STOICHIOMETRY
Reactants Products
Given A+ B—> C+D,
To solve for either product “A conbe svocttied
given reactants + with B.
A. mA mlC tm _ Ae «Con be substituted
‘My A ‘molA molC with D.
me NOTE: NOTE *
g > grams =f guen mol of substan] | @ guen g of substance,
Mn ~ Molar mass convert with: fe [ook for mol, vse:
mol A ~ moles of reactant mold te =A shes mA
wll - moles of product
To DETERMINE THE LIMITING REAGENT :
STEP 1: Solve for product given A.
(it Dis te required product then subsite C w/ D.)
gf. moi -mlC thm C Ae
My A mol A MolC
STEP 2: Solve for product given B.
STEP 3: Compare. the mass of te yield between Ad B.
gla > Co
Wnere :
ga ~ grams of product produced by A. (dield of A)
gCe - grams of product produced by B. (Yield of 8)
The lesser yield is the LIMITING REAGENT.To SOLVE FoR EXCESS REAGENT
USING LIMITING REAGENT :
gtR
__Inol mig MER _ ep
MILK MyLR molLR wi ER
Where :
gtR - given grams of Limiting Keagent
molLR - moles Limiting Reagent
MR ~ Molar mass Limiting Reagent
MER ~ molar mass Excess Reagent
miER - moles Excess Reagent
gER grams of Excess Reagent
SAMPLE PROBLEM
2. Powdered aluminum reacts with iron (III) oxide in the thermite reaction to form molten iron
and aluminum oxide:
2A (s) + Fe20s (s) > 2 Fe(!) + AlzOs (s)
Liquid iron is produced because the reaction releases enough energy to raise the temperature
above the melting point of iron. This liquid iron can be used o weld steel railroad rails. Suppose
that a mixture of 100.0 g Al and 100.0 g Fe,0> reacts
b) Calculate the mass of excess reactant that remains after the reaction is complete
Step 1 FormucA / a
“ 3 lR [mo] mo/ER tm GR
miLR My LR mol LR prep
STEP 2: SUBSTITUTE = CANCEL LIKE TERME (ortonac)
tbr _lalEO; QobAt Je. 781997, Al
wes 9g | MIE Pt | met AT
Step 3? SOLE.
a 2 6-767 g Al 7 BFA gt)
NX
w+ Given 100.Dg of Fe,0, (wich i te Ummive eeécranr) | to ue up he LR,
mast react with 32.799 Al.
Since he prodem asks for the mass of tHe excess reactant AFTER te
reaction bas completed , subtract 33.799 Al from the given ASS 100-0g Al.
“. After the reachon, there is on excess of ApPrOX . 66. 2lg of Al.