BRITISH STANDARD BS EN ISO 105-

E03:2010

Textiles — Tests for

colour fastness
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

Part E03: Colour fastness to

chlorinated water (swimming-pool
water) (ISO 105-E03:2010)

ICS 59.080.01

NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW

 BS EN ISO 105-E03:2010

National foreword

This British Standard is the UK implementation of

EN ISO 105-E03:2010. It supersedes BS EN ISO 105-E03:1997 which
is withdrawn.
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

The UK participation in its preparation was entrusted to Technical

Committee TCI/81, Colour fastness and colour measurement of textiles.
A list of organizations represented on this committee can be obtained on
request to its secretary.
This publication does not purport to include all the necessary provisions
of a contract. Users are responsible for its correct application.
Compliance with a British Standard cannot confer immunity
from legal obligations.

This British Standard Amendments/corrigenda issued since publication

was published under the
authority of the Standards
Policy and Strategy Date Comments
Committee on 31 May 2010

© BSI 2010

ISBN 978 0 580 65751 1

 EUROPEAN STANDARD EN ISO 105-E03
NORME EUROPÉENNE
EUROPÄISCHE NORM April 2010

ICS 59.080.01 Supersedes EN ISO 105-E03:1996

Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

English Version

Textiles - Tests for colour fastness - Part E03: Colour fastness

to chlorinated water (swimming-pool water) (ISO 105-E03:2010)

Textiles - Essais de solidité des coloris - Partie E03: Textilien - Farbechtheitsprüfungen - Teil E03: Farbechtheit
Solidité des coloris à l'eau chlorée (eau de piscine) (ISO gegen gechlortes Wasser (Badewasser in
105-E03:2010) Schwimmbädern) (ISO 105-E03:2010)

This European Standard was approved by CEN on 22 March 2010.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the
official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION

COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels

© 2010 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 105-E03:2010: E
worldwide for CEN national Members.
 BS EN ISO 105-E03:2010
EN ISO 105-E03:2010 (E)

Foreword
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

This document (EN ISO 105-E03:2010) has been prepared by Technical Committee ISO/TC 38 "Textiles" in
collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the secretariat of which is
held by BSI.

This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by October 2010, and conflicting national standards shall be withdrawn at
the latest by October 2010.

Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.

This document supersedes EN ISO 105-E03:1996.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,
Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,
Sweden, Switzerland and the United Kingdom.

Endorsement notice

The text of ISO 105-E03:2010 has been approved by CEN as a EN ISO 105-E03:2010 without any
modification.

3
 BS EN ISO 105-E03:2010
ISO 105-E03:2010(E)

Foreword
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.

International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.

The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.

Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.

ISO 105-E03 was prepared by Technical Committee ISO/TC 38, Textiles, Subcommittee SC 1, Tests for
coloured textiles and colorants.

This fourth edition cancels and replaces the third edition (ISO 105-E03:1994), of which Clauses 2 and 5 have
been technically revised and instrument assessment added to the appropriate clauses.

ISO 105 consists of many parts designated by a part letter and a two-digit serial number (e.g. A01), under the
general title Textiles — Tests for colour fastness. A complete list of these parts is given in ISO 105-A01.

© ISO 2010 – All rights reserved iii

Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

BS EN ISO 105-E03:2010
 BS EN ISO 105-E03:2010
INTERNATIONAL STANDARD ISO 105-E03:2010(E)

Textiles — Tests for colour fastness —

Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

Part E03:
Colour fastness to chlorinated water (swimming-pool water)

1 Scope
This part of ISO 105 specifies a method for determining the resistance of the colour of textiles of all kinds and
in all forms to the action of active chlorine in concentrations such as are used to disinfect swimming-pool
water (break-point chlorination).

Three alternative test conditions are specified. The active chlorine concentrations of 50 mg/l and 100 mg/l are
intended for swimwear. The active chlorine concentration of 20 mg/l is intended for accessories such as beach
robes and towels.

2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.

ISO 105-A01, Textiles — Tests for colour fastness — Part A01: General principles of testing

ISO 105-A02, Textiles — Tests for colour fastness — Part A02: Grey scale for assessing change in colour

ISO 105-A05, Textiles — Tests for colour fastness — Part A05: Instrumental assessment of change in colour
for determination of grey scale rating

ISO 3696, Water for analytical laboratory use — Specification and test methods

3 Principle
A specimen of the textile is treated with a weak chlorine solution of a given concentration and dried. The
change in colour of the specimen is assessed by comparison with the grey scale or instrumentally. Three
alternative test conditions are specified.

4 Apparatus
4.1 Suitable mechanical device, consisting of a water bath containing a rotatable shaft which supports,
radially, glass or stainless steel containers with a diameter of (75 ± 5) mm and a height of (125 ± 10) mm of
(550 ± 50) ml capacity, the bottom of the containers being (45 ± 10) mm from the centre of the shaft. The
shaft/container assembly is rotated at a frequency of (40 ± 2) min−1. The temperature of the water bath is
thermostatically controlled to maintain the test solution at the prescribed temperature ±2 °C.

Other mechanical devices may be used for the test, provided that the results are identical to those obtained in
the apparatus described above.

© ISO 2010 – All rights reserved 1

 BS EN ISO 105-E03:2010
ISO 105-E03:2010(E)

4.2 pH-meter, having an accuracy of 0,02 units.

4.3 Grey scale for assessing change in colour, complying with ISO 105-A02.

4.4 Spectrophotometer or colorimeter for assessing change in colour, complying with ISO 105-A05.
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

4.5 Analytical balance, accurate to ± 0,01 g (see ISO 105-A01).

5 Reagents
5.1 Sodium hypochlorite (NaOCl), aqueous solution, having the following composition:

⎯ active chlorine: 140 g/l to 160 g/l;

⎯ sodium chloride (NaCl): 120 g/l to 170 g/l;

⎯ sodium hydroxide (NaOH): 20 g/l maximum;

⎯ sodium carbonate (Na2CO3): 20 g/l maximum;

⎯ iron (Fe): 0,01 g/l maximum.

All sodium hypochlorite solutions should be prepared just prior to use.

5.2 Sodium hypochlorite (NaOCl), aqueous solution, containing 100 mg of active chlorine per litre, at
pH = 7,50 ± 0,05.

Prepare solutions as follows, using grade 3 water (5.7):

⎯ Solution 1: dilute 20,0 ml of sodium hypochlorite solution (5.1) to 1 litre;

⎯ Solution 2: 14,35 g of KH2PO4 (5.5) per litre;

⎯ Solution 3: 20,05 g of Na2HPO4⋅2H2O (5.6) per litre, or 40,35 g Na2HPO4⋅12H2O (5.6) per litre.

To 25,0 ml of Solution 1, add excess potassium iodide (Kl) and hydrochloric acid (HCl), and titrate the
liberated iodine with a sodium thiosulfate solution, c(Na2S2O3) = 0,1 mol/l, using starch as indicator.

Let the volume of sodium thiosulfate solution required be V ml.

For each litre of working solution at pH 7,50 ± 0,05, use:

705,0
ml Solution 1
V

100,0 ml Solution 2

500,0 ml Solution 3

Dilute to 1 litre, with water.

Before use, check the pH of the solution using the calibrated pH-meter (4.2).

If necessary, adjust the pH using either sodium hydroxide, c(NaOH) = 0,1 mol/l, or acetic acid,
c(CH3COOH) = 0,1 mol/l.

2 © ISO 2010 – All rights reserved

 BS EN ISO 105-E03:2010
ISO 105-E03:2010(E)

5.3 Sodium hypochlorite (NaOCl) aqueous solution, containing 50 mg of active chlorine per litre, at
pH = 7,50 ± 0,05.

Follow the same procedure as in 5.2, except that, for each litre of working solution at pH 7,50 ± 0,05, use
705,0
ml of Solution 1.
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

2V

5.4 Sodium hypochlorite (NaOCl), aqueous solution, containing 20 mg of active chlorine per litre, at
pH = 7,50 ± 0,05.

Follow the same procedure as in 5.2, except that, for each litre of working solution at pH 7,50 ± 0,05, use
705,0
ml of Solution 1.
5V

5.5 Potassium dihydrogenphosphate (KH2PO4).

5.6 Disodium hydrogenphosphate dihydrate (Na2HPO4⋅2H2O), or disodium hydrogenphosphate

dodecahydrate (Na2HPO4⋅12H2O).

5.7 Grade 3 water, complying with ISO 3696.

6 Test specimen

6.1 If the textile to be tested is fabric, use a specimen measuring (40 ± 2) mm × (100 ± 2) mm.

6.2 If the textile to be tested is yarn, knit it into fabric and use a specimen measuring
(40 ± 2) mm × (100 ± 2) mm, or make a wick of parallel lengths, (100 ± 2) mm long and about (5 ± 2) mm in
diameter, tied near both ends.

6.3 If the textile to be tested is loose fibre, comb and compress enough of it to form a sheet measuring
(40 ± 2) mm × (100 ± 2) mm. Determine the mass of the fibre and sew it onto a piece of polyester or
polypropylene cloth to support the fibre. The liquor ratio (see 7.1) shall be based on the mass of fibre only.

7 Procedure
7.1 Each specimen shall be tested in a separate container in the mechanical device (4.1). Immerse the
specimen in the sodium hypochlorite solution (5.2, 5.3 or 5.4), of liquor ratio 100:1, ensuring that the specimen
is thoroughly wetted. Close the container and agitate at (27 ± 2) °C for 1 h in darkness.

7.2 Remove the specimen from the container, squeeze or hydroextract it, and dry it by hanging it in air at
room temperature in subdued light.

7.3 Assess the change in colour of each specimen with reference to the original specimen by comparison
with the grey scale (4.3) and/or instrumentally (see 4.4).

© ISO 2010 – All rights reserved 3

 BS EN ISO 105-E03:2010
ISO 105-E03:2010(E)

8 Test report

The test report shall include the following information:

a) a reference to this part of ISO 105 (ISO 105-E03:2010);

Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

b) all details necessary for the identification of the sample tested;

c) the numerical grey scale ratings and/or instrument assessment for the change in colour of each
specimen;

d) the concentration of active chlorine used (see 5.2, 5.3 and 5.4.);

e) any deviation, by agreement or otherwise, from the procedure specified.

4 © ISO 2010 – All rights reserved

 BS EN ISO 105-E03:2010
ISO 105-E03:2010(E)

Bibliography

[1] ISO 105-J01, Textiles — Tests for colour fastness — Part J01: General principles for measurement of
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

surface colour

[2] ISO 105-J03, Textiles — Tests for colour fastness — Part J03: Calculation of colour differences

[3] AATCC TM 162, Colorfastness to Water: Chlorinated Pool

© ISO 2010 – All rights reserved 5

 BS EN ISO 105-
E03:2010
BSI - British Standards Institution
BSI is the independent national body responsible for preparing British
Standards. It presents the UK view on standards in Europe and at the
international level. It is incorporated by Royal Charter.
Revisions
British Standards are updated by amendment or revision. Users of British
Licensed copy: I P, The University of Leeds, Version correct as of 12/04/2013 07:43, (c) The British Standards Institution 2013

Standards should make sure that they possess the latest amendments or
editions.
It is the constant aim of BSI to improve the quality of our products and services.
We would be grateful if anyone finding an inaccuracy or ambiguity while using
this British Standard would inform the Secretary of the technical committee
responsible, the identity of which can be found on the inside front cover. Tel:
+44 (0)20 8996 9000. Fax: +44 (0)20 8996 7400.
BSI offers members an individual updating service called PLUS which ensures
that subscribers automatically receive the latest editions of standards.
Buying standards
Orders for all BSI, international and foreign standards publications should be
addressed to Customer Services. Tel: +44 (0)20 8996 9001. Fax: +44 (0)20 8996
7001 Email: orders@bsigroup.com You may also buy directly using a debit/credit
card from the BSI Shop on the Website http://www.bsigroup.com/shop
In response to orders for international standards, it is BSI policy to supply the
BSI implementation of those that have been published as British Standards,
unless otherwise requested.
Information on standards
BSI provides a wide range of information on national, European and
international standards through its Library and its Technical Help to Exporters
Service. Various BSI electronic information services are also available which
give details on all its products and services. Contact Information Centre. Tel:
+44 (0)20 8996 7111 Fax: +44 (0)20 8996 7048 Email: info@bsigroup.com
Subscribing members of BSI are kept up to date with standards developments
and receive substantial discounts on the purchase price of standards. For details
of these and other benefits contact Membership Administration. Tel: +44 (0)20
8996 7002 Fax: +44 (0)20 8996 7001 Email: membership@bsigroup.com
Information regarding online access to British Standards via British Standards
Online can be found at http://www.bsigroup.com/BSOL
Further information about BSI is available on the BSI website at http://
www.bsigroup.com.
Copyright
Copyright subsists in all BSI publications. BSI also holds the copyright, in the
UK, of the publications of the international standardization bodies. Except as
permitted under the Copyright, Designs and Patents Act 1988 no extract may
be reproduced, stored in a retrieval system or transmitted in any form or by any
means – electronic, photocopying, recording or otherwise – without prior written
BSI Group permission from BSI.
Headquarters 389 This does not preclude the free use, in the course of implementing the standard,
Chiswick High Road, of necessary details such as symbols, and size, type or grade designations. If
London, W4 4AL, UK these details are to be used for any other purpose than implementation then the
Tel +44 (0)20 8996 9001 prior written permission of BSI must be obtained.
Fax +44 (0)20 8996 7001
www.bsigroup.com/ Details and advice can be obtained from the Copyright and Licensing Manager.
standards Tel: +44 (0)20 8996 7070 Email: copyright@bsigroup.com