1.

Write chemical equations for the following reactions:

(i) Reaction of ethanolic NH3 with C2H5Cl.

(ii) Ammonolysis of benzyl chloride and reaction of amine so formed with two moles of CH3Cl.

2. Arrange the following compounds in an increasing order of basic strengths in their aqueous solutions:

NH3, CH3NH2, (CH3)2NH, (CH3)3N 

3. Arrange the following in increasing order of their basic strength in aqueous solution: CH 3.NH2, (CH3)3N, (CH3)2NH 

4. Draw the structure of following compounds

1)N-Ethyl-N-methylethanamine, 2)N-Methylpropan-2-amine, 3) 2, 4, 6-Tribromoaniline 4)N, N Dimethylamine,

5) N, N-Dimethylbutanamine.

5. These questions consist of two statements, each printed as Assertion and Reason

i). Assertion : Aromatic 1°amines can be prepared by Gabriel phthalimide synthesis.

Reason : Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.

ii). Assertion : Only a small amount of HCl is required in the reduction of nitro compounds with iron
scrap and HCl in the presence of steam.
Reason : FeCl2 formed gets hydrolysed to release HCl during the reaction.

3. Assertion : Amines are basic in nature.

Reason : Amines have lone pair of electrons on nitrogen atom.

4. Assertion : Acetanilide is less basic than aniline.

Reason : Acetylation of aniline results in decrease of electron density on nitrogen.

5. Assertion : Nitration of aniline can be conveniently done by protecting the amino group by
acetylation.
Reason : Acetylation increases the electron-density in the benzene ring.