ESCUELA SUPERIOR POLITECNICA DEL LITORAL -ESPOL, DEPARTMENT OF CHEMICAL AND ENVIRONMENTAL SCIENCES - DCQA TERM 2018-2019 COURSE POLICIE COURSE INFORMATION Title:Chemical Academie Unit: Career:Chemical Prerequisites: Chemical Weekly load. 2. TEACHER INFORMATION ‘Name’ Title: Work Experience:Quality Consultation hours 3. GENERAL OBJECTIVE Thermodynamics IL Departmentof Chemical and Environmental Sciences Engineering Thermodynamics I Theory:2 hours Practical: 1 hour Diana Tinoco Caivedo Engineer Engineer, Technology Coordinator and Technical Manager of PSI Environmental Laboratory (2014 - present. Research at the University of Las Palmas de Gran Canaria on topies related to water treatment (2013 = 2017), Research at the Renewable Energy Laboratory of ESPOL (2010 - 2012) 15 minutes at the beginning of each class will be usedcase theconsultation requires more time, a time and date will be arranged by mail, MSe, at Industrial To strengthen the student's ability to analyze and evaluate systems from the thermodynamic point of view by applying the laws of thermodynamics and the laws of mass and energy conversation, so that he’she can apply them in Chemical Engineering processes. 4 Target ECIFIC OBJECTIVES AND INDICATORS, Deliverable I, To develop independence in the Investigate a specific case based on asearch and selection of information] to solve problems. identified problem, which is unique to each student. And prepare a report containing: Scope, Objective, Problem Statement, Justification, Development, Conclusion, References. 2. Encourage discipline in managing time to carry out various activities in order of priority. Read at home the topic for the next class and take a reading quiz each week. Develop 2 application problems to exercise what has been learned on a weekly basis. 3. Question and discem using technical knowledge to intemalize what has been learned. Develop written lessons containing true and false statements with justification in both situations, and Application problems. 4. Strengthen teamwork and value the contribution of each person on the team according to the multidiseiplinary potential that exists. Prepare a group case in order to solve a problem, Identify the functions of each group member and evaluate the performance of each group member decade during the work. Identify 2 strengths found in each member with a specific example each. Carry out the presentation of the work. 5. Sharing their knowledge and doubts with classmates. Teaching and reaffirming their knowledge by means of the oral interaction. 6. Evaluate each student's own level of knowledge periodically and make action plans to improve their level. Conduct support groups according to their academic level applying the PALS technique. Periodically each student should make a control diagram. Highlighting at least 2 personal strengths found and an objective to develop for the next unit. At the end of each ‘unit the report must be handed in according to the format provided by the teacher, COURSE SYLLABUS UNITS HOURS unr . Thermodynamics of Flow Processes: DIAL 1.2. Balance Equations 1.2. Flowsin compressible fluid pipelines 6 pav2 1.3. Expander Systems 1.4. Processes of speciic volume reduction by pressure applications 2. Production of energy from heat DAY 3 anos 24. The steam power plant 22. Power processes with reactive mixtures 6 2:3. Gasturbine power plant 2.4. Chemical reaction propulsion processes6. Refrigeration and liquefaction DAY 5 & 6 3.1. Carat refrigeration 3.2. Vapor Campression Pracesses 3.3, Comparison of innovative refrigeration cycles 3.4, Absorption cooling 3.5, Heat pumps and liquefaction processes Liquid-liquid and solid-liquid phase equilibria DAY 77012 4.1. The onset of liquid-liquid instability 4.1.4. Simple vapor-liquid-liquid equilibrium (VLLE) calculations 4.1.2. LLE predictions using Flory-Huggins theory: Polymer blends 4.2. Gibbs stability and Excess Energy 4.3. Binary LLE graphing the Gibbs energy of the mixture 4.3.1. LLE predictions through graphical representation 4.4, LLE: Activities 4.4.1. The binary LLE algorithm using MAB and SSCED models. 45. VLLE with immiscible components 45.1. Steam distillation 46. Binary phase diagrams 47. Platting ternary data LE 4.8. Critical points in binary liquid mixtures 4.8.1. Liquid-liquid critical point of the one-parameter Margules model 48.2. Flory-Huggins model liquid-liquid critical point 4.9. Numerical procedures for binary, ternary balance LLE 4.10. Solid-liquid equilibrium 4.10.1. Variation of solid solubility with temperature. 4,102. Eutectic behavior of chloronitrobenzenes 4,103. Eutectic behavior of benzene + phenol 4.104. Precipitation by the addition of antisolvent 4.105. Wax precipitation ‘Statistical thermodynamics DAY 13 AND 14 5.1. Systems, First Principle. irreversibility. 5.2. Microstate and wave function 5.3. Gibbsian sets, statistical postulates and canonical sets. 5.4. Independent particles, 5.5, Entropy and number of accessible states 5.6. Third principle: inaccessibility of absolute zero, Nemst theorem and consequences, 5.7. Independent particle systems 5.8. Configuration partitioning function in real gases 5.9. Main interactions of two non-ionic particles 5.10. General expression of intermolecular potential COURSE SCHEDULE, Partial Units Date 1. Thermodynamics of Flow May 8 - 15 Processes 2, Energy production from May 22-29First heat 3. Reffigeration and liquefaction Tune 5-19 4, Liquid-liquid and solid-liquid phase July 3-31 Second equilibrium. 5. Statistical thermodynamics ‘August 7-21 7. HOURLY LOAD TEACHING HOURS OF HOURS OF TOTAL HOURS APPLICATION | AUTONOMOU WEEKLY (dassroom PRACTICE S LEARNING HOURS: leaming) 2 1 3 6 8. COURSE EVALUATION The following qualification procedure shall be adopted: Deliverable Score Frequency Case Resolution Report 8% 1 partial Reading tests 10% I weekly Home Application Problems 5% 1 weekly ‘Written lessons 12% T weekly Group project 3% 1 partial Support couple workshop 5% L weekly Report with control diagram and chart 3% Teach (Printed) Examination 30% 1 partial TOTAL 100% = “IMPROVEMENT: 100 points “Improvement is cumulative. 9. GUIDE AND COMPLEMENTARY TEXTS BASIC 1, Themis Matsoukas (2013) FUNDAMENTALS OF CHEMICAL ENGINEERING, THERMODYNAMICS, USA, First edition, EdRorial Pesson, 2MSmithH Van Ness4M, Abbett (2003) Introduction, a ‘Tharmodynaiics in Chamical Engingoring, Mexico , Sbth Edition” Me raw Hilfirteramericana citores. ‘COMPLEMENTARY 1, Ellot Richard), Lira Car, Introductory Chemical Engineering Thermadynamics, USA, 2 Eaton, Prentice Hall 2. Michael Morén (2004), Fundamentos de Tesmedindmica Técnica, Spain, second edition, Editorial Revert. 3. Gangel Yunus, (2012), Thermodynamics, Maxico, seventh edtion, Ector Mera Fl10. GENERAL COURSE POLICY According to the class schedule, the student must make use of his/her autonomous work hours to prepare for the next class, reading the basic and complementary texts, as well as the material sent by the professor for a specific topic. During the first 20 minutes of class, the topies to be developed will be evaluated by means of a reading test in order to evaluate the student's autonomous work. Also at the end of certain classes there will be a lesson of internalization that each student must develop individually in order to evaluate that the knowledge given in class has been received and understood. It will not be evaluated that the student knows formulas or complex data by heart, so the student must prepare a booklet of formulas, which will be reviewed by the teacher. The formula booklet may be used in lessons and exams, as long as it contains only formulas and basic data that the teacher has indicated during the classes. The student is responsible for the level of technical knowledge that he/she is developing, so he/she must record his/her grades and make a control chart that shows the development of his/her level. Students must commit themselves to identify opportunities for improvement and apply corrective actions to improve their level of knowledge in each unit. For this purpose, a self-evaluation form will be provided, which must be uploaded to the sidweb at the end of each unit. MSc. Diana Tinoco DCQA Professor