AINS Facult: HAMS Final Hama yaa Foe \eaygasrny olymrey yenee and ay 2018 fajor Cheminastmistry (CHESSER, ‘Answer All the Following Questions: - (Total marks = 70 d. i ef /«) Distinguish between Three only of the following: grees) ie Thermosetting and thermoplastic polymers. ii: linear polymers and cross-linked polymers. “fife Isotactic and syndiotactic polymers. a Homopolymer, copolymer and polyblend. Mb< Soo cadwulet If the average molecular weight of a polystyrene sample is 800 000 g mot" the deetnce unit of poly styrene is polymerization of this polymer. ~CH2-CH(CoHs)-. Calculate the number average degree of (16 degrees) zation of styrene (CHa- CH.Ph) initiated by © 2-a) Write a reaction scheme for polymeri: propagation and termination. ‘chemical initiator, including initiation, a) Describe the main kinetic laws of free ra ¢) Show by ‘equations the inhibitory action o! the kinetic curve. ical polymerization, namelYs (18 degrees) f benzoquinone. catalysts with water as co-catalyst and indicate the mechanisms Jh they can initiate: BFs + 0 + CH:- CHX = they are known of the above polymerization ee (18 degrees) © 3-a) Consider the following of polymerization whic eb) Derive the kinetic equations as for nm. 0.02 0.0 ion, the following data are provided: n 4-a) Using the Scanned by TapScannerAIN SHAMS UN Fray of Women YEAR EXAMINATION Ueation, Physical Chemistry CHEM 315 1-bistinguish between: — aa Natural, modified and synthetic polymers wie - Thermoset and thermoplastic polymers. i He Stereo- regularity of polymers (isotactic, synditactic and atactic). fo potmetztin of vin clride (HCHO) Pe Scanned by TapScannerSa . @2- Characterize two methods only creas free-radical polymerization _ : - 6 3¢escribé'the main’ kinetic laws of fre “fadlicel polymerization naming the ; “kinetic curve. reaction. Fn Lo? ze Write by ae the if the catal polymerization And | Scanned by TapScannerAIN SHAMS UNI UNIVERSITY COLLEGE FoR wi ; Final Eeanioaiion tert A The Course of Physical Chemistry ae a of Polymers (course code chem, ay I relation between the « ratio_of th ofthe reaction rat (20.marks) igeie'tha reel dca ed hs <= i 5 see el Show i net prota ~ 20 +i the eopater cc cma mp othe resulting copolymers Scanned by TapScannerAIN SHAMS UNIVERSITY rely UNIVERSITY COLLEGE FOR WOMEN Pass od Final Examination For hy ply The Course of Physical Chemistry PLAS a sla se of Polymers (course code CHEM 315) Oss tn) dun :2021 Time:2 h Answer the following questions: Total marks 70 1- a) Outline the general characterizations of the chemistry of radical chain ( addition ) polymerization. b) Explain the steady-state kinetics of vinyl radical polymerization. {20. marks) 2-Discuss briefly the mechanism and the kinetics of polymerizing of a monomer using cationic polymerization . Show the effect of polarity of the medium on the degree of polymerization of the obtained macromolecules, {20 marks) 3-Give an account on copolymerization, your answer also must include: *) Types of copolymers. **) Determination of copolymer equation. {28 marks) 4-Write short notes on TWO only of the following ( give examples ): (i) Organic and inorganic macromolecules, (ii) Thermoplastics and thermosets , (ili) the mechanism of termination reactions of vinyl radical polymerization. marks)AIN SHAMS UNIVERSITY Faculty of W Final Examination of Polymer Ch (CHEM Scniary 2021 Time: 2h ‘Answer all the following questions: 7. Distinguish between three only ofthe following: ‘Thermoseiting and thermoplastic polymers i Linear polymers and cross-linked polyme Rubber, plastic and fibers. (18 degrees) Solution and bulk polymerization, Lot of the overall rate versus time and show where a steady- (8 degrees) Derive the main kinetic equation of free radie effect of the monomer concentration and temperatures on the rate o: polymerization and molecular weight of results polym (12 degrees) 4. fOutine the main features of cationic polymerization. f Derive the kinetic equation of cationic polymerization (16 degrees) 5- a) Using the copolymer equation : Calculate F, for 20%, 50% and 70 % of fl using the follower: My =styrene, Mz= butadiene: rj =0.8: r2 = 1.25 CONS tie isthe bh State the method of preparing graft copolymer aPune AIN SHAMS UNIVERSITY Faculty of Women for Arts, Science and Education, Final Examination oj of Polymer ( Chemistry (CHEM 315) > fajor Chemistry Physical Chemistry Ti (Total marks = 70 degrees) swer All the Following Que: 3 Write a reaction scheme for polymerization of acrylonitrile (CH= CH.CN),including both, combizrafion and disproportionation, as possible modes of termination. ‘Sketch a plot of overall/ratéwersus(ime, and show where steady- state occurs. c) Derive the main kinetic lays of free radical polymerization. What would be the cffect of increasing the mioomer concentration and the tetaperaturé upon the regularity, rate and molecular weight of polymers of polymerization? escribe the main features of cationic polymerization, b) Consider the following catalysts and indicate the mechanisms of polymerization which they can (isin ENeNH, ii-BF)+Wate, ~ +c) Write the feaction mechanism, indetails, of one of the previous (quistion 2b) and derive the kinetic laws of this mechanism. 362) Using the copolymer equation, calculate the copolymer composition for an equimolar mixture ‘The following data are provided: = M2 1 np i butadiene 0.8 «1.25 vinyl acetate 100 Ol st are the types of these copolymers? ‘the copolymer composition equation, calculate F; for the given values off;;(20, 40, 60, 80 ). The following data are provided: M:= styrene; Mz. maleic anhydride; r1= 0.05 28 |, Estimate the type of the copolymer. 1 the methods of preparing graft copolymers<=<— are the advantages and disadvantages of bulk and solution polymerization?of Polymers af'7/.2020 Discuss briefly the follow! polymerization. ady- state kinetic AINSHAM! UNivERsiry versiTy 3E FOR Worn ation For code CHEM 315) Tiese: 90 min Total marks: 80 \tions of free radicat { vinyl radical polymerizat (gor 2, Discuss the Kinetics of cationic polymerization. Show the effect of monomer and catalyst concentrations on the degree of polymerization of the obtained polymers, 3. Give an account @n copolymerization, Yo i. Types of copolymers. ji.The linear method for determinin ratios (r1 and rz). ii, Applications of eopolymerization i 4.Write s i. Thermoplastics and ther ii, Natural and synthe! short note on ONE only of tl mosets macromolecu (15 marks) nswer must include the monomer reactivity different fields. (25marks) he following, give examples {40 marks)