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EE - Unit 4.ppt (Compatibility Mode)
EE - Unit 4.ppt (Compatibility Mode)
Chlorination & other disinfection methods Chlorination & other disinfection methods
♦ Sterilization: Process of destroying pathogenic & non-pathogenic organisms Mechanism of Disinfection
in water Act on cell protein to inactivate the critical enzyme systems essential for
♦ Disinfection: Process of destroying pathogenic organisms only in water microbial life
♦ Depends on the nature of disinfectant & type of microbes present Damage to cell wall
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Chlorination & other disinfection methods Chlorination & other disinfection methods
Steps involved Methods of disinfection
1. Penetration of disinfectant through the cell wall 1. Chlorination
Cell wall is negatively charged 2. Ozonation
HOCl 80 to 100 times more powerful than OCl- 4. Excess lime process
5. Application of iodine or bromine
2. Reaction with enzyme within the cell wall
6. Potassium permanganate
Mostly neutral ions are more active compared to anions
7. Metal ions Silver ions (bactericidal), Copper (algicidal & fungicidal)
Cl2, O3, Chlorine dioxide Inactivate the critical cell matter
8. Alkali and acids pH < 3 or >11
Chlorination & other disinfection methods Chlorination & other disinfection methods
Chlorination: 1. Chlorination:
Chlorine (Cl), Atomic wt = 35.45, Melting point = 101.5 °C, Boiling point = 34.5
°C
Action of Chlorine: Free available chlorine Vs Combined chlorine
Disinfecting power ∝ Contact time X Chlorine concentration
Determination of chlorine dosage: Residual of 0.2 mg/l after 20 minutes of
contact period
Chlorine demand = Chlorine added (–) Residual chlorine
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Chlorination & other disinfection methods Chlorination & other disinfection methods
1. Chlorination: 1. Chlorination
A. How is chlorine applied? B. Forms of chlorination: Depends on the point of chlorine application
Compressed Cl2 gas Stored in 1. Plain chlorination:
cylinders chlorine solution (most
Surface water with no other treatment
commonly used)
Used: Low turbid waters, unpolluted source, emergencies
In powder form as calcium
hypochlorites or sodium High organic content High Cl2 dose
hypochlorite
Dosage – 0.5 to 1 mg/l
Chlorine dosage ∝ Volume of flow
and chlorine demand of water 2. Prechlorination:
Application of chlorine before any other treatment
Chlorination & other disinfection methods Chlorination & other disinfection methods
1. Chlorination
1. Chlorination
B. Forms of chlorination:
B. Forms of chlorination: Depends on the point of application
4. Break point chlorination or Free residual chlorination
3. Post chlorination:
Only free Cl2 exists Powerful disinfectant
Addition of Cl2 after all other treatment
Common practice
Residual Cl2 at the P.O.E = 0.1 to 0.2 mg/l after a contact period of 20 minutes
4. Double chlorination:
Cl2 application at two or more points
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Chlorination & other disinfection methods Chlorination & other disinfection methods
1. Chlorination 1. Chlorination
B. Forms of chlorination: Depends on the point of application B. Forms of chlorination: Depends on the point of application
5. Super chlorination: 6. Dechlorination:
Highly polluted waters & need for quick disinfection Remove excess Cl2 from water causing taste problems
Cl2 applied beyond the stage of break point to maintain a residual chlorine Residual chlorine after dechlorination = 0.1 to 0.2 mg/l
after break point of 1 to 2 mg/l
Methods:
Dosage = 5 to 15 mg/L Aeration
30 to 60 min contact period required Adding chemicals like sodium thiosulphate, sodium metabisulphate,
sodium sulphite, sodium bisulphite, & sulphur dioxide
High bacterial removal Activated carbon
5. Form of chlorination & contact time On-site Ozone generators due to its
unstability
Disinfection by free chlorine – 30 minutes
Dosage – 2 to 3 mg/L
Combined Cl2 i.e. chloramines – 60 minutes
Removes color, T&O
6. Type & concentration of microbes:
Highly unstable & cannot be stored
Discrete or Floc type
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Other disinfection methods Other disinfection methods
3. UV light disinfection:
4. Excess lime process:
Wavelengths = 2000 to 3900 A°
Softening + disinfection
Destroys all types of bacteria & viruses
Excess lime in water increase pH. pH > 9.5 kills most of the bacteria (99
Low- pressure mercury vapor lamps to 100%)
No T&O problems & no danger of Dosage – 14 to 45 mg/L of excess lime
overdose
Need Recarbonation to remove excess lime
No residual effect for protection
Obsolete
Not suitable for highly turbid waters
High cost & needs technical skills
5. Iodine & Bromine addition:
Used for pools, small systems
Dosage – 8 to 10 mg/L
Contact time = 5 min
Produces medicinal taste to water
Expensive than chlorine
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