Synthesis, characterization, electrochemical behavior, and catalytic activity of cobalt(II) metal complexes with

pincer-type methylbenzamide derivative ligands

Ebru Keskin 1, Ersan Turunc 1 and Hakan Arslan 2,*

1
Department of Nanotechnology and Advanced Materials, Institute of Science, Mersin University, 33343 Mersin, Turkey
2
Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343, Turkey

* Corresponding author: Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, TR 33343,
Turkey, e-mail: hakan.arslan@mersin.edu.tr

Supporting Information (SI)

Index Page
Figure 1S. 1H NMR spectrum of H3L1 in DMSO-d6. 2
Figure 2S. 1H NMR spectrum of H3L2 in DMSO-d6. 2
Figure 3S.1H NMR spectrum of H3L3 in DMSO-d6. 3
Figure 4S. 13C NMR spectrum of H3L1 in DMSO-d6. 3
Figure 5S. 13C NMR spectrum of H3L2 in DMSO-d6. 4
Figure 6S. 13C NMR spectrum of H3L3 in DMSO-d6. 4
Figure 7S. 1H NMR spectrum of K2[Co(H3L1)2] in DMSO-d6. 5
Figure 8S. 1H NMR spectrum of K2[Co(H3L2)2] in DMSO-d6. 5
Figure 9S. 1H NMR spectrum of K2[Co(H3L3)2] in DMSO-d6. 6
Figure 10S. FT-IR spectrum of H3L1. 6
Figure 11S. FT-IR spectrum of H3L2. 7
Figure 12S. FT-IR spectrum of H3L3. 7
Figure 13S. FT-IR spectrum of K2[Co(H3L1)2] in nujol. 7
Figure 14S. FT-IR spectrum of K2[Co(H3L2)2] in nujol. 8
Figure 15S. FT-IR spectrum of K2[Co(H3L3)2] in nujol. 8
Figure 16S. GC spectrum of K2[Co(H3L1)2] in in oxidation of PPh3 to OPPh3. 8
Figure 17S. GC spectrum of K2[Co(H3L2)2] in in oxidation of PPh3 to OPPh3. 9
Figure 18S. GC spectrum of K2[Co(H3L3)2] in in oxidation of PPh3 to OPPh3. 9
Figure 19S. GC spectrum of K2[Co(H3L1)2] in in oxidation of Ph2S to Ph2SO. 9
Figure 20S. GC spectrum of K2[Co(H3L2)2] in in oxidation of Ph2S to Ph2SO. 10
Figure 21S. GC spectrum of K2[Co(H3L3)2] in in oxidation of Ph2S to Ph2SO. 10
Figure 22S. GC spectrum of H3L1 in oxidation of PPh3 to OPPh3. 10
Figure 23S. GC spectrum of H3L2 in oxidation of PPh3 to OPPh3. 11
Figure 24S. GC spectrum of H3L3 in oxidation of PPh3 to OPPh3. 11
Figure 25S. GC spectrum of H3L1 in oxidation of Ph2S to Ph2SO. 11
Figure 26S. GC spectrum of H3L2 in oxidation of Ph2S to Ph2SO. 12
Figure 27S. GC spectrum of H3L3 in oxidation of Ph2S to Ph2SO. 12

1
Figure 1S. 1H NMR spectrum of H3L1 in DMSO-d6.

Figure 2S. 1H NMR spectrum of H3L2 in DMSO-d6.

2
Figure 3S. 1H NMR spectrum of H3L3 in DMSO-d6.

Figure 4S. 13C NMR spectrum of H3L1 in DMSO-d6.

3
Figure 5S. 13C NMR spectrum of H3L2 in DMSO-d6.

Figure 6S. 13C NMR spectrum of H3L3 in DMSO-d6.

4
Figure 7S. 1H NMR spectrum of K2[Co(H3L1)2] in DMSO-d6.

Figure 8S. 1H NMR spectrum of K2[Co(H3L2)2] in DMSO-d6.

5
Figure 9S. 1H NMR spectrum of K2[Co(H3L3)2] in DMSO-d6.

Figure 10S. FT-IR spectrum of H3L1.

6
Figure 11S. FT-IR spectrum of H3L2.

Figure 12S. FT-IR spectrum of H3L3.

Figure 13S. FT-IR spectrum of K2[Co(H3L1)2] in nujol.

7
Figure 14S. FT-IR spectrum of K2[Co(H3L2)2] in nujol.

Figure 15S. FT-IR spectrum of K2[Co(H3L3)2] in nujol.

Figure 16S. GC spectrum of K2[Co(H3L1)2] in oxidation of PPh3 to OPPh3.

8
Figure 17S. GC spectrum of K2[Co(H3L2)2] in oxidation of PPh3 to OPPh3.

Figure 18S. GC spectrum of K2[Co(H3L3)2] in oxidation of PPh3 to OPPh3.

Figure 19S. GC spectrum of K2[Co(H3L1)2] in oxidation of Ph2S to Ph2SO.

9
Figure 20S. GC spectrum of K2[Co(H3L2)2] in oxidation of Ph2S to Ph2SO.

Figure 21S. GC spectrum of K2[Co(H3L3)2] in oxidation of Ph2S to Ph2SO.

Figure 22S. GC spectrum of H3L1 in oxidation of PPh3 to OPPh3.

10
Figure 23S. GC spectrum of H3L2 in oxidation of PPh3 to OPPh3.

Figure 24S. GC spectrum of H3L3 in oxidation of PPh3 to OPPh3.

Figure 25S. GC spectrum of H3L1 in oxidation of Ph2S to Ph2SO.

11
Figure 26S. GC spectrum of H3L2 in oxidation of Ph2S to Ph2SO.

Figure 27S. GC spectrum of H3L3 in oxidation of Ph2S to Ph2SO.

12