'''0 5 0 6 5 ;5 (6 5 5 ,
' ! %
# ' ' 6 ' '
SDS : 040292 35 45/48

" D ! && !
+ && ,0
" & && !

+ && ,0
/
D
& 0 & / ' ! && &
= "1 + K$.8 & ,0

CHLORIDE FOR THE PRODUCTION OF NICKEL METAL
for Nickel (2008/2009).
. '= & , " 7 (

$! % $ ! %
" 6 " ;D
" 6 " ;D
"
" ' + " + , +" &
+ 6 '
61, ' + 61, " L$ 03 6 F , " L 03
,
#;2L$ 6 F
#;2L.0. -
.0..33 .0.. ) .0 4 .0.9 .0..)
. ' + , " 7 (
$! % $3 % .&
" 6 " ;D " 6 " ;D
" + , + ,
+ 6 ' , " L$ 03 6 F " L40 6 F
" " #;2L$ #;2L.0. -
' + 61, ' + 61, 0 0 0 0 0 0
& & &
>;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9. >;2L$ 3$ >;2L 9.
6 6 6 6 6 6
.0...9 .0...3 .0 3 .0$4 .0.9 .0.$ .0..- .0..
SDS : 040292 36 46/48

. '' . " & 7 (
" " 6 "

" 6 "
" * M
" 6 "
# * M + ',
" > + ',
3.8 3.8 '
& + , $..8 '
$..8 ' 9.8 &
+ 6 , " L 0- " L.0$
+ 6 , ' 9.8 " L.0$
6 #;2L$ 6
+ 6 '', & 6
#;2L.0.3
+ 6 '', #;2L.0. -
04$ .0)
$ 03 $ 0 . .0 .09 .0 $

THE USE OF NICKEL CHLORIDE FOR THE USE OF NICKEL CHLORIDE
FOR THE PRODUCTION OF NICKL METAL
. '4 ) $ % &
" & ' + 61,
.0.

FOR THE PRODUCTION OF NICKEL HYDROXYCARBONATE

(STP) FOR THE USE OF NICKEL CHLORIDE FOR THE PRODUCTION OF
NICKEL METAL
. '5 reports the calculated Ni concentrations in the effluent of the on-site WWTP. For the generic exposure
. '5 7 & &

5
(& HH* + 61,
" 2 ' .0 4
" .0 4
SDS : 040292 37 47/48


ASSESSMENTS FOR THE USE OF NICKEL CHLORIDE FOR THE
PRODUCTION OF NICKEL METAL
. '6 # # &
" N " O
+* 6 ,
+ 6 , + 6*, & + 6 , + 6 3, + 6 3,
$-... $ 4 33. 3 $
*: based on IFDM air Model
SDS : 040292 38 48/48

MSDS Cloruro de Niquel - MSDS (En 10.04.17) - Anders Peru S.A.C.

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Page 1/10

Safety Data Sheet

* SECTION 1: Identification of the substance/mixture and of the company/

* SECTION 2: Hazards identification

GHS06 skull and crossbones

Acute Tox. 3 H301 Toxic if swallowed.

GHS08 health hazard

SDS : 040292 1/48

Aquatic Acute 1 H400 Very toxic to aquatic life.

Skin Irrit. 2 H315 Causes skin irritation.

GHS06 GHS08 GHS09

· Signal word Danger

SDS : 040292 2/48

* SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

* SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

SDS : 040292 3/48

* SECTION 7: Handling and storage

* SECTION 8: Exposure controls/personal protection

SDS : 040292 4/48

* SECTION 9: Physical and chemical properties

SDS : 040292 5/48

* SECTION 10: Stability and reactivity

* SECTION 11: Toxicological information

SDS : 040292 6/48

* SECTION 12: Ecological information

SECTION 13: Disposal considerations

* SECTION 14: Transport information

SDS : 040292 7/48

· 14.3 Transport hazard class(es)

· Class 6.1 (T5) Toxic substances.

· Class 6.1 Toxic substances.

· Class 6.1 Toxic substances.

SDS : 040292 8/48

* SECTION 15: Regulatory information

SECTION 16: Other information

SDS : 040292 9/48

SDS : 040292 10/48

Generic Exposure Scenarios

(as presented in the Nickel Chloride Chemical Safety Report)

SDS : 040292 11/48

SDS : 040292 2 12/48

1. GENERIC EXPOSURE SCENARIO FOR NICKEL CHLORIDE

1.1 GES 1: PRODUCTION OF NICKEL CHLORIDE FROM NICKEL MATTE

SDS : 040292 3 13/48

< & & '

SDS : 040292 4 14/48

? ! +@$$. A ,B0 5 + & ,

" (& 0"

SDS : 040292 5 15/48

: % # " +22 3 ; 2 ., ? && ! ' " $4)F ..$ 3 )33 5 & 6 6

0 ' / + -., 3-. G

SDS : 040292 6 16/48

= (& .0- &

& ! (& 0 & ' 0

SDS : 040292 7 17/48

! & ' ' ' ! 5 & ' 0

& " " # " # #

* 6 )0) $ 0 .0$ $ 03 .0-- ! * 35#H

1 5 .0...44 .0... -$ .0-9 + , #

1 5 6 3 .0.- .0.4 .0 9- &

$< ! & ! ' ' 0