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CHEMISTRY PAPER

SECTION B

NOTE: Do any 10 question .Each carry equal marks.

Qno1: what are isotopes.Explain the different isotopesof hydrogen.

Qno2: Describe two methods for the pepration of water gas and give two
methods for the separation ofpure hydrogen form.

Qno3: Refer to the list of the given copmpounds:

Compund A B C D
Specific Carnallite Plaster Of Bleaching Baking Soda
Name Paris Powder

 Write the formula of A & D.


 The equation for the prepration of B.
 Give only one common use of B.
 Give the equation for the reaction of C with HCL.

Qno4: Give the refining of almunium of hook’s electrolytic method(no digram


need).

Qno5: What is aqua regia ? How does gold dissolve in it? Give the reaction

Qno6: Describe the prepration of chlorine gas by castnerkellnear cell or nelson


cell.

Qno7: Define isomerism.Give its types with examples.

Qno8: Define the following.

1. Polymerization
2. Homologous series

Qno9: Draw and explain the orbital structure ot Acetylene methods of its
preparation.
Qno10: Give mechanism of these electrophilic substitutionreaction of Benzene.

1.Friedel-Craft acylation

2.Sulphonation

Qno11: Give the reaction of Benzene with Chlorine:

* In presence of Lewis acid catalyst

*In presence of sunlight

Qno12: Benzene prepared commercially from petroleum?

Qno13 : What is meant by Elimination reaction? Explain the

mechanism of unimolecular elimination reaction (E1)

Qno14: Write the chemical equations to show that products will

be formed when CH3MgCl reacts with:

(i)CO2

(ii)acetone

(iii)Methyl chloride

(iv)water

Qno15: Why do alky; hallide gines SN2 machanism while 3 alkyl halide gives SN2
mechanism.
SECTION C

NOTE: Do any 3 parts of your own choice ,2 parts from Q1 and 1 from Q2.

Qno1

a) What is orientation in Benzene? Explain orientation in mono substitution


benzene .Give the name of ortho-para meta directing group
OR
Give Kekule's structure of Benzene. Write the objections against it. How
were these objections removed
(b) How is Soda ash manufactured by Ammonia Solvay process? Draw the
flow chart also.
(c) Give the similarities and dissimilarities of Hydrogen with the elements
groups IA and VIIA.
Qno2:
(a) Define Polymerization. How many types of Polymerizations are there?
Give the preparation of following:
*PVC
*Bakelite

(b) What is B-Elimination reaction? Write the mechanism of E, and E2


reactions.

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