Professional Documents
Culture Documents
Test 3
Test 3
4NO(g) + 6H,0(8) NO + 1/20, —+NO, ;3NO,+H,O Q75 Q.76 QT Q78 Q.79 Q.80 Qst » HNO, +NO. © lonisation energy depends on electronic configuration and atomic size. Mgand Behas[inert gas] ns* configuration and, therefore have higher 1* ionisation energies. Li and Na has [inert gas] ns' configuration and thus belong to same group ie. alkali metal. Down the group the size of atoms inereases and so the distance of valence shell electron from nucleus increases and ionisation energy decreases. Hence sodium (Na) has lowest first ionisation energy. (a) Critical temperature « vanderwaal constant(a) maximum "a" = gas with maximum T, => easiest liquification = NH, @ HOH ® CHONe ® HOH S45 cH ® © SS CHO-CH, Dries ether delete CH, > CH, -Br—3->CH, -CH, (less than four 'C') @) Ch LL * mbromotoiene @) Nitrous oxide (N,O) occurs naturally in environment, In automobile engine, when fossil is burnt dinitrogen & dioxygen combine to yield NO & NO, ) Mn0; —>Mn? ; Se” gain a) Cloz—+€0, ; 26° loss 2) multiplying (1) by 2 and (2) by 5 to balance 2MnO, +5C,0,. —>2Mn* +10CO, on balancing charge; 2MnO, +SC,0,? +16H’ —>2Mn’ +10CO, +8H,O —ve and An, veQ.83 Q.84 Q.85 Q.86 Q.87 Q.88 Q.89 High P, Low T, favour product formation «@ Vanderwaal constant (a) sc forces of attraction (b) (en A If[A], = doubled, t,, = doubled © let BE. of x, , y, & xy are x kJ mol", 0.5x kJ mol and x kJ mol respectively 200 kImol eel 4x, +Ly, 94H aa AH =-200=3(BE),..., —2(BE), [} x(x)+— }x(o5x) + [1x(x)] BE. of X, = 800 kJ mol! @ Mech: cri cH cH -c1-8Sky c,-CH-CH AlCl, AH cH sa “ SS cation P) bi - O-oH Cpe, Camere Hydroperoxide OH ‘I oye Phenol MOM Q @ The molecule which forms zwitter ion is glycine. HOOC-CH, NH, —=00C-CH, -NH, Zwitter ion (a) a es ehcp Shop CHS HO b i nas = (dd) CO? Cr°“dimagnetic C10? Cr'“dimagnetie MnO,? —-Mn""dimagnetic MnO; Mn"’Paramagnetie ET [1] Unpaired electron is present so d-d transition is possible oD ao mM Belore ‘Alter transition tanstion ) tetrahedral geometry and dimagnetic Ni—>3d" 4s? sp’ hybridisation (b) Fe(CO), EAN = Z-0.N. + 2(C.N.) 6+ 10 6 only one central metal atonvion is present and it follows EAN rule, so it is mononuclear. @) Magnetic moment (u) = n(n +2)BM. (a) Co” + Is’2s’2p"3s°3p*4s°3d° at aad 4(4+2) = V24BM. (b) Cr’* ~+ s*2s*2p*3s*3p*4s°3d° AT a=3 w= 3642) =VI5 BM. (©) Fe™ — Is’2s?2p°3s? 3p°4s°3d° 4 {441} 4]4 w= \56+2) = V35BM.Q.93 Q.94 Q.9s Q.96 (d) Ni - Is*2s*2p°3s*3p*4s°3d* CH3COOH +PCls — CHyCOCl 1 4 w= 2242) =V8 BM. () effect is caused by more Electronegative atom eg No,,Cl © -NO, group is meta-directing group No, NO, : vou (Less stable due to more e~ withdrawing effect, of -NO,) No, No, No, « 4, 1 ye ¥ ¥ (More stable due to less e- withdrawing effect of -NO,) (b) CH, =CH- (d) When carboxylie acid reacts with PCl,, acid chloride formed and acid chloride on reaction with benzene (or its derivatives) forms ketones and this process is known as Freidal Craft acylation carried out in presence of anhydrous AICl,. ketones on reaction with Grignard reagent form tertiary alcohols, ae? Clls ~ COCKHs J CattyMeBr/ether on Ho -6 catty cats (2 — phenyl — butan — 2 — ol) Q.97 (b) Given ions (C2 Gi) He, (iii) O, (iv) NO Totale 14 3 17 15 Bondinge 1021010 ‘Anti 4 I 7 5 bonding e B.O. 10-4 2 10-7 10-5 2 2 2 2 3 S li =25 Q98 @) Down the group in Gr—16 hydrides M-H bond length increases (due to increases in size) Hence acidic nature increases Hence Kat while pKa Q.99 @ because Na,Cr,0, is hygroscopic hence give less priority. Q.100 (a) On strong heating only Li gives normal oxide while other alkali metlas gives peroxide or super oxide