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Clariant Mining Solutions

PHOSPHATE
Clariant Solutions
FOR PHOSPHATE

»Committed to Enhancing
Phosphate Production«


For over half a century, Clariant has been the market leader in ONE OF CLARIANT’S
developing and supplying specialized reagents that enhance the value production facilities –
Morocco
of mineral ores around the world.

With local infrastructure in key Phosphate production areas such as


North Africa, North America and Brazil, and a presence in nine global
geographic regions, Clariant is well positioned to help you address
your key technical challenges with a wide range of products.

With comprehensive global logistics, localized production and on-site


service, Clariant is able to ensure our Phosphate customers continuity
of supply, today and as their needs grow.

Let the global Clariant Phosphate ore team show you how we can give
you “Performance and Value Delivered.”

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Phosphate
BENEFICIATION PROCESS
Flotation Collectors 3 Dust Control Agents 2

Feed

Emulsifiers Dust Control


for Explosives 1 Agents 2

Tailings

Phosphate Rock + H2SO4


Phosphate Rock + H3PO4

Phosphoric
Acid Phosphate Rock + H2SO4
4
Defoamers
Accelerators 6 Accelerators 6
H3PO4

Filter Aids 5 Gypsum


TSP SSP

H3PO4

NH3
Granulation
MAP, DAP
Antidust Additives 10
Anticaking
Granulation Aids 7 Additives 9

Granulation Scrubber
Defoamers 4

Colorants 8 Antidust Additives 10

1 2 3 4 5 6 7 8 9 10
EMULSIFIERS DUST CONTROL COLLECTORS DEFOAMERS FILTER AIDS ACCELERATORS GRANULATION COLORANTS ANTICAKING ANTIDUST
FOR EXPLOSIVES AGENTS For direct and reverse For Phosphoric acid To improve dewatering, To improve the AIDS ADDITIVES ADDITIVES
Consistently reliable To keep control of dust flotation of Phosphate attack reactors and filtering and cake efficiency of the attack To grow more product in the To prevent To reduce dust in
emulsions with long on roads, stockpiles, (silica, carbonates and granulation scrubbers formation of Phosphate rock in consistent granules marketplace agglomeration in handling
term stability conveyor belts, railway dolomite gangue) Example Products: Example Products: making SSP and TSP Example Products: storage Example Product:
cars, trucks and tailings Example Products: FLOTIGAM V 5689 FLOTICOR FL 35747 Example Products: FERTALA 4938 Refer to Clariant’s Example Products: FERTALA 7155 (MAP)
Refer to Clariant’s FLOTIGAM 5806 FLOTICOR DF 7283 FLOTICOR FL 35749 FERTALA 6009 FERTALA 4968 Fertilizer Additives FERTALA 4900 (NPK)
Emulsifiers for Refer to Clariant’s FLOTINOR SM 15 FLOTICOR DF 7332 (SSP reaction) brochure for product FERTALA 4902 (DAP) Refer to Clariant’s
Explosives brochure Processing Aids FLOTINOR V 2711 FERTALA 7039 recommendations FERTALA 7286 (TSP) Fertilizer Additives
for product brochure for product FLOTIGAM 3135 (TSP reaction) brochure for product
recommendations recommendations FLOTINOR 7004 Refer to Clariant’s recommendations
FLOTINOR FS 2 Fertilizer Additives
FLOTINOR 7092 brochure for product
FLOTINOR 7093 recommendations

2 PHOSPHATE 3
Clariant Phosphate
TECHNOLOGY OVERVIEW
1. EMULSIFIERS FOR EXPLOSIVES RECOMMENDED PRODUCTS

· To prepare consistently reliable emulsions with long term stability Refer to Clariant‘s Emulsifiers for Explosives brochure for additional details

2. DUST CONTROL RECOMMENDED PRODUCTS

· To manage dust on roads, stockpiles, conveyor belts, railway cars, trucks and tailings Refer to Clariant‘s Processing Aids Brochure for product recommendations

3. FLOTATION REAGENTS RECOMMENDED PRODUCTS

· A wide range of collectors for the flotation of Phosphate rock, with customized solutions for each type of Phosphate rock APPLICATIONS FLOTATION TYPE CLARIANT PRODUCT*
· Specialty fatty acids and blends for direct flotation of Phosphate Phosphate Flotation Direct (Collectors) FLOTIGAM 5806
· Amines and Phosphoric Acid Ethers for reverse flotation of Phosphate FLOTINOR 7004
· Customized blends of Phosphate esters and ether amines to beneficiate difficult to process ores FLOTINOR 7085
· Specialty collectors for Dolomite, a growing challenge in the global Phosphate industry FLOTINOR FS 2
FLOTINOR FS 5
FLOTINOR FS 34
FLOTINOR FS 100

Direct (Modifiers) FLOTINOR 5730 (for Apatite)

Carbonaceous/Silicaceous/ Reverse (Collectors) FLOTINOR SM 15


Dolomitic Gangue FLOTIGAM 3135
FLOTINOR V 2711
FLOTINOR 7092
FLOTINOR 7093

Barite Reverse (Collector) FLOTINOR 7089

Reverse (Frother) FLOTANOL 123/93

4. DEFOAMERS FOR PHOSPHORIC ACID PRODUCTION RECOMMENDED PRODUCTS

· Phosphoric acid defoamers to control foam in attack reactors , evaporators, and granulation scrubbers DESCRIPTION CLARIANT PRODUCT*
· Product range includes traditional oil based defoamers and equipment-friendly water based defoamers that minimize degradation of rubber seals Water based FLOTIGAM V 5689
Oil based FLOTICOR DF 7283
Oil based FLOTICOR DF 7284
Water based FLOTICOR DF 7332

5. PHOSPHORIC ACID FILTER AIDS RECOMMENDED PRODUCTS

· To improve dewatering, filtering, and cake formation FLOTICOR FL 35747


FLOTICOR FL 35749
FLOTICOR FL 7188

6. ACCELERATORS RECOMMENDED PRODUCTS

· To improve the efficiency of the attack of sulfuric acid or phosphoric acid on Phosphate rock in making SSP and TSP APPLICATIONS CLARIANT PRODUCT*

SSP FERTALA 6009


TSP FERTALA 7039

7. GRANULATION AIDS RECOMMENDED PRODUCTS

· To grow more consistent granules in granular fertilizers FERTALA 4938


· Throughput is optimized as fewer oversize and undersize granules are formed and recycled FERTALA 4968

8. COLORANTS RECOMMENDED PRODUCTS

· To differentiate your products in the market place Specific recommendations provided upon request

9. ANTICAKING ADDITIVES RECOMMENDED PRODUCTS

· To help fertilizers remain flowable and easy to use APPLICATIONS CLARIANT PRODUCT*
· Products include concentrates for dilution by the customer, wax based solutions and oil based solutions that can be tailored to the needs of each customer
NPK Complex Fertilizers FERTALA 4900
· Refer to Clariant‘s Fertilizer Additives brochure for product recommendations
DAP FERTALA 4902
TSP FERTALA 7286

10. ANTIDUST ADDITIVES RECOMMENDED PRODUCTS

· Dust control for MAP, DAP, TSP, SSP, NPK and other Phosphate fertilizers APPLICATIONS CLARIANT PRODUCT*
· Cost-effective solutions customized to the individual needs of customers, including considerations such as REACH registration, renewable content, etc.
TSP dust control FERTALA 7258
· Refer to Clariant‘s Processing Aids Brochure for product recommendations
MAP dust control FERTALA 7155

4 PHOSPHATE 5
CLARIANT MINING SOLUTIONS
2750 Technology Forest Blvd.
The Woodlands, Texas 77381
Tel: +1 281-465-9100
Fax: +1 281-465-9200

WWW.MINING.CLARIANT.COM

This information corresponds to the present state of our knowledge and is intended as a general descrip-
tion of our products and their possible applications. Clariant makes no warranties, express or implied,
as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes no liability
in connection with any use of this information. Any user of this product is responsible for determining
the suitability of Clariant’s products for its particular application. * Nothing included in this information
waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise
in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes
in our products and applicable national and international regulations and laws, the status of our products
could change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet information before
handling any of these products. For additional information, please contact Clariant.® Trademark of
Clariant registered in numerous countries.

* For sales to customers located within the United States and Canada the following applies in addition:
NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
CMS-071514

FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE.

© 2014 Clariant International AG, Rothausstrasse 61, 4132 Muttenz, Schweiz


® Product and service marks protected by Clariant

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