ay | COMMON QUARTERLY EXAMINATION 2022 - 23 CHEMISTRY (Max, Mt Allowed : 3.00 Hours} PART ~1 Note: i) Answer all the questions. IN 10. "1 12. 13, 14 15. li) Choose the most suitable answer from the given four alternatives and Option code and the corresponding answer. When 22.4 litres of H,(g) is mixed with 11.2 litres of Cl,(g),each at 273 K at 1 atm the HCig), formed is equal to a 2) Zmolesof Hel) b) 0.8 moles ofHcl(g) o) 1.6 moles of Hcl(g) 4), 1 moles of Hela) Splitting of spectral lines in an electric field is called a) Zeemaneffect * b) Shielding effect c) Compton effect Assertion: Number of radial and angular nodes for 3p orbital are 1,1 respectively. Reason : Number of radial and angular nodes depends only on principal quantum, number 2) _ Both assertion and reason are true and reason is the correct explanation of assertion. b) Both assertion and reason are true but reason is not the correct explanation of assertion both assertion and reason are false 4) Starketfect ©) Assertion is true but reason is false ) Which one of the following elements will have the highest electronegativity? ‘ a) Chlorine b) _ Nitrogen ©) Cesium @) Fluorine 4 Which of the following pairs of elements exhibit diagonal relationship? 2) Beand Mg by Liand Mg c) BeandB 4) Beandal In solid ice, oxygen atom is'surrounded a) tetrahedrally by 4 hydrogép’atoms ) octahedrally by 2 oxygen and 4 hydrogen atoms ©). tetrahedrally by 2 hydrogen and 2 oxygen atoms d) octahedrally by 6 hydrogen atoms The units of Vander Waals constants ‘b' and ‘a’ respectively a) molL-tand L atm? mot* b) mol Land L atm mo ©) mol* Cand L?atm mol* d) none of these Consider the following statements i) Atmospheric pressure is less at te top of a mountain than at sea level |) Gases are much more compressibel than solides or liquids i) When the atmospheric pressure increases the height of the mercury column rises select the correct statement. a) landil ¢) land i Match the following. ‘A ‘Adibatic process 1+ Refractive index B Isolated system 2 _Internaleneray C* Intensiveproperty 3 Noexchange of energy and matter D_ Staté function 4 Notransfer of heat 2) A(3),B(1), (4), 0) b) AC), B(1), C2), 3) ©). AA), B), C(1), 02) 4) A@3),B(4), C(t), 2) Solubility of carbon dioxide gas in cold water can be increased by a) increase in pressure b) decrease inpressure c) increase in volume d) none of these Consider the following reversible reaction at equilibrium, A + B=*C, If the concentrationof the reactants Aand B doubled, then the equilibrium constant will a) bedoubled b). becomeone fourth c) behalved Ortho and para - nitro phenol can be seperate by 2), azeotropicdistillation _b) destructive distillation c) steam distilationd) cannotbe separated ! The isomer of ethanol is a) acetaldehyde b)_ dimethylether__—_c)_ acetone 4) methyl carbinol Homolytic fission of covalent bond leads to the formation of . a) electrophile b) nucleophile ©) carboneation i Assertion Tertiary Carbocations are generally formed more easily than primary Carbocations fons Reason: Hyper conjugation as well as inductive effect due to additional alkyl group stabilize tertiary b) Manditt ©) andl d) remain the same 9) free radical + carbonium ions: a) Both assertion and reason are true and reason is the correct explanation of assertion b) Both assertion and reason are true but reason is not the corret explanation of assertion fm 4) Bothassertion and reason are false CH/11/Che ©) Assertion is true but reason is false Scanned with CamScannerMu, 6 7 1a 19 20 21 2 2B 36. 36, 33, Give one example for f elimination reactions? PART-B. Answer any six questions. Question No, 17 Is compulsory. Oxd=12 Calculate the number of moles presentin 9 q of thane sya) saan How many unpaired elections ae present in tho ground stato ot Fo" (2°20), MM¢y 25) and nan as Predict the position ofthe element in poriodic table vat fying the electronic configuration (1-1) et 6 Arrange NH, H,0 and HF in the order of incroa sing magnitude of hydrogen bonding and basis for your arrangement Distinguish between Diffusion and Etusion PTT tren eee The equilibrium constant of a reaction is 10, what will bo tho sign of 4G? Will this reaction be spon shal Write the kp and Kc for the following reactions, (i) 280,(9) + 0, =*2S0,(g) (i) 2CO ha Osa) + (5) Wile the molecular and possible structural formula ‘of tho frst three members of homolog, of carboxylic acids 2b What are electrophiles and nucleophiles ? Give examples each? tT, Sls ¢ PART-C Obes ceePl 24 Anigwer any six questions. Question No. 32 is compulsory. Sra Per carneycilf@tences between molecular mass and molar mass? Calcualte the molecular 5 ‘and molar mass for carbon monoxide on any dla! nodes for 2s, 4p, Sd and af orbitals exhibit? How many angular nodes? . Explain the flown give appropiate reasons. lonisation potential of Niteoer Is greater than that of Oxygen ‘Compare the structures of H,O and H,O, Sw p Gs - 2 Explain why aerated water bottles are Kept under water during summer? , Predict the feasibilty of a reaction when {2 ath sitand aS positive (i) both Hand AS negative (i) 411 decreases but increases Give oneexamplefor (i) K=K, i) KK eget ll) K, < K, 7.284 9 of an organic substande gave 0.287 9 AgCI in'a Carius method for tle estimation of halogen, Find the Percentage of Cl in the compound, nah PART-D Answer allthe questions, ">. 5x5=25 (i) (@) Acompound on analysis gave Na = 14.31%, S= 9.97% H = 6.22% and O = 69.5% calculate the molecular formula of the compoundjfall the hydrogen in the compound is present incombination with oxygen as water of crystalization, (Molecular mass of the Compound is 322) (©) ExplainAngularqunatum numbers? oR (@) (2) Wrtie the rules to finding oxidation number (b)_ Distinguish orbit and orbital, (Using Stater’s rule calculate the effective nuclear charge on a 3p electron in Aluminium and chlorine. (©) Write the expected formulas for the hydrides of 4th period elements What is the trend in We cotmulas? In what way the frst two numbers ofthe series different rom the otrerc oR (® (2) Why second ionisation energy is greater than fst ionisation energy? (©) Wile short note on ortho hydrogen and para hydrogen, { (@) Detive the relation between AH and AU for an ideal gas. Explain each term involved in the equation. (0). State Joule Thomson effect. oR ()(@) State Datton’s law of partial pressure. (0) Write down the Born - Haber cycle forthe formation of CaCl, 0 @ Pine ettaton between and OR (@) Write a balanced chemical equation for an equilibrium reaction for which the equilibrium Constants is given by expression, Ke = INHLI*10,]* INO} [H,O} (0) State Le -Chatelier's principle () (@) White structural formula forthe folowing compounds ()_m-dinitrobenzene (i) p-dichlorobenzene (i) 1,3,5-Trimethyl benzene (©) Whatis inductive effect Give on example? oR ® (@) 0.269 of an organic compound gave 0 0399 of water and 0.245 g of carbon dioxide on Combustion. Calculate the percentage of Carbon and Hydrogen, (©) Explain homolytic and hetrolyrtic bond cleavage? Give example, CH/I/Che/2 ‘ 7! Scanned with CamScanner