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    8 views8 pages

    H2 Chemistry Electrochemistry SgExams

    Uploaded by

    Priya

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    Electrochemical, ceil Bag Reduction and Oxidation halt equation occurs mM seperate half tall Half-cell consists ot species containing elements in beth oxidised and reduced form, Electede, Electrelyle, Salt Bridge > Concise of non-teacting ions that allows tons to pass jwaegn G sUtcrance tread Lontaing electrical conducting, aobile ions, fe COA heat Solid Clectral Conductor eae “Cqysid, ware loses electvens, = To ensure Tre oxidation halt cel is the arcde, witin ve pdarity — anox,RedCor teen The reduction halt cell 1s +he cuttede, with +0 pan’ = To ene GS gains elec decryral sectvallity. Without a salt bridge, it will leod +o charge imbalance and current tow. steps. Usually contains ron-reacing OAS Cenog exc.) Salt Badge In the COM] G4 halt call, Gu 1s being oxidised toGet G ae) Cu Oy 420° sine Cou] >LM0F 7, shuton ts net te. ie Pre Vice versa for. Arg | Any Wath call. a Agios Mevenest of 27 tem Cn avode to By cottode NO: vo . 3d produtey Aecrterty Lin Mingwan (2020) Stondard Hydrogen Clectrede (S-4-E) Consiste ot Platinum wite with platinised platinum Ciners O, FE ts spertaeous Wren E%eh SO, man vot spontageus Relationship between ESyand AG ==nF a c Need Feraday’s constant total charge carried by (mole Urol Y4-65x104C molt free EEEEEI] Bae Limitations of Standard Colt Potential 1) Only tell us about. spertaenous vor kinentc Reasibitty eg. Cut +H, Cut 2Ht, SR yeto-suy Bat im realiny there's vo seaction due te hyh Ea. 2) Non-standard Conditions Charge. in concentration, temperature, pressure will atest Evalue, CLEP) (0) €ttect of teenp. Not +e7 = Nats) AH=-ve €*= -2-45y By temperature iMerease, EP ut be nore Neective oS oxdechen igfovoured. Wi eftert ot pressute. C22, +2e7 2 2Ee7 Wii) E8fecr g& concectedion 42207 SS Gu Fl ¥ in pressure ce : In order +0 partially ofeset wo oxidation reduction ct way ts fovoured, Forming, MOTE wan » Heng, eduction potential becomes more/less. postive /neqaiwe “ Eeeayy CUOMO ore] Leas egachve/posttive Since Zak = Seat Eoeg Concentretion Calls Apprcottion of Eleuhochemcal celle, a ») Non-rechargabie alkaline bocteny wo Ganls) | u**Cag) [| CuPGag) | Gas) 7 ; [2 7 eee e HAnO2 into paste Sanevsy ec Bye, | OS gruphite fnodeC-) Coxdotion) lz) O-Lmrol{den® (eo arn CY Bes) +204 Gaq) PRAAs) +HAOLAIHE q AC 7 eer = “hewtradie’ CothodeGr) Creduction) Gann. O-BSrclidm® 0-56 eel [dnd OY MaOrCs) + uHyOLe) MALO) +20 Overall: Bn) + Mai + POLL) > MOG I+ Ha COWL 2) alter ry ‘Saver beetton bectieny 2)Rechangable Lead-Reid, Battery, Zine ancde , Binc/Pecwotyte Brade PCs) + HaS0u lag) > PRSOuCs)+ LH" Cag) + De Metal Cormede C+) Costonle: PhO, CS) + HasOq log) FR 4227 > PHSOy. (6) + Fey porte Overall: PSOA(S) +POS)+2HaSO4Laq) 22PRSOA TM + AH.OLe) = AnedeC-) :Bn(s)+ 20H Cag) 9 ZnOCs) + HOLL) +267 Dong Rechorayma 2PLSOuCsD + ZHOLe) > PROr(s) + PbLs) +2HasO4F \F aq) Cotrodels) : Ag OCs) +4002) +267 > hats) +20H'Coq) Sean Overall Bn + Ago Bn0 +24 Seales Coy 4) Lata ton: Barton (Recmargaite) fede: LE). LK FET in orgute Stvent CU very contanse) : or LIC) + COOLEY PLUME een Satrode’ LIT + Corts) 4e7 > LiCoO.Cs> Prode+ Hy + 20H" 2H20 +207 0: Costode +O, +240 +e” > GOH! 2 ey ta Got KOHLoq) _ Porous grapritt otectade S metal Comalyet Adhvantages of Fel colt ~ Minimal poltation Disadvantage > txpeewe ~ High eftrcienny and good energy *omacs ratio ~ High HMpeture to opemte “Silent when opening slong opeutingtine ~Aeeare ereahatyte = Mainroin AcKIONUnn EMERY capewity cept, . = Sle reaction Aen vem COL ie Blecrolyais - elecmial enegy i wed to drive a ron-spostueous wenctiin ig a Fa ee Ratioy pulls elechons. out of the anode and pushes tt. to cattade 3 5 cottode (-) (Shorter terminal is ve) Ey COttracts, Carton) THecrolyte Can be a nolten liquid gh jonie Salt, or aguenus schutton® tons. Arodec+) CPtHtracts Anion), Bechalysis et Molten Salt eg. PBr(2) Cottode: Pb'* +227 > PbC*). Brode :2Br” > Begg) + 227 wha pein Slerolysis of Aquesis Sdutton ger r Must consider water, Cation, anton ete Bone at high temperature “Fo melt Pen, Only ene, species discharged Ht an Cleumede at any | time Crelective disthorge). Tre more positive the €%, He more Wkaly it gen reduced at He cutteda. Vier versa.” PNitrare cunnct be oxidised as Ht Og ‘already, +6. Sulfate have a ven) low Hrdunuy to be onclised. Shlect ot Concentration of ion en discharge. Dilue Nace frode: 24,0. —> Otte He <% Coteda: 204227 —> Hat 20H" E%=-O8N gore more batic over tiene San LAW gets wore acdc over time Concantrased..Nace Anode: 26€° > Cha #247 SB = iggy. Ae change in gH Cathode: 220 +20" > H+ 2047 £* = -0.g3y pr increases Sver aie, By right: more positive £8; will be oridivedl ext the erode. However C&M oxtdised. This is becauve high CECT due to cone. Nace pusres qm of 260 ER, +6 forward. This mates Sox move pasitive thon Sox ct water 12aNd. RHlect of nature of eleriade, On discharme HF inert eleorade CPt /graght®) are used, Consider

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