OS ees ayes ye bb 10. ee 12. 13. is (a) Ca on (3) 2n a Which of the following is isoelectronic? (2) €O, , NO, (2) NO; , co, eet . co ‘The isoelectronic pair is “i Sane (1) €4,0, ICh- (2) IChy, C10, pre Dstincicdseuii z 2 (3) IFp* , ly (26, Cy Of the following sets which one does not contain isoelectronic species ? (1) PO,*, S047, ClO, (2) CN, No, C32 (3) SOs? COE, NOs (4) BO,%, CO,2-, NOw Which of the following is weakest bond? (1) lonie (2) Covalent (@Aetallic (4) Vander Waal LEWIS THEORY ‘Among the following electron deficient compound is, (a) CCl, (2) PCI, ( ly (4) BCI, Which of the following is the electron deficient molecule? (1) CoH (2) SiH, (3) PH, re In a triple bond there is sharing of (1) 3 electrons (2) 4 electrons (3) several electrons (4)46%electrons In Lewis formula of Og, there are (1) 2c, 12, 4 lone pairs of electrons (2) 1a, 2m, 1 lone pairs of electrons (3) 2g, 6 lone pairs of electrons (4). 20, 27, 3 lone pairs of electrons Which of the following is obeying octet rule (2) Bee (2) In (3) Cae (of BONDING Which of the following compounds will not undergo decomposition on passing electricity through aqueous solution ? (Ue=CC AG FH a) CH, rad HH 29. Which of the following are arranged in the decreasing order of dipole moment exce?’ (1) CHCl, CH,Br, CHF (2) CH,Cl, CH,F, CH,Br (3) O4,Br, CH,Cl, CH,F (4) CH,Br, CH,F, CH,Cl31 32. 33. 34. 36. Sia 39. 41. 42. 43. tnt Sree ni Which of the following would have a permanent dipole moment? (a) BFs (2) SFy 2) Si, Which of the following has zero dipole moment ? ; (4) Ker, oe are, (8) SF 4 (4) What causes nitrogen to be chemically mert ? (4) CrCl, (1) Absence of polarity aneniceAnere {g) Short internuclear distance ‘ ane Which of the following bonds require the k condensed? largest amount of bond energy to dissociate the atoms (1) HSH bond in H, (2) C-H bond in CH, bond in N, (4) O=0 bond in O, In which of the following molecules, all the bonds are not equal i length? (a) NF3 (2) BFs (3) Ay (4) Of, Which of the following is true ? 1 se bond energy (2) B6hd order = bond length ac ———__ ‘bond eneray ree (1) Bond order = od length 1 bond length {@) Bond order « eect ‘ond energy (4) Bond order « bond length « bond energy VSEPR THEORY In BrF, molecule, the lone pairs occupy equatorial positions to minimize (1) Lone pair-lone pair repulsion only (2) Lone pair-bond pair repulsion only (3) Bond pair-bond pair repulsion only (4) Lone pair-lone pair repulsion and lone pair-bond pair repulsion ‘Among the following pair which of the two species are not isostructural? (1) PF and SF, eee SF, (3) 10, and XeO, (4) BH," and NH," a of the following molecules has trigonal planar geometry? re (2) BF3 (3) PCl, (4) IF 3s Among the following molecules () XeO3 (ii) XeOF, (iii) XeFe Those having same number of lone pairs on Xe are: (1) @ and (i) only (2) (i) and (ii) only (3) (ii) and (ii) only (4A), (li) and (ii) Which of the following species has a linear shape? (1) Os fo: (8) $0, (4) No; Which of the following ane with SiC? (1) NH; (QACL. (3) SOF (4) Por In which of the following pairs the two species are iso-structural? (@) 0? and No; (2) BF; and NF; (@8FO, and XeO (4) SF, and XeFs The shape of gaseous SnCl, is (1) Tetrahedral (Qfhnear lowing molecules will have unequal bond lengths ? ls (3) Angular (4) T-shaped Which one of the followi (1) NF, ae (3) PF, (4) SF, TsTorget : 150 (Stage-I) ara O are Fespectively GT electrons of ce 45. In OF,, number of b ‘and lone a 7 to (4) 2,9 () 2.6 (9/2, 2 ‘ 46. A Jone pair of electron in an atom implies : ee lec! (2) A pair of el ing 0) Ap of valence electron not invole in bonding of orderly arrangemen (1) A pair of valence electrons (3) A pair of electrons involved in bon 47. The geometric form of crystals is the result only (1) Moleggles only Ce Molecules, atom or ions @ ; (3) Atohs ony f both species is 48. The pal A epecar havieg nose teal Ee OU MeL eames (NCR, SF, (1) Xe, CO, (2) BF, PCh (3) PF, Is 2 CO, 49. Total number of lone pair of electrons in XeOF, 1s wa (0 (21 oe ee, 50. ‘Which:ohtee febowing, bas inte VORIPMeManOn are of F a afr, (2) NH, (3) CIF, 51. Which of the following hgs square planar structure? (a sic (1) BHY (Pcl? (3) S0,* E 52. Opis iso structural with? (1) HaCl, (2) SaCl, (3) HC=CH (@fNO2 53. Which of the following doegmot have linear shape? (1) SnCly (2)Xco- (3) CS, INO" 54. Which of the following species are expected to be planar ? (@) NH; (0) NH? (0) CHs* (@) PCls The correct answer is (Lbertd (2) ¢ and d (3) b and d iaiiapancid 55. Which of the following is/arginear? Qi, ae (3) PbCl, eee VBT 56. Number of ¢ and x bond in SO} are + 4,2 (2) 4,3 (3) 4, 4 (4) 2,3 57. Structure of acetylene molecule is ~ (1) Linear (2) Triangular planar (3) Square planar (4) Tetrahedral 58. What will be the number of o & x bonds in CHy COOH? (47 (2) 5.2 (3) 71 (4) 3.2 59. Which of the following has maximum (C-C) bond length? (1) CH (2) CoH, (3) CoHe (4) CH,Br. 60. InN, triple bond there is = (1) 30 (2) 1m, 20 (3) 2x, lo (4) 32 61. How many m-bonds are present in naphthalene molecule? (3 (2) 4 (3) 5 (a6 62. Fluorine molecule is formed by : (1) The axial p-p orbital overlap (2) The sideways p-p orbital overlap (3) The s-s orbital overlap (4) The s-p orbital overlapeee he following statements Sean seer ea 1, A sigma (6) bond is formed when two. s-orbital overlap 11, A pila) bond Is formed when two p-orbitals axially overlap Ill, A o-bond is weaker than m-bond Which of the above statements is/are correct 2 (1) Land I (2) Nand It (3) | alone (4) Il alone 64. Appibond may be formed between tw they approach each other appropriat (1) x - axis (2) y — axis (8) 2 ~ axis (4) both (2) & (3) 65. The sigma and n-bonds present in benzene (1) three sigma and three pi P, orbitals containing the unpaired elects Boislcn ron each when ring are (2) six sigma and three pi (3) six pi and three sigma (4) nine sigma and three pi HYBRIDISATION 66. Hybridisation of 'O' atom in ether is :- (a) sp® (2) sp? (3) sp (4) dsp2 67. Hybridisation state of C in diamond is := ()) sp (2) sp? (3) sp3 (4) sp3d 68. In which of the following species is the underlined carbon having sp"-hybridisation 2 @) CH-GOOH — (2) CH.CH,OH (3) CH,COCH, (4) CH,=CH-CH, 69. The states of hybridization of boron and oxygen atoms in boric acid (H,BO,) are respectively (1) sp? and sp? (2) sp? and sp? (3) sp? and sp? (4) sp? and sp? 70. The molecule of CO, has angle 180° because it has:- (1) sp° hybridisation (2) sp? hybridisation (3) sp hybridisation (4)d?sp? hybridisation 71. Hybridization of C atom in carbonyl Sc—0 group is - (1) sp (2) sp? (3) sp3 (4) All "72, Nature of hybridization in NH, molecule is (1) sp (2) sp? (3) sp3 (4) sp°d 73. The hybridization of the atomic orbials of sulphur in SO,,S0,% and SF, are respectively (1) sp, sp%, sp? (2) sp, sp?, sp’d_— (3) sp, sp, sp? (4) sp?, sp?, spd 74, The central atom assumes sp? hybridization in (1) PCh, (2) SO (3) BF3 (4) NO; 75. Which are true for hybridisation? () Hybrid orbitals form relatively stronger bonds than pure atomic orbitals. (i) Hybrid orbitals form only bonds (ii) Orientation of hybrid orbitals depends upon the type of hybridisation (iv) Promotion of electrons from lower sub-level to higher sub-level of the valence shell is essential for hybridisation, 1) () and (ii) (2) (i), (ii) and (iv) 9, (i) and (ii) (4) All76. 77, 78. 79. 81. 82. 83. 85. 86. 87. 88. 89, 90 ) iS vide molecule can parti, THOTae ber of hydrogen bonds in which hydrogen fluor ae Patticinay aximum number (4 : (2 (2)3 thyl thiol because The boiling point of methanol is greater than that of methy) termolecular hydrogen ton, (Q) There is intramolecular hydrogen bonding in methanol and inte ending in methyl thiol rogen bonding in rethyy (2) There is intermolecular hydrogen bonding : pa si i ia: ae ee (3) There is no hydrogen bonding in methanol an¢ rae dingy ar (4) There is intramolecular hydrogen bonding in ee and no hyd bi In dry ice the bond present between two molecules inder Waal 2) Ionic bond (2) Covslent gry, )yavars ae ; Which of the following hydrogen bonds is the strongest? EE wy () FH... F (2) OH.....0 eile AUC aan to, is The maximum possible number of hydrogen bonds a water mol (a1 () 2 24 Gs Hydrogen bonding is absent in := (1) CH,CooH (2) H,0 (Ce a The reason for double helical structure of DNA is operation a : (1) Dipole-dipole interaction (2) Hydrogen bonding (S) Electrostatic attractions (4) Van der Walls’ forces Hydrogen bonding is maximum in : (1) Ethyl chloride (2) Triethylamine _(3) Ethanol (4) Diethyl ether Two ice cubes are pressed over each other until they unite to form one block, Which following forces dominates for holding them together? (1) Dipole-dipole interaction (2) Van der Waals’ forces (3) Hydrogen bond formation (4) Covalent attraction The hydrogen bond is shortest in @ snes (2) N-H—o (3) S-H-O (4) FI VANDERWALL FORCES (5) What occurs when HyOp evaporates (i) Covalent bonds are broken. one of the (8) Only dipole-dipole forces are overcome. (ii) Heat is absorbed by water from the surroundings (iv) It becomes oxygen and hydrogen gas, (2) Only (i) and (ti) occurs (2) Only (i) and (ii) occurs (3) (i), ii) and (i) oceurs (4) (), (i, (ii) and (iv) take place Intermolecular forces in solid hydrogen are (1) Van der Waals’ forces (2) Covalent forces (3) Hydrogen bonds (4) None of these Among the following mixtures, dipole-dipok le as the major interaction, is present i (1) KCI and water (2) enzene and carbon tetrachloride (3) Benzene and ethanol (4) Acetonitrile and acetone At room temperature HCI is a gas while HF is a low boiling liquid. This is beca (1) H - F bond is covalent (2) H - F bond is ionic (3) H - F has metallic bond (4) H - F has hydrogen bond Which one of the following molecules will fon (1)_NH. ) (4) HE10, International Junior Science Olympiad (Chemistry) When two atoms combine to form a molecule (1) eneray Is released (2) energy Is absorbed {@) energy Is nether released nor absorbed (4) energy may either released or absorbed ‘Valency expresses: (1) total electrons in an atom {@) oxidation number of an element (2) atomicity of an element (4) combining capacity of an element The combination of atoms occur because they want: (a) to decrease number of electrons in the outermost orbit (2) to attain an inert gas configuration {@) to increase number of electrons in the outermost orbit (4) to attain 18 electrons in the outermost orbit The ion that is isoelectronic with CO is; (a) CN" (2) Cs (3) 0; (@) Nj ‘The attractive force which holds various constituents (atoms, ions etc.) together in different chemical species is called a 1) chemical bond (2) chemical compound ( (3) ionic bond (4) covalent bond LEWIS THEORY Which of the following Lewis representation of the molecules NF, ©, and HNO, is correct ? Choose the correct option(s). carn : ne (1) Only! (2) Only II (3) Only I (4) 1, D and Il What are the formal charges on central sulphur and each terminal oxygen atoms in SO,? (1) 0, 0, 0 (2) + 2, 0,-1 (3) 0, -1, +1 (4)+2,4+2,+2 The formal charge on the central oxygen atom in O, molecule is : (yo (2) +1 (3) -1 (4) -2 Which of the following is the correct electron dot structure of N,O molecule? (3) (4) :N=N () N-N-=0: If the atomic number of element X is 7 the lewis diagram for the element is : (8) Se (4) sXe () Xe (2) 9Target : SO (Stagect) ata 12, 13, 14. 15. 16. ay. 18, 19. 20. 21. 22. ze 24. 25. is represented by ~ The correct sequence of increasing covalent char () BeCly < NaCl < LiCl estes . (8) BeCl, < LiCl < NaCl (4) LiCl < NaCl < 2 The correct order of increasing ionic character Is i Perro Bse, PH, > ASH, > SbH, (2) jollowing hydrides is NH, > AsH. (3) SbH, > AsH, > PH, > NH, 4) PH NEE naa > SbH,, ‘The electronegativty diference between N and F is greater thas th concn dipole moment of NH (1.5 D) is larger than that of NF ( (2) In NH the atomic dipole and bond di are in the same direction Sadie Gane than that between N a ind H yet ROME UY cance posite directions whereas in NF these (2) In NHg as well as in NF, the atomic dipole and bond dipole are in the same directi ion @) In NHg the atomic dipole and bond dipole are in the same direction are in opposite directions whereas in NF; these (4) In NHg as well as NF the atomic dipole and bond dipole are in opposite directions The dipole moment of HBr is 0.78 x 10-1# i oe eaaee or Her'c esu cm and interatomic spacing is 1.41A. The w7s (2) 11.7 (3) 15 Which of the following has maximum dipole moment? cat (a) NH3 (2) H,0 (3) HI (4) So. Which of the following has maximum dipole moment ? j (1) CCl (2) CH,CI (3) CH,Cl. Which compound shows dipole moment? aie Wee (1) 1,4 di-chlorobenzene (2) 1,2 di-chk (3) Trans-1,2 di-chloroethene (4) ira ae The molecule having non-zero dipole moment is () H,0, (2) CH, @) GH, (4) BF, Which one of the following arrangements of molecules is correct on the basis of their dipole moments ? (1) BF, > NF, > NH, (2) NF, > BF, > NH, (3) NH, > BF, > NF, (4) NH, > NF, > BF; Which of the following hydrocarbons has the lowest dipole moment ? HC. cl oe ae (2) CH,C = CCH, (3) CH,CH,C = CH (4) CH, —CH — C = CH Which one of the following pairs of molecules will have permanent dipole moments for both members? ()NO, and CO, (2) NO, and 0, (8) SIF, and CO, (4) SIF, and NO, The values of electronegativity of atoms A and B are 1.20 and 4.0 respectively. The percentage of ionic character of A-B bond is (1) 50% (2) 72.24% (3) 55.3% (4) 43% The correct order of C-O bond length among CO, CO}, CO is (1) CO < co#< COz (2) coz BFy > NO;* (esa ae (3) Br,0 > C1,0 > OF, (4) PCly > PBra > 46. Which of the following have same geometry/hybridisation 2 NU | (co, (2) Sn¢l, ser Wale ceomeny 7 47. In which species the actual shape of molecule is the same as the Melechlas geomenry 7 (2) Be, (2) PF, (3) SF, ee 48. Which of the following is planar ? (1) Xe0, 2) KeOF, (3) Xe0,F, ore 49. Which of the following are isostructural? (1) XeF,, IF, (2) NH,, BF, (OO PC's IK 50. Shape of O,F, is similar to that of : () GF, 2) H,0, (8) HF, cs 51. Which of the following are isoelectronic and isostructural? (NO,", CO,*, CIO,”, SO.) (1) NO,, CO,;? (2) $0,, NOs (3) ClO; CO,* (4) CO,*, SO, 52. Structure of H,O, is = (1) Planar (2) Non-planar (3) Linear (4) None 53. The molecular shapes of SF4, CF, and XeF, are (1) The same with 2, 0 and 1 lone pair of electrons on the central atoms, respectively (2) The same with 1, 1 and 1 lone pair of electrons on the central atoms, respectively (3) Different with 0, 1 and 2 lone pair of electrons on the central atoms, respectively (4) Different with 1, 0 and 2 lone pair of electrons on the central atoms, respectively 54. Among the following species identify the isostructural pairs. (NF, ; NO,, BF,, H,0°, HN, ) (1) (NF,, HN,) & [NO,-, BF,] (2) INF,, H,0*] & [NO,-, BF, (3) INF,, H,O°] & (HN,, BE,] (4) INF,, NO,] & [BF,, H,0°] 55. Molecular formulae and shapes of some molecules are given below. Choose the incorrec Shay - |Trigonal pyramidal Tetrahedral > [T-shaped + |Trigonal bipyramidal SSSInternational Junior Science Olympiad (Chomisry) . 3 Following statements is not correct for sigma and pi bond formed between two carbon atoms! a) Free rotation of atoms about a sigma-bond is allowed but not in case of a pi-bond ssigmabond determines the direction between carbon atoms Sie inthis regord but @ pi-bond has no primary 3) ssigma-bond is stronger than a pi-bond (4)Bond energies of sama and pi-bonds are of the order of 264 kJ/mol and 347 1J/mol respectively he number and type of bond between two carbon atom in calcium carbide are e (a) One sigma, one Pi (2) One sigma, two pi (g) Two sigma, one pi (4) Two sigma, two pi gs. The number and types of bonds between carbon atoms in Mg,C; are : (1) one sigma and one a-bond (2) two sigma and one a-bond {@) one sigma and two m-bond (4) two sigma and one n-bond 59. ently the correct sequence of increasing number of x-bonds in the structures of the following molecules ( H,S206 (il) HzSO3 (it) H,S,05, qi Wu (2) 0, MM, 1 (3) M1, 1, (4) 1, 1, 0 60. In the formation of r-bond , the atomic orbitals overlap in such a way that (a) their axes remain parallel to each other and perpendicular to the internuclear axis (2) their axes remain parallel to each other and parallel to the internuclear axis {@) their axes temain perpendicular to each other and parallel to the internuclear axis (4) their axes remain perpendicular to each other and perpendicular to the internuclear axis HYBRIDISATION 61. Among the compounds, BF,, NCI,, H,S, SF, and BeCl,, identify the one in which the central ‘atom has the same type of hybridisation? (1) BF, and NCI, (2) H,S and BeCl, (3) BF,, NCI, and H,S (4) NCI, and H,S 62. Hybridization of Cl in ClO,- is - (1) sp (2) sp? (3) sp? (4) None 63. There is change in the type of hybridization when (1) NH, combines with H* (2) AIH, combines with H (3) NH, forms NH,- (4) None of these "64. What is the hybridization of oxygen atom in an alcohol molecule? (1) sp3 (2) sp (3) sp? (4) p? ___ 65. Ina chemical change PCl, + Cl, ——>PCls, the hybrid state of P changes from (1) sp? sp? (2) sp?» sp3d2_ (3) sp*> dsp? (4) sp3 > sp3.4 bs Gal66. 67. 69. 70. 71 72. 73. 74 75. The order of strength of hydrogen bond Is + ) CHC NHN > OmHinO > FaBianF (2) NH.....N > Cl+H..... 8) OFH..WO > NH (4) PH..F > OH... The reason for exceptionally high boiling point of water Is (2) its high dielectric constant (4) bydrogen bonding in the molecules of water (1) its high specific heat (8) low ionization of water molecule Hydrogen bonding is formed in compounds containing hy (2) highly electropositive atoms drogen and (2) highly electronegative atoms (3) metal atoms with d-orbitals occupied (4) metalloids Hydrogen bonding would not affect the boiling point of CH,OH MH (QH,0 (3) NH, ee The boiling points at atmospheric pressure of HFH,S, NH, can be arranged in the following order: () HF > NH,>H,S (2)HF > H,S>NH, @)HFB-F (2) B-F>C-FsN-F (3) COPSN-F>B-F (4) B-FaC-Fsn-F If HCI molecule Is completely tonic the H+ and Cl- ions would b is would bear a unit charge equal 4,80 x 107° esu and the bond distance between H and Cl atom ie liees of HCl is a 127A then the dipole moment a 3.779 (2) 7.742 D (3) 6.096 D (4) 2.976 D [01 ion Is represented as () for (2) fo] (3) [oy (4) [oy The valencies of two elements A and B are +2 and + 3 respectively. Then, the formulae of sul of Band chloride of A respectively are Sila aig (1) Bs(SOq)2 and ACI, (2) BASO,4); and ACI, (3) BSO, and A,CI (4) BySO, and ACI Which species below has the same general shape as NH; ? (1) $O32- (2) CO,2- (3) NOx (4) SO, Which set contains only covalently bonded molecules? (1) Bly, SiC, PCI; (2) NHyBr, NoH,, HBr (3) 1p, HS, Nal (4) Al, 03, Asy Which bond is expected to be the least polar? (1) O-F (2) P-F (3) Si-N (4) B-Cl Which species has a Lewis diagram and structure most like that of the carbonate ion, CO,2? (1) NO3- (2) CH, (3) SO,2 (4) PO, Which of the following Lewis dot structures best describes the structure of peroxide ion of sodium peroxide? X - electrons from oxygen * - electrons from sodium MOO OO OIC). oC: aK XX XX a XX xx 4 XX Xx XX Electronic configuration of Na* is (2,8) and that of sodium element is (2,8,1). Choose the correct statements. () Nat) is more stable than Navy (ii) Na*(g is less stable than Naja) (ii) Na*jgq) is more stable than Najeq. (iv) Na*(aq) is less stable than Najaq) (1) ii, iff (2) i, iii (3) ii, iv (4) i, iv The maximum number of hydrogen bonds in which hydrogen fluoride molecule can participate (2 (2) 3 (3) 4 (4) 5=> Atty, Target : USO (Stage-1) AS + @ —1 TES ga, ete ma Ie | ia wom [one |97031| 4727] (tie [ews Identify element A. (4) Fluorine () Nitrogen (2) Oxygen (3) Carbon 13. What occurs when Hp0q evaporates (i) Covalent bonds are broken. (ii) Only dipole-dipole forces are overcome: (ii) Heat is absorbed by water from the surroundings (iv) It becomes oxygen and hydrogen gas. 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