SAFETY DATA SHEET

1. Identification
Product identifier Isotol 80
Other means of None known
identification
Recommended use Cleaner
Recommended restrictions Not available
Manufacturer/Importer/Supplier/Distributer information
Manufacturer: Mancuso Chemicals Limited
5725 Progress Street
Niagara Falls, ON, Canada
L2G 0C1
Company telephone 1-905-357-3626
Emergency telephone 1-800-567-7455 (Terrapure Environmental)
Supplier Refer to Manufacturer

2. Hazard(s) identification
Physical hazards Flammable liquid Category 3
Health hazards Acute toxicity, Oral Category 5
Skin corrosion/irritation Category 2
Serious eye damage/irritation Category 2a
Reproductive toxicity Category 1b
Specific organ toxicity, single exposure Category 3 (Respiratory system)
Label elements

Signal word Danger

Hazard statement Flammable liquid and vapor. May be harmful if swallowed. May be harmful if inhaled. May cause
respiratory tract irritation. Causes skin irritation. Causes serious eye irritation. May damage fertility or
the unborn child.
Precautionary statement
Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear
protective gloves/eye protection/face protection.
Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. IF ON SKIN
(or hair): take off immediately all contaminated clothing. Rinse skin with water. In case of fire: use
dry sand, dry chemical or alcohol resistant foam to extinguish.
Storage Keep container tightly closed. Store in a well-ventilated place. Keep cool. dGround and bond
container and receiving equipment. Use explosion proof electrical/ventilation/lighting equipment. Use
non-sparking tools. Take precaution to prevent static discharges.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazards not otherwise None known.
classified
Supplemental information None.

3. Composition/information on ingredients
Chemical name Common name and synonyms CAS Number % w/w
1-Methyl-2-pyrrolidinone N-Methyl-2-pyrrolidinone, NMP 872-50-4 60-70
Tripropylene glycol methyl ether 25498-49-1 20-30
Ethyl 3-ethoxy propionate 763-69-9 20-30

4. First-aid measures
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 Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute
and delayed
Indication of immediate
medical attention and
special treatment needed
General information
5. Fire-fighting measures
Suitable extinguishing
media
Unsuitable extinguishing
media
Specific hazards arising
from the chemical
Special protective equipment
and precautions for
firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Hazardous combustion
products
Isotol 80
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Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a POISON CENTER or doctor/physician.
Take off immediately all contaminated clothing. Wash off with soap and water. Get medical
advice/attention if you feel unwell. Get medical attention if irritation develops and persists.
Wash contaminated clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and
persists.
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use
mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid
of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation.
Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
Take off immediately all contaminated clothing. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible).
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.
Water spray. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).
Not available.
Do not allow run-off from firefighting to enter drains or water courses.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In case of fire and/or explosion do not breathe fumes. Use water spray to cool fully closed
containers.
Use standard firefighting procedures and consider the hazards of other involved materials.
Flammable liquid
Toxic fumes, gases or vapours may evolve on burning. Carbon oxides. Hydrocarbons. Nitrogen
oxides (NOx).
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6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning
up
Environmental
precautions
7. Handling and storage
Precautions for safe
handling
Conditions for safe
storage, including any
incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
Canada. Ontario OELs
Components
1-Methyl-2-pyrrolidinone (CAS 972-50-4)
Ethyl-3-ethoxy propionate (CAS 763-69-9)
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
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Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate
all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other
non-combustible material and transfer to containers for later disposal. Wipe up with absorbent
material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never
return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from open flames, hot surfaces and sources of ignition. Do not breathe
mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste
or swallow. When using, do not eat, drink or smoke. Should be handled in closed systems, if
possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective
equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse.
Observe good industrial hygiene practices.
Store locked up. Keep away from heat, sparks and open flame. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an
area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS)
Type Value
TWA 400 mg/m3
TWA 50 ppm
300 mg/m3
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should
be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash
station
Chemical respirator with organic vapor cartridge and full facepiece.
Wear appropriate chemical-resistant gloves.
Wear appropriate chemical-resistant clothing. Use of an impervious apron is recommended.
Chemical respirator with organic vapor cartridge and full facepiece
Wear appropriate thermal protective clothing, when necessary.
When using do not smoke. Keep away from food and drink. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or smoking.
Routinely wash work clothing and protective equipment to remove contaminants.
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9. Physical and chemical properties
Appearance
Physical state Liquid
Form Liquid
Color Clear to light yellow
Odor Slovent like
Odor Threshold Not available
pH Not applicable
Melting point/Freezing point Not available
Initial boiling point 165 °C
Flash point 57 °C
Evaporation rate Not available
Flammability (solid, gas) Not applicable
Lower explosive limit Not available
Upper explosive limit Not available
Vapor pressure Not available
Vapor density Not available
Specific gravity 1.005 g/ml
Solubility(ies)
Water solubility Not soluble
Partition coefficient Not available
(water/octanol)
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity <10 cP

10. Stability and reactivity

Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
Avoid heat, sparks, open flames and other ignition sources.
Thermal decomposition may release toxic gases or fumes. Carbon oxides. Hydrocarbons. Nitrogen
oxides (NOx)

11. Toxicological information

Information on likely routes of exposure
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Skin contact Causes skin irritation.
Eye contact Causes severe eye irritation.
Ingestion May be harmful if swallowed.
Most important Not available.
symptoms/effects, acute
and mild

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 Components Species Test Results
1-Methyl-2-pyrrolidinone (CAS
972-50-4)
Acute
Oral LD50 Rat 3914 mg/kg
Inhalation LC50 Rat >5100 ppm (5 h)
Dermal LD50 Rabbit 8000 mg/kg
Tripropylene glycol methyl
ether (CAS 25498-49-1)
Acute
Oral LD50 Rat 3200 mg/kg
Inhalation LC50 Not available
Dermal LD50 Not available
Ethyl 3 -ethoxypropionate
(CAS 763-69-9)
Acute
Oral LD50 Rat >5000 mg/kg
Inhalation LC50 Rat >998 ppm (6 h)
Dermal LD50 Rabbit 4080 mg/kg

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory Not available
sensitization
Skin sensitization Not available
Germ cell mutagenicity Not available
Carcinogenicity No component of this product at levels greater than or equal to 0.1% is identified as a probable,
possible or confirmed human carcinogen.
Reproductive toxicity Not available
Specific organ toxicity
Single exposure Inhalation – May cause respiratory tract irritation.
Repeated exposure Not available
Aspiration toxicity Not available
Chronic effects Not available

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12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
1-Methyl-2-pyrrolidinone (CAS
972-50-4)
Acute (aquatic)
Crustacea EC50 Water flea (Daphnia magna) >1000 mg/l (24 h)
Fish LC50 Leuciscus idus (Golden orfe) >500 mg/l (96 h)
Ethyl 3 -ethoxypropionate
(CAS 763-69-9)
Acute (aquatic)
Crustacea EC50 Water flea (Daphnia magna) >479.7 mg/l (48 h)
Fish LC50 Pimephales promelas (fathead minnow) 45.3 mg/l (96 h)
Persistence and Not available
degradability

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal Dispose in accordance with all applicable regulations.
regulations
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the
waste disposal company.
Waste from residues / Dispose of in accordance with local regulations. Empty containers or liners may retain some
unused products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated Empty containers should be taken to an approved waste handling site for recycling or disposal.
packaging
Since emptied containers may retain product residue, follow label warnings even after
container is emptied.

14. Transport information

DOT
UN Number UN 1993
Proper shipping Flammable Liquid, N.O.S. (Ethyl 3-ethoxy Propionate)
name
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group III

IATA
UN Number UN 1993
Proper shipping Flammable Liquid, N.O.S. (Ethyl 3-ethoxy Propionate)
name
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards
ERG code
Passenger and cargo
aircraft
Cargo aircraft only
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 IMDG
UN Number UN 1993
Proper shipping Flammable Liquid, N.O.S. (Ethyl 3-ethoxy Propionate)
name
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant No

15. Regulatory information

US federal regulations
TSCA Section 12(b) Export All hazardous products listed.
Notification (40 CFR 707, Subpt. D)
CERCLA Hazardous Substance List
(40 CFR 302.4)
OSHA Specifically Regulated Not listed
Substances (29 CFR 1910.1001-
1050)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard No
Delayed Hazard No
Fire Hazard Yes
Pressure Hazard No
Reactivity Hazard No

16. Other information, including date of preparation or last revision

Issue date August 16, 2022
Revision 1

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