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Modelling heat exchanger and other networks enables the use of dynamic
fouling models in performance assessment and predictive studies
F
ouling of crude and prod- rapid events are flagged up improved reconciliation of
uct streams in oil refineries quickly and this can only be monitoring data that can flag
is an inescapable problem done where the fouling inside up rapid fouling episodes, the
that causes very significant individual shells can be detailed heat exchanger model-
financial, environmental and inferred correctly from plant ling in SmartPM allows
safety problems. For example, measurements. These measure- dynamic models for crude
refinery preheat train (PHT) ments are often inadequate for blend and product stream
networks nearly always suffer spreadsheet-type analysis, chronic fouling to be inferred
from fouling, resulting in where the geometries of the from the reconciled data. These
reduced throughput, increased individual exchangers are in models allow operators to
energy consumption and more any case over-simplified. compare capex-heavy solutions
frequent shutdowns. The finan- (revamps and so on) with opex
cial, environmental and safety Pragmatic framework routes (such as regular clean-
impact of fouling on processing A comprehensive research ing). Using detailed (rigorous)
73 million barrels of crude oil programme into crude oil foul- thermohydraulic exchanger
per day worldwide is enor- ing was completed in 2010 in modelling and dynamic fouling
mous. It is estimated that crude the UK. This programme was models, SmartPM models
fouling in PHTs costs 0.25% facilitated by IHS and guided correctly the behaviour of
BOE of all refined crude, or 66 by the majority of the networks of heat exchangers.
million barrels per year. super-major oil companies plus The wide range of generic and
Prediction of fouling is an several technology providers. proprietary heat exchanger
increasingly challenging task, The group identified that a configurations, including
with laboratory fouling studies pragmatic framework to apply arrangements such as helical
able to assess blend compatibil- the research knowledge to baffles and tube inserts, is
ity but often little more than a networks such as PHTs was included.
first approximation of real needed. SmartPM (Smart Within a state-of-the-art,
plant performance. Refinery Predictive Maintenance) is the simple-to-use graphical inter-
networks such as PHTs often software tool that fulfils this face, SmartPM is a turnkey
exhibit fouling that builds up purpose, and is now assisting application that connects opera-
relatively slowly and is often refinery operators, engineers tion, maintenance, engineering
managed by exchanger clean- and managers to make deci- and fouling research, with each
ing or improved exchanger sions on how to alleviate group accessing the appropriate
design, as well as rapid fouling fouling in existing and new facilities of the software for the
events. It is imperative for plant. same refinery model. For exam-
effective refinery operation that In addition to greatly ple, whilst operation and
h.ft2.ºF.BTU−1.h−1
8C
mixture of petrochemicals and
Fouling rate,
2.0
9DE
impurities and is prone to foul- 1.6 8B 9BC
ing.1,2,3 US refineries are 1.2
reporting new fouling prob- 0.8
8A 3
lems that are a direct 0.4
5
consequence of the increasing 0
7
amounts of domestic tight oils 280 320 8 Crude-side velocity,
360 390 430 460
ft.s−1
in the crude slate. These prob- 500 540 570
lems arise from the changing Crude-side film temperature, ºF
nature of the slate (one refinery
for example is seeing swings Figure 2 Comparison of fouling in exchangers downstream of the desalter. The
upwards of 5-10 API points on surface indicates a fit of a dynamic fouling model
a day-to-day or week-to-week
basis), additives in the crudes Figure 2 is an illustration of components to vaporise at this
and crude incompatibility heat exchanger fouling behav- stage. The surface plot in Figure
issues. iour in a crude preheating 2 represents a model fit for
Many tight oils have added system introduced in Figure 1.1 chemical reaction fouling.
corrosion inhibitors (usually The figure shows the sensitivity In the last decade, identifying
amine based) and drag reduc- of the fouling rate with the and utilising dynamic fouling
ing agents. This can lead to operating conditions of the heat conditions for best practices has
operating issues in the preheat exchanger, namely the crude gained importance in refinery
exchangers and furnaces, and stream film temperature and operation, engineering design
in the atmospheric distillation the crude stream velocity. and management decision-mak-
towers where the amine salts Apart from exchangers E8D ing.6,7 Recognising the
are deposited, inhibiting heat and E8C, the fouling rates have increasing importance of utilis-
transfer and fouling the tower. an increasing trend with ing fouling knowledge to
Increased deposition of sand increased film temperature and practice, IHS developed
and particulates are observed reduced crude-side velocity. SmartPM combining fouling
in heat exchangers upstream of This dynamic behaviour process physics and proprie-
the desalter. In usual PHT matches reported experimental taryheat exchanger technology
operation, chemical reaction fouling literature where crude – developed over the last 40
fouling dominates the fouling undergoes chemical reaction years by IHS – with new,
mechanism downstream of the fouling.5 The outliers, E8D and advanced simulation and clean-
desalter. Operational irregulari- E8C, are the second and third ing analysis techniques
ties such as inefficient desalting heat exchangers downstream of developed at Cambridge
can lead to inorganic deposi- the desalter. These units are University. This article high-
tion. Such problems are suspected to experience salt lights the use of SmartPM
exacerbated as tight oils stabi- crystallisation due to inefficient software in refinery wide foul-
lise emulsions in the desalter desalting with water carryover. ing mitigation studies.
and increase heat exchanger Salt crystallisation might not be
fouling in downstream units observed in the exchanger Novel approach to fouling
Desalting efficiency can be immediately downstream of the management
further challenged by wax desalter as the thermodynamic Refineries are dynamic environ-
precipitation in the cold train conditions might not be suffi- ments with operational
exchangers.4 cient enough for the water parameters varying with the
type of crude processed to the Any information on the loca- Case study 1: Advanced data
type of products required by tions of monitoring tags and reconciliation
the market. Heat recovery associated measurement are In SmartPM, monitoring data
systems endure these opera- also entered, either through are linked to the network simu-
tional dynamics, making the connecting to the plant’s lator model though the
prediction of heat exchanger distributed control system graphical attachment of tags to
fouling a ‘complex process’. (DCS) or through importing appropriate streams (Figure 4
SmartPM breaks the ‘complex data storage files. Data recon- shows tags attached to a UK
process’ to manageable, smaller, ciliation is performed to fit the refinery crude preheating train).
problems, unmasking the key available data to a physical These tags store time-depend-
parameters responsible for foul- model (a heat and mass ent flow rate, temperature,
ing. The refinery’s store of balance). During this analysis, and/or pressure measurement
historical raw performance a full network simulation is data. Not all streams have
measurements are assessed for performed to generate all engi- temperature/flow measure-
viability and validity and foul- neering geometrical and ments. The thermophysical
ing physics models are fitted to operational parameters of the properties of the streams and
track historical fouling perfor- exchangers (for instance, the actual available tempera-
mance. This enables the stream film coefficients, ture/flow measurements have
operator with a wide range of Reynolds numbers, surface uncertainties. Data reconcilia-
planning scenarios, from the shear stresses and metal tion approach is based on three
development of optimum temperatures). Fouling analysis steps:
predictive maintenance sched- is performed for the reconciled 1. Generation of missing data
ules to the assessment of the data where fouling propensity through simulation using full
economic and environmental factors are obtained for particu- heat exchanger modelling
performance benefits of lar crude blends. Fouling 2. Filtering unreliable data
revamps and even network propensity factor is defined for through a ‘trusted’ heat balance
redesign. Even without histori- a crude blend and represents 3. Grouping heat exchanger
cal data, the fouling physics the degree of fouling in a monitoring data into periods of
models can be used to guide specific operating condition. processed crude blends.
these scenarios based on perfor- An example form of the rate of Figure 4 highlights a snapshot
mance of other refineries fouling of a heat exchanger is of the agreement of the availa-
processing similar crudes. Key shown by: ble plant measurements with
components of SmartPM are the calculated temperature at
shown in Figure 3. 𝑑𝑑𝑅𝑅! 𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹𝐹 𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝𝑝
= 𝑒𝑒𝑒𝑒𝑒𝑒 −
𝐸𝐸
𝑓𝑓 𝜏𝜏!
the tag locations. The tags are
𝑑𝑑𝑑𝑑 ℎ 𝑅𝑅𝑇𝑇!"#$
Heat exchanger specification (1) coloured green, orange or red.
sheets, P&ID diagrams and ‘Green’ implies that the moni-
stream thermophysical proper- Here, h is the film transfer tored data have a very close fit
ties provide the information to coefficient, E is the activation following the mass and heat
build a preheat train model. energy, R is the gas constant, balance. ‘Orange’ is an indica-
tion to handle the data with The green area in the fouling 2011, reducing the fouling
caution due to possible inaccu- resistance graph (see Figure 5) trend. The profiles for heat
racies in thermophysical is a fit of the dynamic fouling duty and the crude-side shear
properties or monitoring model described by Equation 1. stress for this exchanger are
instruments. ‘Red’ indicates This describes a ‘fouling shown in Figure 6. While the
data outside a usual range, propensity’ of 450 h-1, for the shear stress remains constant,
perhaps due to the adjustment crude blend, crude A and the heat duty has reduced
of the reconciled temperature crude blended in a specific significantly due to the
to ensure the heat balance or average proportion over the increased thermal resistance.
an incorrect tag measurement. period January 2011 to October The historical cleaning action is
A key output is the historical 2011. The sudden drop in foul- superimposed on the plot,
operational parameters (such ing resistance around August denoting a minimum fouling
as variation in transfer coeffi- 2011 denotes a heat exchanger resistance identified following
cients, stream velocities) cleaning event. The fouling a cleaning event.
including fouling resistance resistance profile no longer
(Rf) profiles for each exchanger follows the trend given in Case study 2:
with time. When a heat Equation 1 using ‘fouling When to clean which units
exchanger is selected, a combi- propensity’ of 450 h-1 as the A common strategy to mitigate
nation plot (see Figure 5) shows crude blend composition has the effects of fouling is to peri-
the change in Rf profile with changed. A third crude has odically clean fouled units.
variation in the crude blend. been introduced from October Systematic cleaning of fouled
0.05
isolated individually or as a
0.04
group
0.03
0.02
2. Operational constraints: for
0.01 instance, operation at constant
0 pumparound heat duty/return
Jan 2011 Apr 2011 Jul 2011 Oct 2011 temperature, furnace firing
capacity limits
3. Economic constraints: for
Figure 5 Combination plot of the variation in crude slate and fouling resistance instance, cleaning budget for
over an operational period. The green area on the fouling resistance is the the financial year.
fouling resistance predicted via Equation 1 Once the mechanical, opera-
tional and economic constraints
are specified together with the
economic parameters (cost of
Crude-side equivalent
0.04
temperature drop, and so on)
0.03
0.02 could be extracted from the
0.01 software. The net benefit for
0 each financial year and the CO2
Jan 2011 Apr 2011 Jul 2011 Oct 2011 emission savings are summa-
rised in Table 2.
When there are product
Figure 6 Combination plot of the variation in crude-side surface shear, heat streams connecting heat
duty and fouling resistance. The vertical stripe indicates a historical cleaning exchangers above and below
event (hydro blasting). ‘Star’ on the fouling resistance graph identifies the the desalter (see Figure 4),
minimum fouling resistance after a cleaning action cleaning actions downstream of
15
13
13
14
14
14
15
downstream of the desalter is
01
01
20
20
20
20
20
20
20
r2
l2
ov
ct
ec
n
Ju
Ap
Ja
Ju
Au
M
N
D
15
23
6
29
13
22
16
29
Case study 4:
Limits on furnace operations
Furnaces (fired heaters) are
also known to undergo coking
Figure 8 Preheat train diagram with a list of tube-insert models available in on the crude side, where the
SmartPM rate of coking is strongly influ-
enced by the variation in FIT.10
Insert type, geometry and energy benefit due to heat transfer enhance- The properties of the coke
ment and fouling reduction deposits are further compli-
cated as they are subject to
Insert type Insert geometry Annual energy benefit, US$
ageing.11 Coke formation in
Twisted tapes 360 turn per 100 mm 304 000 furnace tubes can increase the
Hitran Loop density of 1 370 000 tube surface (skin) temperature
Petroval 4:1 463 000 through impeding heat trans-
fer. The mechanical integrity of
Table 4 the furnace could be hindered
through exposure of its tubes
six-month period). When clean- Case study 3: Capex heavy to temperatures above the
ing heat exchangers at plant solutions maximum specified safety
shutdowns, there would be no SmartPM enables the user to limits imposed by the manu-
additional energy cost for the explore retrofit and revamp facturer.12 SmartPM explores
furnace but the cost of cleaning options in a series of stages. the variation of the tube skin
the actual unit could be tripled Heat exchanger modifications temperature (TST) of a crude
due to contractors charging a (addition of tube inserts, furnace throughout its opera-
higher cost. If the heat switching crude from shell-side tion. FIT is directly influenced
exchanger is to be cleaned at to tube-side, swapping out a through the degree of heat
the plant shutdown, the segmental baffle for a helical recovery in the PHT. A typical
network will lose the energy baffle, and so on) can be crude furnace consists of two
benefit that could have been assessed based on individual main sections: a convective
recovered through cleaning the performance and network section and the radiant section.
unit ‘today’. performance. SmartPM As the crude within the furnace
FIT, ºF
radiant section consists of
500
several factors including heat
480
transfer from the burner flame
to the tubes, the refractory wall 460
to the tubes and the gas to the 440
tubes. As only one side of the
420
tubes is facing the burner, the 0 10 20 30 40
degree of coke formation Time, months
within the tube internal is B
1160
Scenario 1 with HEX cleaning
non-uniform.13 The case study Tube skin temperature, ºF 1150
Scenario 1 without HEX cleaning
illustrated in this section uses 1140 Maximum skin temperature
SmartPM to investigate the 1130
influence of heat exchanger 1120
cleans on the variation in TST 1110
and the operating strategies for 1100
safe operation of the furnace.
1090
The preheat train network
1080
illustrated in Figure 1 is utilised
1070
to describe the following three
1060
scenarios. 0 10 20 30 40
Time, months
Scenario 1: Influence of FIT on
TST in the absence of furnace Figure 9 Scenario 1, in the absence of furnace coking: (a) variation of FIT with
coking time, and (b) variation of TST with time. Solid line: no cleaning; discontinuous
The performance of the line: with cleaning actions; horizontal bold discontinuous line in (b): maximum
preheat train was simulated, (i) safety specification for TST
without any cleaning actions,
and (ii) with an optimised FIT, to maintain a constant Scenario 2: Influence of FIT on
cleaning schedule. Without FOT, the furnace has to TST with furnace coking
any cleaning actions, FIT drops provide the additional duty. With furnace coking, the TST
considerably (approximately Higher furnace duty results in would be higher as the coke
90°F drop in three years; solid increased TST, depicted in material would have a lower
bold line in Figure 9a). In Figure 9b. When no cleaning thermal conductivity than the
actual operation, the heat actions are performed, TST has tube material. For illustration,
exchangers are subject to increased to about 1140°F Scenario 1 was repeated
cleaning and would maintain a (615°C) by the end of the simu- including a constant coking
higher FIT. The variation in lation. This has increased rate. Figure 10 illustrates the
FIT for an optimum cleaning beyond the safety operating variation in TST with operating
schedule is plotted as the limit of 1103°F (595°C), period. Without any cleaning
discontinuous line in Figure 9a. denoted in the horizontal actions, TST has increased to
The sharp drops in the FIT dashed line. Under the opti- 1160°F (625°C) by the end of
correspond to heat exchanger mised scheduling, TST the three years. This is ~50°F
cleaning actions. Table 5 repre- increases considerably, corre- higher than the case in the
sents the optimum schedule on sponding to the period when absence of furnace coking. It is
when and which units are the heat exchanger is offline also noticeable that several
cleaned. With the reduction in for cleaning. cleaning actions force the TST
1140
1130 Scenario 3: Control of TST by
1120
variation in crude throughput
Several studies discuss illustra-
1110
tions of imposing a maximum
1100 furnace firing capacity in
1090 preheat train scheduling stud-
1080 ies.14,15 The furnace in case
1070 studies 1 and 2 did not reach its
maximum furnace capacity
1060
0 10 20 30 40 during the simulated period
Time, months and hence exhibited a constant
throughput. TST is a variable
Figure 10 Scenario 2: Variation in TST with time with furnace coking. Solid line: which is not always continu-
no cleaning; horizontal bold discontinuous line: maximum safety specification ously monitored (or calculated)
for TST; discontinuous line: with cleaning actions by furnace operators. In order
to control the TST (that is, to
A Scenario 3 with HEX cleaning maintain the TST below its
820
Scenario 3 without HEX cleaning maximum operating limit),
Crude throughput, 1000lb.h−1
Months
HEX 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
E8D X X X
E9A X X X X
E9B X X X X
E9C X X X X
E90 X X X
E9E X X X
8A X X
8B X X
8C X X X
Table 5