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Effectofsalineintrusiononthepropertiesofcohesivesoilsinthe Red River Delta Vietnam
Effectofsalineintrusiononthepropertiesofcohesivesoilsinthe Red River Delta Vietnam
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Effect of saline intrusion on the properties of cohesive soils in the Red River
Delta, Vietnam
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Nguyen Ngoc Truc, Lena Mihova, Toshifumi Mukunoki & Duc Minh Do
To cite this article: Nguyen Ngoc Truc, Lena Mihova, Toshifumi Mukunoki & Duc Minh Do (2019):
Effect of saline intrusion on the properties of cohesive soils in the Red River Delta, Vietnam, Marine
Georesources & Geotechnology, DOI: 10.1080/1064119X.2018.1550827
Article views: 13
Effect of saline intrusion on the properties of cohesive soils in the Red River
Delta, Vietnam
Nguyen Ngoc Truca,b, Lena Mihovac, Toshifumi Mukunokid and Duc Minh Dob
a
VNU School of Interdisciplinary Studies, Vietnam National University, Hanoi, Vietnam; bVNU University of Science, Vietnam National
University, Hanoi, Vietnam; cDepartment of Geotechnics, Faculty of Transportation Engineering, University of Architecture, Civil Engineering
and Geodesy, Sofia, Bulgaria; dX-Earth Center, Faculty of Advanced Science and Technology, Kumamoto University, Kumamoto, Japan
CONTACT Nguyen Ngoc Truc trucnn@vnu.edu.vn Building G7, No. 144 Xuan Thuy str., Cau Giay dist., Hanoi, Vietnam.
ß 2018 Informa UK Limited, trading as Taylor & Francis Group
2 N. T. NGUYEN ET AL.
Figure 1. The Red River Delta location with the distribution of young sediment of the Thai Binh formation (light yellow).
properties. Soils dominated by smectite-clay minerals are The role of saline solution is obviously expressed in sab-
easily degraded by brine water and thus present low water kha soils. They consist mainly of loosely cemented sandy silt
retention and liquid limit and high hydraulic conductivity; to silty clay and are highly compressible (Al-Shamrani and
on the contrary, soils dominated by allophane-clay minerals Dhowian 1997). The collapse of sabkha soils induced by per-
exhibit high water retention and liquid limit and low meation with seawater is greater than that produced by per-
hydraulic conductivity in seawater (Komine 2007a). meation with freshwater because of the high concentration
MARINE GEORESOURCES & GEOTECHNOLOGY 3
study sites were located inside the delta far from the infected by domestic wastewater or chemical substance of
saline sources. industrial and agricultural activities on the surface. Table 2
shows chemical composition of river water and groundwater
in the RRD. The predominating cations in the two types of
In situ procedures for sampling water are NH4þ, Mg2þ, Mn2þ, Ca2þ, Fe2þ, and Kþ. The
The in situ procedures were aimed at collecting soil samples ions of Naþ and Cl are at a low concentration. In other
from boreholes. The cohesive soils in medium state at 17 words, the soil under water table has not been infected by
sites in five provinces of the RRD, that is, Ninh Binh, Nam salt yet. The data in the table also imply that the interactions
Dinh, Thai Binh, Hai Phong, and Hanoi City, were investi- of sediment and pore water significantly influence the
gated. Figure 2 reveals the investigated sites in the RRD, and groundwater composition (Postma et al. 2007).
Figure 3 shows the 11 investigated sites in Hanoi City. The Soil specimens with height of 20.0 mm, diameter of
field work included sampling and Standard Penetration 63.5 mm, and cross area of 3166.9 mm2 were saturated to
Test (SPT). simulate the saline contamination process of ground in
In the RRD area, the groundwater table appears close to studying the effects of salt on subsoil properties. The process
ground surface. The samples collected from boreholes were of saline intrusion occurs gradually when saline water mixes
below groundwater level. Sampling was conducted for undis- with freshwater and ground is saturated by the brackish
turbed and disturbed samples from drilling core. solution. The salinity of groundwater is approximately zero
Undisturbed samples were obtained using a thin-wall sam- first and then the salinity of mixed water rises but at a low
pler with a diameter of 76 mm and a length of 20–60 cm. level. When seawater increasingly predominates, the salinity
of brackish water also increases. This process usually occurs
The depth of sampling varied not more than 13.0 m where
over a long time at the boundary zone of freshwater and
medium state cohesive soils were found. The depth of sam-
saline water or at the near-surface subsoil strata where the
pling was not large to limit the impact of pre-consolidation
interference of rainy and groundwater is observed. To a cer-
pressure. The general description of the sites is briefly
tain stage, freshwater is pushed back and seawater occupies
depicted in Table 1.
the entire space of groundwater. At that time, the salinity of
SPT was applied in the borehole parallel with drilling
underground water is similar to that of seawater.
process and was conducted at 1.5 m intervals for all bore-
The average salt concentration of seawater in Vietnam is
holes. The value of N30 and the number of disturbed sam-
reported to be 33& or 33.0 g/L. When seawater is not rising,
ples were obtained from the split spoon sampler. SPT was
the salt concentration of groundwater in inland area is 0&
mainly used in the study to estimate the relative stiffness
or 0.0 g/L. To simulate the saline intrusion process, soil
and strength of soils. SPT can be used to determine the state
specimens were saturated with saline water in the laboratory
of soil in the stratigraphy and select the research samples. at four designated salt concentrations, that is, 0.0, 9.9, 19.8,
SPT is not ideal for cohesive soils. However, the obtained and 33.0 g/L. These concentrations corresponded to 0, 30,
results are appropriate for the considered soils of medium 60, and 100% salinity of seawater. The saline solution was a
state, that is, the values of N30 vary from 4 to 8. These val- mixture of pure water and sea salt. This solution could be
ues are found on the boring log of each site. considered artificial seawater. The basic chemical compo-
Figure 4 shows the representative boring logs of the nents and contents of sea salt were NaCl (92%), SO42
studied sites. The stratigraphy of the sites in the considered (2.7%), Mg2þ (1.3%), and Ca2þ (0.65%).
depth is simple. The arrangement of layers follows the order Soil specimens were saturated in a closed process with
of sediment rules, that is, fine sand is located under cohesive two phases, that is, capillary and pressure saturations. Each
soils. Most of the investigated soils are silty clay sediment; saturation phase was conducted at least 5 days to ensure
several sites in Hanoi, for example, Gia Lam 2 (GL2) and that soil specimens would be fully intruded by saline water.
Yen So (YS), are made of clay. A few places show organic The capillary saturation phase is executed first. Soil speci-
matter in soil with a negligible content, thereby showing a mens are put into the rings like that in 1D consolidation
dark gray color of cohesive soil. test. The filter papers were laid on two faces of soil speci-
mens. The porous stones that were soaked are centered on
the faces of the test specimens. The testing sets were
Sample preparation
lowered carefully into the water reservoirs. Each testing set
All the studied soils were collected under the groundwater is placed in one reservoir and marked in order of 0.0, 9.9,
table in a Holocene aquifer. The groundwater is partially 19.8, and 33.0 g/L. The water reservoirs were filled with
MARINE GEORESOURCES & GEOTECHNOLOGY 5
Figure 4. Boring logs of the Yen So (YS) and Gia Lam 2 (GL2) sites.
solution of different salinities in correspondence with the Table 2. Water composition in the RRD and in the Holocene aquifer close to
the research sites (Con et al. 2013; Postma et al. 2007; Norrman et al. 2008).
above marks until the specimens are submerged in half.
Parameter River water Groundwater
Load was placed directly on the upper porous stone to pre-
EC (mS/cm) 290 880
vent soil specimen from being swollen due to saturation of Temp. ( C) 30 26.4
saline solution. This procedure is expected to saturate speci- pH 7.18 6.95
mens naturally. Fe2þ (mmol/L) <0.001 0.27
Ca2þ (mmol/L) 0.53 2.76
After 5-day capillary saturation, specimens are moved to Mg2þ (mmol/L) 0.18 1.91
pressure saturation section on the 1D compression equipment Naþ (mmol/L) 0.2 0.23
of oedometer. Pressure is applied on the specimen by hydro- Kþ (mmol/L) 0.04 0.1
NH4þ (mmol/L) <0.006 0.17
static head from saline water in the standpipe. The level of Alkalinity (meq/L) 2.38 10.2
saline water column in standpipe is limited at <10 cm from SO42– (mmol/L) 0.06 0
Cl– (mmol/L) 0.11 0.08
specimen surface to make sure that the head does not disturb NO3– (mmol/L) 0.01 0
specimen. Saline water impacts the soil specimen from the PO43– (mmol/L) <0.001 0.01
bottom to push air and pore water in the void out. The con- Si4þ (mmol/L) 0.27 0.57
stant load is also applied, but restricted at the specimen sur-
face. The application of load must be ensured so that weight
of load does not induce the deformation of specimen. This
aims at preventing soil from swelling. Specimen is absolutely
saturated when saline solution appears on its surface.
test applied five pressure stages, that is, 25, 50, 100, 200, and
400 kPa. Each stage of pressure lasted at least 24 h until
deformation of specimen, which was recorded by transducer,
stabilized. The parameters determined from this experiment
were used to estimate the characteristics of the deformation
and bearing capacity of the studied soil.
The experiment was simultaneously executed in four
apparatuses corresponding to four salt concentrations. The
deformation e (%) of soils was denoted by the correlative
Figure 7. Assumed embankment on saline subsoil. curve of specimen settlement by time with pressure range.
The deformation of salt-affected soils can be estimated from
their modulus. In this study, deformation modulus, which
depends on the level of stress in soil, was evaluated.
From the experimental curve pressure (r)/void ratio (e)
can be calculated confined modulus, Eoed, with the expres-
sion:
r2 r1
Eoed ¼ ð1 þ e0 Þ (2)
e1 e2
where e0 is the initial void ratio; e1 and e2 are the void ratio
corresponding to pressure stages r1 and r2.
By using Poisson’s ratio, l, it can be evaluated uncon-
fined modulus (Young’s modulus), E0, with the formula:
2l2
E0 ¼ 1 Eoed (3)
1l
A case study on a 5-m high embankment located on a
three-layer subsoil was performed to clarify its bearing cap-
acity in saline intrusion conditions. The top and bottom
layers were sand and the middle one was soft soil layer with
a thickness of 5.4 m. The consolidated deformation was
expected to occur in the soft soil. The precise parameters of
embankment and ground are given in Figure 7.
The safety from bearing capacity failure is expressed by
P/A qult/F, where qult is the ultimate bearing capacity of
the foundation, P is the structural loads at the footing level,
A is the footing area, and F is the appropriate safety factor
that accounts for the uncertainties involved in the determin-
ation of the total load (P) and the ultimate bearing capacity
(Manjriker 2006). This study focused on the safety factor of
subsoil under an embankment not on the bearing capacity
value of subsoil. A finite element method with u, c – reduc-
tion technique was carried out with the PLAXIS program to
implement the task setup. To evaluate the quantitative
change of the safety factor of bearing capacity, the gradient
of the “safety factor–salinity” function DFs was used. This
function is expressed by the following equation:
Fs;i Fs;i1
DFs ¼ (4)
Sa;i Sa;i1
where the index i is a serial step of calculation and corre-
sponds to a given value of salinity Sa and safety factor Fs.
k Fundamental properties
Cv ¼ (5) The experiments for determining the physical properties of
mv :qw
cohesive soil were conducted for all the studied soil samples.
where k is coefficient of permeability, qw is the density of The derived results comprised moisture content, unit weight,
water, mv is coefficient of volume compressibility and deter-
specific gravity, consistency limits, and organic matter con-
mined from consolidation test data.
tent, which were then used for evaluating other characteris-
Parallel to the consolidation test, the direct shear test was
tics of soils including their behavior with salt. Table 3 shows
also performed with the similar sample set. This test was to
the average value of those parameters.
determine shear strength parameters of the salt-affected
The studied soils in natural state were wet and rich in
cohesive soils, which was used for modelling analysis.
organic matter. Their moisture and organic matter contents
However, direct shear test was not conducted on all soil
were 47.26 and 9.11%, respectively. The values of specific
samples. Only the cohesive soil in GL2 and HD1 sites were
gravity and unit weight were at around 2.61 and 18.5 kN/
measured for the strength parameters of c and u.
m3, respectively.
Results
Zeta potential
Clay mineral composition of cohesive soil in The experimental results show that the zeta potential on the
saline media surface of clay particles increases significantly with the salin-
The clay mineral composition of cohesive soils in the RRD ity of solution. This finding indicates that high values of
was investigated after processing with saline solution. The zeta potential correspond to high salinities. The zeta poten-
XRD analytical results indicate that the common point of tial increases quickly with the highest level from 600 to
the experimented soils is the domination of illite (from 15 230 mV when salinity increases from 0.0 to 9.9 g/L. In this
to 29%), followed by kaolinite (up to 27%) and chlorite (up period, the reaction between saline solution and clay particle
to 10%). The swelling clay mineral of montmorillonite occurs intensively. The value of the potential continuously
appears in a small rate (approximately 5–8% in maximum) increases to an asymptotic value of 0.0 mV but in a slow
and in a negligible rate at some places (under 1%). The level when salinity is high. As salinity increases from 9.9 to
quantitatively prevailing non-clay minerals include quartz, 19.8 g/L, the zeta potential of clay rises to 100 mV, which
feldspar, goethite, and some other minerals with low con- can be considered as a transitional stage. This value grows
tent. The clay mineral composition of the soils stated above slowly at approximately 40 mV when the salinity of
MARINE GEORESOURCES & GEOTECHNOLOGY 9
Figure 10. Average line of zeta potential of clay mineral surface of the RRD
soils versus salinity.
Figure 13. Deformation modulus, E0, versus pressure stages of silty clay (HD1 and HK) and clay (GL2 and YS).
Table 4. Properties of the soil at site HD1. corresponding to four salt concentrations cross one another.
Silty clay (HD1) The deformation moduli of four salt-affected soils do not
Parameter Dimension Sa ¼ 0.0 g/L Sa ¼ 9.9 g/L Sa ¼ 19.8 g/L Sa ¼ 33.0 g/L follow any order. Discrepancies arise and become increas-
c kN/m3 18.20 18.12 17.95 18.08 ingly apparent as compression pressure becomes increasingly
e0 – 0.996 0.999 1.027 1.037 high. From pressure levels of 100 400 kPa, the changing
u deg. 12.42 11.97 11.53 10.93
C kPa 14.72 13.92 13.13 12.07
rule is coherently established. The deformation modulus
Eoed kPa 3717 3515 3390 3234 curves corresponding to small salt concentrations show less
– 0.35 0.35 0.35 0.35 deformation and are located at the top. Meanwhile, the
Cc kPa–1 0.179 0.189 0.199 0.209
k 105 m/day 5.79 5.31 5.20 4.99
curves corresponding to high salt concentrations exhibit sig-
nificant deformation and lie at the bottom.
The general modulus value of a soil type is the deform-
Table 5. Properties of the soil at site GL2. ation modulus at a pressure stage from 100 to 200 kPa. The
Clay (GL2) value is shown on the small graph in each soil type in
Parameter Dimension Sa ¼ 0.0 g/L Sa ¼ 9.9 g/L Sa ¼ 19.8 g/L Sa ¼ 33.0 g/L Figure 13. In fact, linear lines in the four small graphs are
c kN/m3 19.20 19.15 19.19 19.10 the lines that appeared in Figure 14. They are given again to
e0 – 0.824 0.825 0.831 0.846 illustrate the general modulus values in a range of salinities.
u deg. 3.50 3.31 3.12 2.87
C kPa 32.47 31.20 29.94 28.25
From the graphs, the curves are found to fall into two
Eoed kPa 4742 4495 4256 3992 separate groups. The first group is composed of curves with
– 0.42 0.42 0.42 0.42 shape of branch of hyperbola. The deformation modulus
Cc kPa-1 0.128 0.135 0.143 0.154
k 10–5 m/day 1.01 0.950 0.959 0.942
reduces gradually as compression pressure increases from 25
to 400 kPa. This group represents the clay samples. The
second group is composed of zigzag curves. After the first
level of compression load, that is, 25 kPa, deformation
modulus rises to the next pressure level, that is, 50 kPa,
before gradually decreasing with the increase in load from
100 to 400 kPa. This group represents the silty clay samples.
The deformation modulus curves against pressure stages of
all silty clay samples are in such zigzag form.
In general, the obtained results of the deformation modu-
lus of cohesive soils in the RRD are small. The moduli last
from over 1000 kPa to under 3200 kPa. The largest values of
E0 are at a salinity of 0.0 g/L or when soils are saturated
with pure water. The smallest values are at soils fully satu-
rated by a saline solution of 33.0 g/L. The deformation
modulus of all soil samples decreases. The changing trend of
E0 present in Figure 14 denotes a good linear reduction
through four salt concentrations. The significant change in
modulus is reflected by the slope of the trend lines.
Therefore, the deformation modulus of the studied soils
decreases after saturation with saline water.
A comparison between the change in modulus against
salinities among Sa ¼ 0.0–9.9, 0.0–19.8, and 0.0–33.0 g/L was
Figure 15. Model of 1D consolidation analysis. conducted to obtain a quantitative assessment. The results
show that the variation in modulus when salinity changes
from 0.0 to 9.9 g/L is the smallest, but it also increases by
salt-affected soils helps define the behavior, particularly the
14.5% in maximum. The variation is 16.8% when salinity
deformation, of the studied soils in saline media.
reaches 19.8 g/L and is more than 22% when salinity reaches
Deformation modulus is assumed to be constant during a
33.0 g/L. The changes are small in the D5 and HD sites. The
loading interval but depends on the level of stress in soil.
change in deformation modulus confirms the increase in the
Therefore, in this research, the variation in deformation of deformation of soils as a result of saline intrusion.
salt-affected soils was firstly investigated in the range of
pressure stages. Particularly, this research clarified the
deformation characteristics of clay and silty clay, which is Deformation of an assumed salt-affected subsoil
shown in Figure 13. Settlement estimation for an embankment with a subsoil
Similar to the four stress–strain curves of soils saturated intruded by different salt concentrations was conducted to
by four salt concentrations as mentioned above, the intersec- investigate the deformation in salt-affected soils. The soil
tion curves are very tangled at the early stage of the types mentioned above were assumed to be intruded by
compression process. At pressure levels of 25 and 50 kPa, saline water with salt concentrations similar to those in the
they do not separate clearly. Specifically, the curves laboratory. The properties of the soils taken into account are
12 N. T. NGUYEN ET AL.
Figure 16. Relationship between salt concentrations and pore water pressure and settlement over time: (a) silty clay of the Hoai Duc-1 (HD1) site; (b) clay of the
Yen So (YS) site.
shown in Tables 4 and 5. In these tables, shear strength consolidation analysis could be applied (Schlosser 1973). A
parameters of c, u and the coefficient of permeability, k, are 5.4-m high soil column with a structural load of 100 kPa,
restrictively determined for HD1 and GL2 only; the values which was modelled by eight-node quadrilateral finite ele-
of Eoed is specified for the range of compressive pressure ments, was considered as in Figure 15. The limit of horizon-
between 100 and 200 kPa. The soil’s properties express their tal node displacements and the zero value of excess pore
changing trend with increasing of the salinity. pressure on the top and bottom surfaces of column were
The assumed embankment in the field (Figure 7) was specified as the boundary conditions. The changes in settle-
investigated by conducting a full coupled consolidation ana- ment and pore water pressure in soil column over time
lysis with the linear theory of Biot (1941, 1956) using a were computed.
finite element method through the GeoStudio program. The The obtained results are typical for any vertical cross sec-
finite element equilibrium and the flow equations were sim- tion of subsoil under the embankment. The results were
ultaneously solved using a backward difference scheme for expressed through the relationship among salt concentra-
the time integration (Mihova and Truc 2016). The width of tions, dissipation of pore water pressure, and settlement
the embankment was over four times as great as the thick- over time. Although soil samples in the sites were consid-
ness of the soft soil layer; thus, the model of 1D ered, the derived results in Figure 16 are shown only for the
MARINE GEORESOURCES & GEOTECHNOLOGY 13
Figure 18. Failure mechanism of the embankment subsoil identified by the dis-
placement rate: (a) at initial time t ¼ t0 (undrained); (b) at time t ¼
t100 (drained).
Figure 19. Safety factor of bearing capacity for the subsoil in the HD1 and GL2 sites at undrained and drained conditions (time t ¼ t0 and t ¼ t100).
Table 6. Safety factor of bearing capacity for the subsoil at the HD1 site (mark “” means decrease).
t ¼ t0 t ¼ t100
Fs ðt100 Þ
Salinity (Sa, g/L) Fs DFs (%) per 1 g/L DFs,0 (%) Fs DFs (%) per 1 g/L DFs,0 (%) Fs ðt0 Þ
0.0 1.17 1.62 1.39
9.9 1.11 0.60 5.05 1.56 0.65 3.94 1.41
19.8 1.05 0.58 9.93 1.50 0.65 7.88 1.42
33.0 0.98 0.56 16.27 1.41 0.65 13.19 1.44
Table 7. Safety factor of bearing capacity for the subsoil at the GL2 site (mark “” means decrease).
t ¼ t0 t ¼ t100
Fs ðt100 Þ
Salinity (Sa, g/L) Fs DFs (%) per 1 g/L DFs,0 (%) Fs DFs (%) per 1 g/L DFs,0 (%) Fs ðt0 Þ
0.0 1.91 2.04 1.07
9.9 1.84 0.77 3.97 1.96 0.85 4.11 1.07
19.8 1.76 0.76 7.90 1.88 0.82 8.08 1.07
33.0 1.66 0.77 13.23 1.76 0.86 13.61 1.06
gradient reduces from 0.56 to 0.65% for each 1.0 g/L salt and settlement velocity, particularly increase in deformation
concentration for the silty-clay subsoil at the HD1 site and and decrease in bearing capacity of the salt-affected subsoil.
from 0.76 to 0.86% for the clay subsoil at the GL2 site. As dissolved salt exists in subsoil, several chemical reac-
The ratio between the safety factor in the drained and tions occur (e.g. the reaction equations below). The dehy-
undrained conditions was also analyzed. The ratio for the drated reactions of newly generated salt occur and increase
subsoil at the HD1 site is approximately 1.4 whereas that at the content of [OH], thereby increasing the pH degree in soil
the GL2 site reaches only 1.07. The significant difference in solution. The said reactions also generate gelatinizing substan-
the safety factor increases at the end of consolidation at the ces (viscous). When seawater continues to be supplied, the
HD1 and GL2 sites and is due to the considerable difference content of dissolved salt in soil solution increases. The inter-
between the shear strength parameters of the soil at these action between gelatinizing substance and clay particles con-
sites. The silty clay at the HD1 site possesses a small cohe- tinues. This substance is in a micro-meter size and functions
sion and friction angle, and its strength is greatly influenced as a lubricating material. Once the above-mentioned reactions
by excess pore pressure. The clay at the GL2 site possesses a proceed, new gelatinizing substance is generated continuously.
very low friction angle and high cohesion, which are influ- The old one is saturated by the positively charged ions and its
enced by the pore pressure on the shear strength of soil. texture is destroyed. Positively charged ions in soil solution is
Consequently, the consolidation process at the GL2 site does increasingly provided. Negatively charged ions are neutralized
not considerably reflect the bearing capacity of the subsoil. significantly, thereby degrading the electrical static force of
adherence among clay particles. Consequently, soil loses its
own cohesive property. These processes occur to a level. As a
Discussion
result, the negatively charged ions are nearly nuetralized and
The changes in the characteristics of soil are thought to be positively charged ions, for example, Naþ, Kþ, and Ca2þ,
involved in the chemical–physical interaction between clay become redundant, are crystallized, and adhere to clay par-
minerals in soil and dissolved salt in water. Therefore, the dis- ticles. The increase in Na2CO3 and OH as the products of
cussion will focus on clarifying that relationship to explain the the reaction increases the pH degree of soil solution. The pH
changes in the fundamental properties including zeta potential value reaches over 9.0 and disperses the clay. Soil textures are
MARINE GEORESOURCES & GEOTECHNOLOGY 15
broken and becomes non-texture. These processes contribute concentration reduces the surface potential with the constant
to the change in the soil properties mentioned above (Lan surface charge condition, and the decay of potential with
2002) distance is rapid. The diffuse layer becomes thin, and the
Clay þ Naþ þ Kþ þ Cl ! ClayNaþ þ ClayKþ þ ClayCl midplane concentration and electrical potential for interact-
ing parallel plates (clay particles) at a given spacing decrease
ClayNaþ þ CO2 þ H2 O ! ClayHþ þ Na2 CO3 as concentration increases. Thus, the interparticle repulsive
forces decrease (Mitchell and Soga 2005). The electrostatic
þ
ClayK þ CO2 þ H2 O ! ClayH þ K2 CO3 þ interaction of negatively charged layer around clay particle
and positively charged layer in saline water results in neu-
ClayAl3þ þ Hþ þ OH ! ClayHþ þ AlðOHÞ3 tralizing the charge of clay minerals in salt-affected media.
Naþ þ Kþ þ CO3 2 þ H2 O ! ðNa; KÞHCO3 þ OH This phenomenon and the decrease in interparticle repulsive
forces are the main reasons for the degradation of soil.
In terms of mineralogy and microstructure, all the soils
Especially, reduction of the repulsive forces among particles
are dominated mainly by illite mineral, followed by kaolinite
is one of the main causes bringing about increasing settle-
and chlorite. The rate of clay mineral of montmorillonite is
ment velocity of the soil solution. Visual images of deter-
small and even negligible in several places. Apart from these
mination test of transmission coefficient by cuvette showed
clay minerals, mixed-layer minerals are also found in the
this. Testing values also indicated that the transmission coef-
soils. These mixed-layer clays are mainly illite-vermiculite,
illite-smectite, chlorite-smectite, and kaolinite-smectite. The ficient was higher in specimens with greater salinity.
dominating non-clay minerals are quartz and goethite as a On the one hand, expandable clay hydrates because the
result of inert chemical reaction. This reaction barely affects dipolar water molecule is attracted by the diffuse double
the properties of salt-affected soils (Kirov and Truc 2012). layer in the clay particle. On the other hand, the dehydra-
Kaolinite particles are positively charged on their edges tion process occurs in expandable clay particle owing to
in a low pH environment but are negatively charged in a dipolar water molecule being attracted by ions of Naþ and
high-pH (basic) environment. Under normal conditions, Cl in saline solution. These hydration, dehydration, and
kaolinite minerals are not expandable (Kleven and Alstad degradation processes occur in the salt-affected specimens.
1996). Chlorite and illite minerals present similar aspects However, the hydration process is slow and weak because
with each other. Their cation exchange capacity (CEC) is the soils are nearly saturated by the non-saline groundwater
from 10 meq/100 g to 40 meq/100 g, and their specific sur- in the field. The dehydration and degradation processes pre-
face area is approximate together (10–55 and 10–100 m2/g). dominate in salt-affected soils. This predominance is
Montmorillonite exhibits strong swelling capability and expressed by the change in the properties of the soil tested
increases the surface area and CEC. Among the four major in the laboratory, which include moisture content, unit
clay minerals mentioned above, montmorillonite possesses weight, specific gravity, etc.
the largest CEC and the most specific surface area but the Salt-affected soils undergo changes in volume related to
weakest bonds between layers. The mixed-layer clay miner- dehydration phenomena. The investigation results of some
als of smectite group, which come from natural environ- cohesive soils in Hanoi showing that, after being affected by
ments ranging from surface to low-grade metamorphic and saline solution, water content and bulk density decreased.
hydrothermal conditions, can promote the swelling potential The coefficient of volume compressibility mv is increased.
of the cohesive soils in Hanoi. Swelling clay minerals present The dehydration phenomenon and the degradation of soils
insufficiently strong chemical bond, large CEC, and large change the properties of the salt-affected soils of Hanoi; spe-
specific surface area. Although the amount of montmorillon- cifically, deformation modulus and coefficient of consolida-
ite in some sites is negligible, the presence of montmorillon- tion decrease, whereas the compressibility index, coefficient
ite and mixed-layer clay minerals of smectite in soil of volume compressibility, and secondary compression index
enhances the expandable capacity of soil, which directly increase (Truc and Mihova 2015).
affects the deformation and bearing capacity of subsoil. In this research, soil saturation by saline water takes at
In the salt-affected media, soil properties depend on the least 10 days and consolidation experiment takes 6 days.
type of clay minerals present in soil. Soils rich in clay min- Such time may be insufficient for the completion of the
erals of allophane, clay minerals originated from weathering reaction between clay minerals and salt in artificial seawater.
2þ Accordingly, changing the clay minerals in the soil is diffi-
of bedrock (e.g. kaolinite), or carbonates (e.g. Ca and
2þ
Mg ) exhibit positively improved properties in saline water. cult. Carretero et al. (2007) explored clay minerals processed
Inversely, soils rich in montmorillonite, illite, and chlorite with seawater for up to 120 days and found no mineral-
present mostly degraded properties in saline water (Gbenga, ogical change but observed differences in crystallite size and
Oluwole, and Shodolapo 2009; Germanov and Kirov 1985; basal spacing. The current results agree well with the find-
Eggestad and Sem 1976). The Hanoi’s cohesive soils contain ings of previous work. In particular, no change in clay min-
expandable clay minerals (Kirov and Truc 2012). Thus, the eral composition is found while soil is intensively deformed
negative change in soil deformation and bearing capacity in by the existence of salt.
this study is consistent with that of the previous studies. Earth works, for example, sea dyke, river dyke, road
Electrolyte concentration in saline solution is higher than embankment, and civil constructions, in the coastal areas of
that in pure water solution. The increase in electrolyte the RRD are the most affected objects under saline-intruded
16 N. T. NGUYEN ET AL.
conditions. Once saline intrusion occurs, salt reacts with the consolidation) than in the drained condition (at the
clay minerals in the soil. As a result, the properties of the end of consolidation).
subsoil (e.g. the decrease in deformation modulus and the
increase in time of consolidation) change. These changes Disclosure statement
influence the bearing capacity and stability of the construc-
No potential conflict of interest was reported by the authors.
tions above the soil.
This study only focuses on young sediment belonging to
Thai Binh formation in the RRD, particularly cohesive soils Funding
in Hanoi area. The studied soils have much in common.
This research was funded by the Vietnam National Foundation for
Other coastal soil types of different formations, which have Science and Technology Development (NAFOSTED) under grant num-
different age, state, mineral composition, etc., have not been ber 105.08-2014.45.
investigated. Under the same saline intrusion conditions
associated with sea level rise, changes in the properties of References
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