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    3. CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

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    14 views5 pages

    Classification of Elements and Periodicity in Properties

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    syntia mahyarani

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    © All Rights Reserved
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    JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X R K M A LI K 's Enjoys unparalleled reputation for best results . . in terms of percentage selection NEWTON CLASSES www.newtonclasses.net CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES (NEET CHAPTER WISE SOLVED PAPERS) R.K.MALIK S NEWTON CLASSES JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X PSs 1. Which of thé following elements has maximum electron affin- | (1) Br, < Cl, 2, : Oxidising power iy? Electronegativty wa @ Br G)_ BryK> > Rb >Ce (2) Ko > Nat >Rb' SCs (3) Ce >Rb'>K! > Nat (4) Rb >K* >Cs' > Nav (AIPMT 2008) Which one of the elements with the following outer orbital configuration may exhibit the largest numberof oxidation tates? () 384s @ 304s @) 364s (364s (AIPMT 2009) Amongst the elements with following electronic configuration. Which one of them may have the highest ionization energy? () NeBssp) @) Neps'3p') @) NeBs'3p'] ) ArBarss4p’) (AIPMT 2008) ‘The comect order of the decreasing ionic radii among the following isoelectronic species is (1) Ch>S* >a > Ke GB) K’>Ca* > Cro (2) S*>Ch>K >Car (4) S* >Cl->K* >Ca* (AIPMT PRE 2010) ‘Which of the following represents the cortéet order of increas- ing electron gain enthalpy with negative sign for the elements, 0,8, F and C1? (@) OF>0> @) F>O->Ne (4) APY > Mg > NE (AIPMT 2014) ‘The species Ar, K* and Ca* contain the same number of elec- trons, In which order do their radi increase? () Ca carck’ Q) Ca cK iiteasing ionic sige) (2) BBr, >F, Answer (4) ‘Topic: Periodic Trends in Properties of Elements. ‘The bond energy of F, is abnormally low-(126 kI mol) while bond energy of Cl, is 210 IJ mol: Fluorine atts are small, the F-F distanceiis also small, afd hence internuclear repulsion is appreciable. The large eléctron-electron repulsions between the lone pairs of electrons on the two fluorine atoms weaken the bond. Answer (2) ‘Topic: Periodié Trends in Properties of Elements The Z,, ineréases in a period, hence fist ionization potential increases. Beryllium (Be) has fully il6d 25° orbital hence it has higher ionization pateitial. than Boron (B) which attain fully filled 2s* configuration’ on losing/one electron. Therefore, the correct grderof ionization potential is Li < B< Be RB’ >K* >/Nat Answer (3) ‘Topic: Periodic Trends in Properties of Elesnents 304s? has maximum slamber of electrons in the outermost shell; thefefore, it can‘exhibiflargest number of oxidation states. Answer (4) ‘Topicyi{Blkeetronic Configuration of Elements and the Periodic Table Half filled eleotfonic configuration is more stable and the ioniza- ‘tion energy decreases down the group. Therefore, Ne [3s 3p"]has the highest electronic configuration among the given elements. ‘Answer (2) “Topic: Periodic Trends in Properties of Elements Cations have smaller radii than atoms whereas anions have larger radii than the corresponding atoms. For isoelect species greater the anionic charge larger will be the radi. Thus, the correct order is $*> Cl >K* > Ca* Answer (2) 106 , 6" Floor, Hariom Tower, Circular Road, Ranc! |, Ph.; 0651-2562523, 9835508812, 8507613968 CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES (NEET CHAPTER WISOLVED PAPERS) 5 . Topic: Periodic Trends in Properties of Elements 18, 9 a. 2. Electron affinity isthe tendency of the atoms to gain electrons. Ina group, there is decrease of electron affinity in general but for p-block elements only the EA, of second period element is less than EA, of third period element. The third period elements have larger size and vacant 3d orbitals, which can accommodate incoming electron easily, ‘Second period (0) < Third period (S) Ina period, electron affinity increases from left to right a8 Z,¢ increases. C1 has the highest electron affinity among halogens. Hence, the correct onder is O.<$ < F< CL Answer (1) ‘Topic: Periodic Trends in Properties of Elements ‘There isa general decrease of atomic radius in a period Bedise the effective nuclear charge (Z,,)iicreases aSf68s row Aforic radii increase down the group. This is due to successive use of ‘orbitals with principal quantum number (n) one higher than the last. Therefore, the onder is Clee P < Mg F >\Nar, ‘Answer (Nome) ‘Topic: Periodié-Trendsiin Properties of Eleivents ‘The atomic radiui or ioniélradius = 1/Effective nucleai charge. (Z,.). Due to increate in the positive chafgelieffective nuclear charge increases resulting inthe reduction of the atomic radius or ionic radius. So, for isoelectronic species the Gorrect order is Ca

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