Name: Kathleen L.

Pagilagan
15/15
Activity Name: Problem Set 2.2
Activity Topic: Chemical Equilibria
SCORE

III. Tutor – Calculate K from Equilibrium Concentrations

Some COCl2 is placed in a sealed flask and heated to 728 K. When equilibrium is reached, the
flask is found to contain COCl2 (9.57×10-4 M), CO (2.05×10-2 M), and Cl2 (2.26×10-2 M). What is
the value of the equilibrium constant for this reaction at 728 K?

COCl2(g)   CO(g) + Cl2(g)         K = 

IV. Tutor – Determining the Equilibrium Constant I

Carbon tetrachloride can be produced by the following reaction:
CS2(g) + 3 Cl2(g) ⇄ S2Cl2(g) + CCl4(g)
In an experiment, 0.120 mol of CS2 and 0.360 mol of Cl2 were placed in a 1.00-L flask at a
particular temperature. After equilibrium has been achieved, the mixture contains 0.020 mol
CCl4. Calculate the value of K under the experimental conditions.

K = 
V. Master – Reaction Quotient: Calculate
Q2: Consider the following reaction where Kc = 83.3 at 500 K.

PCl3(g) + Cl2(g)  PCl5(g)

A reaction mixture was found to contain 3.99×10-2 moles of PCl3(g), 3.63×10-2 moles of Cl2(g)

and 9.08×10-2 moles of PCl5(g), in a 1.00 liter container.

Is the reaction at equilibrium?

If not, what direction must it run in order to reach equilibrium?

The reaction quotient, Qc, equals  .

The reactionfill in the blank 2

A. must run in the forward direction to reach equilibrium.
B. must run in the reverse direction to reach equilibrium.
C. is at equilibrium.

Q3: Consider the following reaction where Kc = 7.00×10-5 at 673 K.

NH4I(s)  NH3(g) + HI(g)

A reaction mixture was found to contain 5.20×10-2 moles of NH4I(s), 1.14×10-2 moles of NH3(g),

and 8.37×10-3 moles of HI(g), in a 1.00 liter container.

Is the reaction at equilibrium?

If not, what direction must it run in order to reach equilibrium?

The reaction quotient, Qc, equals  .

The reactionfill in the blank 2

A. must run in the forward direction to reach equilibrium.
B. must run in the reverse direction to reach equilibrium.
C. is at equilibrium.
VI. Master – Equilibrium Concentrations: Calculate
Q1: The equilibrium constant, Kc, for the following reaction is 10.5 at 350 K.

2CH2Cl2(g)  CH4(g) + CCl4(g)

Calculate the equilibrium concentrations of reactant and products when 0.278 moles

of CH2Cl2 are introduced into a 1.00 L vessel at 350 K.
[CH2Cl2] =  M
[CH4] =  M
[CCl4] =  M

Q3: The equilibrium constant, Kc, for the following reaction is 1.80×10-4 at 298 K.

NH4HS(s)  NH3(g) + H2S(g)

Calculate the equilibrium concentration of H2S when 0.202 moles of NH4HS(s) are introduced

into a 1.00 L vessel at 298 K.

[H2S] =   M
XIII. Master – Calculate K: From Initial ‘ One Final Concentration
Q1: A student ran the following reaction in the laboratory at 720 K:

H2(g) + I2(g)       2HI(g)

When she introduced 0.211 moles of H2(g) and 0.237 moles of I2(g) into a 1.00 liter container,
she found the equilibrium concentration of HI(g) to be 0.348 M.

Calculate the equilibrium constant, Kc, she obtained for this reaction.

Kc = 

Q2: The equilibrium constant, Kc, for the following reaction is 1.73×10-3 at 547 K.

COCl2(g)  CO(g) + Cl2(g)

When a sufficiently large sample of COCl2(g) is introduced into an evacuated vessel at 547 K,
the equilibrium concentration of Cl2(g) is found to be 0.300 M.

Calculate the concentration of COCl2 in the equilibrium mixture.   M