Professional Documents
Culture Documents
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12 The use of weld surfacing to solve some wear problems in a chemical plant 67
P.FURNIVAl
M.BARTlE, MIM, MIWM, is Materials Technologist, British 'Steel Corporation, Teesside Division
D.J .E lUS, MIM, MWeldl, is Market Development Manage( BOC Murex, Rotherham
P.FURNIVAL, BSc, is Materials Engineer, Materials Group, Imperial Chemical Industries Limited,
Agricultural Division
A.M.HORSFIELD, MA, FIM, FWeldl, is Technical Director, Welding Rods Limited (formerly
I
of ESAB AB, Gothenburg, Sweden)
1
2-The m echanism of wear
V. H. Davies and L. A. Bolton
Wear of plant and equipment is incurred by all 'environmental' information with a visual or
fields of industry and has, until quite recently, microscopic examination of the worn surface it
tended to be accepted as a fact of life. Damage by is, then, possible to build up a picture of the
wear phenomena leads to enormous economic various wear mechanisms which have the most
losses across the many branches of industry critical effect on component life.
and, although wear itself may not alone limit It must be recognised that friction and
the life of, and investment in, a piece of wear resistance are not intrinsic properties of
plant, it is certainly the cause of a large a material but are characteristic of the total
expenditure on maintenance and remedial engineering system and its operating environment.
repairs. However, a considerable part of this Any change in stress, speed, or temperature,
expense could be saved by the practical appli- for example, can have a significant effect on
cation of present-day technology. Corrective the type of wear or wear rate of a component.
measures could, it was estimated in a 1966 It is primarily for this reason that specialists
Government report, save more than £20M in in wear have attempted, in the past, to
the British steel industry alone and a staggering eliminate as many of these variables as
£ 515M within UK industry as a whole. * possible to simplify experimental conditions.
The implementation of tribological principles Thus, although we are now building up an i
in the industrial environment has, in the past, I
understanding of the following speCific wear I
been unacceptably slow, but now, with an mechanisms, under controlled conditions, it j
4
I
now forced to slide across each other. plastic deformation which occurs during asperity
Continued movement results in the asperities contact can cause material to work-harden in
fracturing at the weakest point thus allowing the area of the microwelds. Subsequent
sliding to continue. The amount of adhesive relative motion of the bodies will then cause
wear which occurs during this displacement fracture to occur at the base of the asperities,
depends upon a number of factors ' including the as these are now the weakest pOints, leading to
applied load, speed, temperature, true contact gross surface damage and the production of
area, and cleanliness of the rubbing surfaces. loose wear debris.
It is also dependent on the crystallographic Adhesive wear is likely to be most severe
structure of the surfaces, in that materials of when materials of Similar crystal structure rub
similar structure have a greater tendency to together under load with little or no lubrication.
weld together. Thus two chemically clean Under these conditions particles will be torn
surfaces of a similar crystal structure may from one or both surfaces forming wear debris.
adhere strongly ' to each other simply when When operating under heavy loads and high
placed in contact. speeds the wear debris will appear as 'large,
The volume wear is proportional to the mainly metallic particles (severe wear).
load applied and distance travelled by the Operation under light loads and low speeds,
relatively moving surfaces, i. e. Volume wear however, will produce a fine oxide wear debris
kWy, where W is load and y is displacement, (mild wear), Fig. 2.
Fig. 1. The rate of wear takes into account the If the two metals rubbing together are of
contact area of the surfaces and the time of dissimilar crystal ·structure considerably less
relative motion, thus: surface adhesion occurs, which consequently
reduces their susceptibility to adhesive wear.
Rate of wear = ~
At
= kPV Considerable dissimilarity of crystal structure
is, however, rarely achievable and therefore a
lubricant is usually required to separate and
where A is contact area, t is time, and P is cool the surfaces and thereby maintain a low
pressure. wear rate.
The constant, k, in these equations is The ability of a surface to form a low
known as the 'wear factor' and can vary quite shear strength film, by oxidation or smearing
dramatically depending upon the materials in of a soft microconstituent, can also reduce
contact, or the 'wear-pair' as they are known. adhesive wear. Similarly, many surface
It is related to the mutual solubilities of the diffusion treatments rely on their ability to
wear-pair, which give an indication of their alter the surface structure of a metal to pro-,
welding propensity. The true contact area of duce nonadhesive or antiwelding characteristics
the surfaces is a function of the con!act yield and so enhance the wear properties of the
stress of the softer material. Thus the wear rubbing metal surfaces. Noskuff, Sulfinuz, and
factor, k, is dependent upon the mechanical Tufftriding, are typical surface treatments
properties of the contacting materials, with which are widely employed to improve the wear
lower yield point materials giving rise to resistance of cast iron and steel components
larger areas of true contact, thereby causing operating under adhesive conditions.
greater wear.
The work-hardenability of the contacting Scuffing
materials also influences the wear rate. The This particular process of adhesive wear
occurs during the initial stages of the rubbing
of metal surfaces under poor lubrication con-
/
Increased oxidation allowing
re-formation of surface filmS!
Severe wear
Time/load
5
ditions. It is essentially a rlllDing-in problem Lubricant impregnation of some of these coat-
and is particularly likely to occur to a new ings has been seen to enhance their effective-
component if full load and speed are applied ness. Coatings used are typically phosphating,
too qUickly or if the finish of the rubbing Tufftriding, and Sulfinuz for steel and anodised
surfaces is poor. This type of wear can occur coatings for aluminium. Spray coatings of
in engine cylinders during their initial running':' aluminium and the use of rubber and PTFE
in period and can be identified on cast iron inserts have been adopted in some instances to
piston rings as a series of roughened bands on
the contact faces. Scuffing can also occur
after a considerable amount of service time if
separate the mating surfaces and take up the ·
relative movement between them.
ABRASIVE WEAR
I
there is a lack of lubrication. Because of the
high loads and speeds associated with the
scuffing process severe surface damage often
occurs. The necessity for somewhat lengthy
Abrasive wear, which accounts for more than
50% of industrial wear problems, occurs when
material is removed from a surface by the
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periods of rwming-in, which improve the
surface finish of the mating parts, can be
significantly reduced through the use of suitable
cutting or gouging action of hard particles.
The rate of wear depends on the degree of
penetration of the surface by the abrasive and
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surface diffusion treatments. is therefore related to the surface hardness of
Fretting
Fretting, another form of wear, occurs when
the material.
Systematic investigation has shown the
considerable influenc;,e that the reiative hard-
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two contacting surfaces undergo very small
oscillatory movements. Small particles of
wear debris are removed from the surfaces by
nesses of abrading and abraded material have
on the wear rate. If the attacking material has
a far greater hardness than the surface upon
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adhesion · and may be prevented from immedi- which it is acting, considerable wear takes
~
ately escaping by the small slip excursion. place. If, on the other hand, the .abrasive is
The wear debris can either rema.in trapped softer than the surface, .the wear rate is low
between the mating surfaces, leading to a and generally little advantage may be gained in
condition of seizure, or it may ooze from the
jOint resulting in a loss of fit. This wear
debris is often in a highly oxidised state and
appears as a characteristic red -brown deposit
increasing surface hardness in an effort to
reduce wear. In the region where hardnesses
of the attacking material and the surface are
approximately equal, any slight change in
I !
on ferrous base materials and a black deposit
on aluminium alloys. Typical situations which
are prone to fretting wear are jOints,
hardness of either material can cause a sub-
stantial change in the wear rate, Fig. 3. To
create a stable situation it is therefore
I I
6
Table 1 Hardness values of some abrasives and material phases
7
ness of the wearing surface are not generally
critical and therefore relatively brittle, hard,
wear-resistant materials may be used. The
I
inherent hardness of the surface minimises
penetration by the abrasive and consequently
reduces the wear rate.
Low stress abrasion occurs typically on
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chutes handling free-flowing minerals, where
little or no impact occurs. Alloy cast iron
and cer'amic tiles are therefore often used to
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advantage in these applications.
High stress abrasion
High stress abrasion, Fig. 4c, occurs in
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equipment where abrasive materials, often
minerals, are trapped between two loaded
surfaces. This condition occurs in milling
equipment, rock drills, and final crushers
30 45 60 90
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Impact angle, 0
where size reduction of relatively small
mineral particles takes place. The wear
surface is subjected to very high stresses
5 Erosive wear: effect of impingement angle on materials I
which not only cause mineral particles to At larger angles of impingement, however,
penetrate the surface but may result in fracture
of the brittle phases present (carbides, borides,
etc.) and plastic deformation of the matrix.
erosive particles impact and cause deformation
of the surface which can result in spalling or
pitting. Thus it is ·necessary for a material
I
Such conditions are often experienced in ball
mills and grit-contaminated bearings. Surface
damage, which is caused by scratching, fatigue,
to adsorb a greater amount of energy without
deformation or cracking to exhibit a high
erosive wear resistance. In this respect
I
and plastic deformation, can be reduced by use resilient rubbers and polymers can give good
of a material with an appropriate combination
of high yield strength and hardness to absorb
the high specific contact pressures involved
results because of their low eiastic modulus.
Through plant design it is possibie to
exert a considerable influence on the rate of
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and resist the rubbing action of the abrasive.
EROSION
erosion by affecting both impingement angle
and particle velOCity. Thi s is particularly
true of slurry pipework systems, where pipe
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This wear mechanism, which is strongly size and bend radii are critical factors in the
related to abrasive wear, results from the
impingement of free-flowing solid particles or
liquid droplets on to a surface. These
determination of these parameters. DeSign,
therefore, not only plays a large part in
influencing the selection of erosion-resistaJ?t
I
particles or droplets are carried in a fluid
stream, generally at relatively high velocities
compared with those experienced under low
materials but can be considered as a method,
in its own right, of controlling erosion.
CONTACT FATIGUE
I
stress abrasion conditions. The rate of
erosion is dependent on the kinetic energy of
the eroding particles and the way in which this
energy is dissipated when the particles impinge
The wear mechanisms discussed so far have
involved the progressive loss of material from
a surface. Contact fatigue occurs in machine
I
on a surface. Ductile .surfaces tend to suffer components, such as bearings or gears, which
indentation and gouging damage, but on brittle are subject to rolling contact and may appear
materials the particle energy is dissipated as a sudden loss of material from the surface
through crack propagation. The extent of this through pitting or spalling. This wear mech-
damage is dependent on particle size, shape, anism is attributed to the cyclic loading of two
concentration, velocity, and angle of attack, surfaces in mutual contact and usually occurs
the last being the most critical in terms of without major loss of surface material. It is
materials selection, Fig. 5. closely related to the general phenomenon of
At relatively low angles of impingement fatigue failure which is encountered in many ~.~
erosive wear occurs as a result of the cutting engineering environments, and is similarly I
or machining process and its wear rate is subject to an 'incubation period' prior to the
critically dependent on surface hardness, as appearance of surface damage.
with low stress abrasion. This form of Components that roll, or roll and-Blide,
erosion is often encountered in slurry transport against each other under high loads exhibit a
systems and shot-blasting equipment. For fatigue life that is strongly dependent upon the
such conditions the hard alloy irons, ceramics, stresses present at the component surfaces.
or chromium plating are often used successfully. These high surface stresses cause the
8
propagation of cracks which may eventually regions of the liquid. When entering areas of
become joined, resulting in the formation of higher pressure these bubbles become lIDstable
large loose particles. There are two basic and collapse. When this occurs at a liquid/
mechanisms of contact fatigue, one resulting metal interface a pressure equalisation takes
from surface-initiated cracks and the other place and the continual attack on a surface by
from cracks initiated within the material bulk, these collapsing bubbles leads to a mechanism
frequently at voids, inclusions, or hard car- of wear known as cavitation wear or cavitation
bide particles. erosion. The continual implosion of bubbles at
Contact fatigue originating from a surface the metal interface causes cyclic stressing and
crack usually occurs on hard components in surface fatigue of the metal surface. This
counterformal contact when both rolling -and typically exhibits itself as surface pitting which
sliding occur at the surface (cams, tappets, can act as a nucleation site for corrosive
gears, etc.). The debris formed is generally attack by the liquid medium, espeCially if any
triangular in section resulting from the acute protective films have been ruptured.
angle of crack propagation and steep exit angle This type of wear damage is normally
of the crack. This type of wear failure is associated with components such as ships'
known as pitting, and when it occurs on a propellers, pump impellors, and water-cooled
rotating component it generally exhibits, at components where a sudden change in direction
least in the early stages, an arrowhead of liquid occurs. There is no direct relation-
appearance. An increase in surface hardness ship between cavitation wear and the properties
of the component generally increases its pitting of the material involved. However, at high
resistance. Also, as this wear mechanism rates of cavitation erosion it has been shown
originates from surface defects, the surface that materials with a high ultimate resilience
finish is very important. These two factors characteristic exhibit a better resistance to this
can, however, conflict in that an increase in type of wear. This is essentially a measure-
surface hardness reduces the surface- ment of the capacity of a material to dissipate
adjustment tendency of the component. This the energy of the bubble implosions and can be
property can be critical in the production of a expressed as:
suitable surface finish during running-in. It is
therefore common practice to manufacture one (tensile strength)2
of the contacting surfaces slightly softer than
Ultimate resilience liz - -
elastic modulus
the other to assist this surface-adjustment
process. The relative cavitation erosion resistance of
Contact fatigue, which originates from a some commonly used materials is indicated
subsurface nucleated crack, occurs when pure in Table 2.
rolling, or rolling and sliding, contact gives
rise to stress concentrations in a plane CORROSIVE"WEAR
slightly below the surface. This crack Wear is primarily a remov al of surface
propagates parallel to the surface with sub- material by mechanical action, which would
sidiary surface cracks appearing. mtimately, tend to discount any contribution from corrosion.
these minor cracks join up forming loose In many instances, however, chemical action
rectangular particles. These particles upon a material surface can affect the process
generally remain held in their original position of mechanical wear; this is known loosely as
but can, in certain circumstances, fall out of corrosive wear. Corrosive wear involves the
the surface. In case-hardened components interaction of the wear surface and a corrosive
when insufficient depth of hardening exists, environment. Under such conditions it may be
this cracking frequently occurs at the interface the corrosion product which is being removed
between the core material and the case-
hardened surface layer and may lead to severe Table 2 Resistance of various materials to
spalling. This type of wear mechanism also cavitation
occurs in plain bearings and is sensitive to
the bearing temperature and the availability of Stellites
lubrication. Hard materials are also desirable
in this situation, but are less conformable and
become more dirt-sensitive. As a compromise,
the material which is chosen is usually just
Nylon
Nickel-aluminium bronze
Austenitic stainless steel
t
Increasing
Stainless steels cavitation
strong enough to give adequate performance. Monel resistance
- CAVITATION WEAR Manganese bronze
Cast steel
Cavitation occurs when a liquid is subjected to Bronze
rapid changes of pressure causing the formation Cast iron
of gas or vapour bubbles in the lower pressure
9
more easily than, and in preference to, the material. The latter technique can offer
base material. This then exposes the base distinct economic advantages on components
material to further corrosive attack. which are wear-sensitive, i. e. r equire replace-
ment after only a small amount of wear has
Conversely, in some circumstances the
corrosion product can reduce the t~ndency for
materials to wear. Thls is particularly true
occurred. The maximum benefit can thus be
gained from the wear-resistant coating before
I
of the adhesive wear process, where the wear scrapping the cheaper base material.
rate can be drastically reduced by the presence
of an oxide film.
It is therefore a fact that considerable
A number of surface treatments, including
carburising and nitriding, have been used for
many years to enhance the service life of new
I
components and as such represent a design
variation in wear rate can occur with most of
the aforementio~ed wear mechanisms owing to
the influence of corrosion. For this reason it
. reqUirement. There are, however, many
surface coatings, both flame sprayed and weld
applied, which are used primarily to reclaim
I
is essential to examine the environmental
conditions, and thereby determine the likelihood or rebuild worn components though they 'are
of corrosion occurring, prior to making any equally capable of producing a wear-resistant
surface to improve life of a new component.
final decisions in terms of materials selection.
It is perhaps because these coating processes
SUMMARY
lend themselves to reclamation work that they
have not been adopted as widely as they could I
When a component becomes unacceptably worn be for wear protection of new components.
in service it is common practice to replace it
with a new unit. Its limited service life is
accepted and allowances usually made in the
This poor utilisation, in part, highlights the
continuing need for communication between
engineers, tribologists, and desi~ners, not
I
maintenance schedule for its routine replacement. only to identify and solve individual wear
Direct replacement is often the most
economic proposition. However, in some
problems but also to encourage the implemen-
tation of these solutions and create an aware- I
situatiorls there are more cost-effective methods ness of their economic potential.
of 'replacement' available. It may be possible
through redesign to reduce component wear to
a more acceptable level, or indeed to make
There is no simple panacea for wear
problems nor is there ever likely to be. Each
requires careful study and choice of a delicate
I
replacement far Simpler and quicker, thus balance of materials properties to achieve
minimising maintenance delays. Alternatively optimum wear resistance for specific conditions.
it is possible to manufacture a new component The final economic decision depends not only on
from a more wear-resistant material and the relative cost : life ratio of the various
thereby improve its service life. In this candidate materials but also on the effect that
respect the relevant wear mechanisms, service their increased life has on the reduction of
environment, and design limitations are all maintenance costs and production delays.
criticai considerations in the selection of an These are particularly significant factors in
appropriate material.
In many instances design limitations,
operational requirements, and economics · place
large integrated works, where the cost of
maintenance and production delays can far
outweigh that of the component which failed.
I
restrictions on the bulk properties of a
component. However, the properties required
In this instance it may be necessary to choose
a material which will achieve not only long I; I
to combat wear are essentially specifiC to the
surface, and the use of surface treatments or
service life but will also suit the maintenance
frequency of the plant. A reliable and predict- ·~
coatings may therefore afford a compromise of
those requirements. In this way it is, for
able service life can therefore be as important
as a long one, and in this context the per- I, I
"" •. I1
example, possible to combine good care tough- formance of plant trials is not only valuable in i
iI···
ness with high surface hardness and wear ranking the wear resistance of competitive ~I
:. .
resistance, or to minimise component cost by rna terials but also in the accurate prediction .,
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applying only a thin coating of expensive wear- of their service life and therefore their i
resistant alloy on a relatively cheap base economic viability. ~II
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10
3-M aterials for hardfacing
E.N.Gregory and M.Bartle
- -- -- ---
high stress grinding abrasion. Widely different
properties are required by hardfacing alloys to
resist these different wear mechanisms and all
200
100
- - --
the possible combinations of abrasion, impact,
and high temperatures.
Hardfacing alloys vary in hardness from 0.2 0.4 0.6 0.8 1.0
250 to over 1000HV compared with about 150HV
Carbon, %
for normal constructional steels. There is,
however, much confusion over the relationship 2 Relationship between hardness and carbon content of carbon
between wear resistance and hardness and it is steels-manensitic (quenched);--pear!itic {air coo/} (after
commonly thought that higher hardness will Bullens)
always result in increased wear resistance. sand sliding down a chute, it is generally true
This is probably because under conditions of that the highest wear resistance is obtained by
simple abraSion, as in the above example of the use of the hardest available hardfacing
alloy. Similarly, a constructional alloy steel
~.r. ' ' ''_ t r
' fi \( '" "'-':-v" .~' " .- will have its resistance to simple abrasion
::..,-r.' , - ;-~__ :'~, ,:- :~'I.{ :' ~"j");.ii~ ~ increased if its hardness is increased by heat
, -~ '
." :--:# : .~1-'1(~::""- ~-L~:::..'>-:,
\---;-1-'~:..r .
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treat~~~~ver, for the same level of hardness, the
' hardfacing alloy will have a much longer life
r 1, and is ;;OHV.
11
steel the ferritic areas may become rapidly
worn away and the iron carbides may fracture
under the high stress because of lack of support.
Therefore, the wear pattern can change depending
on the nature of the abrasive media and the level
I
of stress. A hardfacing alloy is designed to
resist a combination of abrasive conditions; the
microstructure of a typical martensitic hard-
I
facing deposit is shown in Fig. 5. The combina-
tion of a network of carbides containing chromium,
tungsten, or vanadium, etc. and a matrix of hard
alloy martensite provides resistance to both low
I '
stress scratching abrasion and high stress
grinding abrasion.
12
·< ,~ ' the high temperature promotes oxidation of the ': l are separated into those containing less than
freshly ~xposed metaLor reaction with whatever: . and those containing more than 20% alloy additions.
gaseous' or other environment is present. This The nonferrous hardfacing alloys can be classified
':. chemical reaction, which is in effect high tem- as cobalt- or nickel-based and the fourth Group
perature corrosion, causes rapid wear to take consists of those containing tungsten carbides.
place so that hardfacing alloys for high tempera- Typical alloy compositions classified in this way
ture service require two properties. Firstly, are shown in Table 1.
high temperature hardness which promotes An alternative system of consumables
resistance to softening at the service temperature, classification has been devised by a Hardfacing
and, secondly, the inclusion of alloying elements Working Party set up within the British Steel
such as chromium in sufficient quantity to cause Corporation (BSC). This classification is shown
the rapid formation of surface films resistant in Table 2 and is to be included in a four-part
to oxidation. These properties are necessary series of standards to be issued within BSC under
for alloys applied to valves or valve seats operat- the general heading 'Applied Surfaces ,for Wear
ing at high temperatures, or to the seating areas Protection' as:
of blast furnace bells which form a gas-tight seal
with the charging hopper. Part 1 Weld deposited surfaces
The choice of hardfacing alloy must be made Part 2 Spray deposited surfaces
with as much knowledge as possible of the service Part 3 Wear resistant linings
conditions under which the component is expected Part 4 Typical applications of applied surfaces
to operate. Given this knowledge, the selection
must be made from the bewildering range of These standards are being compiled because
hardfacing alloys available. widespread enquiry has revealed that, even within
BSC, there have been many instances of ineffectuiil
CLASSIFICATION OF ALLOYS attempts at hardfacing where it seems that there
Hardfacing alloys can be generally classified by ha ve been shortcomings in the technique or
dividing them into four Groups. Iron-based alloys inadequate advice available on material selection.
Nonferrous
Co-Cr-W 26 R 3 400 Gas, arc Co Cr-A
Co-Cr-W 1.4 31 R .1 500 Gas. arc Co Cr-B
Co-Cr-W 2.5 32 12 R 3 630 Gas , a rc Co Cr-C
Ni-Cr-B 0.4 11 R 2.5 400 Gas, arc Ni Cr-A
Ni-Cr-B 0.6 13 R 3 530 Gas, arc Ni Cr-B
Ni-C r-B 4 0.8 15 R 4 720 Gas, a rc Ni Cr-C
Ni-Cr-Mo-W 5 0 , 06 15 16 4 II 300 Arc AWS A5.U-69
E Ni Mo Cr-1
. Cr or Ni. 10-50%Fe
Also covered by AWS A5.21 - 70 'CompoSite surfaCing welding rods and electrodes I
13
.....
>I>- Table 2 Consumable classification - British Steel Corporation
f~"';~ )'o;.t.f.:r''''
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~..: ..,d.w) ~ll~;:j iWZlIl:¥J eil ~ (i.E iiIliJ t:fii ~ .. .. - - .. .. .. 111M
Table 2 continued
Mn, Mo, V. 500-750 High abrasive wear resistance, low to Suitable for conformal contacts
2
1 j j j j j j W, Ni, Nb, responds moderate impact resistance (Ni: hard in adhesive wear situations .
Martensitlc Bal
4 10 total up to to heat type). Nb improves wear resIstance S,crapers. bucket tips, forming
irons
25% treatment In hot conditions up to 400 0 C rolls, cutting tools
Cobalt-
0. 7 25 3
chromium- Bal 350- 400
1.4 32 6
tungsten
low alloy
2
Cobalt-
chromium- 1.0 25 7
Bal 400-500
tungsten 1.7 32 10 Abrasion, erosion, cor roston, nnel Valve coatings, pump
medium combinations of these faotors at shafts. sleeves. Wear
4
alloy e levated temperatures . Hardness rings, hot shear
Cobalt
retained at high temperature, . blades. Ingot tongue
alloys
Manufao tu rer of speclallst guidance bits , dies. Steelworka
Cobalt- necessary on seleotion mill equipment
1.7 25 II
chromium- Bal 550-650
3. 0 35 20
tungsten
high alloy
4
Cobalt-
1.2 20 10 20
ch,romium- Bal
2.0 25 15 25
tungsten-
nickel alloys
Copper ,
Up to 40%Zn, balance Cu
zinc, Good resistance to adhesive wear,
brasses anti-seizing properties. and Bearings, s lid eways ,
reasonable corrosion resistance gears , s hafts,
Copper
propellers
alloys
Copper, P~imarily intended Cor lubricated
silicon, Up to 4%SI, balance Cu bearing applications
silicon
bronzes
indicates possible presence of significant constituents
3
Copper,
aluminium, 8-15%Al, balance Cu Good resistance to adhesive wear ,
5
aluminium anti-seizing properties, and
Copper
bronzes reasonable oorroslon resistance Bearings, slideways , gears, shafts,
alloys
(cont'd) propellers
4
Primarlly intended for lubricated
Copper,
bearing applications
tin, 4-12%Sn, balance Cu
phosphor
bronzes
+ 10 mesh
(+ 1.7mm)
2
- 10 + 20
mesh
(-1. 7mm Min. of 40% tungsten carbide normally In an iron base matrix but can
+ 74Q~m) be In a copper or cobalt matrix
Extreme wear resistance and Impact
Sinter plant high wear areas : main suction
3 Classification is according to the tungsten carbide pcrtic1e size resistance dependent on particle
fan Impellors, sinter breakers, etc.
6 - 20 + 40 size range, dispersion, and matrix
Crusher hammers, scrapers, various
Tungsten mesh The designation -10 +20 mesh means material which will pass through hardness
carbide (-745 + a sieve of 10 mesh and does not pass through a sieve of 20 mesh
150~m)
Figures in parenthesis are the corresponding nominal aperture size
4 of sieve in accordance with BS 410
- 40 + 100
mesh
(-jl90 +
1 9 °~)
5
- 100 mesh
- 150~
/
80 20 750-850
boron arc or gas weld technique, Very Chutes, selected fan blade applications
paste hard wear-resistant surface, low
impact resistance
f-'
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/
/
••~.~,,,'',y''c:;.L,'''· \. '' '''· ~ ''''..·1·..~\1·; 'X: IC l'. :r"',.Ifr..'I:. " U;'""· ' ,r.!'-:-::: ' h~"':I,"T.;orA""""'~.:r~~ ... _ ._~ _____ •
"7:"":"': "" ~~"""' ''·~ ~ ~A- .'''' -'' . ~'''.~7;t - - - -- --- --- ------ .------.-
In drawing up the plans for the proposed standard Table 3 Dilution levels of different welding
it was decided that it should contain a philosophical processes
element with the aim of being instructive to the
user. The document is intended to facilitate the Process Dilution, %
control · of subcontracted work and work under-
taken within BSC 's own workshops. It provides Spray fuse Nil
and sets down procedures for the manufacture
Plasma spraying Nil
of new components specifically designed for
hardfacing. giving advice on the most economic Oxyacetylene <5
combination of base and surface coating materials. Powder welding <5
Effect of dilution Manual metal-arc 10-30
The chemical compositions and the hardness Flux-cored 10-30
levels quoted in Table 1 apply to undiluted weld
metal which would be typical of multipass welds Submerged -arc 10-40
or the top run of a two- or three-layer weld
deposit. a weld deposit having a hardness of about 240HV
The degree of dilution that occurs depends
which can subsequently be heat treated to higher
upon the difference in chemical composition hardness if required. The weld metal has high
between the weld and parent metal, the inherent tensile and compressive strength as well as high
dilution of the welding process, and the welding
impact strength. The resistance to abrasion is
technique. The spray fuse process gives virtually
no penetration into the parent metal and con-
sequently dilution does not occur. On the other
fairly low and the main application of this alloy
is in building up castings of similar composition.
I
It can also be · used as a buffer layer between a
hand submerged-arc welding can produce up to
40% penetration with a corresponding change in
composition of the first layer of weld metal.
softer base metal and a harder surfacing alloy.
Very few manufacturers of consumables supply .
this type of filler metal because its abrasion
I
Table 3 shows typical clilution levels of different
resistance is low and buffer layers can be made
processes.
with hydrogen-controlled basic covered electrodes
The effect of welding technique in reducing
of appropriate strength.
dilution by increasing the degree of overlap of
adjacent weld beads i~ shown in Fig.6.
Low alloy steels
If an expensive high alloy hardfacing deposit
The martensitic alloy steels are the most widely
is to be applied it is obviously desirable to use
used hardfacing alloys and are - characterised by
a low dilution welding process, but this is not
low cost and a wide range of properties depending
always possible or indeed economic because the
low dilution processes generally have low deposi-
tion rates, so that, . if large areas are to be
on the composition. They contain, in addition to
carbon, varying amounts of chromium, manganese,
I
molybdenum, and nickel as well as smaller
hardfaced, the high deposition rate processes
additions of tungsten and vanadium.
have to be used. In this situation dilution must
Molybdenum, manganese, and nickel pro-
be controlled by welding technique.
mote hardening of the steel to form a martensitic
or bainitic matrix; chromium, molybdenum;
tungsten, and vanadium form wear-resistant
carbides. The hardness of the weld metal varies
with the composition and can range from
250-800HV. As the hardness increases there
is an increase in abrasion resistance and a
·I
h
"
'
18
resistance. Their resistance to abrasion under be replaced or built up to their original dimen-
metal-to-metal wear in the 300 0 -600 0 e range of sions by hardfacing with manganese steel
temperatures has led to their successful use for electrodes.
hardfacing steel mill rolls and rollers. They Manganese steel castings contain 1% or
are also used in other metal-to-metal wear more of carbon which precipitates in the form
situations such as roll necks and cra~e wheels, " of carbides on slow cooling which causes
and the higher carbon varieties can be used to embrittlement. ~4e heat treatment involving
tip metalworking tools. quenching prevents) carbide precipitation and
'·. t
to the H42 and H41 grades, respectively, of the ment so the problem is overcome by lowering
molybdenum hot work tool steels classified by the carbon content of weld deposits to ab9ut 0.7%.
the American Iron and Steel Institute and the At normal weld metal cooling rates this carbon
Society of Automotive Engineers. The Fe 5-C level is held in solution in the austenite and is
alloy has a reduced carbon content which makes not precipitated. If the cooling rate of the weld
it more suitable for applications requiring greater metal is slowed down by preheating or by allowing
toughness. High speed steels are by definition the component to become too hot during welding,
tool steels that can be used to cut metals at rapid carbide precipitation and embrittlement can occur.
rates and withstand tool temperatures of For this reason 14'% Mn steel is not available in
500 0 -600 0 e without softening. The hardnesses the form of rods for gas welding which would
quoted in Table 1 are those of as-deposited welds produce severely embrittled weld deposits.
and can be reduced to approximately 300HV by Both the nickel- and the molybdenum-
'asuitable annealing treatment to allow machining containing 14%Mn steel electrodes can be used
operations to be carried out. The weld deposit either to hardface or join manganese steel parent
can be subsequently rehardened by quenching and metal. When hardfacing a carbon steel or a low
tempering. alloy base metal a manganese steel electrode is
These alloys are used for hardfacing metal likely to develop a brittle interface because of
cutting tools, hot-work dies, ingot tongs, and the formation of martensitic alloys by dilution
other components that require wear resistance of the weld deposit. This brittle zone may contain
at elevated temperatures. cracks and will certainly develop extensive crack-
ing followed by spalling of the weld deposit if
Austenitic manganese steel heavy impact occurs in service. The solution
Weld metal containing 12-14%Mn has an austenitic to this problem is to butter the faces of the
structure that is soft (200HV) but which work- carbon or low alloy steel with. austenitic stain-
hardens at the surface to about 600HV under less steel before surfacing with the manganese
conditions of heavy impact. In the soft as- steel. In welding manganese steel inserts to
deposited condition there is little resistance to carbon steel the same problem can occur and
low stress scratching abrasion, which occurs, the weld should be made with austenitic stain-
for example, when digging in sandy soil, and less steel electrodes.
the weld metal is steadily lapped away. Austenitic manganese steel electrodes are
If heavy impact is involved, as with rock used where conditions of heavy impact occur in
crushing hammers, the weld metal deforms and service as in rock crushers, railway points and
work-hardens at the surface giving high resist- crossings, or excavating equipment working in
ance to further impact. This type of deposit rocky soil.
will also work-harden if used for digging in soil
that contains boulders, and the surface will IRON·BASED CONTAINING MORE THAN 20% ALLOY
develop resistance to abrasion by the soil ADDITIONS
particles. Manganese steel deposits may develop The dividing line of 20% which separates Groups 1
cracks in service but this does not necessarily and .2, Table I, is purely arbitrary and from
reduce the life because the alloy has high resist- technical considerations there is a great deal in
ance to the propagation of cracks. This is .. ~ favour of combining the Groups into one. From
contrary to the behaviour of most alloys in which economic considerations, however, there is
a crack cons iderably reduces the stress required .justification in separating the more highly alloyed
for failure. and therefore more expensive alloys from the
Fourteen per cent manganese steel is some- generally cheaper varieties which include the
,
\
times used in the form of cast inserts, water- least expensive martensitic alloy steels. ~
quenched from 10000C to produce a fully austenitic
f
Austenitic chromium manganese steel'
!
structure. The inserts, which may, for example,
be in the shape of digger teeth, are welded in This alloy is used for similar applications to E
pOSition and when they have worn they may either the austenitic manganese steels of Group 1 but
19
I
l
f
has certain advantages over these which must
be set against the higher cost. It was developed
in the USA from the low nickel stainless steels
which were introduced during the nickel shortage
in 1952-3. In these steels each percentage of
nickel was replaced by twice the percentage of
manganese and by increasing the carbon content
to the 0.35% level the impact resistance was
markedly increased . . Because of the high alloy
I
content tbese electrodes can be used to weld
direct on to the carbon steel base metal without
the formation of a brittle martensitic interface,
and they can also be used to weld manganese steel
I
inserts direct to carbon steel. Because of the
high chromium content the weld metal cannot be
cut or gouged with a gas flame.
7 Microstructure of high chromium austenitic iron weld deposit
I
showing hexagonal chromium carbides and smaller carbides in
High speed steel
A number of high speed steels are available in
Group 2 which have a wide range of compositions
matrix of austenite {Courtesy BOC-Murex} x 175
NONFERROUS
I
but all contain tungsten, chromium, molybdenum, Cobalt-based
and vanadium either separately or together.
These are used mainly for tipping the edges of
The most widely used hardfacing alloys in the
nonferrous Group are those based on the ternary
I
metal machining tools. Because only a small system cobalt-chromium-tungsten originally
deposit is used each time a tool is tipped the cost
per tool is low.
developed un~erthe trade name Stellite. Cobalt
endows the alloys with hot hardness so that they
can be used at service temperatures above 600 0 C
I
Austenitic stainless steel without softening or deformation. The presence
Stainless steels which contain around 18%Cr and
8%Ni have good impact resistance and low abrasion
of chromium forms a closely adherent oxide film
which provides oxidation resistance, and this
I
resistance. Their impact resistance is inferior element together with tungsten brings about
to that of the austenitic manganese steels and they
are also more expensive. Therefore their main
use is for buttering carbon or alloy steels before
appreciable secondary hardening by the precipita-
tion of carbides, Fig. 8 •
The lower carbon alloys, typified by
I
manganese steel is deposited. As stated above Co Cr-A in the AWS claSSification, are widely
this avoids the formation of brittle alloys which
occurs at the interface between manganese steel
used fo1," hardfacing the mating surfaces of valves
subject to impact at elevated temperatures. I
and carbon or alloy steels. Examples are exhaust valves of internal com-
20
The higher carbon varieties are harder and
have higher abrasion resistance but lower resist-
ance to impact. These alloys are used for metal-
to-metal wear under abras ive conditions where
their high polish and low coefficient of friction
give good bearing properties and resistance to ,- '
indentation.
Nickel-based
The most common nickel-based hardfacing alloys
contain chromium, boron, and carbon, and have
a microstructure which consists of wear-resistant
chromium carbides and borides in a nickel-
chromium matrix. Weld deposits have high 9 Oxyacetylene deposit of tube carbide (Courtesy B.0C-Murex)
oxidation resistance up to 950 0 C and retain
their hardness well at temperatures up to about geneous deposit consisting of un melted carbide
500 0 C. Corrosion resistance is excellent against p~rticles in a steel matrix, Fig. 9. The matrix
steam, salt water , and salt spray. Resistance which is formed by the steel tube contains tungsten
to low stress scratching abrasion is good at all and carbon from incipient melting of some of the
temperatures and increases with carbon content, carbide, and this alloyed matrix provides good
but resistance to high stress grinding abrasion support for the unrnelted carbides. This type of
is low. Deformation produces cracks in the deposit is useful for cutting operations such as
extremely hard chromium borides (4000HV) so rock drilling in which the matrix is slowly worn
that the alloys should not be used under conditions away to expose the cutting surfaces of the tungsten
of impact. carbide particles.
Typical applications involve abrasion and Metal-arc deposition causes most of the
corrosion at elevated temperatures and include tungsten carbide granules to melt and produces
valves, seating rings, and screw conveyors. a more homogeneous alloy cast iron even when
the electrode contains the coarsest grade of
Nickel-chromium-molybdenum-tungsten carbide, Fig .1 O. The few granules that remain
These alloys are used primarily for corrosion unmelted sink to the bottom of the molten pool
resistance but also have good -heat resistance. and, because of the degree of penetration into the
The composition listed in Table 1 corresponds base metal, often lie below the original surface
to that of Hastelloy C, which is used extensively level.
for surfacing the seating areas of blast furnace The tungsten-iron alloy has a hardness of
bells and hoppers, where advantage is taken of over 1000HV and has v~ry high abrasion resist-
its excellent resistance to erosion and abrasion ance but does not equal the extreme wear resist-
by hot furnace gases carrying fine abrasive ance of the weld metal produced by oxyacetylene
particles. This alloy has also been used S\lccess- deposition.
fully for surfacing hot-work tools such as die
blocks.
TUNGSTEN CARBIDE
Tungsten carbide has extreme wear resistance and
hardfacing rods contain tungsten carbide particles
which consist of both WC and W2C in a steel tube;
the relative amount of tungsten carbide to steel
is about 60/40. The sizes of tungsten carbide
granules vary from 200 to 8 mesh (0.0002 to 3mm)
and welding rods generally contain different
ranges of mesh sizes, e.g. 10/20, 20/30, etc.,
depending on the service conditions. The tubes
may be bare for oxyacetylene deposition and either
bare or coated for arc welding. Rods are also
available in sintered form which contain up to 80%
10 Microstructure of tungsten-iron-carbon hardfacing deposit
tungsten carbide. showing secondary W-Fe carbides and eutectic colonies in
Oxyacetylene deposition produces a hetero- matrix of martensite (Courtesy BOC-Murex) x 250
21
4- Selection of m aterials for hardfacing
E.N. Gregory
PROPERTIES REQUIRED
properties on a general basis. Table 1 shows
the most widely used types of alloy assembled
horizontally in order of increasing abraSion
I
The main factors to conSider, apart from cost, resistance from left' to right (which shows the
when choosing a hardfaCing alloy are: corresponding decrease in impact reSistance)
and vertically down in order of increasing
I
1 Resistance to abrasive wear; in low stress resistance to heat and corrosion. A chart such as
scratching abrasion this is synonymous
with high hardness. When high stress
grinding abrasion OC9urS the inherent wear
this gives only a general picture because there
will be variations in heat and corrosion resist-
ance between alloys in each horizontal line, and
I
resistance of carbides of some sort is vertical lines will not necessarily intersect
necessary alloys having similar abrasion or impact resist-
2 Resistance to impact, i. e. toughness ance. In addition to this it is difficult to
LOW
HEAT AND
CORROSION
RESISTANCE
HIGH
' .'j
22
U
Table 2 General properties and applications of martensitic alloy steel . hardfacing alloys of different
hardnesses
,,<t:~
predict the behaviour of a hardfacingalloy under the test and bear little or no relation to the .. ..r--: '
complex working conditions which could vary results that are obtained in service. Likewise
from heat phis heavy impact to low stress impac t strength, as measured in a Charpy
scratching abrasion in a corrosive environment. impact testing machine, is associated with the
Despite these limitations, Table 1 indicates the energy required to break a notched specimen
gerieral principles that should be considered for and cannot be related to the impact blows in
the selection of a suitable alloy. service which tend to deform the surface of a .-
"r -,
This type of chart may also be of value to component and result in cracking and chipping
the welding consumables manufacturers because, of that surface.
if they list all their hardfacing alloys in this In hardfacing we are not concerned with
manner, it is easy to see the gaps that should precise numerical values of ab~asion or impact
be filled if a comprehensive and matched set resistance, although the hardness level will
of alloys is to be marketed. Furthermore, it give some indication of whether the wear
is possible that the manufacturer may discover resistance in terms of low stress abrasion or
unnecessary duplication in his range of products, of impact is high, medium, or low.
the proliferation of which may give a temporary Table 2 shows some typical applications
advantage to the enthusiastic salesman but is of martensitic low alloy steel hardfacing
not in the long-term interests of either the deposits. These alloys are available in the form
supplier or the customer. of covered electrodes or as tubular wires.
23
wears away and act as very efficient cutting
surfaces in operations such as rock drilling.
Tungsten carbide alloys find widespread
quarrying operations. Because of their
increased heat resistance they can be used for
some hot wear applications such as hot coke or
I
use in oil well drilling, coal and mineral
mining, and quarrying in which the many types
of drill bits used have their lives ext~nded con-
iron ore sinter chutes .
I
from the oxyacetylene welding rods by covering an abrasion-resistant weld deposit until they
them with flux, presumably on the assumption are run in, and the high chromium irons are
that similar deposit charaCteristics could be often used for this purpose.
obtained in combination with a faster welding The necessity to run in manganese steel
process. This hope has certainly not been before it is used under abrasive conditions was
realised despite the claims of some suppliers demonstrated in World War 2 when tank tracks
that the use of low weldirg currents and made from this alloy bella ved well in the
correct, but undefined, electrode manipulation desert if they had been used on metalled roads
would limit solution of the tungsten carbide beforehand. Replacement tracks fitted in desert
granules. workshops wore out much more rapidly.
Whatever the arc power and however the Although the impact resistance of the 18-8
electrode is manipulated the majority of the · chromium-nickel steel is high and it work-
carbide granules which pass through the arc hardens in service, it is not as good as the
are melted, and the weld should be considered 14%Mn steel for resistance to heavy impact and
as a high hardness martensitic alloy steel tends to deform to a greater extent in the
having very good abrasion resistance and low initial stages of work-hardening. It can be
impact resistance. This difference between used to hardface components subject to shock
the arc and oxyacetylene deposits of tungsten loading in service such as wobbler or spade
carbide types accounts for their relative posi- ends of reversing mills.
tions in the top line of Table 1.
The high tungsten deposit has much better
Abrasion plus impact plus heat resistance
heat resistance than the oxyacetylene weld in
which the primary tungsten carbide particles If any degree of heat resistance is required, as
become oxidised rapidly at around 500 0 C. in rolling mills, e.g. primary mill rolls,
However, the arc deposit is not generally used pinch rolls, or table rolls, martensitic low
for heat-resisting applicatiOns. alloy steel weld metal may be used from
The austenitic and martensitic irons often Group 1 provided it contains a minimum of 5%Cr;
referred to as the chromium carbide types have although higher heat resistance and hot strength ,
slightly lower abrasion resistance than the is obtained by the use of one of the martensitic f:l,.
tungsten carbide types but are somewhat cheaper stainless steels which come in the second n
[j
and are used extensively in earthmOving and horizontal line of Table 1.
~ I
24
0': I
-·-' 1
" I
I
,/
25
I
4 Steel mill roll journal built up with Cr-Mo-Mn alloy steel deposit
I
t
(Coutesy Stubs Welding Ltd and Dowding and Mills Ltd)
I
I
26
The preheating temperatures are generally deposition of alloys of 600HV and higher.
lower than would be used for making welded Post-heat treatment is sometimes required
jOints in the same parent metal because hard- either for the reduction of residual stresses or
facing consists of bead-on-plate deposits which to soften hardened HAZs. If a hardfaced com-
gi ve rise to the lowest restraint of any type of ponent in a high hardenability low alloy steel
weld. For example, hardfacing medium carbon is to be subjected to shock loading in service
steel rails is carried out with a preheat of a quite complex and carefully controlled heat
lOOoC whereas a butt weld in the same treatment cycle may be required.
material would require a preheat of 200 o C. When welding tool steels which are heat
Higher preheats are required when treated after welding an electrode must be
depositing the harder alloys because they are chosen to produce a weld deposit that will
more brittle, and preheating reduces the respond to heat treatment in the same way as
differential contraction on cooling of the base the tool material. This does not mean that the
and weld metals and prevents cracking of the weld metal should have the ·same c()mposition
low ductility deposit. The level of preheating, as the tool steel, but it should be able to
which should be applied to mild as well as tolerate the same heat treatment cycle whether
hardenable steels, can· be up to 5000 C for the it is oil, water, or air hardening.
27
5-Met allurgical aspect s of weld surfacing I
D. J. Ellis and S. S. Peate
I
In modern industry increasing use is being made of surfaced materials as a means of achieving the
I
optimum balance of strength, special surface properties, and economy.
The factors which affect the choice of process and surfacing material for a specific application
are quite complex, because no single factor is overriding. When consideration is being given to
weld surfacing components the questions when, why, and how must be asked. The following
I
checklists may be helpful as a guide to answering some of these questions.
CHECKLIST 1 - THE DECISION TO WELD SURFACE I
Stages Factors to be considered Further information
1 Establish facts i
ii
Materials currently used
iii
components
Actual or anticipated life
erosion, corrosion, and oxidation
Consult maintenance, service,
I
of component and performance records
iv
v
Minimum economic life
required
Consequential costs that
Ask the user
Examine:
I
can result from surface (a) cost of replaceme~t
deterioration (b) labour costs for replacement
(c) lost production costs
I
(d) cost of consequential
damage to other equipment
(e) time scale for replacement
(f) extended customer delivery
date
I
/
"
iii
Hold extra spares
(c)
and changes in material of
component(s)
consider metallurgical and
I
mechanical aspects arising
from (a) and (b)
(d) simplify design to facilitate
servicing
(e) incorporate scope for fJ
salvage schemes for parts a!
subject to surface
-deterioration '
28
nient needed, and metallurgical
compatibility of base and sur-
facing material with respect to
heat treatment response
General factors
Surfacing process available Processes available on the shopfloor may limit
available options
Available forms of particular surfacing alloys Som!,!, alloys are available for one or two
prooesses only
Weight of coating to be applied Choose appropriate process, consider deposition
rate
Previous methods of fabrication Welding, brazing, soldering, shrink bolting,
could fabrication fail during surfacing?
29
CHECKLIST 3 - FACTORS AFFECTING CHOICE OF CONSUMABLES
Several surfacing alloys may often be selected to meet the conditions of the application. Some may
perform better than others, they may vary in price, different application processes may be
required, and so on. Below are listed, without specific order, many of the considerations which
will assist selection.
Properties required of applied surface
General factors Comments
What is the service temperature? Look for required properties in the surfaCing
alloys
What is the working environment? Corrosive, oxidising, abrasive, etc?
What conditions have to be accommodated?
Are testpieces needed? Important if difficulties are anticipated i I
Is dimensional rectification needed prior to
surfacing?
Will future repairs be needed? Some materials can be built up again, others
need removal before reclamation
Will surfacing repairs be needed? Ensure process and consumable availability
Can the base material be changed to improve Often enables the choice to be extended and
weldability ? better alloys selected !
What is the overall function of the surface? 'Wear' is a complicated problem, the particular
I
environme.n t must be critically assessed
What are the permitted defects? Ensure standard can be met
Microhardness needed in deposit Often specified but may not accurately determine
'wear' resistance
Microstructure needed Resistance to a heavy metal load needs a
different structure from, say, high stress
abrasion
Resistance to: Abrasion High stress? Low stress? Rubbing or impact?
Corrosion Often affected by minor alloying elements;
consider service stresse~ in relation to stress ,
Oxidation
Erosion
corrosion
Wet or dry? Static or dynamic?
Solid? Liquid or gaseous?
I
Seizure Mating surfaces and conditions are important
Is coefficient of friction important? Can be very low with many surfacing alloys
What impact forces encountered in use? Has toughness to compromise hardness; is
subsurface toughness an advantage?
Is thermal conductivity important? At times yes; a thermal barrier can be
engineered
Is electrical conductivity important? Bond properties, conductivity of surfacing
material
30
Is degradation of surface in service a problem? Process time/temperature can modify surface
Need deposit metallurgy by controlled? Process temperature can alter composition/
structure significantly
CHECKLIST 5 - FINISHING NEEDED ON DEPOSIT
What surface finish is necessary? Can the part be used I as-deposited ' ; need it be
machined?
How much distortion is permissible? Must heating be uniform; must it be minimal?
i
i
I
I
I
I
E
~
~
~
I
31 r
!
r
f
6...,Weld surfacing processes I
A. M. Horsfield I
The purpose of this Chapter is to give a
I
REPAIR AND MAINTENANCE OPERATIONS
general introduction to the subject of weld
surfacing by the arc welding processes. Other Most reasonably large manufacturers have a
material covering more specific applications Maintenance Department responsible for keeping
will be found in subsequent Chapters. the production units running, partly by
INTRODUCTION
Weld surfacing is a process in which a metal
preventive maintenance schemes and regul.-ar
servicing of machinery and partly by repairing
worn equipment and making emergency repairs
I
is deposited on the surface of a base metal
either to build it up to the dimensions required
or to impart special surface properties such
when a stoppage occurs.
Welding naturally plays a big part in such
work, particularly for emergency repairs or
I
as resistance to wear, abrasion, impact, or building up worn parts, but unfortunately in far
corrosion. It can be used in maintenance and
repair applications to reclaim worn parts, or
it can be used as part of the production process
too many situations such work is regarded as
a temporary expedient 'to keep the wheels going
round until we can get a replacement part' ..
I
I
in the manufacture of new articles. Today this attitude is wrong in that it
In both these situations the primary object neglects the advances which have been made in
is to save money and materials, and what welding technology and thus wastes resources
started out as a process for making an emerg- which could be more profitably employed
ency repair until a new part could be obtained
is today an economic tool enabling manufacturers
and users to cut costs by reducing the consump-
elsewhere .
In heavy engineering it has been common-
place to scrap a component once its useful life
I
tion of expensive metals such as chromium, is over; a fact which a visit to the scrapyards
nickel, molybdenum, tungsten, and niobium.
A piece of chemical plant made from
in any large industrial city will confirm.
USing the welding techniques available today
I
S"Omm thick acid-resisting stainless steel could many a scrapped component could have been
often be replaced by one made from 70mm
thick unalloyed structural steel, weld clad with
an Smm layer of the same aCid-resisting
reclaimed at least once thus doubling or trebling
its useful life. .
Why then is it so difficult to persuade
I
stainless material with appreciable savings in management to abandon the throwaway philoS-
cost. Instead of stainless steel other materials ophy and adopt a save and reclaim policy?
such as nickel, Inconel, or even aluminium There are several reasons why this
b-ronze can be used according to the environment should be so, and they will be dealt with under
and service conditions to which the object will
be exposed. Complex, relatively expensive
wear-resisting alloys can be deposited on
the following headings:
to throwaway worn parts which could be which means starting as near the top as
;
salvaged by welding, and, although maintenance possible. As most welding manufacturers !;
H 11
and repair welding has grown very much during know, this is not always easy and calls for ~
!j
:;:. .:
the past decade, there is still much to be done. persistence and a different approach from that g
~
(;1
~I ~J
~
~]
32 ~ sa
I
needed to sell filler materials for welding mild 4 Metal B: i. e. more or less undiluted
and low alloy steels. filler Iretal which gives the desired sur-
Fortunately, in the large heavy engineer- face properties. Naturally the influence
ing concerns there is a growing awareness of of the base metal becomes less as the
the need to reclaim equipment wherever number of layers is increased. Normally,
possible; small and medium-sized engineering after the third layer, the weld metal is
companies are often more difficult to approach. almost entirely free from base metal
Fear of premature failure of the repaired part It is quite clear that the composition and
state of the base material are going to affect
By this is meant the suspicion that welding will the properties of the first layer of weld metal
only make things worse. This attitude is deposited since the first layer will always be
common amongst Production Managers who at diluted with the base material. To avoid
some stage in their career have been obliged possible difficulties it is therefore highly
to learn something about welding. They have desirable to know the composition of the base
heard about things such as carbon equivalents metal, particularly its carbon content, before
and the fact that precautions should be taken attempting a repair. The carbon content can
if the carbon equivalent exceeds 0.45, and are
have a great effect on the hardness of the first
therefore very difficult to convince that certain
layer, particularly if the surfacing composition
commonly used medium to high carbon steels
is a low carbon chromium-molybdenum type.
can be welded with any degree of success. There is also a risk of cracking in the HAZ if
It is also unfortunate that, when a repair
the cooling rate is too fast, and a rutile elec-
weld does fail, it attracts far more attention trode was used instead of one that was basic
than the hundreds of successful welds whose covered. If the base metal compositi~n is
service life exceeds expe'ctations. known it enables the best electrode to be
It is worth mentioning here that the
selected and the optimum welding procedure
causes of failure are often obvious to the and heat treatment to be worked out. If the
specialist and can usually be traced to ignor- base material is particularly difficult to weld
ance in the choice of either the filler material
it may be necessary to find a compatible
or the welding technique or both. material to use as a buffer layer (often a fully
The weld can be regarded as four distinct
allstenitic stainless type) before depositing the
zones, Fig.l: final layers.
If troubles are going to occur they usually
1 Metal A: base material unaffected by the
do so in the first layer, but it is possible that
welding process
the defects will not be noticed until subsequent
layers have been deposited. The increased
2 Metal A: heat-affected zone (HAZ). The
level of contraction stresses and residual
heat from welding has been sufficient to
stresses may then cause cracks to open up.
cause structural changes in this region.
Two types of surfacing application were
If the heat input is high the HAZ can
mentioned in the Introduction, 1. e. reclaiming
itself be further subdivided
worn and the production of new parts. Most
cases of failure occur in the former group for
3 Mixed zone: first weld layer whose com-
the simple reason that the object in question is
position consists of approximately 70%
made from a material whose composition is
filler metal and 30% base material.
usually unknown. The person responsible for
These figures depend very much on the
the repair has therefore probably made a guess,
welding process and welding parameters
or at the most done a spark test, and arrived
used. Dilution, i. e. the percentage of
at the wrong conclusions, thus greatly increas-
base material in the deposit, can be any-
ing the likelihood of using the wrong filler
thing from lO to 60%. As a general rule
material and the wrong welding technique.
it should be kept as low as possible
If the maker of the part is known the
first step should be to contact him and ask for
the composition of the part in question. When
this is not possible a chemical analysis and
metallographic examination should be carried
out wherever possible, and all cracks (including
subsurface ones) should be removed completely
before attempting a repair. This means that
the part must be carefully tested nondestructively
and thoroughly cleaned and degreased before
Four zones across welt'! area: metal A is base material, metal B is welding. ..
weld surfaced material Where weld surfacing or hardfacing is an
33
integral part of the design of the component using covered electrodes offers the widest
the problems are much simpler, since the range.
welding metallurgist cim now select the Solid wires for GMA or submerged-arc
materials he needs to give the desired results. welding are available in a restricted range of
He can in fact go a stage further and design compositions, but metal-filled tubular electrodes
the component for subsequent reclamation after are available in quite a wjde range. Tubular
a calculated amo).IDt of wear has occurred. wires of the self-shielding type are also
This is a very important concept which
could save many millions of pounds annually if
available in a wide range of compositions.
In stainless cladding using wire, solid
wires are available for GMA and submerged-
I
only it was adopted more widely.
arc welding . in all the standard qualities, and
Components subjected to wear should be
the same applies to strips for strip cladding.
designed in such a way that. they can
Assuming that suitable filler material is
be resurfaced economically after a
available the next factor to influence the choice
predetermined amount of wear has taken
of process is the size and configuration of the
place
workpiece and the type of surfacing operation
Of course not everything can be designed in
to be carried out.
this way, but it is being applied to steel mill
rolls with very promiSing results. Other suit-
able objects which could be dealt with in a
similar way are blast furnace bells and hoppers,
SUBMERGED-ARC WELDING
For a workpiece such as a large steel mill roll
I
in which the weight of surfacing material to be
crane wheels, crushing hammers, hot shear
blades, etc.
The big advantage of planned reclamation
deposited is measured in tonnes rather than
kilograms it is essential to use a high
deposition process such as submerged-arc,
I
is that the useful life of the object can be
increased many times at a cost little greater
than that of the original component. Component
life can thus be maximis~d and costs minimised.
preferably with twin electrodes connected to
the negative pole of a DC power source.
With such a system, deposition rates up
I
to 25kg/hr at 1200A are possible for each weld-
It is in this field, i. e. the design of parts for
ing head. Note that negative polarity has two
fabrication and subsequent reclamation by weld-
advantages: it decreases penetration into the
ing, that much work remains to be done.
base material and increases the deposition rate
The cost of repair is too great compared with the of the electrode by an appreciable amount.
cost of a new part . For example, at 800A the deposition rate is
about 9kg/hr electrode positive and 13kg/hr
This is often given as the reason for not
electrode negative.
attempting a resurfacing or repair operation on
Since in most instances a certain working
a worn component, but before deciding whether
temperature has to be maintained, and it is
this assumption is true it is first of all
usually better to weld the job to completion
necessary to decide which welding process is
without stopping, the increased deposition rate
the most . economical. There are three arc
welding processes to choose from:
on negative polarity is very valuable apart
from savings in labour costs.
I
Blast furnace bells and hoppers have been
1 t. Manual welding with MMA electrodes
reclaimed using the submerged-arc process in
2 Gas-shielded metal-arc (GMA) welding
a so-called twin-hot/twin-cold system, i. e. twin
using alloyed wires (either solid or
current-carrying wires are used in the normal
tubular*). Usually carried out under a
way, but two non-current-carrying wires are
gas shield of argon, C02, or argon/C0 2
fed into the arcs to increase deposition rate
mixtures, but wires are also available
and decrease dilution. The current-carrying
which require no gas shield or external
wires are normally connected to the negative
flux
pole, the cold wires being accurately fed into
3 Submerged-arc welding using alloyed wires
each arc at a predetermined rate.
(solid or tubular) and plain or alloyed
fluxes
Deposition rates varying from 30J<g/hr at
llOOA to 42kg/hr at 1400A can be obtained by
this process. Since the amount of weld metal
'..
D
~
,-
J '
The choice of process depends first of all upon
to be deposited in this application can be about
availability of suitable filler material com-
5000kg, deposition rate is clearly important
positions, and it is here that MMA welding
if the surfacing operation is to be economic.
In twin-wire welding the electrodes are
fed through the same contact nozzle and are
*When tubular wires are used the process is thus electrically in parallel. The welding
sometimes refelTed to as flux-cored arc currents quoted above are thus divided evenlY
welding. between each electrode. A series of curves
34
showing the deposition rate for different modes Table 1 Submerged-arc welding
of submerged-arc welding is given in Fig. 2.
The wires used are metal-filled tubular types Main characteristics
4mm diameter; the deposition rates would be
somewhat lower with solid wires. 1 Fully automatic process
. The submerged-arc process has also been 2 High deposition rates (15kg/electrode/hr)
used to surface small diameter shafts. In such 3 Wide range of consumables available
cases a single electrode is used since there 4 Excellent deposit appearance; minimum
are difficulties in supporting a large weld pool fintshing required
on small diameter workpieces. An advantage 5 Equipment expensive
of the submerged-arc process is the ease with 6 Regular maintenance of equipment
which it can be mechanised. necessary
The main characteristics of submerged- 7 Suitable for workshop use only in sub-
arc welding are summarised in Table 1 .. stantially fixed installation ,although
special portable equipment for "in situ
GAS-SHIELDED METAL-ARC WELDING
deposition is available
This process, sometimes referred to as metal 8 High penetration and dilution but can be
inert gas (MIG) welding, can be used for semi- reduced by appropriate procedure and
automatic welding or in fully mechanised technique
systems using solid or metal-filled tubular 9 Generally limited to simple round or flat
wires. As with the submerged-arc process components
the choice of solid wires is limited because 10 Strip electrodes and equipment available
many of the highly alloyed compositions needed for strip cladding
for hardfacing are difficult or impossible to
produce in wire form. It is for this reason Typical applications
that tubular wires made from a mild steel
sheath with the alloying elements in the form 1 Steel mill rolls and rollers
of metal powder placed inside are being used 2 Crane wheels
in increasing quantities. Such material is 3 Shafts
4 Blast furnace bells and hoppers
50
48 easy to draw or roll to the required diameters,
46 and an increaSingly wide range of compositions
44 is becoming available. The process can also
42
Twin hot - twin cold 40mm extension be used without shielding gas using the so-
Electrode negative called self-shielding or open-arc type of
40
tubular wires. A comprehensive range of
38 Cold electrode feed
compositions is available, and, as external
36 speed 900-1400mm/min
shielding is unnecessary, longer wire extensions
34
can be used to improve the deposition rate.
32 Where very high deposition rates are
30 concerned GMA welding cannot compete with
'- 28 the multiwire submerged-arc process described
--
.<::
t J)
.Yo 26 in the previous Section. It can, however,
~ 24 compete with the single-wire submerged-arc
e process and the small diameter shaft could
c 22
...
0
35
filler material manufacturers) have shown that it is clear that, for a given weld metal com-
the cost of the weld metal deposited by the position, the labour c ost will alway s be lower
GMA process is approximately half that of MMA with the GMA process .
weld metal. The calculation, . which was made Since the semi - automatic welding machines
in the Netherlands, took into account: maintain a constant arc length the final result i·
I
is not so dependent on the skill of the welder I
as it is when the MMA process is used.
Labour cost
A summary of the main characteristics of
Depreciation of we lding plant
the GMAprocess using tubular wires is given I:
Gas consumption
Power consumption in Table 2, which also applies in many respects
to self-shielded processes. The GMA process
Efficiency of flux-cored wires (85%)
using solid wires is also very suitable for
Duty cycle (arc time factor): 45% for GMA,
surfacing with nonferrous metals such as copper
30% for MMA
and its alloys, nickel alloys, and stainless
Net price of consumables
steels. .
Submerged-arc can be used for certain of
Note that the efficiency of the flux-cored wires these alloys too, such as lnconel, stainless
was taken as 85%. If the wires were only steel, aluminium bronze, and Monel, but again
metal filled (no flux) the efficiency would be at the most suitable process to choose depends
least 95%, but in practice slag formers are upon the size and shape of the area to be
present so that each kilogram of wire gives surfaced. For the internal cladding of pressure
about 850g of weld metal.
The actual costs obtaineq for lkg of weld
meral were:
vessels and chemical plants with stainless steel
or Inconel, the submerged-arc strip cladding
process has been extenSively used. The GMA
I
MMA electrode
Tubular wire
5mm dia .
1. 6mm dia.
£9.40
£5·. 40
process using an oscillating electrode to make
wide, low penetration beads is also a l.lseful
technique to employ on certain types of work-
I
Tubular wire 2.4mm dia. £4.50 piece. A summary of the characteristics of
the GMA process using solid wires is given
in Table 3.
This was for a low alloy wire glvmg a hardness
of 250-300HV. Although these figures will vary THE MMA PROCESS
according to the composition of the weld metal Although predictions have been made that stick
electrode welding will eventually be forced to
Table 2 Tubular flux - core wire welding, give way to GMA or sUbmerged-arc processes
self-shielded or with gas shield it is still very much alive, and there are good
reasons to assume that it will be with us for a
Main characteristics long time yet. It has the following very
important user advantages:
1 Continuous process that can be used semi-
automatically with a hand-held gun or be 1 Capital investment is low
made fully automatic by traversing the gun 2 There are a large ·number of alloys to
or workpiece mechanically choose from
2 Wide range of consumables available 3 There are a large number of electrode
3 Medium penetration similar to MMA arc manufacturers to choose from
process 4 It is a flexible process and the only one
4 No gas required for self-shielded process that can readily be used for on-site
5 High deposition rates of up to 8kg/hr for maintenance and repair
C02-shielded process and llkg/hr for 5 Special compositions can be made easily
self-shielded process and quickly in small quantities
6 Equipment relatively expensive
7 Regular maintenance of eqUipment is Limitations
necessary
8 Restriction on transportation similar to 1 Low deposition rates mean relatively high
the GMA process with solid wires labour costs
(see Table 3) 2 Results depend upon the skill of the welder
36
Table 3 Gas-shielded metal-arc welding,
solid wires CJ
Main characteristics
37
I
The first three apply to the deposited weld
metal, the fourth to the base material.
In many situations 100% defect-free weld
metal is not essential and some cracks or
porosity have little effect on the service life
or performance of the welded part. However,
small cracks remain. The workpiece should
then be cleaned and degreased before starting
the repair.
. Dilution can cause the deposited weld
metal to have a hardness which differs widely
from the value expected, owing to pickup or
•. ~
if the surfaced component is subject to tensile loss of carbon and alloying ~lements. The
I
or alternating stresses, e. g. a shaft or' steel
mill roll, cracking must be avoided otherwise
fatigue failure is probable.
greater the difference in composition between
the workpiece and the undiluted weld metal, the
greater the effect of dilution. This effect can
I
Heat-affected zone cracking should be be minimised by using an inherently low
avoided in all circumstances, but particularly dilution process or by modifying the deposition
when alternating or impact stresses are
involved. The danger here is that the crack
will propagate and eventually cause the weld
metal to part from the base material.
Causes of weld defects
technique of a normal dilution process. One
example of a low dilution process is gas .
tungsten arc welding (GTA) , often referred to
as tungsten inert gas (TIG) , which is unfortu-
ately slow and therefore suitable only for
relatively small jobs. Manual metal-arc and
t
When investigating the causes of weld defects the semi-automatic gas-shielded processes can
the following suggestions may help to pinpoint give reasonably low penetration if the arc is
the source of the trouble: directed more toward-s the previously deposited
(a)
(b)
filler material was unsuitable
wrong welding procedure was used
weld metal than the surface of the workpiece.
This technique, which is sometimes referred to
as 'shingling', appreciably reduces penetration
I
(c)
(d)
surfaces to be welded were dirty
there were cracks in the part to be
welded
into the workpiece and hence decreases dilution.
To minimise the risk of porosity and
.. cracking good welding practice should always be
I
I,·
(e) excessive weld metal dilution was . followed. Remember- that many of the materials
obtained used in surfacing applications are appreciably
more highly alloyed than those used for 'welding
The wrong filler material may have been structural steels, so that problems caused by .
chosen because the composition of the base hydrogen in the weld metal are intensified,
material was unknown or because insufficient . particularly in air-hardening steels and weld
attention was paid to the service conditions metals.
and type of wear involved .
.·If the base material has poor weldability Table 5 Applications of weld surfacing
it may be necessary to use a ductile buttering
layer compatible with both the base metal and 1 Internally cladding vessels with stainless
the wear-resistant weld metal. . steel or Inconel ~
The welding procedure is largely dictated 2 Externally cladding rolls with stainless II
by the type of material involved and particular steel or hardfacing alloys
attention must be paid to preheat, heat treat- 3 Depositing wear-resistant metals
ment after welding, and final cooling rate. In 4 ReinforCing excavator buckets and dredger
some applications the deposited weld must have buckets with corrosion- and abrasion-
a uniform metallurgical structure if uneven resistant welds. Fig. 2
wear is to be avoided. This is usually 5 Rebuilding hot-working tool forging dies
achieved by putting the welded object into a etc. with cobalt/t.ungsten-alloyed hot
furnace immediately after welding, heat treating working alloy
it, and then allowing it to cool at a controlled 6 Rebuilding high speed tools with a high
rate. This is often done with steel mill rolls carbon Cr, Mo, W ,V high speed steel
where uniform wear is essential. In deciding . deposit
upon a suitable heat treatment TTT (Time - 7 Depositing fully austenitic manganese steel
Temperature - Transformation) diagrams are to give a soft deposit which work-hardens
very useful and have been determined for some 8 Depositing austenitic high carbon/high
of the alloys used in roll cladding. Those TTT chromium-iron alloys for abrasion
diagrams determined for a particular steel can resistance combined with corrosion
also be used for weld metals having a similar resistance
composition. 9 -Depositing coppe-r-based materials to give
In repair applications cracks must be a nonseizing bearing surface combined with
completely removed before welding. After the corrosion resistance
workpiece has been prepared for welding it 10 Buildup of worn parts
should be crack-detected to ensure that no
38
.":;"...'.""1-', :
Irrespective of the job or welding process applied to the reclamation of worn parts; but
used, all wires , fluxes, covered electrodes, the importance of the technique in the manu-
etc . should be dry, free from rust, and facture of certain components has also been
stored according to the makers' instructions. stressed.
Where the base material is hardenable As alloying elements become scarcer,
thoroughly dried basic covered electrodes or and henceniore expensive, increasing efforts
basic fl1,lXes sho~d be used. will have to be made to conserve them by
their correct application. One way of doing
APPLICATIONS this in applications involving wear, corrosion,
A summary of the main applications of weld or abrasion is to make the component of
surfacing using arc welding processes is given unalloyed steel and then surface those areas
in Table 5. There are many others, some of which will be exposed to attack. In many
which are described in detail in subsequent instances this is clearly cheaper than making
Chapters. Table 5 is therefore a list of the the whole component of stainless or wear-
main groups rather than a detailed list of resisting steel.
specific jobs which can be carried out. To ensure minimum costs the correct
filler metal and most suitable welding process
must be chosen and correctly applied.
CONCLUSIONS
Consumables manufacturers usually have expert
The aim of this Chapter has been to arouse staff ready to give advice. Do not hesitate to
interest in weld surfacing, particularly as make use of this service.
39
7-Welding st eelworks rolls II
~
considered in terms of economics, deposition product quality, mill scheduling, and roll
rate, quality, and Htpess for purpose. The maintenance. It is essentia.! to
consider all
cOIl~ept of weld surfacing as a method of these factors when endeavouring to improve the
duplex roll construction is illustrated by overall performance of mill rolls.
reference to' development work on the
submerged-arc and electro-slag cladding of
Within any specific type of mill there can
be a number of rolls and rollers, but the
major cost item is normally the work roll.
I1
rolls within the British Steel Corporation.
INTRODUGTION
In recent years there has been an increased
Tables 1 and 2 give some indication of the
Table 1 Roll types* I
awareness of the possibility of using surfacing Work rolls for A uxiliary rolls including
techniques to improve the performance of
steelworks plant. This trend has been the Blooming Edgers I
result of developments inboili equipment and Slabbing Downcoilers
materials technology. Most notllble is the
significant conceptual step of the fully designed
-and engineered weld-surfaced roll, which is
Section
Billet
Plate
Table/ transport
Plate levelling machine
rolls
I
!2reaking away from the constraints of roll Hot strip Billet straightening
reclamation and offers the user much more
scope for improved roll performance and
Rod
Bar
roils
I
reliability. Tube
The influence which the performance of
rolls has upon the technical and economic
operation of a mill varies in degree with the
Cold strip
40
.... '.~ ."'11
Table 3
41
readily deposited by metal spraying ,the nature APPLICATION OF SUBMERGED-ARC CLADDlNG-
of the bond with the parent metal and the HOT MILL ROUGHING ROLLS
stresses in the deposited layer impose limits In general the metallurgical requirements of
to the thickness and tbe application for which hot mill roughing rolls are for hardness levels
such coatings are ·suitable. Conseq.uently, one of between 3 QO and 650 Shore, and, depending
would not expect to see this technique applied on actual application, for varying degrees of
to large or higbly stressed work rolls. resistance to both wear and thermal fatigue_
Roll design usually allows for several
Gas-shieldlll;! metal-arc welding campaigns within the mill, with intermediate
roll dressings, and typically deposits of 50rum
Semi- or fully automatic GMA welding is not
thickness are required to accommodate the
widely applied for work roll surfacing, but has
reduction in roll diameter to scrap size. It is
been successfully used to deposit thin layers of
essential, therefore, that the metallurgical
stainless steel on shafts. It is a multilayer
characteristics of the deposit are uniform .
process and compared with submerged-arc
throughout the thickness and tbat the effect of
welding has the advantage of being fluxless.
structural changes associated with beat-affected
This aspect migbt be considered significant
zones between adjacent weld beads is minimised.
where very higb quality deposits are required.
Usually 1. 6 or 2.4mm welding wires are
used and deposition rates are lower than for
Tbe submerged-arc clad roll must compete
directly with cast or forged steel rolls, which
m:ty be differentially hardened. In general,
I
submerged-arc welding.
I
owing to tbe bigh servfce stress and hardness
Submerged-arc welding requirements, large backup rolls and alloy
iron rolls for use in finisbing stands are not
With a single bead deposition rates of up to
normally clad by the submerged-arc process.
I
30kg/br are attainable using twin 4mm welding
To summarise, the technical requirements
wires. For large plain barrelled rolls two
for a submerged-arc weld . deposit are:
welding heads can be operated side by side to
give high deposition rates for thick multilayer
deposits. A range of properties can be
obtained, depending upon the composition of the
weld deposit and the subsequent heat treatment
1
2
3
Higb deposition rates (minimum of 20kg/br)
Freedom from significant weld defects
Uniform weld metal composition and
-I
response to heat treatment
procedure. Compositions are restricted by'
4 Adequate properties to meet mill
metallurgical factors affecting both hot and cold
requirements
cracking.
Electro-slag cladding
Spray MIG SA ES
Russian and Czecb literature indicate that the
Expanding
process, which produces a single layer of from activity
15-100mm thickness, can be operated at
deposition rates of 200-400kg/br depending on
roll diameter. Tbe intrinsically high heat
input of the electro-slag process influences the
Selective Growth
solidification pattern and metallurgy of tbe growth ?
surface. The process is most suitable for
cladding plain barrelled rolls.
Each of tbe four welding processes
considered has some relevance to roll surfac- Growth
potential
ing, and in Fig. 2 an attempt is made to
indicate the likely distribution of techniques
between roll types and to suggest the likely
potential for future application. The BSC
development programme is based on an
assessment which considers the metallurgy of
available materials, the type of mill, and
0 Primary + SM
42
The BSC and the Swedish welding company
ESAB have completed a joint development
rogramme on submerged-arc cladding of work
p .
rolls, which has involved the design and
development of special welding equipment, the
formulation of a range of consumables for use in
steel mills, along with process and application
know-how. *
Plant development
For the submerged-arc cladding of large rolls
it is necessary to develop special equipment
suited for continuOUS three-shift operation, with
roll preheat temperatures of greater than 3000 C
and resistant to flux dust or fumes. To obtain
satisfactory deposition rates it is necessary to
have a welding system capable of twin-wire
welding .at 1250A if a 4mm diameter electrode
is to be used.
The BSC - ESAB development has resulted
in custom-built equipment which meets these
stringent requirements. The welding head is
the most critical item of equipment, and the
design which has · proved successful incorporates:
I Welding consumables
To achieve the range of deposits and properties
necessary to meet the requirements of a
variety of mills, there has been a continuing
development programme which, in general 1-5
New development
~
Consumable development
*The joint ESC-ESAB technology on submerged- 9-12 Commercial production monitoring leading to initiation of
arc cladding has been called SARCLAD further development
technology. SARCLAD is a registered trade-
mark. 4
i
· 43 i"U
assessment of economic and technical require-
ments is made, and then a number of candidate
materials which may be based on several alloy
systems are evaluated. Weldability, analysis
control, heat ~reatment response, temper
resistance, wear rate, and thermal fatigue
6
I
resistance are each considered in detail. To
a chieve uniformity of composition and '~ I
properties it is essential that the weld metal! <U
flux system is stable over a wide range of
single and twin-wire welding parameters. !1 ;.
I
u
0
e '--I
materials~ It has been noted, both in the
laboratory thermal fatigue tests and in service,
that the fine structure of a weld deposit
performs better than the equivalent wrought
I
material. The 12%Cr series of deposits was
selected because of their unique combination of
hardness, strength, and toughness coupled with (bl Alloys tempered 500°-575°C
temper resistance and resistance to oxidation.
They can be heat treated to a uniform metal-
lurgical structure which makes them particularly
well suited to plain barrelled rolls where surface 5 Comparative properties of conventional roll and weld-
finish is important. surfacing alloYS: (a) wear, (b) thermal fatigue
Recommended
Nominal composition hardness range
44
\-
Figure 6 shows a selection of clad rolls. last five years duplex chrome-iron rolls
In primary mills excellent results have been produced by double pouring and centri-spllnling
obtained for both blooming/slabbing and have given marked improvements in service
universal slabbing mills, the most Significant life, particularly in the intermediate stands of
improvement in performance compared to modern hot strip mills. Electro-slag cladding
conventional forged and cast steel rolls .. offers an alternative method of manufacture of
Results in hot strip mill roughing applications these types of rolL Laboratory results indicate
are at least equivalent to the best differentially that the electro-slag process gives a· more
hardened roll currently available. uniform carbide structure in nickel and chromium
white irons than is obtained by conventional
ELECTRO-SLAG CLADDING casting techniques. Also, the possibility of
The characteristics of the electro-slag process reclaiming hot strip mill rolls by electro-slag
outlined earlier in this Chapter have been used cladding of either iron or steel rolls with an
for the 'production of duplex alloy iron rolls. alloy iron appears economically attrar;:tive.
The process offers: The BSC has undertaken a major develop-
ment programme over the last five years to
1 Single layer deposits assess the application of electro-slag cladding.
2 The ability to deposit high carbon alloy One of the techniques evaluated is shown in
irons Fig. 7. The arrangement consists of a number
3 A refined metallurgical structure free of wire feed units arranged round a static
from defects arbor and water-cooled copper crucible so as
to deposit a uniform shell of iron on the roll
For this reason BSC has evaluated electro-slag body. The alternative technique, developed by
cladding for ·the manufacture of hot strip mill the Paton Institute in the USSR, is to melt a
finishing rolls. centri-spun tube electrode on to a central roll
Indefinite chill iron rolls are commonly body. Although Simpler in principle, this
used for hot strip mill finishing rolls, and technique proves to be difficult with large rolls
loll between 2 and 3000 tonnes of strip before and limits the choice of alloys which can be
returning to the roll shop for dressing. In the deposited.
(a)
(b)
ACKNOWLEDGEMENTS
The authors wish to thank Dr K. J. Irvine,
Manager, Sheffield Laboratories, ESC, for
permission to publish this material and their
many colleagues who have contributed to the
8 Longitudinal section through NiCrFe clad medium carbon steel development work described.
arbor --
46
f¥!ifX~\;i.f;~";1'; """
:'
47
During the years on home ore practice, A summary of service lives through the
wear protection developed from mild steel and periods which have been referred to is given
special steel wear plates to mild steel plates in Table 1.
with various levels of weld-applied coatings,
the ultimate success being achieved with the
selective use of high percentage chromium
(b) hardfacing applications
Internal workshops, with specialised sections
I
carbide and tungsten carbide, when lives in equipped to carry out most methods of applica-
excess of 21h years or 2. 5 · million tonnes of
sinter were achieved.
With the introduction of a high percentage
tion, are used for the majority of hardfacing
appllca tlons. This probably unique position has
ensured adequate technical support to all appli-
~
., ~
I
of foreign ore into the raw mix for sinter pro- cations and has considerably assisted develop-
duction, wear on the impellors was increased
considerably. This was such that, with the
ment both in methods of application and the
selection and testing of available consumables.
I
levels of wear protection which gave the maxi- The wearing plates hardfaced for the impellors
mum success on home ore practice, impellor
lives dropped to three to four months.
Considerable development work took place
are 9.5mm minimum thick and vary in shape
and size up to 864 x 610mm; special attention
is given to jigging eqUipment, preheat, and
I
and with greater use of high chromium carbide cooling. The details of the present ~pplications
and tungsten carbide deposits the service lives
were improved to just tolerable maintenance
for main suction fan impellors are set out in
Fig. I.
I
levels. These were inadequate and a coordi-
Costs and economics of wear protection
nated study of a wide speCtrum of coating
material, techniques of application, and a com-
parative assessment of their wear resistance
It is always difficuft to establish with any accuracy
what in terms of cash is saved by the introduction
I
was instigated. The redeSign of wear plates, of improvements to a particular plant component.
area, and thickness of applied coatings was
considered, and as a result considerable
The cost of wear protection for each impellor
to the standard set out in Fig. 1 is CUrrently
I
improvement in impellor life was achieved. around £5000. Therefore, · based on eighteen
At present it has been found that tubular
tungsten carbide rods deposited by gas welding
give the highest wear resistance and provide
months' service life producing approximately
1. 25 million tonnes of sinter, the present cost
works out at 0.4p/tonne of sinter produced.
I
the most economical results. in the main suction The value of wear protection is best related
fan environment. Current service lives vary to and measured in terms of improved plant
between sixteen and eighteen months, 900 000- availability. For example, on present operatil)g
1 250 000 tonnes of sinter. Some in situ repairs costs of the sinter plant the cost of 1hr down-
are necessary after eight months and subsequently
at three to four month intervals.
Development work with similar consumables
time is approximately £150. Thus .a savl)1g· of
only four 8hr shifts' downtime in ·a service life of
eighteen months would justify the present cost
I
for manual electric arc and more automatic of £5000.
methods of application is continually in hand for
a number of reasons. The assessment of new SINTER BREAKER TIPS AND BARS
materials using small-scale test rigs and
various systems of in-plant test backed with Introduction
metaUographic examination is given high priority The agglomerated sinter cake which is the end
to improve the present standards. product of the sinter strand has to be broken
Table 1 Sinter plant main suction fan impellors, summary of service lives
Service life
Sinter
Wear protection
practice Sinter output,
Months
tonnes
48
produced. With the change to a high percentage
of foreign ore raw mixes a sinter was produced
both at higher discharge temperatures and with
higher abrasion values. It was soon evident that
improved breaker units would be necessary to:
temperature areas which have to be taken into of sinter plant downtime at £150 /hr . i
t
account in the selection of the wear protection. -- Breaker bars [
49
Table 2 Sinter breaker tips, summary of service lives
Service life
Sinter Breaker Initial cost Cost/ tonne
practice tip type Sinter output, of unit, £ sinter, p
Months
tonnes
2057
51 38
-11-
T-- =r
305
l~ ____________~
~...~
3 Breaker bars for '£' plant showing hardfaced area (shaded): 3mm
Edges ground to allow
full -length heavier bu11dup
~,
..J'
nominal thickness; approximately 6mm along edges; high
.~ percentage tubular tungiten carbide (75-80%W in· filler); gas or
electric application. Dimensions in millimetres
\
\ ~
'~'
~ \ Table 3 Sinter breaker bars, summary of service lives
IJ l
~
50
e of sinter. This is one-fifth the The service life of this test mat was
nn
O. DIp / t°th standard mild steel bar, and seventy weeks, i. e. 579 000 tonnes of sinter.
c ost of ea saving of O. 04p/tonne of sinter is The average life of standard mats, which
therefore involved four changes during the seventy-week
. d' using the hardfaced bar. Based on
achIeve In
e bandied, the ratio is 5.8 to 1 for test period, was thirteen weeks, 114 000 tonnes
sinter tonn ag
to standard bars. The increased of sinter.
har df ace d .
_ f the bardfaced bar of approxImately £22 The cost of hardfacing the test mat, which
cust 0 . tif' d .. was provisional, plus plant fitting, was approxi-
can therefore be JUs Ie on a savlllg lll:
mately £115. The cost of standard Jl}.ats plus
Cost of fitting of 3 to 1 fitting was approximately £30. The economics
1
Downtime, thus loss of sinter output, of of coating screen mats was therefore promising,
2
showing overall a 4 to 1 advantage in favour of
3 to 1
coated mats.
HOT SINTER SCREENS
(b) subsequent progress
Introduction Trials were projected to a full set of screens
After the sinter is discharged from the end of on a screen deck using the same type of
the strand it passes through the breakers and coating. A coated standard mat used in these
then over a screen deck to remove the fines. tests is shown in Fig.4. The results based
In most sinter plant the hot screens are on service life and tonnage of sinter handled
did not equal that of the initial test, but still
respon sl'ble for a considerable
. amount of lost
production tiIlle owmg to the frequent need for showed a 3.5 to 1 advantage. In view of this
maintenance and replacement. and because changing screen mats can be a
The hot sinter screen plate material high manual intensive maintenance operation,
should be capable of withstanding the abrasive the development and wider use of hardfaced
action of the sintered product, often at tempera- screen mats has been considered to be an
tures in excess of 5000 C. It must also possess economic proposition.
adequate mec1:J.anical strength to cope with the
Future developments
stresses imposed by the vibrating action of the
screen and from the impact of large pieces of Further trials are in hand to assess potential
sinter. coating materials and investigate techniques of
application and associated metallurgical
Wear resistance and protection problems. For example, uniformity of
The standard mats, overall size approximately aperture size and shape and overall evenness
1448 x 1067mm , are made in 6mm plate, of deposit will best be achieved by some
punched with 25 x 6mm slotted holes; chemical automated form of application.
composition 0.3-0.45%C and 1. 7%Mn. The The porosity and cracking in the coated
average service life is twelve weeks or deposit on this particular type of screen can
approximately 100 000 tonnes of sinter screened. prove very detrimental in service and must
Initial work was directed to improved
steels, but the practicability of punching the
holes or apertures restricted the better
possibilities. Those successful in the austenitic
stainless steel and medium carbon range proved
to be uneconomic because of the high unit cost
and negligible increase in wear resistance
compared to relatively cheap standard mild
steel mats.
As a result, investigations were directed
to the possibilities of using hardfacing coatings
on thin mild steel screen plates.
51
I
i
I
I
,
"1
~
~
~
therefore be minimised. Premature bilures
of the screens, arising from bad applications,
could quickly destroy any advantages and put
-.i.
.~ I
up screen maintenance costs rather than '
reduce them.
All the tests and comments refer to small
I
aperture screen mats. There is more con-
clusive evidence both on application and service
life with larger aperture screen mats. This is
particularly so in less abrasive conditions such
I
as coal- and coke-handling plant.
tungsten carbide. A service life of five to service life; home ore !linters, fb) redesigned fabricated blade
, six months, i. e. at least 21/2 times the
original life, was readily achieved with the
witfJ hardfaced coating of gas-applied tungsten carbide
\1
,
I
reclaimed blades. With twelve fans in use low as eight weeks during the period of home
this was still not satisfactory from a mainten- ore sinters, i. e. slower abrasion conditions,
ance point of view, but provided time for when original impellor blades had lasted ten to
experimentation. twelve months.
A new fabricated type of blade, Fig.5b,
was eventually designed and approved which
had a much thicker blade construction. This
allowed more adequate hardfacing to be applied,
(b) current fabricated hardfaced blade
The blade is fabricated in 0.35%C, 16mm
thick, steel plate and welded to machine-
I "
1\
and has resulted in service lives of between prepared bosses in similar material. The
twelve and fourteen months.
Wear protection
forward side of the blade is fully hardfaced,
nominally 3mm thick, with a slightly heavier ~
~c
f~·'
52 r'l
e,
;
\;.:...1
~
The cost of production of these fabricated twenty. The service life, as previously stated,
carried out in internal engineering varies between twelve and fourteen months or
bIn d e S
1 shops was approximately £650/set of 900 000 tonnes of sinter produced.
wor,{
........
53
9-Applications of w eld surfacing to pow er plant
T. R. Rowberry
INTRODUCTION I
Boilers and turbines of conventional coal- and
oil-fired power plant are constructed with little
recourse to weld surfacing, apart from valve
seats and stems, the base material properties
usually being adequate for the early life of the
plant. Also the Central Electricity Generating
Board has operated until recent times with a
requirement for high availability from its plant
and, to ensure that maintenance programmes
were kept to plan, favoured complete replace-
ment of worn or damaged components. The
increasing average age of plant, replacement
costs, and delivery lead times now necessitate
a far more critical evaluation of the pOSSibilities
I
for reclamation of worn or damaged items
using a variety of techniques. In certain areas
it has" been possible to improve the life of the
component by coating with materials which will
I
withstand the operating regime but retain the
properties of the base material, but before
considering whether to surface a component it
is important to identify the offending wear
mechanism or mechanisms which may be
abrasive, erosive, adhesive, corrosive, surface
fatigue, cavitation, or fretting.
A major wear area is found in the handling, 1 Wear pattern found on pulverised fuel fan blades
transportation, and grinding of coal. The air /
coal mixtures produced after grinding are not
only potentially explosive "but are extremely blades, 12mm thick and surface-hardened by
erosive to the materials which handle and
convey these mixtures. Pulverised fuel (PF)
from the grinding mills has in the past been
the cyanide process, were standard. The fans
consist of a six-armed spider to which are
attached blades which wear in a characteristic
I
conveyed by cast iron pipework from the PF manner, Fig.1. Considerable variation in the
fans to the boiler for firing. However, life of such blades was experienced and trials
following instances of fires, pipework, fans,
and casings must now be produced which are
resistant to thermal and mechanical shock and
erosive wear.
54
by Mitchell and Skinner1 were instituted to
establish the most economic materials. Failure
. of a blade results in severe damage of the
spider assembly, Fig. 2. Tests on homogeneous
materials using the whole range of alloy steels
gave only marginal improvements in wear life
over mild steel, mainly because the high
hardness materials proved susceptible to failure
under shock because of their low ductilities .
coated materials, however, offered a greater
compromise by utilising the ductility of a mild
steel base allied to the hardness of a coating.
Many methods are available to produce such
coatings not all of which include welding or its
allied processes, and the range examined
included welded, sweated, fused coatings,
attached layers such as tungsten carbide tiles
and vitreous enamel, and surface-hardening
techniques, e. g. case hardening. To rationalise
the data an economic appraisal was evolved:
55
.....,
) i
O-Surfacing for impact resist ance •
~
J
i
P. A. Symons ·1
·i
ROCKCRUS~ERHAMMER~
Introduction
58
wear tolerance (d) operational procedure
(a) ear tolerance that was dependent upon a The operator enters the crushing chamber,
A ~er' s ability to replace worn hammers now adjusts the equipment to suit the welding
we m es a planned maintenance procedure. position, and then resumes his position outside
co
be
UsiIlg an aut oma t"lC we ld'mg mach · · 1t IS
me . the chamber, Fig.4.
ossibl e to replace worn metal at a predeter- Using two switches on a remote control
p . ed rate, giving a flexible wear tolerance. pendant the operator controls the welding
mIll
operation and carriage direction. Control of
(b) alloy selection the amperage and wire feed speed is located
previouS experience of hammer maintenance on the wire feed unit.
the need to avoid spalling and encourage Welding is continuous until the operator
an d
an even rate of wear point to a high chromium considers the buildup to be sufficient. The
austenitic manganese steel: same procedure is used in all other rotor
positions until all hammers have been built up.
Cr Mn
C
0.3 17.0 14.0 %
3 i
Worn hammer
profiie
I
!~
~
g~
~
~
~
~
j " , .'
~
~
.~
~
~
~
~
Rotor position 2 ,,•'
~
g
~
2 4 *
G
t4
~
~
59
'.
~,
r.
l
(e) equipment (b) parent metal
A 650A rectifier with a wire drive unit linked Both mild steel and 14 o/olVln steel have been
to a BUG-O track and carriage · assembly. used with economics slightly in favour of the
. Results
60
alloys, stainless steels, and austenitic niobium carbide structure has pr~ed to be
manganese steels for impact resistance, to the successful in similar applications , having a
high carbon chromimn and tungsten carbide hardness of 700IN with a high resistance to
alloys for resistance to abrasion. When com- impact. The composition is:
bined, as in this instance, it is necessary to C , Cr Mo Mn Nb ,Si V
select an alloy capable of . resisting impact 4.0 26.5 0.9 0.8 OZ.9 1. 5 0.4 %
without spalling and being sufficiently hard to
Welding technique
withstand abrasion. .
(il) blank preparation
(e) choice of process . Precut the corners of the blank representing
The process offering the widest selection of the area of wear tolerance, F Ig
' .5.
consumables and adaptability to workshop and
site conditions was MMA.
Solution
(a) parent metal
Using the MMA process it was considered
economically sound to choose a mild steel · blank.
6 8
61
(b) weld preparation blocks and repeat procedure for the second
Clamp a 37mm square x 127mm copper block corner. Apply a wash layer tq the top, front.
between two copper backing plates 127 x 127 x
12. 7mm, Fig. 6.
and back faces, Fig. 8. Allow. to cool, slowlY·
Results I
Using this solution to the problem it is noW
(Q) wllltUn; fjtl;jgedure, F1rt.7 possible to achieve a throughput of 1000 tonnes
Using an llmin diameter tubular electrode at before changing hammers. The technique
350A, strike an arc in the 'well' provided by effectively provides a wear-resistant volume of
the copper blocks and continue to weld, main- alloy in the area of wear tolerance, resultIng
taining a molten pool, filling the prepared
corner until square. Remove the copper
in a reduced wear rate and more efficient
production. I
I
I
I
I
. '1 -
~.
~.
62
c
ardfacing civil engineering plant
E. N. Gregory
Ci';il engineering plant includes earthmoving A general view of a tractor is shown in Fig. 1
and heavy construction equipment which becomes and the components that are suitable for
worn in service under the vigorous operating periodic reclamation are indicated. The moving
conditions. Wear is caused by a number of parts that engage with other metal components
factors such as adhesive - metal-to-metal - are subject to adhesive or frictional we'ar as
wear, abrasion, and impact acting singly or in well as abrasion from hard mineral particles
combination. These wear mechanisms are such as sand or earth.
described in detail in Chapter 2.
Hardfacing is used extensively to reclaim Track rollers, idler wheels, carrier rolls
civil engineering plant either in the field or in These components, which are changed during
repair depots and gives the following economic major overhauls, are generally reclaimed at a
advantages: depot or base workshop by specialist contractors.
The most economical method of reclamation is
1 Maintains surface dimensions and profile by mechanised submerged-arc welding on
of cutting edges which increases efficiency specially built equipment, Fig. 2.
and reduces power costs. Examples
Preparation for welding
include teeth on mechanical shovel buckets,
and ripper, ditcher, and trencher teeth All dirt, rust, and grease is removed from the
2 Prolongs life of components which reduces surfaces to be rebuilt by wire brushing, and by
frequency of replacement and downtime solvents or steam cleaning if necessary. Any
for reclamation . cra'c ks or rolled over flanges are removed by
3 Reduces capital cost, because a hardfaced air-arc gouging, grinding, or by pneumatic
carbon steel component is generally chisels, followed by repair with mild steel basic
cheaper than one manufactured from a covered electrodes.
wear-resistant alloy
4 A Smaller stock of replacement parts is
required
Dozer
I!
r.
end bits \
I!
Grousers
Idlers
I
I
Ripper teeth ;
and shanks ; Sprockets.
Track rails i
r.
1
General view of tractor and hardfaced components (Courtesy 2 Submerged-arc hardfacing tractor idler wheel (Courtesy
i
~
63 \/
/
./
in
~
~
l
t
Local preheating to lOOo-200 0 C, depending be reclaimed on custom-built submerged-arc
on the parent metal, should be applied. Flat equipment. This equipment includes a bed in
spots caused by track rails or links skidding which the track links are aligned and clamped
over a seized roller should be built up. and a welding head or heads which move along
The shells of some rollers contain grease a track over the track links. Provision for
which can cause high pressure buildup during automatic arc initiation and extinction can be
welding if the grease holes are plugged with included; this operates as the welding he~d
dirt. Care should be taken to ensure that moves over each link.
such holes are unblocked before welding. Depending. on the width of the track link
Preheat up to eight runs of weld metal may be deposited
On a new component, or on one from which all side-by-side and a maximum of two layers is
traces of previous hardfacing deposits have used. One run is deposited on successive links
worn away, preheating to lOoo-2000C will be in turn to avoid overheating the track links,
necessary, depending on the carbon content of which could cause distortion of the link,
the component which will generally vary from increase penetration into the parent metal, and
0.35 to 0.55%. If a previous hardfacing deposit give difficulty in slag removal.
Templa~es are used when the welding
is present it may be necessary to increase the
preheat up to 2500C to prevent the new weld procedure for a particular size of track link is
deposit from cracking. It is not always being qualified. This ensures that the shape of
possible to determine the composition of the the rebuilt links is similar to that of new links
component nor of any previous weld deposit, so that machining or grinding can be avoided.
and a useful guide to the correct level of
preheat is the visual appearance of the weld
The same weld metal as used for rollers gives
satisfactory service for track links. If mech-
anised welding equipment is not available semi-
I
deposit. High carbon or alloy content of
parent metal or previous weld deposits will be automatic welding with flux-cored ' wires or
diluted into the new weld deposit and may MMA can be used to rebuild track links.
cause hydrogen-induced cracks, which are
apparent on the weld surface running transverse Grousers
to the weld. If these are present it is an
indication that the preheat should be increased.
The track pads on a tractor are Imown as
grousers and have transverse bars or lUgs
which provide grip when the tractor moves.
I
Welding
Mechanised hardfacing produces a smooth even
deposit that in some instances will not require
These lugs become worn down fairly slowly
and the Simplest and traditional method of
reclaiming worn grousers is to flame cut the
I
machining. If machinability does not have to lugs off and weld on mild or high tensile steel
be considered, increased abrasion resistance
can be obtained by the choice of a martensitic
bars with basic covered electrodes. In the
field the most convenient bar stock to use is
25mm diameter reinforcing bars which are
I
alloy steel weld having a hardness of 450:-500HV.
If machining is to be carried out, a softer alloy welded in situ in the flat pOSition. A preheat
is chosen having a hardness of 250-350HV. of lOOoC is applied before welding.
Weld deposits having harqnesses above 300HV
are generally machined with carbide tools to Drive sprockets
reduce tool wear.
Semi-automatic welding with flux-cored
wires or manual metal-arc (MMA) welding can
The teeth of drive sprockets are reclaimed by
building them up to within 5mm of the final
profile with mild steel weld metal deposited by
I
also be used to reclaim the above components, MMA with basic covered electrodes or by semi-
and with these processes the smoothness of automatic welding with flux-cored wires. The
the deposit is increased by welding semi- teeth are then hardfaced to bring the contours
vertically from the 2 O'clock to the 1 O'clock up to finished size with low alloy martensitic
positions with a weaving motion over the width steel weld metal having a hardness of approxi-
of the surface to be hardfaced. mately 350HV. Preheat appropriate to the
Whatever process is used a maximum of parent metal is applied before welding as
two layers of hardfacing is deposited to give a described above for rollers.
maximum buildup of lOmm. If the components
are worn to a depth of more than lOmm a Ripper teeth and shanks
preliminary buildup with mild steel weld metal Ripper teeth are used to break up the surface
I?hould be applied. of ~alted roads and for similar applications
in which very high abrasive wear with little
Track links impact is experienced. Therefore it is usual
These components, which are bolted to the practice to hardface the tops and sides of the
track pads, become worn on one face and can teeth with a tungsten carbide deposit up to a
64
of 50rnm from · the point. Welding is
distance .
. d out by either the MMA or seml-
carne
.c processes. The front face of the
automa t 1
the portion of the tooth not coated
shank and
. h tungsten carbide are hardfaced with high
WIt
chromium aus ten1·t·lC Iron
· d
eposl·t s.
I
I
--- ~
I
.J
66
12-The use of weld surfacing to solve some wear
problems in a chemical plant
P. Furnival
Many people are surprised to learn that the material is crushed in a pulverisor and also
chemical industry has severe wear problems returned to the process. Four items of
as well as those of corrosion. However, the equipment suffer badly from wear: the blunger,
roces s for the production of compound granular the drier feed screw, the drier fan, and the
~ertiliSers involves handling very abrasive swing hammer pulverisor.
mixtures, and weld surfacing is extensively
IMPLICATIONS OF WEAR
used to combat wear of components.
The plant is designed to produce fertilisers for
OUTLINE OF THE PROCESS
24hr a day, seven days a week. However, the
compound fertilisers contain a balanced com- plant must shut down once each month for 8hr
position of plant foods or nutrients, i. e. to enable certain items to be cleaned out. It
nitrogen, phosphorus, and potassium. The is therefore possible · to replace worn components
ratio of these nutrients varies according to the at monthly intervals, provided this does not
end use of the fertiliser in that there is one take more than, sa}" 6hr. Therefore if
formulation for wheat, one for potatoes, and so certain components wear out it does not cause a
on. loss of production, but does incur costs in
The ratios are achieved by mixing together materials and labour. However, if an item
ammonium nitrate, -ammonium phosphate, and fails in less than one month, this means loss of
potash (potassium chloride) with an inert filler, production while it is replaced. Each year
usually ground limestone. Other fertilisers there is a maintenance shutdown lasting about
offer a high nitrogen yield and contain only ten days, so there is an incentive to produce
ammonium nitrate and limestone. components which will last at least twelve
The production process depends on months.
recycling a certain amount of dry fertiliser CASE HISTORIES
fines, to form the nuclei of granules built up
by mixing with the wet and dry ingredients. The blunger
Figure 1 shows a line diagram of the process.
The slurries are corrosive and the solids are (a) component
abrp.sive, and these are mixed in the blunger The blunger is a twin-shafted paddle mixer
to form a moist crumbly mixture which with contra-rotating shafts. Each shaft has
becomes granules of fertiliser as it passes forty-four paddles which intermesh with those
through the process. The material is trans- of the other shaft, Fig. 2.
ferred to the drier by means of a screw
conveyor. The drier is heated by hot air and (b) problem
the fan exhausts hot moist dusty air from the The solids added are potash and limestone,
exit end. The granules are screened and the which is abrasive, and the slurries are
fines returned to the process. The oversize ammonium nitrate and ammonium phosphate
which are mildly corrosive. The fertiliser
compacts into the blunger body in a hard
abrasive mass as shown in the hatched area
Slurries Solids in Fig.2b. Wear of the blunger paddle blades
mainly stems from fine particle abrasion. The
paddles were originally protected from wear
using bolted-on blades of Ni-hard, a nickel-
Fines containing, abrasion-resistant, cast iron. The
life of the blades was between one and. two
months. but the main disadvantage was the
very brittle nature of the Ni-hard as several
cracked in service, or even during installation.
67
Solids Slurries
130
6m
o o I
(a)
1
To drier feed screw
,
1-1·-----175 ------1·1
I
I
I
(b)
68
.- -~
(b) problem
The outer edge or tip of the scroll was
originally hardfaced with No. 13 , a high
carbon electrode giving a hardness around
650I-I V. The life obtained, before it was
necessary to renew the hardfacing, was about
four weeks. However, changes in the formu-
lation of certain fertilisers produced an
unacceptable rate of wear and scrolls were
being replaced after five to nine days. New
hardfacing materials were sought and trials
were carried out, Table 2.
(c) solution
The hardfacing selected was chromium carbide
in an iron-base matrix. The life of the scrolls
increased dramatically to between eight and
twelve weeks, but a new problem now appeared.
The hardfaced tips were lasting so long that
(a) the face of the ribbon was wearing away
adjacent to the tipping. It was therefore
necessary to protect this area of the face.
-This could have been achieved by laying down
a continuous deposit on the outer half of the
ribbon face, which would have been expensive
in material, so a lattice work of weld runs
was deposited, Fig. 5b. The product will
adhere to the exposed mild steel between the
(b)
runs, and provide its own wear facing. A
single layer of weld metal was used for the
5 Drier feed screw showing: (a) buildup offeniliser in trough
lattice, and two or three layers for the tip
and on scroll, (b) lattice hardfacing where the rate of wear is greatest. The life
1 Cast Ni-hard*
2 Tube carbide 1 MMA
3 Tube carbide 2 MN.£A
4 50%Co base, Cr, W, C GTA bare rod
5 86%Fe base, Mo, C GTA bare rod
6 55% Fe base, Cr, Mo, Co, C GTA bare rod
7 50%Fe base, Cr, Mo, Nb, W, e MMA
8 50%Fe base, Cr, Mo, Vj, Nb, V, e MMA
9 Sintered tlUlgsten carbide MMA
10 61%Fe base, Cr, C MMA
11 Developmental alloy GT A covered rod
12 Chromium boride paste GTA fusion
13 Fe base high carbon MN.£A
14 Ni base, W, C, self-fluxing Spray fuse
*Cast Ni-hard was used as the control in the blunger blade trials
69
Table 3 Ranking of wear resistance for
coatings on drier fan blades
use a solid plate vane. This should reduce the
rate of wear and also enable repairs to be
-II
carried out on-line. The new design is to be
Number Coating type Ranking
(1==best)
installed soon, hardfaced with the cheaper
chromium carbides, ' and a long life is expected. '1
CONCLUSIONS
9
8
Sintered tungsten carbide
50%Fe base, Cr, Mo, W,
1
2 These four examples show that it is necessary
! 1
Nb, V, C to understand the mechanism of wear to select
4 50%Co base, Cr, W, C 3 the appropriate type of hardfacing. ' They also
10 Fe base, Cr, C 4 demonstrate that similar compositions can give . -,
11 Developmental alloy 5 very different results. Even when the best
7 50%Fe base, Cr, Mo, Nb, 6 alloy has been selected, this is not the end of
W, C the story. Th~ chemical industry is constantly
12 Chromium boride, 7 changing the processes and products to increase
self-fluxing efficiency and to satisfy a changing demand.
This means that new conditions are created and
expect to achieve twelve months' service from new hardfacing solutions required. Weld
the sintered tungsten carbide coating. This surfacing is extensively used because the
makes the cost of coating greater than the expertise is available in the workshops and the
manufacturing cost of the plain fan impellor. components are amenable to reclamation and
Therefore a new design is proposed which will repair.
I
I
I
I
I
I
7,2
f
.!
HARDFACING PLUGS FOR FLOW CONTROL VALVES The guide spindles of double-beat valves are
frequently hardfaced to avoid 'pickup' with the
Component guide bushes, to minimise wear in the presence
The plug fitted to a double-beat flow control of abrasive solids, and to prevent fretting
have various profiles and, for the when valves are subject to vibration in use.
1 can
vave .
ose of ill ustratmg how hardfacing may be. Hardfacing processes and techniques
purpd to i:rnprove servlce
. life, p 1ugs h '
avmg a
;:~abolic profile will be used as an example. In most hardfacing applications more than one
Typical valVes range from 50-200mm diameter. process can be used with acceptable results;
FloW control valves are used to handle a factors such as equipment availability and the
wide variety of aggressive fluids which may skills possessed by operators may outweigh the
include abrasive solids in suspension. Flow theoretical advantages of a given process. The
rates may be high with a Significant pressure possibilities described below are based on
drop acrOss the valve. actual practice, and comments are given to
explain the advantages and disadvantages in
Materials each example.
Plugs are frequently made from austenitic Protection of seat area only
stainless steel to give satisfactory corrosion (a) oxyacetylene
resistance, but resistance to erosion and Cheap, freely available, and uses the cheapest
abrasion of this steel is low. The guide consumable rod; capable of giving very low
spindle of the plug moves in bushes fitted to intermixing of the hardfacing alloy with the
the valve body and the bearing properties of base metal which is desirable to obtain the
austenitic stainless steel are poor. highest wear-resistant properties in the deposit.
The selection of a hardfacing alloy for a Good" control of weld bead profile. Requires
valve must take into account the particular fairly high preheat in ilie base metal, but, when
working conditions, but resistance to corrosion, used on austenitic stainless, the steel must be
abrasion, and erosion is clearly required stabilised against weld decay with niobium, not
together with good bearing properties. . These titanium, as the latter can lead to porous
require:rnents are best satisfied by hardfacing deposits.
alloys of the cobalt- or nickel-base type, .and
manufacturers publish data and provide advice
(b) gas-shielded tungsten arc (GT A)
on the selection of the most suitable alloy in More· expensive equipment ilian oxyacetylene
the range for a given application. A typical and liable to give less wear-resistant deposits
hardfacing material would be Deloro Stellite owing to dilution wiili base metal. With care
SF 6. and correct technique this effect can be
Extent of protection minimised. More tolerant of titanium-bearing
stainless steel base metals than oxyacetylene.
Most floW control valves are intended to shut
when necessary, so integrity of the two seating
surfaces ~s essential. Erosion can be severe (c) powder welding
when operating with the seats just open, and Similar to oxyacetylene. Powder consumable
any attack on them would prevent subsequent costs more than rod and some powder is lost
sealing. in overspray"
In some applications the seats may be the
Protection of seats, parabolic surfaces, and guide spindles
only area requiring protection, but iri more
severe conditions erosion of the parabolic (a) oxyacetylene, GTA, and powder welding
profile way occur; this will progressively All the comments in the iliree previous para-
affect the flow control characteristics of the graphs apply, and valves have been faced by
valve. In such Circumstances hardfacing the these processes. As a result, however, of
entire parabolic profile is carried out. problems in maintaining a smooth deposit of
Reference has been made above to the uniform thickness on the parabolic profile,
poor bearing characteristics of stainless steel, subsequent machining or grinding is necessary,
but this can be greatly improved by hardfacing. and with hard deposits this is expensive.
73
~
I
Oscillation of head Plasma torch
AC
1
1J
\ --I J
l --I
Base steel
I
8 Plasma hot wire !
Base steel !
transferred arc is maintained between a 1
6 Six-wire multiweave 1·ece. A
tungsten electrode and the workP d metal into
(d) six-wire multiweave
This process employs six oscillating arcs,
Fig. 6. The proximity of each arc is arranged
so that deposits of one overlap and fuse into
.
The proce ss should not be co
e
secondary gas flow feeds powder arc orifice.
the arc plasma stream beloW the d ·th
nfuse W1
sferred arc
plasma spraying in which a nontran5 to 6mm
I
the other_ Deposition rates of 45kg/arc hour
are claimed as possible.
is used. Fused deposits from O. 2
thick can be produced with cobalt-, n
and iron-based hardfl:lcing alloYS .
ickel-
, I
!
I
(e) bulk weld process
In this process an arc is maintained between PROCESS APPLICATION h' h
have 19
the wire electrode and the granular metal, Weld surfacing processes sho ul d s of
. e){ces
both melting to produce the surfacing deposit. deposition rates, preferably 1n a total
The graded granular metal enables a wide
range of compositiOns to be deposited. In
addition, the granular metal absorbs the arc
14kg/arc hour, to be competitive o:ral
cost, time, a nd quality basiS.
processes previously outlined cove
this
_
Se; I
heat in melting, reducing diI ution to a mini-
mum . The use of this process is mainly in
the hardfacing field where deposition rates
requirement, Fig. 9.
.
kg/arc h our, 1. h
e. per our 0
. terms of
These rates are reported ill t'nuo us
f con 1
oduc
tion oper-
I
of 27kg/arc hour have been reported_ The operatIOn. However, actua P r
. - 1 he percentage
process is shown in Fig_ 7.
Rod
ation would not be continuouS.
of time that a process is actuallY
weld metal is referred to as
T depositing
the operatlng
.
duction vary
I
factor. Operating factors in pro may be
from fabricator to fabricator and
anything from 30 to 75%.
J
Travel
.. Two questions then arise:
Flux a technically
1 Which process can produce
Gas·shielded powder
40
10 20
Plasma arc surfacing I Y processes, kg/arc hr
In plasma arc weld surfacing a constricted 9 Reported deposition rates of weld o~,er a
J 78
acceptable deposit? c
~
2 What is the cost (bearing in mind the *-x
previous point) of weld surfacing per tq Austenite
a
square metre of base material area? +
U
*-x
Consideration of which welding process to .use 20
a
cry
The cost of depositing weld metal is a function +
of several variables; Z
*-
Initial equipment investment ....c
1 ., 10
2 Labour overhead and operating factor 0;
.~
3 Cost of welding consumables such as strip, ::l
.,U
wire, flux, and gas .,
~
u
4 Availability of equipment on the shopfloor Z
5 Desired chemistry and thickness of surface
6 Ability to achieve deposits with required
Chromium equivalent = %Cr + %Mo + 1.5 x %Si + 0.5 x %Nb
chemical composition
7 Percentage dilution and number of layers 10
required
It is a well-known fact that fully austenitic
weld metals are prone to solidification cracking.
Referring to Fig.9 it can be seen that the six-
This may be suppressed by either;
wire multiweave process gives the highest
deposition rate in kg/hr with the dual strip
(a)controlling the manganese-to-silicon ratio,
process running fairly parallel. However, the
or
highest deposition rate process does not
(b) deliberately producing a percentage of {;
necessarily give the best technical results.
ferrite in the weld metal structure
These processes may cause problems in
It is more usual to introduce a percentage of
shopfloor techniques and hence somewhat reduce
6 ferrite generally of the order of 5-12% which
process efficiency because of the steps that
ensures metallurgical soundness.
must be taken to accommodate them.
A further problem is that of the carbon
METALLURGICAL VARIABLES FOR WELD SURFACING content of the surfacing. Generally the wire
PROCESSES or strip consumable is limited to O. 03 %C
Since the quality of the weld surfacing is of
maximum. However, when depositing this on
prime importance, the metallurgical variables
to a base material of up to o. 25%C, it is
common to the above processes should be
possible to end up with a carbon content of
briefly explained.
between 0.05 and 0.1% in the surface_ For
Control of weld chemistry c
~ 24
The successful deposition of a single or multi-
~
layer deposit on a carbon or low alloy steel + 23
base material demands a complete understand- Z
ing of the following; *-x 22
a
~ 21
1 The base metal metallurgy +
2 The surfacing metal metallurgy U 20
*-x
3 Control of the welding process and a 19
consumables ~
+ 18
z
Surfacing involves a dissimilar metal *- 17
joint over large areas between the base metal ....c
., 16
and the coating. Unless this operation is 0;
>
.".,-"
correctly carried out it is very easy to obtain J;j 15
very lLTldesirable metallurgical structures. Q;
When surfacing with stainless steel it is ~
u 14
necessary to refer to the Schaeffler diagram, z
13
Fig. 10, to achieve the necessary chemical and
metallurgical control of the coating. 12
79
nI
1971 ANON. 'Open-arc hardfacing: use of high speed cored wire welding'. Welding and
Metal Fab., 39 (7), 1971, 265-7. nI
BELL, G.R. 'Hardfacing alloys, Pt 1: Ni-base alloys'. Surfacing J., ~ (6), April
1971, 1-5.
BELL, G.R. 'Hardfacing alloys. Pt 2: Co-base alloys'. Surfacing J., ~ (7), July
1971, 1-3.
II r
BUCKINGHAM, H. C. 'Roll reclamation by submerged-arc welding'. Surfacing J., 2
(5), January 1971, 1-5.
11I .
ELLIS, D. J. 'Surfacing for wear resistance on screw flights'. Surfacing J . , 2 (5),
January 1971, 5-6.
GALE, K. 'Wearfacing gets more work out of moving parts'. Engineer, 233 (6023), !I
12 August 1971, 23-6.
1972 BUTLER, B. S. 'Protection of blast furnace bell and hopper charging systems by
hardfacing t • Surfacing J., ~ (3), July 1972, 1-5.
II
DAEMEN, R. 'Hardsurfacing a summary of some basic principles'. Surfacing J.,
~ (4), October 1972, 4-9.
DONOVAN, M. 'Report on the NATO Advanced Study Institute meeting on The Science
and Technology of Surface Coatings'. Surfacing J., ~ (3), July 1972, 8-11.
MUYSEN, L. van. 'Arc surfacing with Co-Cr-X alloys' (in French). Cobalt (55),
1972, 67-78; (in English) Arcos (162), 1974, 4365-80.
YUZVENKO, Yu. A. 'Cored electrode wires for metal deposition'. Automatic Welding,
25 (5), 1972, 57-60.
1973 BROUWER, G. and KOSTENSE, J. 'Philips flux-cored wires and their properties'.
." l
.i
I J
Philips Welding Reporter, ~ (1), 1973, 5-14.
II
COOKSON, C. 'Wear facing of fans'. Surfacing J., ! (1), January 1973, 7-12.
KALB, J. 'Wear and Philips hardfacing alloys'. Philips Welding Reporter, Q. (3),
flh i
~
1973, 13-20, 23.
~
MUYSEN, L. van. 'Hardfacing with Co:C'r :X alloys by arc welding process, Pt 1'.
Surfacing J., ! (1), Jan~ry 1973, 1-6.
MUYSEN, L. van. 'Hardfacing with Co:Cr:X alloys by arc welding process, Pt 2'.
Surfacing J., ! (2), April 1973, 1-5.
86
REY, M. 'Outline of a relation between classes of wear and types of surfacing layer
taken from the analysis of industrial examples' (in French). Aciers Sp~ciaux (23),
1973, 23-8.
1974 ANON. 'Surfacing: a sure cure for rundown parts and profits'. Welding Design and
Fab., 47 (8), 1974, 29-33.
COOKSON, C. 'Cheap or expensive: the choice'. Surfacing J., ~ (1), 1974, 16-17.
ANON. 'Hardfacing with EMF electrodes'. Welding Bull. (C82), March 1975, 5-7.
ANON. 'Selection of surfaCing materials'. Welding Design and Fab. , 48 (8), 1975,
40-44.
RIES, G. D. 'Cutting cost with maintenance welding'. Welding Design and Fab., 48
(10), 1975, 73-6.
87
STEPANOV, B. V. et al. 'Development of surfacing materials for components such as
brake pulleys, roilers, and wheels of ingot buggies'. Welding Production, 22 .(1), 1975,
49-52.
UTIN, I. A. and SHA NDRE NKO, G. I. 'Mechanised building up in the manufacture and
reclamation of components of metallurgical machinery'. Weldfng . Production, 22 (4),
1975, 61-2.
1976 ANON. 'Hardfacing, Pt 2: The facts that make it necessary'. Welding News (162),
September 1976, 19-21.
ANON. 'Manual arc hardfacing earthmoving equipment'. Afrox News, January 1976,
11.
ANON. 'New series gets down to basics on hardfacing techniques, Pt 1'. Welding
News (161), June 1976, 22.
1977 HAGUE, F. 'Some aspects of weld reclamation at BHPs Newcastle iron and · steel
works'. Australian Welding J., 21 (6), November/December 1977, 15-20.
I
1378 GREGO~S, E. N. 'Hardfacing'. Tribology Int'l, !l (2), April 1978, 129-34. I
F~
HAGUE, F. et al. 'The effectiveness of hardfacing - the analysis of field trials'. ~
88