Test Paper

SUB : CHEMISTRY
CLASS - XI
Time Allowed: 3 hr Maximum Marks : 70
General Instructions:
• All question are compulsory.
• Q 1 to 20 are very short answer objective type and each carries 1 mark each.
• Q 21 to 27 are short answer question and carry 2 marks each.
• Q 28 to 34 are also short answer question and carry 3 marks each.
• Q 35 to 37 are long answer questions and carry 5 marks each.
• There is no overall choice. However internal choice have been provided in some questions.
• Use of log tables if necessary. Use of calculators is not allowed.

1. The number of nodal planes in px orbitals is

(a) 1 (b) 2 (c) 3 (d) 0
2. For a reaction to be spontaneous at all the temperature:
(a) ∆G –ve, ∆H +ve, ∆S +ve
(b) ∆G +ve, ∆H -ve, ∆S +ve
(c) ∆G –ve, ∆H -ve, ∆S - ve
(d) ∆G –ve, ∆H -ve, ∆S +ve
3. The correct order of ionic radii of the species N3–, O2–, Na+ and F– is
(a) Na+ < F– < O2– > N3–
(b) F– < O2– < N3- > Na+
(c) O2– < N3– < F– > Na+
(d) N3– < Na+ < F– > O2–
4. Which of the following molecule has net dipole moment?
(a) CO2 (b) H2O (c) BF3 (d) CH4
5. Syn-gas is a mixture of
(a) CO+N2 (b) O3 (c) CO + H2 (d) CO + H2CO3
6. Which of the following can act as an electrophile?
(a) CN– (b) OH– (c) H2O (d) BF3
Direction for Question No. 7 and 8 :
(i) If both assertion & reason are true and the reason is the correct explanation of the assertion.
(ii) If both assertion & reason are true but the reason is the correct explanation of the assertion.
(iii) If assertion is true statement but reason is false.
(iv) If both assertion and reason are false statements.
7. Assertion : Number of orbitals in 3rd shell is 9.
Reason : Number of orbitals for a particular value of n = n2.
8. Assertion : Ionic radius of Na+ is smaller than Na.
Reason : Effective nuclear charge of Na+ is higher than Na.
9. If ten volumes of dihydrogen gas react with five volumes of dioxygen gas, how much volume of
water vapour would be produced?
OR
Calculate the number of atoms in 32.0 u of He.
1|Page
10. Complete the reaction
H2(g) + Pd2+ (aq.) →
OR
CO(g) + H2O(g) 673K ,Catalyst→
11. The enthalpy of atomization of CH4 is 1665 kJ mol–1. What is the bond enthalpy of C – H bond ?
12. In a reversible reaction, the two substances are in equilibrium. If the concentration of each one is
reduced to half, then what is the effect on the equilibrium constant ?
13. Write the oxidation number of Cr in K2Cr2O7.
OR
Write the stock notation MnO2.
14. Using VSEPR theory draw the shape of XeF4 molecule.
15. What does B.O.D. stands for ?
16. Complete the following reaction:
CH3Cl + Na dry ether→
17. Draw bond line structure of CH3(CH2)6CH = CH(CH2)2 – COOH

18. Why PbCl4 is good oxidising agent ?

19. What is the unit of ‘a’ in vander Waal's equation ?
20. Write IUPAC name of CH3 – CO – CH2 – CHO.
21. Explain the terms :
(i) Hydrogen economy. (ii) Fuel cell.
22. Balance the following redox reaction in acidic medium MnO4– + H+ + Fe2+ → Mn2+ + H2O + Fe3+ .

23. For the reversible reaction N2(g) + 3H2(g) ↔ 2NH3(g) at 500°C, the value of Kp is 1.44×10–5 atm–2.
Find the Kc value.
24 . (i) Mention the number of radial nodes in 6s orbitals.
(ii) Write electronic configuration of Fe2+ ion. (Given, Z = 26)
Or
Calculate the wavelength of a ball of mass 0.1kg moving with a velocity of 10ms -1. (Given, h =
6.626 × 10–34 Js)
25. The density of 3 M solution of NaCl is 1.25 g mL-1. Calculate molality of the solution.
26. What are the maximum number of emission lines when the excited electron of a H atom in n = 4
drops to the ground state ?
27. (i) Mention the reason of not using Wurtz reaction for the preparation of unsymmetrical alkanes
from alkyl halides.
(ii) How will you convert Benzene to p-Nitrobromobenzene?
28. A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is
98.96 g. What are its empirical and molecular formulas?
29. N2 is diamagnetic while O2 is paramagnetic. Explain on the basis of molecular orbital theory.
OR
Explain the structure of PCl5 according to hybridization. Why all P – Cl bonds.
2|Page
30. A neon-dioxygen mixture contains 70.6 g dioxygen and 167.5 g neon. If pressure of the mixture of
gases in the cylinder is 25 bar, what is the partial pressure of dioxygen and neon in the mixture?
(Atomic mass: O = 16u, Ne = 20u)
31. All electrophiles are Lewis acids while nucleophile are Lewis bases. Explain.
32. Write balanced chemical equations for :
(a) BF3 + LiH →
(b) B2H6 + NH3 →
33. Name the hydrides :
(i) Which is non stoichiometric in nature ?
(ii) Which are stoichiometric compounds ?
(iii) Which has electron rich type hydrides ?
34. (i) State the necessary compound to be aromatic according to Huckel’s rule.
(ii) Explain why alkyl groups act as electron donors when attached to a p system.
Or
(i) Draw the resonance structures of Phenol.
(ii) Suggest a method used to purify the liquids which have high boiling points and decompose
below their boiling points.
35. (i) Show with the help of chemical reaction that Al shows amphoteric behaviour.
(ii) Draw the structure of (a) B2H6 (b) Boric acid.
(iii) Write the formula of Borax.
OR
(i) Explain Lewis acid strength BF3 < BCl3 < BBr3 < BI3
(ii) What are silicones? Give reaction for formation of chain silicones.
(iii) Why CO is poisionous in nature?
36. (i) State Le Chatelier's principle.
(ii) Calculate the pH of 10–8 M HCl.
(iii) A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equalibrium the partial pressure
of HI(g) is 0.04 atm. What is the Kp for given equilibrium?
2HI (g) ↔ H2(g) + I2(g)
OR
(i) Define common ion effect.
(ii) Write the relationship between Kp and Kc for the reaction: N2(g) + 3H2(g) ↔ 2NH3(g)
(iii) Equal volume of 0.002 M solutions of sodium iodate and cupric chlorate are mixed together.
Will it lead to precipitation of copper iodate? (For cupric iodate Ksp = 7.4 × 10 –8)
37. (i) An alkene A on ozonolysis gives a mixture of propanal and pentan-3one. Write the structural
formula of A.
(ii) Complete the following reactions:
(a) CH3CH=CH2 + HBr organic peroxide→
(b) CH3CH2Br + Na Dry Ether→
(iii) Write a short note on Friedel Crafts alkylation.
Or
(i) Why eclipsed form and staggered form of ethane cannot be isolated at room temperature?
(ii) State Markovnikov’s rule.
(iii) Which out of Ethene or Ethyne is more acidic and why?
(iv) What happens with 2-Bromobutane is being treated with KOH (alcoholic)?
3|Page