Déplacements chimiques en ppm de différents types de protons (table 1)

CH3 CH2 CH
CH3-C 0.9 -C-CH2-C 1.3 -C-CH-C 1.5

(cyclique) 1.5 (en tête de pont) 2.2

CH3-C-C= 1.1 -C-CH2-C-C=C 1.7

CH3-C-O 1.4 -C-CH2-C-O 1.9 -C-CH-C-O 2

CH3-C=C 1.6 -C-CH2-C=C 2.3

CH3-Ar 2.3 -C-CH2-Ar 2.7 -C-CH-Ar 3

CH3-CO-R 2.2 -C-CH2-CO-R 2.4 -C-CH-CO-R 2.7

CH3-CO-Ar 2.6

CH3-CO-OR 2.0 -C-CH2-CO-OR 2.4

CH3-CO-Ar 2.4

CH3-CO-NR 2.0

CH3-OR 3.3 -C-CH2-OR 3.4 -C-CH-OR 3.7

CH3-OH 3.4 -C-CH2-OH 3.6 -C-CH-OH 3.9

CH3-O-Ar 3.8 -C-CH2-O-Ar 4.3

CH3-O-CO-R 3.7 C-CH2-O-CO-R 4.1 -C-CH-O-CO-R 4.8

CH3-N- 2.3 C-CH2-N 2.5 -C-CH-N- 2.8

CH3-N+ 3.3

CH3-S 2.1 C-CH2-S- 2.4

CH3-S-NO2 1.6 C-CH2-NO2 4.4 -C-CH-NO2 4.7

C-CH2-C-NO2 2.1

CH3-C=C-CO 2.0 C-CH2-C=C-CO 2.4

C=C(CH3)-CO 1.8

5.9

CH3-Cl 3.0 C-CH2-Cl 3.4 C-CH-Cl 4.0

CH3-C-Cl 1.5 C-CH2-C-Cl 1.7 C-CH-C-Cl 1.6

 CH3 CH2 CH
CH3-Br 2.7 C-CH2-Br 3.3 C-CH-Br 3.6

CH3-C-Br 1.7 C-CH2-C-Br 1.7 C-CH-C-Br 1.7

CH3-I 2.2 C-CH2-I 3.1 C-CH-I 4.2

CH3-C-I 1.9 C-CH2-C-I 1.8 C-CH-C-I 1.9

CH3-CN 2.0 C-CH2-CN 2.3 C-CH-CN 2.7

CO-CH2-Ar 3.8

0.3 0.7

2.6 3.1

Table 2

4.6 7.2

-C=CH2 4.3 -COOH 8.5-13

-C=CH- 5.1 -C=C-OH 11-17

-C=CH- (cyclique) 5.3 R-OH 0.7~5.5

R-C≡C-H 3.1 Ar-OH 4.2~7.1

Ar-H 7-9 Ar-OH (liaison H intramoléculaire) 10-14

-C=CH-CO 5.9 R-NH- 0.6~5

-CH=C-CO 6.8 Ar-NH- 2.9~4.7

R-CHO 9.9 R-CO-NH- 5~8

Ar-CHO 9.9 CHCl3 7.2

H-CO-O- 8 H2O ~5

H-CO-N- 8
Source Internet : http://www.ac-nancy-
metz.fr/enseign/physique/CHIM/Jumber/SPECTRO_RMN/Resonance_magn%C3%A9tique_nucl%C3%A9aire_fichier
s/Spectro_rmn.htm
 Table de déplacements chimiques 13C
Type de carbone δ (ppm)
Composés
Alcanes (sp3) R-CH3 8-30
R2-CH2- 15-55
R3-CH- 20-65

Alcènes (sp2) C=C 100-150

Alcynes (sp) C≡C 65-90

Aromatiques 110-175

Alcools C-OH 40-80

Ethers C-O-C 40-80

Amines C-NH2 30-65

Amides 160-180

Nitriles N≡C 110-135

Aldéhydes R-CHO 190-210

Cétones insaturées R-CO-R 200-220

R-CO-C=C 190-210

Esters R-COO-R’ 160-170

Acides carboxyliques R-COOH 160-185

Chlorure d’acyles R-CO-Cl 160-180

Anhydrides R-CO-O-CO-R 150-180

Halogènes C-I 0-40
C-Br 25-65

Source Internet :
http://www.sou.edu/chem/ch340_00/Spec%20Web%20ll/data%20tables/Relative%2013C%20Chemical%20Shifts.htm
 Constantes de couplage 1JCH

Composé J (Hz) Composé J (Hz) Composé J (Hz)

CH3-CH3 124.9 CH3-NH2 133.0 CH2-Cl2 178.0

CH3-CH2-CH3 119.2 CH3-OH 141.0 CH-Cl3 209.0

(CH3)3-CH 114.2 CH3-Cl 150.0

123.0 128.0 134.0

161.0 205.0

CH2=CH2 156.2 CH3-CH=O 172.4 NH2-CH=O 188.3

C6H6 159.0

249.0 251.0 269.0

Constantes de couplage 2JCH

Composé J (Hz) Composé J (Hz) Composé J (Hz)

CH3-CH3 -4.5 CH3-C-Cl3 5.9 CH3-CH=O 26.7

CH2=CH2 -2.4 (CH3)2-C=0 5.5 CH2=CH- 26.9

CH=0

C6H6 1.0

49.3 61.0

Référence : Silverstein, Bassler et Morill, Identification spectrométrique de composés organiques, Traduction française
de la 5ème édition, 1998, De Boeck Université, p. 247
 Table de déplacements chimiques 31P
H3PO4 = 0 ppm

Type shift ranges

CPH2 -150 to -120 ppm
C2PH -100 to 80ppm
C3 P -60 to -10 ppm
C2PHal 80 to 150 ppm
P(NR)3 115 to 130 ppm
P(OR)3 125 to 145 ppm
P(SR)3 110 to 120 ppm
PHal3 120 to 225 ppm
P(OR)2Hal 140 to 190 ppm
CPHal2 160 to 200ppm
CPHalN 165 to 185 ppm
O=PHal3 -80 to 5 ppm
O=P(OR)Hal2 -30 to 15 ppm
O=P(OR)2Hal -20 to 25 ppm
O=P(OR)3 -20 to 0 ppm
S=P(OR)3 60 to 75 ppm
CP(=O)(OR)2 -5 to 70 ppm
CP(=S)(OR)2 80 to 110 ppm
CP(=O)(OH)2 -5 to 25 ppm
(RO)2POH 0 to 20 ppm
C2P(=O)OR 0 to 60 ppm
CP(=O)Hal2 5 top 70 ppm
CP(=O)HalN 25 to 50 ppm
C3P=OC3P=S 20 to 60 ppm
C2P(=O)Hal 40 to 90 ppm
P(OR)5 -75 to -5 ppm
C4P+Hal- -5 to 30 ppm
Ar3P=CR2 5 to 25 ppm

Source Internet :
http://www.chem.uni-potsdam.de/~thomas/index.php?op=modload&name=PagEd&page_id=611