QUESTION BANK @ NARAYANA JUNIOR COLLEGE TELANGANA - ANDHRA PRADESH SENIOR IPE IMPORTANT QUESTION BANK CHEMISTRY QUESTION BANK ANALYSIS i LAQ SAQ 1 S.NO TOPIC NAME VSAQ | TOTAL 1 | SOLID STATE SS rls |S Fel we 26 =I 2 | SOLUTIONS =} Bebe eah6 jseet 43 i 3. | ELECTROCHEMISTRY 2 -|+37@/ 3 20 36 - 4 | CHEMICAL KINETICS 2 Pa) +] 3a\26 21 40 5 | SURFACE CHEMISTRY - - - 20 31 GENERAL PRINCIPLES OF $ METALLURGY * = Vues 1 4 14 23 7 | p-BLOCK ELEMENTS 8 - -}15 1 - 74 108 8 | d& & BLOCK ELEMENTS - - |-| 6niseys 32 48 » | rouymers ~|-|-[ |= F- 26t teas - Be | wounceal - | = |-/ao) 4} 2theas | 35 y cuemisravinevenvoay| |. ).f.) 2). | as] ae LIFE T | HALOALKANES AND 4; 4 bo Soe m [riavoneenes LS PS A | ORGANIC COMPOUNDS % 4 8 . 8 | CONTAINING C, H&O s seg 2 32 | ORGANIC COMPOUNDS: -|-+}4 2/4 9 | | CONTAINING NITROGEN +a ! 225 SUB TOTAL 25 «5 1 68 59 36 Teer} 58) Bay j | rova pss |e Fe ia (ANA GROUP Page.No 61(CHAPTERWISE MARKS WEIGHTAGE BASEDON IPE MARCH & MAY 2014-17 PAPERS MARKS SNO vq NE WAGHTAGE mais 1 | SOUDSTATE 4M |2(QRQ) 1 2 | SOLUTIONS 6M 1 1 A) ELECTROCHEMSSTRY | 3 |B GEMCALKINTTIGS aM : 4 | SURFACE CHEMISTRY 4M | 2QQ/ 1 GENERAL PRINOPLES OF 5 | METALLURGY 6M ! 2 6 | pBLOCKELEVENIS RM 2 7 | d& BLOCK ELEVENIS 6M 1 2 8 | POLYMERS 4M |2(@R/ 1 9 | BIOVOLECLLES 4M |2@)| 1 10 | CHEMISTRY INEVERYDAYUFE 4M |2@R/ 1 ‘A) HALOALKANES AND HALOARENES By) ORGANC COMPOUNDS 11 | ONTANNGCH&O SM ethersRue QUESTION BANK _ 1L.SOLID STATE SHORT ANSWER QUE: " STIONS (4M) s##}, Derive Bragg’s equation. (Mar-14,17,19 A.P.TS, May (Mar&! -S&A.P) ™ 1 ».TS, May-14 Mar-ISTS &. ; a Desc he ines mn nd corst er concn ec . Classify wing as either a -type semiconduct (i) Ge doped with In ()Stdped wih eee #04, Explain why ionic solids are hard and brite $65, Interms of band theory, what isthe difference between a condu insulator? ‘46, Interms of band theory, what is the ditions hegeen sevodocee msl eee oT, Acie solid ismadeoftwo ements Pand. Atoms of0 area the cores ‘ofthe cube and at ly-centre. What is the formula ofthe ‘coordination ecshe boy cn of the compound? What are the ‘num 49g, Ifthe radius of the octahedral void is ‘r’and radius of packing is ‘R’derive Ibe rags ofthe ota ius of the atoms in close is'R +9, Calculate the efficiency of packing in case of a metal ofbody-centered cubic erystal? 410, Aluminum crystalizes ina cubic close packed structure. Its metal rads is 125pm. (ji) what is the length of the side of the unit cell. (Ans: 354 pm] Gi) How many unit cells are there in |, o0cm? oF aluminum? RY SHORT 1. How do you distinguish between crystal lattice and unit cell? 2, What is Schottky defect? (Mar-18 T.S) 3, What isFrenkel defect? (Mar-18 TS) 4, Stability ofa crystal i reflected in the magnitude ofits melting point. Comment, §, What makes a glass different from quartz? 6 How many lattice points are there in one unit cell of face-centered cubic lattice? $ How many lattice points are there in one unit cell of face-centered tetragonal lattice? £. How many lattice points are there inone unt cell of body centered cubic lattice? ctism with suitable example. sm with suitable example 9. Explain Ferrom 10, Explain Params 11, Explain Antiferromagnetism with suitable 12, Whatare f-centres 13. What isco-ordination naber? ice 14. Whaat is the colour of LiCl crystal in excess 0! yum 1S. Givea soe eaple which shows both schottky defect and fenkel defer? 16. What is metaldeficiency defect? Give e 2.SOLUTIONS HORT ANSWER OU INS (4 #1, Define mole fraction. Se tion of sucrose in water isabelle as 20% w/w. What won be te mole fraction ofeach component in the: solution? ‘ (Mar-14) What is meant by positive deviations from Raoult’s law and how is the sign of A,,,/1 related to positive deviation from Raoult’s law? #93. What is meant by negative deviation fro slaw? negative deviation from! Raoult’s! cor as cg ong,” What is restive lowering of pour PRSSITS" usefllto determine pear cota, water at 293K is 17.535mm.Hg Calculate the vapour Raoult’s law. Vapour of i ; Se ution at 293K whe? 258 ofghucose is dissolved in 450g of water. pressure of the $0 si sn Raoult’ law and how is the sign of A,,, Af related toSRIPE 7, seg, 489 +810, 1 +12 “3, 14 “15, “16. “17. 718. #19. *20. *21. *22. yaypr Ese xe Fs |ON BANK QU! s nv.caloulate the vapour pre wl on conan igor in h imi water at 293K. The vapour pressure of water at 293K an TAP) State Raoult’s Law 7 The vapour pressure of pure benzene at a certain tempe electrolyte solid weighing 0.5g when added to 39.08: es othe solid substance? ature is 0.850 bar. Anon-volatile, non- jar mass 78gmol '). Vapour pressure of the solution, then is 0.845 bar; What is the molar Mar-16,18 A.P) What is an ideal solution? Give sutable exmaples. r di i Calculate the mass ofnon-volatie solute (molar mass 40g mol”! eae me 114g Octane to reduce its vapour pressure to 80% Ee: ‘ty jar-16 T.S) Define molality (m). Calculate molality (m) of 10 gm_ ofGlucose( C,H\.9,) ge pe i How is molar mass-related to the elevation in boiling point ofa solution. How is molar mass related to the depression in freezing point of a solution? A solution of glucose in water is labeled as 10% W’/IV - What would be the molarity of the solution? (Mar-15A.P) Define moleffaction? Calculate mole fraction of ethylene glycol (C, H/,0; ) in solution containing 20% of C,H,0, by mass. (May-15T.S) Define the following: (@)RLVP (b)Ekvation of Boiling point _(c)Osmotic pressure (@Henry’s aw (c)Depression in freezing point (May-16 TS) ), ina solution containing 98% H.,SO, by mass. (Mar-17A.P,18 T.S)(May-16 A.P) Define mass percentage, volume percentage and mass to volume percentage solutions. Concentrated nitric acid used in the laboratory work is 68% nitric acid by mass in aqueous solution. What shouldbe the molarity ofsuch a sample ofthe aed ifthe density ofthe solution's 1.504gmL A solution is obtained by mixing 300g of 25% solution and 400g of 40% solution by mass. Calculate the mass percentage of the resulting solution. 45g ofethylne glyco (C.H,0,)s mixed with 00 gof water, Calculate (a) the freezing oi ) the freezing point of the solution. { red in 50 g of benzene lowered the freezing point ofbenzene by0.40K. The freezing point depression constant ofbenzene is 512 K ke mol" Find the molar mass of the solute. 3 200 cm’ of'an aqueous solution ofa protein contains 1.26 g of the protein. The — ofsuch a solution at 300 Kis found to be 2.57 x 10° bar. Calculate the molar mass of the protei. VERY SHORT ANSWER QUESTIONS (2M) Define the term solution. Define molarity makina Calculate the rnolarity of solution containing SgmofNaOH in 450ml sohition ren oh solution(Mar-17,19 TS) Calculate the molality of 2.5gmofethanoic acid (CH,COOH Jin 7Sgmot Define molefraction? Calculate the mole fraction of H., Si Give an example of solid solution in which the solute is solid, (Mar-15 TS) Define mole fraction. Calculate the mole raation of 11,50, ina solution containing 980% 11,50, by mass? Brine. tes Y ? Define mass percentage of solution? (May-14) What is ppmofasolution? ; What role do the molecular interactions playin solution of alcohol and water? NARAYANA GROUP “Page.No 64IPE State Henry's law. 13. Define osmotic pressure. (May-16A.P) BE yt are eters solstions? Give (Mar-16,18 A.P) i Van’ seg (Mar-15,17A.P\(Mar-16,19 TS) 16. _ Whatis Van't Hoff’s factor ';" and how st related to ‘q' inthe case of binary electrolyte 17. What srelative lowering of vapour pressure? ee binary electro! 18, What are colligative properties, Give examples. 19, What isamalgam? Give example? 20, _ Define plasmolysis and Haemolysis? 21, Calculate weight of Glucose required to prepare S0Omlof0.1M solution. (May-16T-S) 3.ELECTROCHEMISTRY & CHEMICAL KINETICS LONG ANSWER QUESTIONS (8M) ‘s0*], (a) What is electrolysis?and State Faraday’s laws of electrolysis. _ (Mar-14) (Mar-15 T.S) (b) Asolution of CuSO, is electrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of copper deposited at the cathode? (Mar-14)(Mar-15 T.S & A.P) ‘#2, (a) State and Explain Kohlrausch’s law of independent migration of ions. (Mar-15 A.P )(Mar-16 T.S)(May-16 A.P) (b)Give the applications of Kohlrausch’s law of independent migration of ions. ###3, Give a detailed account of the collsion theory of reaction rates of bimolecular gaseous reactions. (Mar-17 4.P,18,19 T.S)(Mar&May-16 T.S&A.P) 4884, What is rate of reaction ? Explain the effect of temperature and effect of catalyst on rate of reaction? (Mar-15 TS) **5, Explain the following terms with suitable examples. (a)av tion (b) slowand fastreactions _(c) order of areaction (d) mole tion _(e) activation energy ofa reaction. ELECTROCHEMISTRY ANSWER QUESTIONS (4M) ***]. Give the construction and working of a standard hydrogen electrode witha neat diagram. +9), Whatare galvanic els? Explain the working ofa galvanic cell with neat sketch taking daniel celas example age rate of a re larity of a res (Mar-i8A.P&TS) ***3. State and explain Nernst equation with the help of metallic electrode and non metallic electrode. **4. What are primary and secondary batteries? Give examples, (Mar-19A.P) **5. What is Metallic corrosion ? Explain it with respect to iron corrosion. 6. Whatare fuelcells? How they are different from galvanic cells? Give the construction of H, — O; fuel cell. (Mar-17 T.S(LAQ)) *7, What are the products obtained at the eathode and the anode during the electrolysis of the following when platinum electrodes are used in the electrolysis. (a) Molten KCI (b) Ag.CuSO, (c) Aq-K,SO, Solution NUM ICAL PI LEMS ‘ Cur? 2 **1 Calculate the EMF ofthe following galvanic elt:2,) * CM ox) > Zn (ag) + Cut) E% neta = 0.160 3E*c* 10 = +0.34V (Mar-16 T.s) °°2.A® for NaCl, HCland CH,COONa are 126.4,425.9 and 91.0 Scm?mol"' respectively © for CH,COOH EE Page.No 65\UESTION BANK SRIPE_ #93, 4, +45, *6. Aa we see =o: ee], ee, Caleilat the emfotcellat 25°C Cr/Cr*(0.1M)// Fe™(0.01M)/ Fe co Benes -0.74V and E.,,, = 0.440 Calculate the equilibrium constant of the reaction Cay) +2Ag" (on) > Cus + 24g, 5) given Emp) = 0-46Y tid Sei ‘a (s) BiVeN Ecce) for the cell The standard emf‘of Daniell cells 1.1'V, Calculate the standard Gibbs energy reaction Zn,,) +Cu;* > Zn) +Ciis, Calculate A’ for CaCl, and MgSO, (given 22. =! 19,42, = 76.3 Ais =106,22,., =160) VERY SHORT ANSWER QUESTIONS (2M) jar-19 TS) What is galvanic cell ora voltaic cell? Give one example. What is standard hydrogen electrode ? What is Nernst equation? Write the equation for an electrode with electrode reaction M4 tne = M,, How is Gibb’s energy (G) related to the cell emf(E) mathematically? What is cell constant of a conductivity cell? Define molar conductivity A. and how is it related to conductivity (K)? State Kohlrausch’s law of independent migration of ions. State Faraday’s first law of electrolysis. (Mar-16,18A.P) State Faraday’s second law of electrolysis (Mar-18TS) What are the products obtained at the platinum anode and the platinum cathode respectively in the electroysis of fused or molten. NaCl? Give the products obtained at the platinum electrodes (cathode and anode) when aqueous solution of K,SO, is electrolysed. What is a primary battery ? Give one example. (Mar-I7A.P) What isa fuel cell? How is it different from conventional galvanic cell? Give the electrode reactions occuring at the anode and at the cathode in 7, —O, fuel cell? ‘What is metallic corrosion? give one example (Mar-15A.P) Write the cell reaction taking place in the cell Ci)/Cul"\y // Ag /Ag.,, (May-16 TS) Write the Nernst equation for the EMF ofthe cell Ni(S)/ Ni?* (ag) // Ag’ (ag)/ Ag How is £2, related mathematically to the equllibrium constant K... of the cell reaction? Give one example for a secondary battery. Give the cell reaction, Define conductivity of material. Give its SI units. 4. CHEMICAL KINETICS = Define and explain the order ofa reaction. How is it obtained ‘What is “molecularity” of reaction? How ist different from the ase s one bimolecular and one trimolecular gaseous reactions (Mar-i417 Ts te eee maa Ne AF . | 0 ——— eee NARAYANA GROUP PageNo 66 7IPE sR. = a JUESTION BANI 695, What shal Mie (7,,) ofareactio DTS TC SOS TOFS IFT Vlas oF Zero and first order reactions. #4, What is Arrhenius equation? Derive an equati Si effect of ris pegerstar= CO) on bora oonont (ete netcoh ries a #05, Discuss the effect of catalyst on the kinetics ofa che ahr wich tiated Derive :mical titable *6. e the integrated rate equation for a first order: feeds Gk with sui diagram. #7, Explainthe terms , (a)Activationenergy (Ea) (b) Collision fr ability factor with respect to Arrhenius equation. ae ey NUMERICAL PROBLEM! #1, Areaction is 50 % completed in 2hours and 75% completed in 4 hours. What is the order of the reaction? ##2, Areaction has a half life of 10 minutes.Calculate the rate constant for the first order reaction. (Mar-16 T.S) #3, Ina first order reaction, the concentration of the reactant is reduced from 0.6 mol/L to ' 0.2moV/L in Smin. Calculate the rate constant. ‘**4, Show that in the case of first order reaction, the time required for 99.9 % completion of the reaction is 10 times that required for 50% completion. (log? = 0.3010). *5. Forthe reaction R —> P , the concentration of a: reactant changes from 0.03M to: 0.02M in 25 minutes. Calculate the average rate of reaction using units in seconds. 46, A first order reaction has a rate constant of |, 15x10"? s~' How long will 5.0 g of this reactant take to reduce to 3.02? #7, From the rate expression for the following reactions determine their order of reaction and the dimensions of the rate constants: (i) 3NO(¢)—+N,0(g) + NO, (g),Rate = k[NO] (ii) H,O, (aq) +31 (aq)+2H* (aq)—> 2H,0(!) +1 , Rate =kH0,)] (iii) CH,CHO(g) —>€ 1H, (g)+CO(g), Rate =k[CH,CHO] + #8. fora first oder reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction. . *9, Identify the reaction order from each of the following rate constants. () k=2.3x109L mols" (i) k=3x10%8* VERY SHORT ANSWER QUESTIONS (2M) Define the speed or rate of a reaction? What are the units of rate of reaction ? What israte law? Illustrate with an example, as Define order of a reaction? Illustrate your answer with an example. (Mar-I5T.S ) ; ? 1 2 3. 4. 5. What are elementary reactions 6 1. 8 What are complex re: Give the units of rate . Define molecularity of @ reaction? bee? ya en dite 9. ve two exampkesfor zero order TEACTiONS?| Blah 10. we pe integrated equation fra fst order Taste interms of [R}, [R],and *t”? ; s first order reactions? ict Give two examples for se @ What is half sey irate your answer wth an example? 3 What pinta GEIB oes ae “ke for first 72a a La -NARAYANA GROUP Page.No 67SRIPE fe the equation usefulto calculate 7, cone 15, Whatare pseudo first order reactions? Give one €X@™MFE soy 16. Write the Arrhenius equation for the rate constant (k)o! # i ‘at temperatures 17. Write the equation which relates the rate co" er reaction? 18. Whatis the effect of temperature on the rate constant? mnstants 19. Whats rate determining step in a complex reaction? 20. Define law of mass action? 21. Whatis positive catalyst?Give an example? SURFACE CHEMISTRY SWI ESTIONS (4) ***1, Whatare different Reser Give ar differences between characteristics of the different types. (Mar-15,19 TS & A.P)(May-16 TS). nin What isan emuision ? Explain the classification of emulbions Bt aa ‘ar- 05, 06,08,16,18 TS, 0 223, What iscatalysis? How is catalysis classified? Give two examples for each 4 (Mar-05, 06,10,14,16.A.P) (May -06,14,16 A.P) Tie formation and cleaning action of soap. between dispersed phase and dispersion ***4. What are micelles? Discuss the mechanism of mice! **#5_ Howare colloids classified on the basis of interaction medium? +46, Name the dispersed phase and dispersion medium in the following colloidal systems (foe (smoke (ii)milk (iv)cloud —_(v)blood (vi) gold sol ##*7, Write any four enzyme catalysed reactions. (Mar-19 A.P) ‘What is coagulation? Explain with suitable examples. What are colloidal solutions? How are they classified? jive examples. **10. Explain the following terms (a) Electrophoresis (b) coagulation (c) Tyndall effect 11. What is an adsoprtion isotherm? Discuss the phenomenon of adsorption of gases on solids with the help of Freundlich adsorption isotherm. VERY SHORT ANSWER QUESTIONS (2M) (May -06, Mar- 13) What is emusifping agent? Giveone examp What is Gold num! What is the general difference between soap and detergent chemically ? 1 2, 3. e What is autocatalysis? Give one example. 6. 7. Whaat is Tyndal effect? What is Brownian movement? f What is protective colloid? 8. Wh at is Hardy-Schulze’s law ? 9 What is adsorption ? Give two applications. 10. Whyis.adsorption always exothermic? IT; Define “promoters” and "powsons "in the phenamenon of catalysis, 12. Easily liquifiable gases are readily adsorbed on solids. Why? 13, __ Why zeolites we treated as shape selective catalysts? i is critical mecelle concentration (CMC) and Kral 15, Whatis peptization and dialysis? p A feenperature (T,)? 16. Whats electrokinetic potential or zeta potential? 17. Skyappears blue in colour. Explain. is electro osmosis and electrophoresis? 19. Define flocculation value. 20. Define occlusion? 5.GENERAL PRINCIPLES OF METALLURGY SHORT ANSWER QUESTIONS (4 M) Giving examples to differentiate roasting and calcination. (Mar- 16,18,19 T.S,16 A.P)(May-16 A-P) NARAYANAGROUP~~O~™O™OOSOOOe NARAYANAGROUP Page.No 68!/ —pales BANK #995, Expl he paricalonofaapiic on by FO DSSS ft = 16TS &A-P) #9*3, Write down the chemical reactions taking place in differen nonce the blast enuce #**4, Outline the principles of refining of metals by the following methods. a) Zone refiningb) Electrolytic refining _c) Poling (Mar 18 A.P)d) Vapour phase refining 25, How is copper extracted from copper pyrites? *6. Write down the chemical reactions taking place in the extraction of zinc from zine blende. #7, Explain electrometallury with an example *§, Explain briefly the extraction of aluminium from bauxite. (Mar-17 T.S) #9, _ Explain the process of leaching of alumina from bauxite. VERY SHORT ANSWER QUESTIONS (2 M) Whaat is the role of depressant in froth floatation? Name the common elements present in the anode mud in the eletrolytic refining of 1 2. copper 3. Whatis the difference between a mineral and an ore ? 4, Give the composition of the following alloys (Mar-17,19AP&TS,18 A.P)(May-16T-S) a) Brass b) Bronze ©) German silver 5, Explain the terms gangue and slag. 6 Write any two ores with formulae of the following metals: (May-14) a) Aluminium b) Zine ¢) Iron 4) Copper 7, Whatis matte ? Give its composition. 8. What is blister copper? Why is it so called ? (Mar-18T.S) 9, What is flux? Give an example. ¢ a method for the refining of nickel. 11. State the role of silica in the metallurgy of copper (May-14) 12, What isthe role of graphite rod in the electrometallurgy of akuminium? 13. What is the role of cryolite in the metallurgy of aluminium? (Mar-15&16 T.S&A.P) 14. What ispoling (Mar-16 A.P) 6.p-BLOCK ELEMENTS ONG ANSWE! STIONS (8M GROUP 15 ELEMENTS ***1, How is ammonia manufactu laber's process ? Explain the reactions of ammonia with (a) ZnSO, (b) CuSO,., (©) AgCl,, (MAR-I7TS,18A.Py(May-15A.P) #992. Write the ortant reactions involved in the manufacture of sulphuric acid by’contact process’. oe a a (Mlari8 TS) as. cacid factured by Ostwald’s process ? How does it react with t ie (Mar-174.P&19 TS) (a) Copper (b)Zn (OS, @P, GROUP 16 ELEMENTS 4. How is ozone prepared from oxygen 7 Explain its reaction with (Mar 17,1819 A.P\MardiMay-164.P) a) CH, b) KI ©) Hg d)PbS €) Ag ***5_ Explain in detail the manufacture of sulphuric acid by contact process. (Mar-16 &May-15 TS) GROUP 17 ELEMENTS **°6. How is chlorine prepared in ratory of Deacon's 1? How does it react with the (Mar-15,18,19 T.S) a)lron_b) NaOH ¢)Acidified FeSO, d)lodine’ ”¢) HS f) NaS.O, (Mar-16T:S) _g)Excess NH, hyCa(OH), . i Jectrolytic method ? Explain it’s reaction with *7._ How is chlorine prepared by ¢! (May-14) (Mar-15,16 A.P) (a) NaOH (©) NH, wer OUP 18 ELEMENTS conditions (Mar-16T-S) —(c) Naf (d) Slaked lime GROUPeaten, QUESTION BANK ere jon with water? ***8. How are XeF,, XeF, and XeF, prepared? Explain their reaction with (Mar-15 A.P) Discuss their structures HORT ANSWER QU JESTIONS 4M 2 1888, Nhat is allotropy? Ex lain the different al che forms of phosphorus ? 2***, How does PCI react with the following? nen b)C.HOH_— c) CH,COOH dag 3**, How does P, react withthe following (a) SOCL, * (b) Si 4**. Complete the follow * fodstons a) Ca,P,+H,O> b) R.+KOH > ©) CuSO, + NH, > d) Mg+N, > ©) (NH,), ChO, £) Decomposition of nitrous acid 5**. Complete the following a) NH,NO,—*> b) HNO, + P.O, > ) Pb(NO,), > ) Zn+dil HNO, > e) it Conc. HNO, f) HgCl, + PH, > GROUP 16 ELEMENTS 6%. Writea short note on the allotropy of sulphur 7***. Which oxide of sulphur can act as both oxidizing and reducing agent ? Give one € 8%. Write the structures of Oxoacids of sulphur 9**. Explain the structures of SF, and SF, 10**. How does SO, react with the following ? a) NaSO,_.b) Cl, c)Fe" ions d) KMnO, 11**, Complet the following a) KCl + H,SO,(cone) > b) Sucrose Coma, ¢) Cu+H,SO, (cone) > 4d) C+H,SO, (cone) > 12**. Describe the structures of $O;? and SO, GROUP 17 EL 13*** How can you prepare Cl, fom HCland HCI from, 14*** Explain the structures of (a) BrF ,(b) IF,? 15***, Write balanced equations for the following ? (May -14) (a) NaCI is heated with conc H,SO, in the presence of MnO, (b) Chlorine is passed into a solution of Nal in water 16***, What are interhalogen compounds ? Give some examples to illustrate the definition how are they classified ? 17***, Give the preparation of Chlorine by Deacon’s process. How does it react with (Mar&May-16T.S) the names and formulae of the oxoacids of chlorine explain their strectures end relative acidic nature 19**, How is CIF, prepared ? How does it react with water ? Explain it’s structure ? 20** Compare the bleaching action of Cl, and 21**, Write ashort note on hydrides of aloes ENTS 1, ? Write the reactions (May-16A.P) EEMENTS 228** How are XeF and XeF, are prepared ? Give their structures. (Mar-17,181:S,19 A.P) How are XeO, and XeOF, prepared? Give their structures, (Ma: 14) Explain the structure of a) XeF, _b) XeOF, y Explain the reaction of the following with water a) XeF, b) xXer, ©) XeF, - Complete the following 1 . a) XeF,+H,O> b) XeF, + PF, > Sy NARAYANA GROUP Page.No 702 eyes FSF, > a +0,F,—> tY SH ©) XeF, ¢) XeF, : GROUP 15 ELEMENTS Why does the reactivity of nitrogen differ from phosphorus? Nitrogen exists as diatomic molecule and phosphorus as P Nitrogen molecule is highly stable- why ? eM Eris? nae ie Why are the compounds of bismuth more stabl ; { ee ee re stable in +3 oxidation state ? ‘Arrange the hydrides of group -15 elements in the de ic strength and increasing order of reducing character ? ae What happens when white phosphorus is heated with cone. NaOH solution in an inert atmosphere of CO, ? Mart: uy NH, forms hydrogen bonds but PH, does not -why ? a ists) How do calciumphosphide and heavy water react ? Ammonia is a good complexing agent explain with an example? (Mar-14) ‘Amixture of Ca,P, and CaC, is used in making Holme’s ° Which chemical sGmpound & formed i the browning elaine md How is nitric oxide (NO) prepared ? NO is paramagnetic in gaseous state but diamagnetic in liqui i ” Pcl, aoa ras wel as baci aeachecy Toe aE Which of the following is more covalent- SbCl, (or) SbCI,? Write the chemical reactions that occur in the manufacture of nitric acid ? Iron becomes passive in conc. HNO, why ? (Mar-15 T.S) Give the uses of (a) Nitric acid (b) Ammonia? Give the disproportionation reaction of H,PO, ? Draw the structures of (a) Hypo phosphoric acid (b) cyclic meta phosphoric acid ? Are all the five bonds in PC/, molecule equivalent? Justify your answer.(Mar-164.P) What are the Neutral oxides of Nitrogen? (Mar-18 TS) What is laughing gas? Why itis so called? Give the disproportionation reaction of phosphorous acid? Draw the structures of PCI, (May-15 A.P) PH, has lower boiling point than NH, . Why? (Mar-16 T:S) What is allotropy? Write any two allotropes of phosphorous, tay Ts ‘What happends when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO. (Mar-19 A.P) GROUP 16 ELEMENTS Why is dioxygen a gas but Sulphur a solid? What happens when , a) KCIO ts heated with MnO, b) O, is passed through KI solution Give two examples each for amphoteric oxides and neutral oxides? (May-15 T.S) Why is H,O a liquid while H,S sagas (May-14) HO isneutral while H,S isacidic explain (May-15 T.S)(Mar-16 T.S) Name the most abundant clement present in earth's crust. (May-16 A.P) Give the hybridization of sulphur inthe following. Bes a) SO, b) SO, SF, ) SF, eae Wate ihe names and formulae of any two oxyacids of sulphur. Indicate the oxidation state of sulphur in them. z= Give one example each for ; a) neutral oxide by peroxide Jey oxide ‘What is tailing of mercury ? How is it removed ? (Mar-15 T.S & A.P) SO, can be used as an anti chiog Explain How does ozone react ethylene ? Page.No 71SRIPE QUESTION BANK 63. 65. 66. 67. 68. 69, 70, 1 72. BB. 74, 1 2 eee 4s see 32, Outof 0, and O,, Whishs parame Paramay ? Write any two uses each for0, and 180, (Mar-16 T.S) are group - 16 elements called chaleogens ? Draw the structures of S, and S, ‘Write the structures of oxoacids and sulphur a Which hal Fl NTS ich halogen produces O, and O, on passing through water? What is the use of CIE,? T wale eae Why are halogens co! Write the re ‘and “CL. with water ? (Mar-14,17 TS) With which ule, C/O” is isoelectronic ? is that molecule a lewis base ? Electron gain enthalpy of fluorine( F, ) is less than that of C,-explain? HF is aliquid while HClis a gas expla a? Bond dissociation enthalpy of “F,” is less than that of “Cl,” -explain ? Write two uses of hydrogen chloride Chlorine acts as an oxidising agent-explain with two examples ? (May-15A.P) What is Aqua regia ? 's reaction with gold and platinum ? How is chlorine manufactured by Deacon’s method ? (Mar-1617 T.S,19.A.P) Chlorine acts as a bleaching agent only in the presence of moisture explain ? The decreasing order of acidic character among hypohalous acids is Give the oxidation state of the halogen in the following (a)Cl,O (b) clo, ()KBrO, —_(d) NaClO, (May-15 T.S) ‘What happens when C/, reacts with dry slaked lime? (Mar-18T.S) GROUP 18 ELEMENTS Why do noble gases have cor es List out the uses of Neon? (Mar-18.A.P) In modern diving apparatus, a mixture of He & O, is used - Why? (Mar-16A.P) Noble gases are inert. Explain? Write the name & formula of the first noble gas compound prepared by Bertlett? Explain the shape of XeF , on the basis of VSEPR theory? (Mar-18 A.P) Why do noble gases form compounds with Fluorine and Oxygen only? How is XeOF, prepared ? Describe its molecular shape ? (Mar-17T.S) Give any two uses of Helium? Give any two uses of Argon? Write the shapes of XeO, and XeF,? (May-16 T.S&A.P) Mention the shape and draw a diagram of XeO, (Mar-16 TS) 2.4 & f-BLOCK ELEMENTS & CO-ORDINATION COMPOUNDS SHORT ANSWER QUESTIONS (4 M) Explain Werner's theory of coordination compounds with suitable examples. (Mar-18 A.P& TS) Qa r-11,14 June-10) (Mar-15 T.S,17 A.P)(May-16A.P) Write the characteristic properties of transition clements(Mar-15 A.P) (May-09) (May-16S) Using IUPAC names write the formulae for the following: (Mar-17 T.S)(May-12) (i) Tetrahydroxozincate( I) (ii) Hexaamminecobalt(IIl) sulphate (ii) Potassium tetrachloropalladate(|1) and (iv) Potassium tri(oxalato) chromate (i) Using IUPAC names write the systematic names of the following: (Mar-19 A.P;T:S) @[Co(wH,). Jeu, Gin [Pe( NH), CU(MHs CHt,)] CLG [71(44,0), * (ivy K, [Pach] (%)K,[Fe(CN), ] (Fes [Fe(CY), }, wid Ni(CO), Jomar-17S) Explain geometrical isomerism in coordination compounds giving suitable examples. ‘What is lanthanoid contraction? What are the consequences of lanthanoid contraction? 4q NARAYANAGROUP Page.No 72Faplain the applications of co-ordination i is gs, Whatismeantty chelate emesis bnbpirsice ry hagieon ex Sapa @ *€204(G) Coordination number (ii) Coordination entity (iv) Central 11.** Why do the transition metal i exhibit characteristic, in aqueous solutions explain giving examples a Pee = Tonic configuration of Ce ion and calculate its magnetic | ‘moment on the basis of ‘spin-only’ formula, vee + 13.* Predict which ofthe ions Cu’, Se, Mn, Fe? are coloured in aqueous solution? Give reasons. o i 14° Writea short note on metal carbonyls, 15.* Account for the zero oxidation state of Nj respectively. 16.* What are homoleptic and heteroleptic complexes? give one! example for each VERY SHORT ANSWER QUESTIONS (2M) CuSO,.5H,0 is blue in colour where as anhydrous CuSO, iscolourless. Why? (Mar-14) How many moles of AgClis precipitated when | mole of CoCl,.5NH, is treated with AgNO, solution? and Fe in [Ni(CO), ) and [ Fe(CO), ] o1. 02. 03. [Cr(NH,),)” isparamagnetic while [.Ni(CN),]” isdiamagnetic. Why? [Fe(CN), |’ and [ Fe(H,0), ]” areofdifferent colours indilute solutions. Why? 05. Calculate the ‘spin only’ magnetic moment of Fe*,_ ion. (Mar-174.P) 06, Among the first transition series ( 3d series) Chromium has highest melting point, Why? 07. What is an ambidentate ligand? Give example. (Mar-16..P) 08. What is an alloy ? Give example 09. What are coordination compounds? Give two examples. 10, What is the difference between a double salt and a complex compound? 1, What isa ligand?Give one example for unidentate ligand, (Mar-18 TS) 12. Why do transition elements exhibits characteristic properties. | _ 13. _ Iniits fluoride (or) oxide, in whicha transition metal exhibits highest oxidation state and why se 14. What is the oxidation state of cobalt in [ Co(CO), ] and [Co(NH,), Tia 15. Write the electronic configuration of chromium (Cr) and copper (Cu) 16, What isa chelate ligand ? give example. ”. What are complex compounds ? Give examples. — : 18, Silver atomhas completely filed d orbitals (4¢") inits ground state. How can you say that itis a transition element? ; sti 19. Why Zn* is diamagnetic where as Mn® is paramagnetic ? (Mar-i5 75,18 A.p) 20. Aqueous Cu" ions are buen colour whereas aqueous Zn ions are colourless Why? (Mar-16 T.S\(May-16 .P) Acts as catalysts (Mar-17 7: NARAYANA GROUP Page.No 73__ Ee 23. Whydo the transition metals readily form alloys ? 24, — What is misch-metal give its peacadi tan uses (Mar-16,194-F) 25. Why do transition elements exhibt more than one oxidation state (variable oxidation states) 26. Give one example each for ionic and neutral ligands | 27. Whats lanthanoid contraction? (Mar-19 T:S)(May-16T.S) 28. Scandium is a transition element ? But Zinc is not why? (May-14) . 29. Using IUPAC norms, write the systematic names of the following. (i) K,[Fe(CN),] (ii) [Cu(NH,),] 80, 30. What is wilkinson catalyst and give its importance? 31. What is EDTA and give its importance? 32. Calculate the Magnetic moment of a divalent ion in aqueous solution if its atomic number is 25? (Mar-16A.P) 8.POLYMERS VERY SHORT ANSWER QUESTI 1 Mention the type of polymerization involved in the formation of the following polymers (Mar 07, 09,2014) a) Bakelite bpvc ) Polyethene 4) Teflon 2. Whats polymerisation? Give an example of a polymerization reaction. (Mar-14) 3. What is PHBV? How is it useful to man?(Mar-18 T.S\Mar-15,16 T.S&19A.P\(May-16 TS) 4 Define an elastomer. 5. Mention the structures and names of the monomers used for preparing the following polymers, a) Bakelite b) Polystyrene ©)Teflon —d) Poly vinyl chloride e) Nylon - 6,6 fGlyptal g)Terylene (Mar-1S&16A.P) 6. ‘What is vulcanization. (Mar -17 A.P,19 T.S)(Mar& May TS) 7. What do you mean by polydispersity index ? (Mar-19.A.P) 8 What is Bio-degradable polymer ? Give two examples. (Mar-18.P) 9. Write the names and structures of the monomers of the following polymers (May-16 A.P) (i) Buna-S- (ii) Buna-N (iii) Dacron (iv) Neoprene. 10. Whatis anaddition polymer ? Give an example of an addition polymer. (Mar-1S TS) 11, What iseross linking agent used in vulcanization, 12. Is {HN.CHR-CO}, ahomopolymer ora copolymer ? 13. Givetwo examples for Semi-synthetic polymers ? 14. What isziegler-natta catalyst? (Mar-19 TS) 15, Give the structure of Nylon-2-Nylon-6 16. Whatare the monomer repeating units of Nylon - 6 and Nylon - 6,6. (Mar-16A.P) 17, Name the different types of molecular masses of polymers. 18. Whatis the difference between Buna-N and Buna-S? 19, Whatare fibers? Give example 20. What are thermoplastic polymers? Give example, 21. What are thermosetting polymers? Give example, 22. What are copolymers? Give example. (May-14) 23. What are homopolymers? Give example. 24, What are monomers? Give example (May-14) 25. Explain natural of synthetic polymers(rubbers)mension their monomers.(Mar-15,16A.P&TS) 26. What are the monomers present in the Nylon 2-nylon-6, (Mar-15 TS) NARAYANAGROUP Page.No 74QUESTION BANK ***1. Give the sources ofthe folowing ajA b)D (Mar-15 Ts &AL ***2. What are hormones ? Give one ex; i) Steroid hormones ii) Poly “itamins and name the diseases caused by their deficiency. ©)E and aK P)(Mar-16 17 A.P&T.S) ‘ample for each, (Mar-18,19 A.P&T.S)May-16 T.S&A.P) Peptide hormones and iii) Amino acid derivatives. ##*3, Write notes on vitamins, (May-11) ***4. Write notes on the functions of diferent hormones in the body. (May-10,12) °*5. Explain the denaturation with suitable examples (Mar-16 T.S) #*6, What are enzyme: “7, ? Give examples. Explain the classification of carbohydrates. **8. Write the importance of carbohydrates, *9. Discuss the structure of; glucose on the basis of ts chemical properties. 10. What is the DNA fing cr printing, mention its applications. VERY SHORT ANSWER QUESTIONS (2M) 1. Name the vitamin responsible for the coagulation of blood. (Mar-09) 2.Why are vitamin A and vitamin C essential to us ? Give their important sources (MAY-09, Mar-10) 3. Define Carbohydrates ? 4. What are anomers ? 5. What is Zwitter ion ? Give an example §. What are essential and non-essential amino acids ? Give one example foreach. (Mar-16'T:S) 7. Why cannot vitamin C be stored in our body ? 8. What is the difference between nucleoside and nucleotide? 9. Name the different types of carbohydrates on the basis of their hydrolysis. Give one example for each. 10. What do you understand from the names. (a) aldo pentose and (b) Keto heptose ? 11, Why are sugars classified as reducing and non reducing sugars? 12. What do you understand by invert sugars ? 13, What type of bonding helps in stabilizing the ar -helix structure of proteins ? 14, Temperature and pH effect the native proteins. Explain. 15, What are amino acids? Give two examples 16, What are proteins? Give an examples. 17. What are fibrous proteins? Give examples. 18, What are globular proteins? Give examples. 19. Write the names of three DER OFRN A is 20. Write the biological functions o 21. What is pbscect How is it different eres ‘awed 22. What are the hydrolysis produets of () suerose and (i) lat 23. What is the basic structural differece between stare lulose. ? Givean example. 2 i esi nn Ce eee of gicose, Wibe ibe soe. (May-14) i —————— eee Page.No 75QUESTION BANK SRIPE ISTRY IN EVERYDAY LIFE VERY SWER QUESTIONS 1. What are antibiotics ? Give example. (Mar-16,18 A.P,19 TS) ~ ‘What are antiseptics ? Give example. (Mar-15,19 T-S & A.P,17 TS) 3. What are antifertlity drugs ? Give example 4. What are artificial sweetening agents ? Give example. (Mar-15 A.P)(Mar-16 T.S)(Mar& May- 5. What are analgesics ? How are they classified?Give one example for each.(Mi 6. What are non - Narcotic analgesics ? Give example 7. What are antacids ? Give example. (Mar-15'T.S)(Mar-14)(May - 14) (May-16T-S&A.P) 8. Whatare antihistamines ? Give example (May = 14) 9. Whatare tranquilize (May-16 TS) 10. What are narcotic analgesics ? Give example. 11. Whatare antimicrobials? 12. What are disinfectants ? Give example. (Mar-15 T.S,17 A.P&TS) 13, What are the main constituents of dettol? 14, What is tincture of iodine ? What is its use ? 15. What are food preservatives ? Give example. (Mar-16 T.S,17 A.P) 16. Name two most familiar antioxidants used as food additives.? 17. What is the difference between a soap and a synthetic detergent ? (Mar-14,18.A.P) 18, Name the macromolecules that are choosen as drug targets? 9.HALOALKANES AND HALOARENES LONG ANSWER QUESTIONS (8 M) ***1. Write the reactions showing the major and minor products when chlorobenzene is reacted with CH,Cl and CH,COCI in presence of AICI, ***2, Explain the mechanism of Nucleophilic bimolecular substitution $y? reaction with one example. ***3, Explain the mechanism of Nucleophilic unimolecular substitution s7y' reaction with one example. ***4, Define the following : (Mar-16A.P) j)Racemic mixture il) Retentionofconfiguration iii) Enantiomers. iv)Recemisation **5. Write the mechanism of dehydro halogenation of -bromobutane? **6. Account for the following statements : *1, Explain sv' & SN? reactions 1) Arythalides are extremely less reactive towards Nucleophilic substitution reactions. 2) p-Nitrochlorobenzene and o, p-dinitrochlorobenzene undergo Nucleophilic substitution readily compared to chlorobenzene. 7, Explain how the following conversions are carried out : 1) Propene to propanol 2) Ethanolto but-I-yne 3) 1-Bromopropane to Bromopropane 8, Name the following halides according to IUPAC system and classify them as primary,secondary, tertiary, vinyl or aryl halides. i) CH,CH(CH,)CH(B)CH, i CHC(CIKC,HCH.CH, iii) m-CICH,C,H,CH,C(CH,), iv) O-Br-C,H,CH(CH,)CH,CH, HALOALKANES AND HALOARENES, SHORT ANSWER QUESTIONS (4 M) (Mar-14,15,16T.S,18 A.P & TS) ***2, Predict the alkenes that would be formed in the following reactions and i ify the major al NARAYANA GROUP Page.No 76 weiii) 2-Chloro -2- methyl butane "22, » Tar? #43, How will you cary out the followi 1)Ethaneto bromocthene 2) Toluene to benzylalcobol ##*4, What is the criteria for optical activity? give two exampl ‘chiral molecules? 5, Write the mecheniam oftie Bloat See n~ Butylbromide+ KCN —£##-2 5 n= butyleyanide #6, Ahydro carbon C,H, doesnot react with chlorine in dark but gives a single monochloro compund C,,C! in bright sun light identify the hydrocarbon. #7, Explain why the dipolemoment of chlorobenzene is lower than that of cyclohexylchloride VERY SHORT ANSWER QUESTIONS@M_ What are the ambident nucloephiles? (Mar-17 T.S)(May-16 A.P) What is the stereochemical result of S\, and ‘Si reactions? (Mar-17T.S) What type of isomerism is exhibited by 0, m, and p-chlorobenzenes ? 1 2 “S 4, Write the isomers ofthe cape formula C,H,Br. $. — Whatare Enantiomers? (May-14,16A.P,19 T.S) 6. Write the structures ofthe following compounds. ii) Bromo-4-sec-butyl-2-methylbenzene highest dipole moment? i) 2-chloro-. 7. Which one of the following has )CH.CI in CHCl, CCl, 8 Which Compound ineach ofthe the following pairs willreact faster in S* reaction with OH” ? i) CH,Br or CHI ii) (CH,), CCI oF CHC (Mar-19 4.P) water? % Explain why he alkyl ales though pla are immiscible with 10. HCHCICH, Which is more easily hydrolysed by aqueous formation of alcohols, while i Treatment x otanyaswion Koi ene een presence of ale.KOH what po Sing reactions are Find the A & B products im dee CH,CH,CI aris ae (Mar-15,17 A.P)QUESTION BANK 15. Whatis Wurtz reaction?Write an example. ra 10.ORGANIC COMPOUNDS CONTAINING GH & 0 ALCOHOLS, PHENOLS AND ETHERS we : __ LONGANSWER QUESTION: (8M 1. Explain why (i) Ortho ntrophenol more acidic than ortho methoxyDheneh ii) OH group attached to benzene ring activates it towards eleertophalic substitution. Bot gn to benzene fee (Mar-17 A.P) suitable example write equations for the OWN: Gther synthesis. sexy (i)Kolbe’s reaction (ji) Reimer-Tiemann reaction. —( 3. Write equations of the below given reactions . i)Alkylationof anisole (i) tration ofanisole_(i) Friedel-Crafts acetylation of anisole (Mar-14) ***4, (a) Write any two methods of preparation of phenol. Phenols i ith that of alcohol. (b) Explain the acidic nature of phenols and compare wit SHORT ANSWER QUESTIONSGM Write the mechanism of hydration of ethene to yield ethanol. 2. Explain the acidic nature of phenols and compare with that of alcohols. (Mar-17 A.P) Illustrate hydroboration-oxidation reaction witha suitable example. Write the products formed by the reduction and oxidation of phenol. (May-14) Write the equations for the preparation of phenol using benzene, cone. H_,SO, and NaOH - (Mar-14) **6. Ethanol with 7,50, at 443K forms ethane while at 413 K it forms ethoxyethane- xplain the mechanism. ¢ IUPAC names are (May-14) **7, Write the structures of the following compounds who: (i) 2-methylbutan-I-ol, (ii) 2,3-diethylphenol, (ii) I-ethoxypropane, (i) cyclohexyimethanol VERY SHORT SWER QUESTIONS(2M acid, benzoic acid and phenol 1. Compare the acidic strength of acetic acid, chloroa (Mar-14) 2. Explain why propanol has higher boiling point than that of the hydrocarbon-butane. 3, _Alocohols are comparatively more solube in water than hydrocarbons of comparable molecular masses. Explain this fact. 4 ents used for the prepartion of phenol from chlorobenzene. 5. Name the reagents used in the following reactions. (i) Oxidation of primary alcohol to carboxylic acid (ii) Oxidation of primary alcohol to aldehyde 6. Write the equations for the following reactions. (i) Bromination of phenol to 2,4,6-tribromophenol (ii) Benzyl alcohol to benzoic acid. ALDEHYDES, KETONES & CARBOXYLIC ACID LONG ANSWER QUESTIONS(8M) *#*1, Describe the following (Maris TS & AP) 1)Acetylation 2)Cannizaro reaction 3) Crossed aldol condensation 4) Decarboxylation 5) Aldol condensation +**2, Explain the following terms. Give an example of the reaction in each case. 1)Cyanohydrin 2)Acetal —-3)Semicarbazone 4) Aldol 5) Hemiacetal 6) Oxime #*3, Howare the following conversions carried in not more than two steps. 1) Ethanol to 3-hydroxybutanal 2)Bromobenzeneto I-Phenylethanol 3) Benzaldehyde to + Hydroxyphenylacetic acid 4) Benzaldehyde to benzophenone NARAYANAGROUPQUESTION BANK EHYD TO! C WE orl. Bap the role ofclectron with drawing and lector releasing groups on the acidity of #2. Arrange the following in the increasing order of their acidic strength: Benzoic acid, Wcthoxybenzoie acid, 4-Nitrobenzoic acid and 4-Methylbenoke acid, ##3, Write the equations of any aldehyde with Fehlings reagent, #04, Whats Tollens reagent? Explain ts reaction with #*5, Explain the following reactions (Mar-15 A.P) i) Reimer-Tiemann reaction ii) Williamson's ether synthesis VERY SHORT ANSWER QUESTIONS(2M) Arrange the following 'g compounds in increasing order of their property indicated. : 1) Acetaldehyde, Acetone, Methyl butyl ketone reactivity onwards CN, 2) Floroacetic acid, monochloroacetic acid, Acetic acid and Dichloroacetic acid (Acid strength) Write the reaction showing c -halogenation of carboxylic acid and give its name. How do you distinguish acetophenone and benzophenone? Explain the position of electrophilic substitution in benzoic acid. Write equations showing the conversion of- 1) Acetic acid to Acetyl chloride 2) Benzoic acid to Benzamide 6, Write the mechanism of esterification. (Mar-15T.S) veer 11.ORGANIC COMPOUNDS CONTAL LONG ANSWER QUESTIONS(8M) ***1, Complete the following conversions Aniline to e ii) Cyanobenzene _ ii) Benzene and iv) Phenol in the following named reactions: (Mar-15 A.P) meyer reaction i) Gatterman reaction (Mar-17 T.S(VSAQ)) ***3, Complete the following conversions i) CH.NC+HgO >? ii) 2+2H,O + CH,NH, + HCOOH ili) CH,CN + C,H, MgBr >? "2-5? iv) CH,CH,NH, + CHCl, +KOH =>? Om RT ANSWER QUESTIONS(4M. ***1_ How do you prepare ehtyl cyanide and Ethyl isocyanide from a. pagent = , (Mar-14)(Mar-ist.s) om?! B the following P (a) Diazotisation ae ® Carbylamine reaction the following? > Bo re eens Peps NARAYANAGROUP Page.No 79SRIPE OW do you carryout al i) N-ethylamine to N, ine, ii) Ani Pa **5. Explain the following: a 4) ps ofaniline is more than that of methylamine. | » ii) Reduction of alkyleyanide forms primary amine whereas alkyl isocyanide forms ‘ secondary amine, 5 **6. Compare the basicity of the following in gaseous and in aqueous state and arrange them in increasing order of basicity. CH, NH,, (CH, ), NH, (CH,),N and NH). *7. Write the IUPAC names of the following compounds ) CH,CH,NHCH,CH,CH, ii) PhCH,CN CH,NC NH, i)| iv) Br a *8. Write the equation involved in the reaction of Nitrous acid with Ethylamine and aniline. *9_ Explain with equations how methylamine, N,N-dimethylamine and N,N,N-trimethylamine react with benzenesulphonyl chloride and how this reaction is useful to separate these amines. *10. Write the steps involved in the coupling of benzene diazonium chloride with aniline and phenol. 1. Write equations f (Mar-14,18 TS) 2. Whatiis Diazotisation, (Mar-14) 3. Explain why ethylamine is more soluble in water whereas aniline is not soluble. 4. Gabriel phthalimide synthesis exclusively forms primary amines only. Explain? 5. Give structures of A, Band C in the following reaction, (Mar-17 TS) C.HN,CL£25. 412" 5 pM gc 6. How do youcarryout the following conversions: i) Benzoic acid to Benzamide, ii) Aniline to p-bromo aniline (Mar-14) 7. Arrange the following bases in decresing order of p** values . (Mar-15,19 T.S) C,H,NH,,C,H,NHCH,,C,H NH ,and(C,H,), NH 8. How isnitrobenzene converted in to Aniline? (Mar-16TS) 9. Explain the reaction of Aniline with nitrous acid. (Diazotisation.) (Mar-18 TS) LIST OF NAMED REACTIONS: 1, Grignard Reaction. (Mar-19 TS) +*2, SN! &SN’ Reactions. ***3, Aldo! Condensation. (Mar-18 A.P&May-16 T.S&A.P) ***4. Cross Aldo! Condensation, (Mar-17 T.S,19 A.P) ***5, Cannizaro’s Reaction. (May-16 T.S)(Mar-16,18 A.P,19 A.P&TS) 6, Clemmensen’s Reduction. 7. Wolff-kishner Reduction. ***8, Carbylamine Reaction. (Mar-19 T.S)(Mar-16 TS&A.P) i ***9, Reimer-Tiemann Reaction. (Mar-19 T.S\(Mar 18 A.P&May-16A.P) NARAYANAGROUP Page.No 80cen (May-16 TS) ie = (May-16 T:S)(Mar-16,18 A-P) ens tanto Tatarstan 167 e 015, HLV.Z. Reaction. ian i9 AF) iiar-t7 TS\Mene 16S) 40216 Diazotisation. (May-16T-S) e017, Wurtz-Fittig Reaction. 18 Fittig Reaction. 19.Wurtz Reaction. '40#20 Kolbe’s Reaction. (Mar-16,19 TS) 21.Hoffmann Bromamide degradation Reaction. 22.Acetylation (Mar-19 A.P) NT LON WER TH OM ORGA! 1 Explain the following with one example (March : 2016)TS a) Williamson's synthesis (Mar-18 T.S) b) Kolbe’s reaction (Mar-18 T.S) ©) Hell - Vothard - Zelinsky (HVZ) reaction(Mar-18 T.S) d) Aldol condensation 2 Explain the following (May :2016)TS a) Aldol condensation b) Estenification c) Williamson's synthesis 4) Cannizzaro reaction 3 Explun the following with suitable example 4) SN" & SN? reactions (March : 2016)TS b) Reimer tiemann reaction (Mar-18 TS) ©) Sandmeyer reaction (May: 2016)TS 4) Gattermann reaction 4, Explain the following a) ‘Carbylamine reaction b) _diazotisation reaction (May: 2016)TS ©) Wurtz reaction * @) Cross aldol condensation Subscribe the YouTube channel for latest updates