66. The molarity ofthe solution containing 2.8% (w/V solution of KOH. i (a) 0.1M o 05M (0) 0.2M @ 1M Mixing, Dilution and Application to Stoichiometry 67. 1f 500 ml of 1 M solution of glucose is mixed with 500 ml of 1 M solution of glucose final molarity of solution will be : (@IM (6) 05M (92M (@ 13M 68, What volume of 0.40 M Ba(OH), must be added to which ns: Atomic and Molecula Masses, AMU 1, The number of atoms in 52 a.m.u. of He is (a) 13 x 108 (@) 1.3 «108 013 @ 10° 2. The mass of carbon present in 0.5 moles of K,[Fe(CN),] is @ 18¢ (6) 18g (© 368 @ 36g 3. How many electrons are present in 180 gm of water (a) 1 mole (6) 10 moles (c) 18 moles (d) 100 moles 4. The total number of protons in 8.4 g of MgCO,is (a) 2.52 x 102 (b) 2.52 « 10% (c) 3.01 « 104 (d) 3.01 = 10? 5. The atomic weight ofa triatomic gas i formula for the number of moles of gas 3w w @* we (©) 3wa Ox 6. How many moles of magnesium phosphate, Mg,(PO,), will contain 0.25mole of oxygen atoms? (a) 0.02 (b) 3.125 « 102 (0) 1.25*102 —— (d) 2.5* 107 7. Maximum no. of hydrogen atoms are in: (a) 16g of CH, (b) 31.28 of CoH (0) 34.2g of C,,Hy:0), (Ad) 36g 0f CH, Mole Concept 1.25 (6) 66 mL (d) 100 mL. (@) 33 mL (c) 133 mL. 69. Volume of 0.6 M NaOH required to neutralize 30 em} of 0.4 M HClis (a) 30cm? (c) 50cm (8) 20cm? (@) 45cm? 70. 10 mL of | M BaCl, solution and SmL 0.5 M K,SO,, are mixed together to precipitate out BaSO, The amount of BaSO, precipated will (@) 0.005 mol (c) 0.025 mol (6) 0.00025 mol (d) 0.0025 mot Sis | 8. A sample contains 200 atoms of hydrogen, 0.05 gm ‘atom of nitrogen, 10° gm atom of oxygen, What is the approximate no. of total atoms (@ 200 (6) 6223 (© 3 «10? (A) none of these 9. The element A (at wt, = 75) and B (at wt. = 32) combine to form a compound X. If 3 mol of B combines with 2 mol of A to give 1 mol of X, the weight of S mol of X is (a) 246 gm (6) 1230 amu (0) 1.23 kg (d) None of these 10. The wt. of NO having the same no. of oxygen atom present in 9.2 gm of NO, is (@) 9.2m (6) 6 gm © 12am (@) 249m Percentage Composition and Empirical Formula 11, A compound contains 28% nitrogen and 72% metal by mass 3 atoms of the metal combine with 2 atoms of nitrogen. The atomic mass of metal is (a) 36 (6) 20 (© 24 (@ 36 12, An organic compound on analysis was found to contain 0.014% of nitrogen. If its molecule contains two N atoms, then the molecular mass of the ‘compound (@ 200 (6) 2000 (©) 20,000 (@ 200000 13, An element, X, have three isotopes 2X, "X and 2X. The percentage abundance of *°X is 90% and its average atomic mass of the element is 20.11.The percentage abundance of 'X should be @% &) 8% (2) 10% 0% eee Scanned with CamScanner1.26 Chemistry 14 The 77 ratio in some meteorites is greater than that Used to calculate the average atomic mass of oxygen on earth. The average mass of an atom of oxygen in these meteorites. .. that of a terrestrial oxygen atom. (a) equal to (0) less than (b) greater than (@) None of these Simplest formulae ofa compound containing 20% of element X (atomic weight 10) and 80% of element Y {atomic weight 20) is (a) XY © (0) XY 7 (@ XY, Stoichiometry and Gay Lussac’s Law 16, The percentage yield of reaction can be described as. 17. 18, 19, 20, the.... times 100% (@) amount of product you could make if the Teaction went to completion (®) total amount of materials involved in a reaction (©) amount of desired product divided by the amount of unwanted product (@) amount of product obtained divided by the ‘maximum possible amount of product The speficic heat of metal approximate atomic weight is (a) 8 (6) 16 () 32 (@) 40 If the hydrocarbon C,H, is burned in 0. and HO are formed as described by the equation CH, +0, I is 0.16 calig. Its > Bas, CO, unbalanced 2 > CO, +H,0. When equation is balanced predict that one mole of CH, will (@) React with | mole of O, () Form 2 moles of CO, (6) Form 3 motes of 1,0 (@ React with 4 moles of 0, A certain element Z reacts with ©; 10 form the O5ge Und 2205, If 0346 g of the clement form, 0.552 g of the compound, what is the 4 ‘mass of the element? (@) 12.3 g mor" (©) 67.4g mot" (b) 74.6 g mot (d) 153 g mot The following sequence of reactions may be used to extract zine from its sulphide ore 2ZnS +30, + 2Zn0+ 280, Zn0+C 2n+CO How many tons of Zn can be obi ied form 10 tons of ZnS, assuming thatthe yield ig 755. 21. 22, 23, 24, (a) 5 () 10 () 12 (15 The explosive TNT (trinitotoluene cay (unbalanced chemical reaction) Mai Gilly + HNO, > CH, (NO,), +19 What mass of HNO, is neede toluene (C,H)? (a) 82.8 g (© Bg 10 react wig, 2% ty (6) 567g (@) 189g A.0.500 g sample of Magnetit. is treated so that the iron is hydroxide. The precipitate 0 0.4980 g Fe,0,. What is © OF (impure Precipitated a is heated and con the percentage Fe the oe? Fe,0, +0, + Fe,0, i (@) 69.0% (6) 96.3% (©) 99.6% (@ 35.0% How many grams of causti tequired to completely neutral (a) 22.4 (c) 6.02 He Potash (KOH) js ise 12.6 pm HNO, (6) 1.01 (@ 2 {isobutane and n-butane are present in gs ba how much oxygen should be required for comer combustion of 5 kg of this gas (@) 17.9 kg () Oke. © 27kg @ 18kg Limiting Reagent, Percentage Yield 25, 26. 27, 28, [SSS TZ The volume of earbondioxide formed when | lit of ©, reacts with 2 litre of CO under the sit conditions is (a) IL (6) 2L, (O3L @ 1st The number of moles of Fe,O, formed when Sit Of O, reacts with 5.6g of Fe is (@) 0.125 () 001 (©) 0.05 (@) 0.10 20 ml of nitric 0; 0 xide combines with 10 ml of 0%)" at STP to give NO). The final volume will be (@) 30m (6) 20m (© 10m (d 40 mi ne $2 Mole ofan alkane on, complete combustion 8 OF CO., The motecular weight of alka? (a) 16 (b) 30 Scanned with CamScanner1.27 SS Mole Concept 29, Sodium carbonate of 92% purity is used in the reaction NayCO, + CaCl; —- CaCOs + 2NaCl. The number of grams of Na,CO, required to yield 1gm of CaCO, (a) 85g (6) 10.5g (52g (d) 1.152g 30. The volume of CO, that can be obtaine at STP from 60 g. of 70% pure MgCO, is (a) 16L, (6) 2b (©) LIL (@) 56L 31. 4g of a mixture of Na,CO, and NaHCO, on heating liberates 448 ml of CO, at STP. The percentage of Na,CO, in the mixture is (a) 84 (0) 16 (©) s4 @ 80 Units of Concentration and Inter Conversion 32, An aqueous solution of glucose is 10% (w/V). The volume in which Imole of glucose is dissolved, will be (@18L (®9L (9 09L (@ 18L 33. How much Ca(NO,), in mg must be present in 50 g. ofa solution with 2.35 ppm of Ca? (@) 0.1175 (6) 770.8 (0) 4.7 (@) 0.48 34, The average concentration of Na* ion in human body serum is 3 to 4 gm per litre. The molarity of ‘Na’ ion is about (a) 0.15M (0) 34M (c) 23M (d) 068M 35. Mole fraction of ethanol in an aqugous solution of ethanol and water is 0.1. The %(w/W) of ethanol is (a) 10 () 90 (©) 22 (a) 78 36. 25.5 g of H,0, solution on decomposition gave 1,68L of O, at STP. The percentage strength by weight of the solution is (a) 30 (6) 10 (©) 20 (d) 25 Mixing, Dilution and Application to Stoichiometry 37. I kg of 2 m urea solution is mixed with 2kg of 4m. urea solution. The molality of the resulting solution is (a) 3.33m © 10m (c) 1.67m (@ 5m 38. 39. 40. I. 42. What will be present in the solution when 50 ml of 0.1 M HCI is mixed with SO ml of 0.1-M NaOH solution? (a) 4.5 millimole of H* (6) 0.05 millimole of OH- (0) 0.1 MNaCl (@) 107 Mof Ht ion One litre of a solution contains 18.9 gm of HNO, and one litre of another solution contains 3.2 gm of NaOH. In what volume ratio must these solutions be mixed to obain a neutral solution? (a) 3:8 (H) 8:3 (o) 15:4 (@ 4:15 0.66 g of H,PO, will require x ml of 0.1 M NaOH for complete neutralization. x is (@) 100 ml (6) 200 mt (©) 300ml (@) none of these To 1 Lof 1.0 M impure of H,SO, sample, 1.0 M NaOH solution was added and a plot was obtained as follows: Molarity Ht ion Os 1015 Volume of NaOH L, The % puirity of HSO, and the slope of curve, respectively, are: (@) 78%,-12(b) 75%, (0) 50%, — 13 (a) 50%, — 1/2 Condiser the ionisation of H,SO, as follows: H,SO, + 2H,0 -+ 2H,0° + SO2- ‘The total number of ions furnised by 100 mL of 0.1 MH,SO, will be (@) 1.2« 108 (©) 0.18 « 103 (B) 0.12 « 103 (d) 1.8 « 108 . Calculate the number of oxygen atoms required to combine with 7.0 g of N, to form NO, if 80% of N, is converted into product N:+}0:—N203 (a) 3.24 « 10 (6) 3.6 103 (©) 18x 108 (d) 6.02 103 I eee Scanned with CamScanner1.28 46. 41. 48. 49. 1100 mL of H,S0, and 100 mL of H,0 are Chemistry : Mole fraction of a solute in at ‘The molality of the solution will be (b) 1.388 (@) 0.0138 1m aqueous solution is (a) 13.88 (0) 0.138, the mass percent of H,SO, in the resulting sofution IS jggog 7 0-9 8 MEM Gyo = 108 mL") (@) 90 (b) 47.36 (©) 50 @ 0 ‘A metal oxide has the formula Z,0,. It can be reduced by hydrogen to give free metal and water. 0.2 g of the metal oxide requires 12 mg of hydrogen for complete reduction. The atomic weight of the metal is (@) 52 () 104 (©) 26 @ 8 ‘The reaction between yttrium metal and dilute HCI produces Hy, and Y** ions. The molar ratio of yttrium to that hydrogen produced is (@) 2:3 () 3:2 (1:2 @2:1 When 10 mL of ethyl aleohol (density = 0.7893 g. mL") is mixed with 20 mL of water (density = 0.9971 g mL") at 25°C, the final solution has a density of 0.9571 g mL”. The percentage change in total volume on mixing is @ 3.1% (b) 24% © 1% (d) none of these 100 mL of mixture of NaOH and Na,SO, neutralised by 10 mL of 0.5 M H,S0,. NaOH in 100.mL solution is (@) 028 () 04g © 06g (a) none of these is Hence, . 0.116 g of CJH,0, (A) is neutralised by 0.074 g of Ca(OH),. Hence, protonic hydrogen (H®) in (Ay will be @! (3 (6) 2 @4 52. 53. 55. 7 Mole ation oF eae = ‘Mole fraction of ethanol in ethanol water migsS 0.25. Hence, the percentage concentration of i i an by weight of mixture is ‘ (b) 75% (d) 54% (@) 25% (c) 46% Hydrogen peroxide in aqueous solution decomp, on warming to give oxygen according to 4, equation, 2H,0,(aq) > 2H,0(1) + 0,(9), nde conditions where one mole of gas occupies 2g) 100 cm? of *X"M solution HO, produces 3 dn! 0). Thus X is: (a) 2.5 (©) 10.0 () 5.0 (@) 30.0 6.0 g of a sample containing CuCl, and CuB,, is solved in 100 mL water. A 10 mL portion ofthis solution on treatment with AgNO, solution resus in complete precipitation of Cl-and Br giving 0.9065 gram of precipitate. The precipitate thus obtinel was shaken with dilute solution of NaBr where al AgCI gets converted into AgBr. Mass of the ner precipitate was found to be 1.005 g. Determine mass of CuCl, and CuBr, in the original sample (@ 25%, 49% (8) 50%, 50% (©) 75%, 25% (@) 20%, 80% An element (X) reacts with hydrogen leading ® formation of a class of compounds that is analogos to hydrocarbons. 5.00 g of X forms 5.628 g of? mixture of two compounds of X(XH, and X,H)# the molar ratio of 2:1. Determine the molar mass of (a) 28 (©) 72 The molecular ma ic acid A ss of an organic acid cers by the study of its barium salt. 42998 the rete, anttatively converted to free acid ®Y Datum th 21.64 mL of 0.477 MSc ™ hydration ne found to have two mole of wi"! ‘a ion and acid is mono basic: ¥ Scanned with CamScanner