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Deformação de Alimentos
Deformação de Alimentos
Deformação de Alimentos
a r t i c l e i n f o a b s t r a c t
Article history: A comprehensive poromechanics-based modeling framework that can be used to model transport and
Received 17 February 2011 deformation in food materials under a variety of processing conditions and states (rubbery or glassy)
Received in revised form has been developed. Simplifications to the model equations have been developed, based on driving
26 August 2011
forces for deformation (moisture change and gas pressure development) and on the state of food
Accepted 1 September 2011
material for transport. The framework is applied to two completely different food processes (contact
Available online 16 September 2011
heating of hamburger patties and drying of potatoes). The modeling framework is implemented using
Keywords: total Lagrangian mesh for solid momentum balance and Eulerian mesh for transport equations, and
Mathematical modeling validated using experimental data. Transport in liquid phase dominates for both the processes, with
Food processing
hamburger patty shrinking with moisture loss for all moisture contents, while shrinkage in potato stops
Porous media
below a critical moisture content.
Solid mechanics
Pressure & 2011 Elsevier Ltd. All rights reserved.
Shrinkage
0009-2509/$ - see front matter & 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.ces.2011.09.001
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6483
generated pressure-driven flow during intensive heating pro- tensor, r, in the representative elementary volume (REV) around
cesses by Ni and Datta (1999), Halder et al. (2007) and the location (Lewis and Shrefler, 1998):
Yamsaengsung and Moreira (2002); nonequilibrium thermody- Z
1
namics based hybrid mixture theory approach towards Case-II r¼ r dV ð1Þ
V V
diffusion by Singh (2002) and Achanta (1995); and, more recently,
application of Flory–Rehner theory to predict swelling-pressure Now, total volume of an REV can be written as a sum of volumes
driven moisture transport in meat by van der Sman (2007). of the solid and the fluids present in the pores:
Fundamentals-based description of deformation in food mate- X
V ¼ Vs þ Vi ð2Þ
rials is even less frequent than the detailed description of i
transport itself. Two different approaches are generally followed:
either the experimental shrinkage data is empirically fitted as a Therefore, the total stress tensor can also be written as a sum of
function of moisture content, or the additivity of volumes of averages in the individual phase volumes:
different components is used to predict deformation from moist- Z XZ !
1
ure loss data (Mayor and Sereno, 2004; Katekawa and Silva, r¼ r dV þ r dV
V Vs i Vi
2006). Modeling of transport in deformable food materials as a Z X Z
Vs 1 Vi 1
solid mechanics problem and solving the linear momentum ¼ r dV þ r dV
V V s Vs V V i Vi
balance for the solid matrix is rare in food, although this approach X
i
is frequently used to study drying of some other materials such as ¼ es r s þ ðei r i Þ ð3Þ
wood and ceramics. Notable exceptions are study of hygrostress i
cracking (Izumi and Hayakawa, 1995), bread baking (Zhang et al.,
where ei and r i are, respectively, the volume fraction and the
2005) and microwave puffing of potatoes (Rakesh, 2010). For
volume-averaged stress of a phase, i. Given that shear stress is
detailed review of drying models that include shrinkage effects,
negligible in fluids, stress in a fluid, ri can be approximated as
including pioneering works by Perre and May (2001), Kowalski
(2000) and others, the reader is referred to the review by r i ¼ pi I ð4Þ
Katekawa and Silva (2006). Substituting fluid stresses from Eq. (4) in Eq. (3), we obtain
With this background, the current study is an attempt to X
develop a poromechanics-based modeling framework for the r ¼ es r s ðei pi ÞI
i
coupled physics of transport and large deformation in food X
materials. The macroscale governing equations are based on ¼ ð1fÞr s f ðSi pi ÞI
i
extended Biot’s theory of poromechanics (Lewis and Shrefler, !
X X
1998). Classical constitutive laws are used in both mass transport ¼ ð1fÞ r s þ ðSi pi ÞI ðSi pi ÞI ð5Þ
(Darcy and Fick’s laws) and conduction (Fourier’s law) and i i
deformation (hyperelastic solid) equations.
Defining the first term on the right-hand side of Eq. (5) as the
effective stress on the solid skeleton, r 0 , and the second term as
2. Mathematical model pore pressure, pf ð ¼ Sg pg þSw pw Þ, the well-known effective stress
principle of Terzaghi is recovered:
A mathematical model is developed that describes deforma- r ¼ r 0 pf I ð6Þ
tion and transport (energy and moisture) inside a food material
during thermal processing. First, the physics of deformation of the Now, by invoking the quasi-steady state assumption for deforma-
solid matrix is described, followed by a discussion on special tion (acceleration term equal to zero), the solid momentum
cases based on the driving mechanism behind deformation. Later, balance leads to divergence-free field of overall stress:
transport modeling in a deforming food material and special cases rr ¼0 ð7Þ
are described.
which implies divergence of effective stress is equal to gradient of
pore pressure:
2.1. Assumptions
r r 0 ¼ r pf ð8Þ
(1) Food is treated as a multiphase porous material, in which In case of two-phase flow, when the pores are occupied by liquid
all the phases are in continuum. (2) Local thermal equilibrium is water and gas (comprising air and water vapor), the pore
assumed, i.e., temperature is shared by all the phases. Also, pressure, pf, can also be written as pg Sw pc . Inserting this
pressure in the liquid water phase is given as the gas pressure relationship in the solid momentum balance (Eq. (8)), we obtain
minus the capillary pressure (or the water potential). (3) The solid
skeleton is an incompressible hyperelastic material. Solid volume r r 0 ¼ rpg rðSw pc Þ ð9Þ
remains constant during any process. Biological materials exhibit where the first term on the right-hand side is the gas pressure
non-linear stress–strain behavior, often following rubber and gradient, and the second term is a function of the temperature and
polymers (Ogden, 1972). For rubber, complex stress–strain beha- moisture content of the food material. Gas pressure gradients are
viors are accommodated using strain energy density functions. significant either for processes involving intensive internal vapor-
Neo-Hookean model is used in the present study, since this model ization such as microwave heating (Ni et al., 1999) or for processes
has been found to fit experimental data for rubber-like materials involving gas generation reactions such as carbon dioxide in bread
for large (30–70%) strains with sufficient accuracy. baking (Zhang et al., 2005). For most other processes, such as drying
and rehydration (soaking), gas is at atmospheric pressure and, thus,
2.2. Deformation of the solid matrix: model development for a the solid momentum balance reduces to
general case
r r 0 ¼ rðSw pc Þ ð10Þ
Macroscopic total stress tensor, r , at any given location in a In Eq. (10), capillary pressure, pc, has a physical meaning only when
food material can be defined as volumetric average of total stress capillary suction is the only attractive force between the solid
6484 A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497
Volume
surface and the liquid water. In the presence of other attractive
forces like monolayer surface adsorption, multilayer absorption, etc.,
water potential, Cw , is a more appropriate term. Kelvin’s law is
usually applied to relate water potential, Cw (expressed in units of
pressure) to water activity, aw (Lu and Likos, 2004):
RT Gradual Ideal
Cw ¼ lnðaw Þ ð11Þ Transition Transition
vw in foods
After replacing pc by Cw , Eq. (10) can be used for liquid water in
the presence of multiple attractive forces. On the other hand, some Critical
high moisture food materials (with water activity, aw 1), which Volume, V*
Mainly Vapor Liquid + Vapor Mainly Liquid
undergo a change in their capacity to hold water with temperature Transport Transport Transport
rise, require a different approach for estimation of pressure in liquid
water. van der Sman (2007) applied Flory–Rehner theory to estimate
swelling pressure (equal to pore pressure in the absence of gas Moisture Content
phase) for such materials (more in Section 3.1.3).
Fig. 1. Volume change vs. moisture content curve for a typical food material.
Fig. 2. Steps indicating multiplicative split in the deformation tensor, separating @cg
moisture, temperature and mechanical effects.
n g,G Þ ¼ I_
þ r ð~ ð25Þ
@t
@ðcg ov Þ
Large deformation: For large deformation analysis, a multi- n v,G Þ ¼ I_
þ r ð~ ð26Þ
@t
plicative split (Vujosevic and Lubarda, 2002) in deformation
gradient tensor, F, can be used to separate volume changes due @cw
n w,G Þ ¼ I_
þ r ð~ ð27Þ
to moisture and temperature changes from volume change due to @t
mechanical effects. As shown in Fig. 2, the material is first The energy equation is used to solve for temperature and the
assumed to go under stress-free deformations due to moisture mass conservation equations for their respective concentrations.
and temperature changes and, then, mechanical stresses act on The gas concentration, cg, is related to pressure by invoking the
this stress-free deformed material. The deformation tensor, F, can ideal gas law. Note that not all four equations are needed for all
be split as processes (Fig. 3). Just as the energy equation is needed only for
F ¼ FT FM Fel ð20Þ non-isothermal processes, the gas phase equation is solved only
in case of significant internal pressure generation when pressure
The dilatation (volume-changing) stress is related to elastic driven flow and/or deformation due to gas pressure gradients
Jacobian, Jel ¼ detðFel Þ, which is obtained as the ratio of total becomes important. Also, the vapor equation is rarely required as
volume change and volume change due to moisture and tem- vapor can be assumed to be at equilibrium with the liquid
perature effects (details in Section 3.1.2). Thermal Jacobian, moisture (more later).
JT ¼ detðFT Þ is often small for food materials and is usually In a deforming medium, since the solid has a finite velocity,
ignored. Moisture Jacobian, JM, can easily be obtained from ~
v s,G , the mass flux of a species, i, with respect to stationary
volume change vs. moisture content relationship (Fig. 1). observer, ~ n i,G , (used in Eqs. (24)–(27)) can be written as sum of
flux with respect to solid and flux due to movement of solid:
2.3.2. Processes with gas pressure as the driving mechanism ~
n i,G ¼ ~
n i,s þci~
v s,G ð28Þ
For some processes, such as microwave heating or bread-
baking, large internal pressure generation (due to water vapor in
microwave heating and carbon dioxide in baking) can cause
swelling/puffing of the material. In such cases, the gas pressure 2.4.2. Mass fluxes
gradient term of Eq. (9) (first term on the right-hand side) may Mass fluxes in an unsaturated porous medium can be attrib-
dominate. Swelling due to gas pressure in such cases can be much uted to two primary mechanisms—convection (for both gases and
larger than shrinkage due to moisture loss, and, therefore, stresses liquids) and binary diffusion (between vapor and air). Reynolds
and strains due to the latter can be ignored. In the absence of number is very low (usually less than one) for transport in food
thermal strains, the total strain is approximately equal to the materials and, therefore, Darcy’s law is applied to determine
mechanical strain: convective fluxes. For binary diffusion between vapor and air in
em e ð21Þ the gas phase, Fick’s law is used:
Fig. 3. A framework for modeling of transport and deformation in food materials based on the state of the material and its processing conditions.
Dry basis moisture content, M, is defined as than other relevant time scales for the process), vapor pressure
cw cw becomes a function of moisture and temperature (through Clau-
M¼ ¼ ð32Þ sius–Clapeyron equation and moisture sorption isotherms) and its
cs ð1fÞrs
conservation equation does not need to be solved. In such cases,
Taking density of solid, rs , as constant, moisture content, M, can vapor flux (ignoring gravity) can be written as
be expressed as M ¼ Mðcw , fÞ (where cw ¼ rw ew ), and Eq. (31) can !
be re-written as kg c2
n v,s ¼ rv
~ r pg Mv Ma Dbin rðpv ðMðcw , fÞ,TÞ=pg Þ
kw @p @M @p @M @p mg rg
n w,s ¼ rw
~ r pg c rcw c rf c rT rw~ g ! !
mw @M @cw @M @f @T
kg c2 pv
¼ rv þ Mv Ma Dbin 2 rpg Dv,cw rcw
kw mg rg pg
¼ rw ðrpg rw ~
g ÞDw,cw rcw Dw, f rfDw,T rT ð33Þ
mw
Dv, f rfDv,T rT ð35Þ
where diffusivity due to moisture gradient, Dw,cw , diffusivity due
to porosity gradient, Dw, f , and diffusivity due to temperature where vapor diffusivity due to moisture gradient, Dv,cw , vapor
gradient, Dw,T, are defined as diffusivity due to porosity gradient, Dv, f , and diffusivity due to
temperature gradient, Dv,T, are defined as
kw @pc @M !
Dw,cw ¼ rw
mw @M @cw c2 D @pv @M
Dv,cw ¼ Mv Ma bin
rg pg @M @cw
kw @pc @M
Dw, f ¼ rw !
mw @M @f
c2 Dbin @pv @M
Dv, f ¼ Mv Ma
kw @pc rg pg @M @f
Dw,T ¼ rw ð34Þ
mw @T !
Eqs. (24)–(27), along with fluxes from Eqs. (29), (30) and (33), c2 Dbin @pv
Dv,T ¼ Mv Ma ð36Þ
solid velocity, ~
v s,G , from solid momentum balance and an explicit rg pg @T
expression for evaporation rate, I, _ complete the model develop-
Now, adding liquid water and water vapor conservation equations
ment. Estimation of evaporation rate, however, is not always easy _ and inserting flux relationships,
to eliminate evaporation rate, I,
(Halder et al., 2010) and an accurate determination of I_ is possible
we obtain the equation for overall moisture balance
only in some special situations, e.g., when local equilibrium
between liquid water and vapor can be assumed. Details of @
ðcw Þ þ r ðcw~
v s,G Þ ¼ r ðK1 rpg þ Dcw rcw þ Df rf þ DT rTÞ ð37Þ
estimation of I_ are mentioned elsewhere (Halder et al., 2010). @t
where
2.4.3. Overall moisture equation !
kw kg c2 pv
If water vapor can be assumed to be in equilibrium with liquid K1 ¼ rw rv Mv Ma Dbin ð38Þ
water (i.e., time-scale required to achieve equilibrium is smaller
mw mg rg p2g
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6487
Dcw ¼ Dw,cw þ Dv,cw ð39Þ 2.5.1. Wet-rubbery state: liquid moisture transport as the
dominating mechanism
In the rubbery state, free shrinkage/swelling compensates for
Df ¼ Dw, f þ Dv, f ð40Þ
moisture loss/gain which means, at equilibrium, change in
volume of a food material is equal to the volume of water lost/
DT ¼ Dw,T þ Dv,T ð41Þ
gained (Section 2.3.1). During rehydration/dehydration of such
are the effective permeability and the effective diffusivities due to materials, the evaporation front stays at the surface of the
moisture concentration gradient, porosity gradient and tempera- material and there is no vapor generation or transport within
the food. So, the evaporation rate, I,_ is equal to zero, there is no
ture gradient, respectively. In Eq. (37), it is assumed that water
vapor can contribute to transport terms but not to accumulation gas pressure gradient term in Eq. (37), and the effective diffusiv-
term (this is because density of vapor is three orders of magnitude ities reduce to just those of liquid moisture. Therefore, the model
smaller than density of liquid water). reduces to Eq. (37) for moisture and Eq. (43) for temperature (gas
For a majority of food processes, moisture fluxes due to phase and vapor equations are not required), with solid velocity,
temperature, porosity and pressure gradients are considered ~
n v,G , from the solid momentum balance:
small as compared to that for moisture gradients (sometimes @T
without justification). The conditions under which these assump- ðreff cp,eff Þ þ ð~
n w,G rðcp,w TÞÞ ¼ r ðkeff rTÞ ð43Þ
@t
tions can be justified are:
For soft materials, shear modulus is very small as compared to
the bulk modulus, which means shear stresses (for an uncon-
Gas pressure is atmospheric ðrpg ¼ 0Þ.
strained material) that restrict free swelling/shrinkage are also
The material is either saturated (f cw =rw and the porosity
small, and volume change at every point in the material can be
gradient term can be merged with moisture gradient term) or
approximated by the free volume change, even under large
the material is rigid ðrf ¼ 0Þ.
moisture gradients. Thus, if the only deformation information
Water activity (in turn, capillary pressure, pc) is independent of
required is volume change at every point and estimation of
temperature gradient (DT ¼0).
stresses and shear strains is not important, solid momentum
balance can be skipped. Divergence in solid velocity can be
In such cases, the overall moisture balance reduces to the well-
estimated from the solid mass balance (assuming constant and
known equation:
uniform solid density):
@cw
þ r ðcw~
v s,G Þ ¼ r ðDcw rcw Þ ð42Þ @ðrs es Þ
@t þ r ðrs es vs,G Þ ¼ 0 ð44Þ
@t
After ignoring the flux due to solid velocity (again, usually done
without justification), Eq. (42) is extensively used in the food Ds es
þ es r vs,G ¼ 0 ð45Þ
literature to model drying-like processes. Its great advantage lies Dt
in the fact that rate of evaporation, I,_ is not required. Also,
1 Ds e s 1 Ds e w
effective diffusivity, Dcw , can be easily estimated by fitting r vs,G ¼ ¼ ð46Þ
es Dt 1ew Dt
experimentally observed drying curves. However, the rate of
evaporation may be required to solve Eqs. (24) and (25) (if where Ds =Dt stands for material derivative in the reference frame
pressure gradients are significant). of the solid. Divergence of solid velocity, vs,G, from Eq. (46) can
now be inserted in the liquid water and energy equations.
Free surfaces
No evaporation (Natural convection
or drip loss heat transfer)
1.8 cm
10 cm Drip loss only
Evaporation and
Heated Plate No axial displacement drip losses
(Heat transfer coefficient)
Schematic of the Simulated geometry
contact-heating process (showing deformation)
Free surfaces
Symmetry
Forced convection heat transfer
Plane
Surface evaporation moisture loss
2 cm
x cm
No axial displacement
Insulated for energy & moisture
equations
Cross-section of potato slab Simulated geometry
(perpendicular to length) (showing deformation)
Fig. 4. Schematic of the two processes simulated: (a) single-sided contact heating of hamburger patties, and (b) drying of potato slabs, showing the modeled geometry and
boundary conditions. Input parameters are listed in Tables 1 and 2.
2.50
3. Model implementation and validation
Meat can be processed and cooked in a variety of ways. For the temperature of 140 1C. As temperature rises, water at the surface
purpose of this study, single-sided contact heating of hamburger of the patty evaporates. Since ground meat is in a rubbery state,
patties (Fig. 4) bought from a local grocery store (USDA Nutrition the patty shrinks with loss of moisture, and, at equilibrium (in the
Database, 2010, entry no. 23557, 95% lean and 5% fat) is selected. absence of gradients of any temperature and moisture fields) the
A refrigerated hamburger patty of cylindrical shape (diameter shrinkage should be equal to the volume of water lost (Fig. 1).
10 cm and height 1.8 cm), initially stored at 5 1C, is heated on a With further rise in temperature, denaturation of muscle proteins
commercial griddle (HotZoneTM Griddle Model No. GR0215G, occurs, which leads to decrease in water holding capacity of the
Applica Consumer Products Inc., Miramar, Florida) at a fixed plate meat. Since the surface of meat in contact with the griddle gets
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6489
heated up quickly, the water holding capacity near the surface Deviatoric part of elastic deformation gradient is related to elastic
1=3
may drop faster as compared to the drop in moisture concentra- deformation gradient, Fel, and its dilatation part, Jel , as
tion due to evaporation. This leads to dripping of water from the 1=3
Fel ¼ Jel Fel ð54Þ
patty. The variables of interest for predicting quality and safety
aspects of meat cooking are temperature, moisture content, Now, to estimate elastic Jacobian, Jel, we need to calculate
shrinkage, evaporation rate and their histories. Jacobian due to moisture change, JM (Eq. (20)). This is easy, as
under stress-free conditions, a patty shrinks/swells by the amount
3.1.1. Problem details of moisture lost/gained. Let V be the REV volume at moisture
The patty is simulated as a 2D axisymmetric geometry, as the volume fraction, ew . Then, change in volume of REV can be
exchange of heat and mass with the outside environment does equated to change in volume of moisture in REV:
not have angular dependence and only a cross-section of the VV0 ¼ ew Vew,0 V0 ð55Þ
cylindrical patty needs to be simulated. The effect of gravity on
mass transfer is ignored as the effect of pressure gradients is V 1ew,0
JM ¼ ¼ ð56Þ
much larger on moisture velocity. Since the patty is in a soft and V0 1ew
rubbery state, evaporation stays on the surface during the entire Similarly, porosity at any time t, fðtÞ, can be determined using
cooking process. Even if a rigid glassy region develops at the incompressibility of the solid skeleton, equating the initial
heated surface, it is assumed to be small and its effect can be volume of solid in an REV to solid volume at time, t:
neglected. Therefore, according to the modeling framework
outlined in Fig. 3, the rubbery state of food can be selected. Also, ð1fðtÞÞVðtÞ ¼ ð1f0 ÞV0 ð57Þ
as the temperature gradients are significant, the energy equation
1f0 1f0
needs to be solved along with the moisture transport and solid fðtÞ ¼ 1 ¼ 1 ð58Þ
VðtÞ=V0 JðtÞ
momentum balance equations. Since there is no internal gas
pressure generation, vapor and gas equations are not required. Note that while Jacobian due to moisture change, JM, is a state
function (depending on the moisture content), porosity, fðtÞ, is a
3.1.2. Solid momentum balance process variable, depending on the actual Jacobian, J(t).
A patty can shrink by 30% or more of its initial volume during
the contact heating process, which necessitates the use of large 3.1.3. Moisture and energy transport equations
deformation analysis for solid deformation. Since the evaporation Moisture flux in case of meat needs to be treated differently
front stays at the surface and there is no internal gas pressure from the discussion in Section 2. Water activity of meat at room
generation, gas pressure gradient term can be ignored for the temperature is 1, which gives capillary pressure, pc, or water
solid momentum balance. For large deformation, Lagrangian potential, Cw , close to zero (using Kelvin’s law (Lu and Likos,
measures of stress and strain are used, and the solid momentum 2004). Thus, Eq. (31) cannot be used to calculate moisture flux.
balance (Eq. (19)) is written in Lagrangian coordinates: Also, with increase in temperature, meat proteins denaturate
leading to a drop in water holding capacity (Tornberg, 2005). As
rX ðS00 FTel Þ ¼ 0 ð49Þ time scales of temperature rise in the patty during intensive
00
where S is the second Piola–Kirchhoff (PK2) stress tensor, and Fel cooking such as contact-heating are smaller than time scales of
is the elastic deformation gradient tensor. PK2 stress, S00 , is related moisture transport, moisture concentration in much of the patty
to Cauchy stress, r00 , by the following relationship: is more than its water holding capacity at equilibrium.
Liquid water pressure (called swelling pressure) in meat has
S00 ¼ J F1 00 T
el r Fel ð50Þ been estimated (van der Sman, 2007) by using the Flory–Rehner
PK2 stress is energy conjugate to the Green–Lagrange elastic theory. Taking the swelling pressure to be zero at equilibrium
strain tensor, Eel: moisture volume fraction, and linearizing the Flory–Rehner
expression near equilibrium, it can be shown that the swelling
Eel ¼ 12ðFTel Fel IÞ ð51Þ pressure is proportional to the difference between the actual and
00
and, thus, S and, Eel are related as follows: equilibrium moisture concentrations:
Table 1
Input parameters Dhall (2011) used in the simulations of single-sided contact heating of hamburger patties. Number under source column refer to bibliographic order.
The energy balance equation remains the same as discussed for In Eq. (66), the first term on the right hand side is the convective
rubbery materials in Section 2 (Eq. (43)). heat transfer coefficient multiplied by the temperature difference,
the second term is the latent heat taken up by surface evapora-
3.1.4. Boundary and initial conditions tion, and the third term is energy carried by convection terms
Solid momentum balance: Normal displacement of the axisym- normal to the boundary.
metric boundary and the bottom surface (lying on the griddle) is Initial conditions: Initially refrigerated at 5 1C, the composition
set to zero. The other two boundaries are unconstrained and free of the patty is taken from USDA Nutrition Database (2010) and is
to move (Fig. 4). listed in Table 1. Since the weight percentages of the proximates
Liquid water equation: The boundary condition for liquid water added up to 100.74, the weight percentages were normalized. The
equation consists of two flux terms: evaporation and drip. The volume fraction of air in the patties is considered small and, thus,
magnitude of the evaporation flux, nw,s,surfe , is simply given by ignored. From this data, the initial concentrations of water and
mass transfer coefficient multiplied by the vapor density differ- solid (protein, fat and ash) can be calculated.
ence between the surface and the boundary:
nw,s,surfe ¼ hm ðrv,surf rv,amb Þ ð63Þ
3.1.5. Input parameters and numerical solution
Water is lost from the matrix in liquid form (as drip) only when Input parameters used in the hamburger patty cooking simu-
surface moisture concentration, cw,surf , is more than the water lation are given in Table 1. Bulk modulus and Poisson’s ratio were
holding capacity, cw,eq . The drip loss, nw,s,surfd , under such condi- estimated considering the patty to be saturated and in a soft,
tions is equal to the total moisture flux reaching the surface rubbery state throughout the heating duration. In a soft material,
subtracted by that taken by surface evaporation, nw,s,surfe : the Poisson’s ratio is expected to be about 0.5. A value of 0.49 was
~ surf hm ðr used to help convergence. For saturated porous materials with
nw,s,surfd ¼ ~
n w,s N v,surf rv,amb Þ ð64Þ
incompressible solid skeleton, the bulk modulus (for small elastic
Therefore, the total moisture flux at the surface with respect to a strains) is given by Hashin (1985)
stationary observer is equal to the sum of drip loss, evaporation
1 4Gs
loss and flux due to movement of the surface itself: K¼ Kf þ ð1ef Þ ð67Þ
ef 3
nw,G,surf ¼ nw,s,surfe þnw,s,surfd þcw~ ~
v s,G N ð65Þ
Since the bulk modulus of water, Kw (2.2 109 Pa) is much greater
Energy equation: For energy equation, forced convection heat than the shear modulus of the solid matrix, Gs ( o 106 Pa), it
transfer boundary condition is applied to get the heat flux at the justifies a Poisson ratio close to 0.5, and Eq. (67) reduces to
surface, qsurf :
X Kw
qsurf ¼ hðTamb Tsurf Þlnw,s,surf ð~ ~ surf
n i,G cp,i TÞ N ð66Þ K¼ ð68Þ
ew
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6491
Predicted restricted to a small region near the lateral surface of the patty.
0.14 Also, even at the end of heating, the minimum moisture content
(near the griddle plate) is still high (0.891), which means the
surface has not dried up. On the other hand, moisture content
0.12 Experiment
close to the exposed top surface (away from the griddle) rises to
2.731 (from an initial value of 2.6) during the process.
0.1
Spatial and temporal distribution of temperature: Fig. 8 shows a
Evaporation loss comparison between predicted and experimentally observed
0.08
temperature histories at two locations on the central axis of the
patty: (1) at the mid-point between the heated and exposed
0.06 surfaces, and (2) on the exposed top surface. With the initial lead
time of about 50 s, temperature at the midpoint follows the
0.04 concave downwards curve reaching a value of 56 1C after
15 min. The predicted curve follows the observed one closely,
0.02 Drip loss with the difference between the two at any time being 1 1C or
less. Temperature history at the surface is more interesting. While
0 the observed history is similar to that of the midpoint, having an
0 3 6 9 12 15 initial lead time followed by a concave downwards curve; the
Time (min) predicted history shows a quick initial heating period which is
absent in the observed history. The discrepancy between the
Fig. 6. Cumulative total (evaporation þ drip) moisture loss (predicted and experi- predicted and observed histories for the first 300 s of heating can
mentally observed, Dhall and Datta, submitted for publication), evaporation
moisture loss (predicted) and drip loss (predicted) for single-sided contact heating
be attributed to changing ambient conditions of temperature and
of hamburger patties. It can be seen that drip loss levels off after 5 min and relative humidity at the exposed surface during the cooking
evaporation loss dominates for the rest of the heating duration. process. At the top surface, a fixed ambient air temperature of
6492 A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497
40
DðtÞ VðtÞ 1=3
¼ ð69Þ
D0 V0
30 Surface
(Predicted) and also plotted. Eq. (69) is obtained by assuming the same
Surface uniform linear shrinkage along the thickness and in the diameter
20 (Exp.) and relating this to volume shrinkage, using the equation
ðV0 VðtÞÞ=V0 ¼ ðpD20 L0 pD2 ðtÞLðtÞÞ=pD20 L0 Þ with DðtÞ=D0 ¼ LðtÞ=L0 .
Surface As shown in Fig. 10, the diameter assuming uniform shrinkage
10 is much larger than the predicted or observed diameters at any
Center
time, indicating the non-uniformity in patty shrinkage. Also, this
means that such a simplified relationship as Eq. (69) cannot be
0
used to predict diameter with solid deformation equations not
0 3 6 9 12 15
solved. Predicted thickness (normalized) and thickness assuming
Time (min)
uniform shrinkage are plotted in Fig. 11. The final value of
Fig. 8. Temperature histories (predicted and experimentally observed, Dhall and thickness is approximately 95% of the initial value, which means
Datta, submitted for publication) at the midpoint and the surface on the central the patty shrinks by less than 1 mm in thickness in 15 min.
axis for single-sided contact heating of hamburger patties. Predicted values of thickness were not compared to its
observed values because of high variability in patty thickness (it
varied by more than 2 mm at different locations on a single patty)
Temperature
and also due to variability in shear effects that cause rise of the
(°C)
bottom surface of the patty near the center. In this simulation, the
bottom surface was considered fixed in the z-direction that could
not be achieved in all the experiments at all times. Some patties
rose by 1–2 mm in the middle, while some others stuck to the
min
15 griddle plate. Therefore, uncertainty (more than 2 mm) in height
was more than the total expected change in height ( 1 mm) and,
thus, it was meaningless to compare the observed and predicted
thickness values.
Fig. 12, which plots the contours of elastic Jacobian, Jel ð ¼ J=JM Þ,
at different times, helps us arrive at a very good (albeit, more
involved) method to predict shrinkage. Fig. 12 shows that the
ratio of actual Jacobian, J, to the Jacobian due to moisture change,
Unheated 1.01
Surface
Fig. 9. Temperature contours (in 1C) after 3, 6, 9, 12 and 15 min of single-sided 0.95
Prediction
contact heating of hamburger patties showing constant heated surface tempera-
ture and gradients primarily in the axial direction.
0.93
Experiment
60 1C (Table 1) and zero moisture flux (moisture loss from the top
surface is negligible as compared to the moisture loss from the 0.91
bottom surface) were used as boundary conditions which may not
be valid at initial times when patty is just put on the plate.
Therefore, an error in surface temperature prediction may be seen 0.89
when the effect of boundary conditions dominates (in the model 0 3 6 9 12 15
the surface gets heated fast due to air temperature of 60 1C). Time (min)
Similar to moisture content, temperature contours (Fig. 9) show
Fig. 10. Diameter change histories (prediction and experimental observation) for
small end effects. The heated surface reaches around 90 1C early single-sided contact heating of hamburger patties. Also, diameter calculated
in the heating process and stabilizes. Temperature at the exposed assuming uniform shrinkage throughout the patty (Eq. (69)) is plotted showing
surface rises slowly and reaches about 50 1C after 15 min. assumption of uniform shrinkage will lead to erroneous results.
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6493
Table 2
Input parameters used in the simulations of drying of potato slabs. Number under source column refer to bibliographic order.
2D Slab dimensions
Height 4,7,10 mm Wang and Brennan (1992, 1995)
Half width 10 mm Wang and Brennan (1992, 1995)
Initial conditions
Moisture vol. frac.
0.865 (Tamb ¼ 55 1C) – Wang and Brennan (1992)
0.838 (Tamb ¼ 40,70 1C) – Wang and Brennan (1995)
Air vol. frac. 0 –
Temperature 32.5 1C Wang and Brennan (1992)
Drying conditions
Temperature 40, 55, 70 1C Wang and Brennan (1992),
Wang and Brennan (1995)
Absolute humidity 0.16 g/kg Wang and Brennan (1992)
Heat transfer coeff. 40 W/m2K Laminar flow
Mass transfer coeff. 0.01 m/s Lewis analogy
Properties
Water activity – – Ratti et al. (1989)
Density Choi and Okos (1986)
3
Water 998 kg/m
Air Ideal gas kg/m3
Solid 1592 kg/m3
Specific heat capacity Choi and Okos (1986)
Water 4178 J/kg K
Solid 1650 J/kg K
Thermal conductivity Choi and Okos (1986)
Water 0.57 W/m K
Air 0.026 W/m K
Solid 0.21 W/m K
Moisture diffusivity 2172 m2/s Wang and Brennan (1992)
4:49 105 exp
T
Binary diffusivity 2:6 106 eg m2/s Halder et al. (2007)
Bulk modulus
109 M 40:3 Pa Estimated for rubbery
106 M o 0:3 Pa Estimated for glassy
Poisson’s ratio
0:49M 40:3 – Estimated for rubbery
0:3M o 0:3 – Estimated for glassy
and 40 1C. The surface temperature rises from 32.5 1C to 50 1C in potato drying (10 mm thick slab at 70 1C). The large value of maxðJel Þ
200 min and stabilizes, reaching about 54 1C after 800 min of in the case of potato is because of the greater shear modulus for
drying. The predicted temperature history closely follows the potato which leads to deviations from free shrinkage. For hamburger
observed one. The predicted moisture content histories for three patties, Poisson’s ratio, n, stays close to 0.5 and, thus, much smaller
different values of slab thickness also follow the observed history deviations from free shrinkage are observed. As a potato slab is under
very well. The shrinkage of the potato slabs at the two drying a much larger expansive strains (near the surface as it dries up) as
temperature values (70 1C and 40 1C) is a little less than the compared to meat, its surface is more prone to cracking. Thus,
volume of moisture lost until moisture content of 0.3, with maxðJel Þ can be used as a criteria to predict and avoid drying
volume at 70 1C equal to or more than that at 40 1C. The situations most prone to cracking. Apart from cracking, other impor-
simulations capture the trends very well, apart from the small tant quality parameters, such as porosity development, case hard-
difference in the observed volumes at the two drying tempera- ening (surface drying leading to large increase in shear modulus and
tures, which the predictions could not capture. As the experi- reduced shrinkage), etc., can also be predicted from deformation
mental error values are not available, it is difficult to conclusively analysis.
say if the small difference in volumes at the two temperatures is
real. Nevertheless, the accurate predictions of moisture loss,
temperature and shrinkage histories for the drying process serve 4. Conclusions
to validate the modeling approach followed.
A poromechanics-based approach to mathematically model
3.3. Importance of solid mechanics analysis the coupled physics of transport and deformation during proces-
sing of food materials is developed. Following this comprehensive
Since the volume change is almost equal to moisture change for approach, food materials existing in a range of states (glassy to
the two food materials studied (above a critical moisture content for rubbery) and being processed under a variety of conditions, can
potato), the advantage of solving the solid momentum equation does be simulated to predict important food quality and safety para-
not lie in predicting volume change due to moisture content. The real meters (spatial and temporal histories of temperature, moisture
value of solid mechanics analysis lies in predicting small deviations and deformation). For deformation, primary driving forces are
from free shrinkage, which lead to stresses and can be important identified and their effect on the solid momentum balance is
indicators of food quality, related to cracking, for example. As an discussed in detail. The driving forces are: (1) gas pressure, which
example, Fig. 15 plots the maximum value of elastic Jacobian, Jel, as a causes the food material to swell (gas pressure gradient can be
function of normalized moisture content for hamburger cooking and directly treated as a source term for the solid momentum
A. Dhall, A.K. Datta / Chemical Engineering Science 66 (2011) 6482–6497 6495
60 1.2
Surface temperature (ºC)
50 1.15
40 1.1
Experiment
(Wang and Brennan, 1992)
30
0 200 400 600 800 1.05
Hamburger
Time (min) patty cooking
4
1
0 0.2 0.4 0.6 0.8 1
Moisture content (normalized)
Moisture content (d.b.)
3
10 mm
Fig. 15. Maximum value of elastic Jacobian, Jel, (ratio of actual volume to free
7 mm volume) vs. moisture content (normalized with respect to initial moisture
content) for the two processes simulated showing larger expansive strains for
2
4 mm Predicted potato drying as compared to hamburber patty cooking.
Experiment (Wang
1 heating processes such as microwave cooking and processes with
and Brennan, 1992)
internal generation such as bread baking. Also, solution of vapor
equation is not required unless local equilibrium between vapor
and liquid moisture breaks down. Assuming equilibrium vapor
0
concentration, liquid water and water vapor flux can be added to
0 200 400 600 800 1000
get the total moisture flux relationship, which with further
Time (min) simplifications takes the form of Fick’s law.
Fig. 13. (a) Spatially averaged surface temperature and (b) moisture content Two different food processes are simulated as implementa-
histories for drying of potato slabs. Moisture content histories are shown for three tions of the modeling framework developed: (1) single-sided
different slab thicknesses of 4, 7 and 10 mm, respectively. Drying temperature is cooking of hamburger patties for which shrinkage is equal to
55 1C and other input parameters are provided in Table 2. moisture loss throughout the process and (2) convective drying of
potato slabs for which shrinkage stops under a critical moisture
content. For both the cases, transport of moisture in liquid form
1
dominates. The difference lies in greater strains experienced by
the potato due to greater shear modulus at low moisture
0.8 contents. Accurate predictions of the experimental observations
for two completely different processes show the versatility of the
Shrinkage, V/V0
Rakesh, V., 2010. Transport in Rigid and Deformable Hygroscopic Porous Media van der Sman, R.G.M., 2007. Soft condensed matter perspective on moisture
During Electromagnetic and Combination Heating. Ph.D. Cornell University, transport in cooking meat. A.I.Ch.E. J. 53 (11), 2986–2995.
New York, United States. Vujosevic, L., Lubarda, V.A., 2002. Finite-strain thermoelasticity based on multi-
Ratti, C., Crapiste, G.H., Rotstein, E., 1989. A new water sorption equilibrium plicative decomposition of deformation gradient. Theor. Appl. Mech. 28–29,
expression for solid foods based on thermodynamic considerations. J. Food Sci. 379–399.
54 (3), 738–742. Wang, L., Singh, R.P., 2004. Finite element modeling and sensitivity analysis of
Scherer, G.W., 1989. Drying gels. 8. Revision and review. J. Non-Cryst. Solids 109 double-sided contact-heating of initially frozen hamburger patty. Trans. ASAE
(2–3), 171–182. 47 (1), 147–157.
Wang, N., Brennan, J.G., 1992. Effect of water binding on the drying behaviour of
Schrefler, B.A., 2002. Mechanics and thermodynamics of saturated/unsaturated
potato. In: Majumdar, A.S. (Ed.), Drying’92 Part B, Elsevier, Amsterdam, New
porous materials and quantitative solutions. Appl. Mech. Rev. 55 (4), 351–388.
York, pp. 1350–1359.
Shilton, N., Mallikarjunan, P., Sheridan, P., 2002. Modeling of heat transfer and
Wang, N., Brennan, J.G., 1995. Changes in structure, density and porosity of potato
evaporative mass losses during the cooking of beef patties using far-infrared
during dehydration. J. Food Eng. 24 (1), 61–76.
radiation. J. Food Eng. 55 (3), 217–222. Williams, R., Mittal, G.S., 1999. Low-fat fried foods with edible coatings: modeling
Singh, P.P., 2002. Effect of Viscoelastic Relaxation on Fluid and Species Transport in and simulation. J. Food Sci. 64 (2), 317–322.
Biopolymeric Materials. Ph.D. Purdue University, Indiana, United States. Whitaker, S., 1977. Simultaneous heat, mass and momentum transfer in porous
Smith, D.M., Scherer, G.W., Anderson, J.M., 1995. Shrinkage during drying of silica- media: a theory of drying. Adv. Heat Transfer 13, 114–203.
gel. J. Non-Cryst. Solids 188 (3), 191–206. Yamsaengsung, R., Moreira, R.G., 2002. Modeling the transport phenomena and
Tornberg, E., 2005. Effects of heat on meat proteins—implications on structure and structural changes during deep fat frying—part II: model solution and
quality of meat products. Meat Sci. 70 (3), 493–508 (Sp. Iss. SI). validation. J. Food Eng. 53 (1), 11–25.
USDA Nutrition Database /http://www.nal.usda.gov/fnic/foodcomp/search/S. Zhang, J., Datta, A.K., Mukherjee, S., 2005. Transport processes and large deforma-
Accessed July 31 2010. tion during baking of bread. A.I.Ch.E. J. 51 (9), 2569–2580.