Gauss-seidel

x1,A=6-2x2,p-3x3,p/-10
A B
x2,a=9-x1,A+2X3,P/8
-10 2 3 6
1 8 -2 9 x3,A=33-3x1,A-X2,A/9
3 1 7 33

-0.08592593 0.0162963 0.04148148 x1 #NAME?

0.01925926 0.11703704 0.02518519 x2 #NAME?
0.03407407 -0.0237037 0.12148148 x3 #NAME?
 TOLERANCIA 0.0005
Gauss-seidel
x1,A=6-2x2,p-3x3,p/-10 ITERACION X1,P X2,P X3,P X1,A X2A
1 5 5 5 1.9 2.1375
x2,a=9-x1,A+2X3,P/8
2 1.9 2.1375 3.59464286 0.90589286 1.91042411
x3,A=33-3x1,A-X2,A/9 3 0.90589286 1.91042411 4.05312819 0.99802328 2.01352914
4 0.99802328 2.01352914 3.99891443 1.00238016 1.99943109
5 1.00238016 1.99943109 3.99906121 0.99960458 1.99981473
6 0.99960458 1.99981473 4.00019593 1.00002173 2.00004627
7 1.00002173 2.00004627 3.99998408 1.00000448 1.99999546
8 1.00000448 1.99999546 3.99999873 0.99999871 1.99999984
9 0.99999871 1.99999984 4.00000057 1.00000014 2.00000013
 X3,A E1 E2 E3
3.59464286 163.157895 133.918129 39.0958768
4.05312819 109.737828 11.8861509 11.3118883
3.99891443 9.23128978 5.12061278 1.35571183
3.99906121 0.43465338 0.70510302 0.00367019
4.00019593 0.27766758 0.0191838 0.0283668
3.99998408 0.04171373 0.01157666 0.00529637
3.99999873 0.00172484 0.00254038 0.00036626
4.00000057 0.00057664 0.00021917 4.61275E-05
3.99999992 0.00014302 1.41249E-05 1.63326E-05
 tol 0.0005
x1 0.71539685
x2 1.51056996

f1 0.00122269 j(x) 1.43079369 -1

f2 -0.00090395 -1.31183404 -1

prod 0.0007754 inv(j(x)) 0.36461383 -0.36461383

-0.00011325 -0.47831283 -0.52168717

x1A 0.71462144 e1 0.10850564

x2A 1.51068321 e2 0.00749651

iteración 1 2 3
x1 0.75036387 0.71539685 0.71462144
x2 1.50072774 1.51056996 1.51068321
e1 33.2686771 4.88777949 0.10850564
e2 33.3656615 0.65155679 0.00749651
 Utilice regresión

x y xy x^2 St Ymod Sr
1 1 1 1 18.2329 -0.55555556 2.41975309
2 1.5 3 4 14.2129 0.90277778 0.35667438
3 2 6 9 10.6929 2.36111111 0.13040123
4 3 12 16 5.1529 3.81944444 0.6714892
5 4 20 25 1.6129 5.27777778 1.63271605
6 5 30 36 0.0729 6.73611111 3.01408179
7 8 56 49 7.4529 8.19444444 0.03780864
8 10 80 64 22.3729 9.65277778 0.12056327
9 13 117 81 59.7529 11.1111111 3.56790123
45 47.5 325 285 139.5561 47.5 11.9513889

yprom = 5.27777778 a1 = 1.45833333 r^2 0.9143614

xprom = 5 a0 = -2.01388889

Pendiente= 1.45833333
Intersección=-2.01388889
coeficiente= 0.91436107
 Regresión lineal
14

12

10 f(x) = 1.45833333333333 x − 2.01388888888889

0
-2 0 2 4 6 8 10 12
-2
 Utilice el siguiente conjunto de datos de presion vs volumen para estimar las constantes viriales de la ecuación

R= 82.05 ml*atm/mol*k
T= 303 K y a0 + a1x

𝑃𝑉/𝑅𝑇=1+𝐴1/𝑉+𝐴2/𝑉 =(𝑃𝑉^3)/𝑅𝑇−𝑉^2=𝐴2+𝐴1𝑉
=(𝑃𝑉^3)/𝑅𝑇=𝑉^2+𝐴1𝑉+𝐴2

P,atm V,ml x y xy x^2 st

0.985 25000 25000 -5936722.56 -148418063927 625000000 1.402344E+12
1.108 22200 22200 -5224536.35 -115984707079 492840000 222802936485
1.363 18000 18000 -4263543.72 -76743786993 324000000 239094177806
1.631 15000 15000 -3585262.55 -53778938223 225000000 1.362481E+12
80200 -19010065 -394925496222 1666840000 3.226723E+12

Yprom = -4752516.3 a1= -234.12696452 r^2=

Xprom= 20050 a0= -58270.656952

𝐴𝑅𝐸=1/𝑛 ∑▒ 〖|(𝑉𝑒𝑥𝑝−𝑉𝑚𝑜𝑑)/𝑉𝑒𝑥𝑝| 〗∗ 100

antes viriales de la ecuación de estado que se muestra a continuación

𝑎1=(𝑛∑▒ 〖
𝑥𝑦 −∑▒〖𝑥∑▒𝑦 〗〗 )/(𝑛∑▒ 〖
𝑥 ^2−(∑▒𝑥)^2 〗 )

𝑎0=𝑦𝑝𝑟𝑜𝑚−𝑎1𝑥𝑝𝑟𝑜𝑚

ymod Sr Pmod Pexp error 0

14000 16000 18000 20000 22000 2
-5911444.77 638966527 0.98504022 0.985 0.00408323
-1000000
-5255889.27 983005235 1.10792876 1.108 0.00642984
-4272556 81221486.7 1.36296158 1.363 0.00281866 -2000000
-3570175.12 227630348 1.63111114 1.631 0.0068141
-19010065 1930823596 5.0870417 5.087 -3000000

-4000000
0.99940161
-5000000

-6000000

-7000000

30000

25000

20000

15000

10000

5000

0
0.9 1 1.1 1.2 1.3 1.4 1.5
18000 20000 22000 24000 26000

1.2 1.3 1.4 1.5 1.6 1.7

De forma experimental se encontraron los siguientes datos del avance de una
reacción química respecto al tiempo. En el experimento se alimento el
compuesto a1 con una concentración (CA 0) = 0.2
Se propone el siguiente modelo para evaluar el cambio de de CA contra el 𝐶𝐴=1/(1/𝐶𝐴0+𝑘𝑡)
tiempo
a) Ajuste el modelo a los datos y estime el parametro correspondiente
b) Verifique el grado de ajuste del modelo

t, min CA, M X y x*y x^2 St

0 0.2 0 0 0 0 99.9926872
10 0.111 10 4.00900901 40.0900901 100 35.887592
20 0.077 20 7.98701299 159.74026 400 4.05064476
30 0.059 30 11.9491525 358.474576 900 3.80062117
40 0.0475 40 16.0526316 642.105263 1600 36.6387754
50 0.04 50 20 1000 2500 100.007313
150 0.5345 150 59.9978061 2200.41019 5500 280.377634

a1=k 0.40007458
yprom= 9.999634353

0 10 20 30 40 50 60 25
0.25 12
20
0.2 10 f(x) = 0.400074579865351 x
R² = 0.999993667424546
8 15
0.15
6
10
0.1
4
0.05 5
2

0 0 0
0 10 20 30 40 50 60 0 10 20 30 40
 𝐶𝐴=1/(1/𝐶𝐴0+𝑘𝑡)1/𝐶𝐴=1/𝐶𝐴0+𝑘𝑡 1/𝐶𝐴−1/𝐶𝐴0=𝑘𝑡

y=a1x

ymod Sr CA mod ERROR

0 0 0.2 0
4.0007458 6.82806E-05 0.1111019 0.09180584
8.0014916 0.00020963 0.07691425 0.11136115
12.0022374 0.002818 0.05881579 0.31222275
16.0029832 0.00246496 0.04761228 0.2363873
20.003729 1.39054E-05 0.03999403 0.01491375
60.011187 0.00557478 0.53443826 0.1277818

r^2= 0.99998012

74579865351 x
3667424546

20 30 40 50 60
Utilizando regresion de minimos cuadrados ajuste un polinomio de segundo grado a los siguientes datos

X Y x^2 x^3 x^4 x*y x^2*y

0.2 500 0.04 0.008 0.0016 100 20
0.5 700 0.25 0.125 0.0625 350 175
0.8 1000 0.64 0.512 0.4096 800 640
1.2 1200 1.44 1.728 2.0736 1440 1728
1.7 2200 2.89 4.913 8.3521 3740 6358
2 2650 4 8 16 5300 10600
2.3 3750 5.29 12.167 27.9841 8625 19837.5
8.7 12000 14.55 27.453 54.8835 20355 39358.5

yprom= 1714.28571 7 8.7 14.55 12000

8.7 14.55 27.453 20355
14.55 27.453 54.8835 39358.5

1.49195381 -2.59402779 0.902018219 a0 #NAME?

-2.59402779 5.73286413 -2.179912261 a1 #NAME?
0.90201822 -2.17991226 0.869492037 a2 #NAME?
los siguientes datos 𝑦=𝑎0+𝑎1𝑥+𝑎2𝑥2

St Y mod Sr 0 0.5 1 1.5 2 2.5

1474489.8 584.262274 7100.1308 700
1028775.51 #NAME? #NAME?
510204.082 #NAME? #NAME? 600 f(x) = 674.006894513465 x² − 233.960863285937 x + 604.09417077382
R² = 0.989424947579503
264489.796 #NAME? #NAME?
500
235918.367 #NAME? #NAME?
875561.224 #NAME? #NAME? 400
4144132.65 #NAME? #NAME?
8533571.43 #NAME? #NAME? 300

200
r^2= 0.98942495
100

0
0 0.5 1 1.5 2 2.5
 1.5 2 2.5
4000

60863285937 x + 604.09417077382 3500

3000

2500

2000

1500

1000

500

0
1.5 2 2.5